• Title/Summary/Keyword: 응결지연제

Search Result 42, Processing Time 0.033 seconds

Analysis of the Characteristics of Manufactured Concrete, according to the Type of Admixture used when Remixing and Placing it (혼화제 종류별로 제조된 콘크리트의 재 혼합 타설시 특성 분석)

  • Ryu, Hyun-Gi;Shin, Sang-Yong
    • Journal of the Korea Institute of Building Construction
    • /
    • v.10 no.5
    • /
    • pp.95-102
    • /
    • 2010
  • In recent years, the demand for the development of high quality and cost effective materials, as well as the competition to ensure a diverse and sufficient amount of ready-mixed concrete, has been increasing rapidly. In this experiment, concretes made with different admixtures are blended with each other in different combinations and ratios, in order to identify potential problems. The first test was a slump level test, in which all of the concretes met the required numbers, as they also did in the test for air content. Plain organic acid concrete scored the highest in bleeding amount, but organic acid mix in general showed a similar outcome. In the early measurement of compressive strength, plain naphthalene concrete was the strongest. Of the blends, the 5:5 mix of organic acid and naphthalene was the strongest. In the standard measurement, the 5:5 mix of naphthalene and lignin was the strongest. Tensile strength tests revealed similar results. Length change rate proved to be greater in blended concrete than in plain concrete, and dry shrinkage rate was highest in the 7:3 ratio blends. Through SEM photo analysis, it was confirmed that the 7:3 ratio blends contained more micro-voids. In conclusion, with the exception of a specific few combinations, it was found that the blending of different types of concrete is undesirable due to the delayed coagulation time as well as the early decrease in strength.

Effect of Alkali Activators on Early Compressive Strength of Blast-Furnace Slag Mortar (고로슬래그 모르타르의 초기 강도에 대한 알칼리자극제의 영향)

  • Moon, Han-Young;Shin, Dong-Gu
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.9 no.3
    • /
    • pp.120-128
    • /
    • 2005
  • In the construction industry, due to the cost rise of raw material for concrete, we have looked into recycling by-products which came from foundry. When using the Ground Granulated Blast-Furnace Slag(SG), it is good for enhancing the qualities of concrete such as reducing hydration heat, increasing fluidity, long-term strength and durability, but it has some problems : construction time is increased or the rotation rate of form is decreased due to low development of early strength. In this study, therefore, to enhance the early strength of SG mortar, we used some alkali activators(KOH, NaOH, $Na_2CO_3$, $Na_2SO_4$, water glass, $Ca(OH)_2$, alum. This paper deals with reacted products, setting time, heat evolution rate, flow and the strength development of SG cement mortar activated by alkali activators. From the results, if alkali activators were selected and added properly, SG is good for using as the materials of mortar and concrete.

Influence of Over-Added AE Water Reducing Agent on Physical Properties of the Concrete (AE 감수제 과다첨가가 콘크리트의 물리적 특성에 미치는 영향)

  • Han, Cheon-Goo;Han, Min-Cheol;Lee, Dong-Gyu
    • Journal of the Korea Institute of Building Construction
    • /
    • v.8 no.1
    • /
    • pp.91-96
    • /
    • 2008
  • This study is to investigate the influence of the over-added chemical agents, such as water reducing agent(WRA) and AE water reducing agent(AEWRA), on the physical properties of concrete to estimate the degree of damage due to over-added chemical agents. For the fresh concrete, slump and slump flow increased with the increase of WRA and AEWRA as expected. Material segregation phenomenon was observed with the over dosage of lignin based AEWRA about 4 times larger than recommended dosage. The over dosage of AE water reducing agent about 4 times larger than recommended dosage resulted in an increase of air contents remarkably. The set retardation occurred greatly with the increase of AEWRA and WRA. For the properties of the hardened concrete corresponding to the over dosage of AEWRA, it is found that compressive strength of over added AEWRA and WRA concrete are much smaller than those of base and recommended dosage concrete proportionally due to associated increasing air content.

The Effects of Hydration Retarding of Portland Cement by $MgSiF_6.6H_2O$ (규불화마그네슘에 의한 포틀랜드 시멘트의 수화 지연효과)

  • 한상호;이경희;정성철;김남호
    • Journal of the Korean Ceramic Society
    • /
    • v.34 no.2
    • /
    • pp.163-170
    • /
    • 1997
  • The retarding effects of MgSiF6.6H2O on the hydration of portland cement were studied. The setting time, flow value and compressive strength of mortar were measured and the mechanism of retardation was also studied by ion concentration in solution, SEM, BET, and X-ray diffraction. The results are as follows ; 1. Setting time was delayed by the addition of MgSiF6.6H2O. 2. The flow value of mortar decreases depending upon the amount of MgSiF6.6H2O. 3. The compressive strength was almost same or some increase on 28 days hydration. 4. The main retardation mechanism of MgSiF6 on the hydration of portland cement may be explained by the following hypothesis. MgSiF6 depressing the Ca++ and K+ ion concentration of cement paste solution be-cause of the recrystalization of K2SiF6 and CaF2 phase. The new products of K2SiF6 and CaF2 deposit on the surface of unhydrated cement powder and harzard the mass transfer through these layer. The low con-centration of Ca++, K+ ion in solution was decreasing the hydration rate of portland cement.

  • PDF

The Analysis of Early Age Properties of Hydration Heat and Autogenous Shrinkage according to Specimen Size and Retardation of Hydration (시험체 크기 및 수화지연 효과에 따른 초기재령 수화발열 및 자기수축 특성 분석)

  • Kim, Gyu-Yong;Koo, Kyung-Mo;Lee, Hyoung-Jun;Lee, Eui-Bae
    • Journal of the Korea Concrete Institute
    • /
    • v.21 no.4
    • /
    • pp.481-488
    • /
    • 2009
  • It has been reported that the magnitude and the development rate of autogenous shrinkage of cement paste, mortar and concrete were affected by history and magnitude of inner temperature at an early age. But it was not enough to explain the relation between hydration heat and autogenous shrinkage at an early age, because there was no certain analysis on histories of hydration heat and autogenous shrinkage in previous studies. In our prior study, to understand the relationship between hydration heat and autogenous shrinkage of concrete at an early age, the analysis method for histories of hydration heat and autogenous shrinkage was suggested. Based on this method, early age properties of hydration heat and autogenous shrinkage of high strength concrete with different sizes and hydration retardation were investigated in this study. As a result of the study, properties of hydration temperature and autogenous shrinkage were different according to specimen size and hydration retardation. However, there was a close relationship between hydration temperature and autogenous shrinkage at an early age, especially between HHV and ASV as linear slopes of the sections where hydration temperature and autogenous shrinkage increase rapidly; the higher HHV, the higher ASV and the greater ultimate autogenous shrinkage. And it was found that, among the setting time, bend point and temperature increasing point, they were close relationship each other on cement hydration process.

Water Repellent Characteristics of Cement Paste Added Silane/siloxane-based Emulsion Water Repellent (실란/실록산계 에멀전 발수제를 혼입한 시멘트 페이스트의 발수특성)

  • Kang, Suk-Pyo;Hong, Seong-Uk;Kang, Hye-Ju;Yang, Seung Hyeon
    • Journal of the Korea Institute of Building Construction
    • /
    • v.21 no.1
    • /
    • pp.31-39
    • /
    • 2021
  • The aim of this paper is to improve durability of cement paste by imparting hydrophobicity to the surface and sphere of cement-based materials. A cement paste mixed with a silane/siloxane-based water repellent, and the initial hydration performance, flow performance, and age-specific compressive strength were measured. In addition, the water contact angle, SEM, and XRD before and after surface polishing were measured. When 0.5% of the silane/siloxane-based water repellent was mixed into the cement paste, the compressive strength increased, but the compressive strength decreased as the mixing amount increased by 1.5% and 3.0%. When a silane/siloxane water repellent was incorporated into the cement paste, the hydrophilicity was improved and the contact angle was increased due to hydrophobicity. In addition, the contact angle after surface polishing was found to be larger than the contact angle before surface polishing.

Initial Performance Evaluation of Fine-size Exposed Aggregate PCC Pavement by Experimental Construction (시험시공을 통한 소입경 골재노출 콘크리트포장의 초기 공용성 평가)

  • Kim, Young-Kyu;Choi, Don-Hwa;Lee, Seung-Woo;Kim, Hyung-Bae
    • International Journal of Highway Engineering
    • /
    • v.12 no.1
    • /
    • pp.87-98
    • /
    • 2010
  • Surface of fine-size exposed aggregate Portland cement concrete pavements is consists of exposed coarse aggregate by removing upper 2~3mm mortar of concrete slab. Fine-size exposed aggregate PCC pavements have advantages of maintaining low-noise and adequate skid-resistance level during the performance period. In order to provide the successful exposed concrete aggregate pavement, uniform distribution of the coarse aggregate on pavement surface through adequate the mix design and exposing method. In this study, evaluated initial performance of fine-size exposed aggregate PCC pavement by experimental construction. And it was known that fine-size exposed aggregate concrete pavement which can reduce the noise and maintain the adequate level of skid resistance and strength.

Effect of the Replacement Ratio and Sources of Blast Furnace Slag Powder on the Fundamental Properties of Recycled Fine Aggregates Based Mortar (고로슬래그 미분말의 산지 및 치환율 변화가 순환잔골재 사용 시멘트 모르타르의 특성에 미치는 영향)

  • Han, Cheon-Goo;Zhao, Yang
    • Journal of the Korea Institute of Building Construction
    • /
    • v.15 no.3
    • /
    • pp.257-263
    • /
    • 2015
  • In this study, the quality of blast furnace slag and the engineering properties of recycled aggregate based mortar with variable replacement of blast furnace slag have been focused. Blast furnace slag(BS) manufactured in various areas in Korea were prepared for this study. For the investigation results, 4 types(among the all of 9 types) of the experimental results were identified as below the standard level when using blast furnace slag chosen from different factories. Especially the particle size of the blast furnace slag was considered as the largest problem. When using BS in the recycled aggregates based mortar, the increase amount of blast furnace slag, increased the fluidity but delayed the setting time and decreased strength at early age. Based on the relationship of the amount of BS and the engineering properties of mortar, this study found that the amount of $SO_3$ and L.O.I affect the setting time, 3 days strength and 91 days strength to the certain standard level.

Evaluating Early Age Shrinkage Behavior of Ultra High Performance Cementitious Composites (UHPCC) with CSA Expansive Admixture and Shrinkage Reducing Agent (CSA계 팽창재 및 수축 저감제의 혼입에 따른 UHPCC의 초기 수축 거동 평가)

  • Yoo, Doo-Yeol;Park, Jung-Jun;Kim, Sung-Wook;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
    • /
    • v.23 no.4
    • /
    • pp.441-448
    • /
    • 2011
  • In this study, experimental tests of chemical and autogenous shrinkage were performed to evaluate the early age shrinkage behaviors of ultra high performance cementitious composites (UHPCC) with various replacement ratios of silica fume (SF), shrinkage reducing agent (SRA), expansive admixture (EA), and superplasticizer (SP). Starting time of self-desiccation, was analyzed by comparing the setting times and the deviated point of chemical and autogenous shrinkage strains. The test results indicated that both SF and SRA augment the early age chemical shrinkage, whereas SP delays the hydration reaction between cement particles and water, and reduces chemical shrinkage. About 49% of autogenous shrinkage was depleted by synergetic effect of SRA and EA. The hardening of UHPCC was catalyzed by containing EA. Self-desiccation of UHPCC occurred prior to the initial setting due to the high volume fraction of fibers and low water-binder ratio (W/B).

A Study on the Resistance Against Environmental Loading of the Fine-Size Exposed Aggregate Portland Cement Concrete Pavements (소입경 골재노출콘크리트포장의 환경하중 저항성에 대한 연구)

  • Chon, Beom-Jun;Lee, Seung-Woo;Chae, Sung-Wook;Bae, Jae-Min
    • International Journal of Highway Engineering
    • /
    • v.11 no.2
    • /
    • pp.99-109
    • /
    • 2009
  • Fine-size exposed aggregate portland cement concrete pavements (FEACP) have surface texture of exposed aggregate by removing upper 2$\sim$3mm mortar of surface of which curing is delayed by using delay-setting agent. FEACPs have advantages of maintaining low-noise and adequate skid-resistance level during the performance period than general portland cement concrete pavements. It is necessary to ensure the durability environmental loading to prevent unexpected distress during the service life of FEACP. In the process of curing, volume change accompanied change in by moisture and temperature could be an important cause of crack in concrete to construct for successful FEACP, The use of chloride containing deicer may accelerate defects of concrete pavement, such as crack and scaling. This study aim to evaluate environmental loading resistance of FEACP, based on the estimation of shrinkage-crack-control-capability by moisture evaporation and scaling by deicer in freeze-thaw reaction.

  • PDF