• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.687-690
• /
• 2009

본 연구에서는 가스 하이드레이트 형성과정에서 발생할 수 있는 유도지체시간을 줄이고 전체 가스 저장량과 반응 속도의 향상을 위하여 이류체 분사 방식을 이용하여 물분자의 액적을 최소화하는 실험을 통하여, 미세액적 분사에 따른 하이드레이트 형성 시간을 확인하였으며, 반응기 내부의 온도 변화를 확인하여 반응기 내부의 하이드레이트 형성 거동을 확인하고 이를 통하여 상용화를 위한 반응기 설계의 기초 자료로 활용하고자 하였다.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2010.04a
• /
• pp.261-262
• /
• 2010

• Membrane Journal
• /
• v.23 no.3
• /
• pp.189-203
• /
• 2013

F-gases, gases containing fluorine such as perfluorocarbons (PFCs), sulfurhexafluoride ($SF_6$), nitrogen trifluoride ($NF_3$) are known to have green house effects. Although the net emission rates of gases containing fluorine are much lower than those of $CO_2$, their contribution to global warming cannot be ignored because of their extremely high global warming potential (GWP). F-gases mainly have been used for a variaty of applications in the semiconductor/LCD processes and in the electric power distribution industry of the national key industry. One of practical solutions of controlling the emission rates of F-gases is to reuse by separation and recovery of F-gases of low concentration from the gases mixtures with nitrogen or air. This work investigates some methods for F-gases recovery and separation around the membrane-based process.

• Journal of Environmental Science International
• /
• v.21 no.9
• /
• pp.1163-1169
• /
• 2012

Destruction and removal efficiency (DRE) of $SF_6$ was tested with low degrees of ionization. The applied dose of ionization energy varied from 63.70 to 212.34 kGy. The initial concentration and flow rate of $SF_6$ gas were 1,000 ppm and 50L/min, respectively. In order to increase the DRE, injection of conditioning agent ($H_2$) were conducted. The DRE of $SF_6$ increased about 2 times with injection of $H_2$ gas.

• Journal of Climate Change Research
• /
• v.4 no.3
• /
• pp.269-278
• /
• 2013

Sulfur hexafloride($SF_6$) emission to atmosphere is lower than $CO_2$, but $SF_6$ GWP is 22,800 times lager than $CO_2$. In recent years as restriction of $non-CO_2$ gas has been greatly reinforced, development of environment-friendly technology with $SF_6$ removal is becoming to main issue. This study shows that $SF_6$ used insulator electrical equipment has emission characteristics during the each phase(maintenance, use, diposal), and analyzed $SF_6$ emission reduction technology related phase. The major technology applies maintenance and disposal step is that improvment of gas recovery rate($85{\rightarrow}99%$), manufacturing catalysts, internal inspection of circuit breaker using endoscopy. Using those technolgies can reduce $SF_6$ emission in atmosphere.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.18 no.3
• /
• pp.39-43
• /
• 2004

국제적인 환경 규제 문제($CO_2$, SF$_{6}$(육불화황), PFC (과불화화합물) 등)가 새로운 무역장벽으로 등장하여 우리나라 주요 산업 부문에 미치는 영향이 점차 현실로 나타나고 있다. 이러한 환경 규제에 적절한 대처를 하기 위해 에너지 소비 증가와 이에 따르는 에너지 소비 패턴 및 인식에 대한 새로운 접근 방법이 요구되고 있다. 그동안 전력기기의 고효율화, 에너지 효율 향상과 수요관리 강화, 미활용 에너지원의 이용률 제고, 집단에너지 보급 확대 등 하드웨어적인 기술개발에 중점을 두고 추진되었으나, 앞으로는 전원설비, 전력전송 설비, 부하설비 등의 최적 설계기술을 통한 에너지절약 기술개발과 같은 소프트웨어적인 기술 개발이 요청되고 있다. (중략)

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.11a
• /
• pp.122.2-122.2
• /
• 2011

Sulfur hexafluoride ($SF_6$), one of the most potent greenhouse gases, is known as a hydrate former and has been studied at the high pressure up to 1.3 GPa with gas mixtures and with aqueous surfactant. Since we regard $SF_6$ as a potential promoter molecule that can stabilize hydrate structure more effectively compare to the other promoters, further investigation is required to verify the stabilizing ability of $SF_6$ in the hydrate structure. However, the insoluble nature of $SF_6$ in water or gases hinders fine scale analyses. This work discusses the data obtained by using molecular dynamics simulations of structure II (sII) clathrate hydrates containing $SF_6$ and $H_2$. The simulations were performed using the TIP4P/Ice model for water molecule and a previously reported $SF_6$ molecular model (optimized at the pure $SF_6$ single phase system (Olivet and Vega, 2007)), and a $H_2$ molecular model (adapted from the THF+$H_2$ hydrate system (Alavi et al., 2006)). The simulations are performed to observe the stability of $SF_6$ and $H_2$ in the sII clathrate hydrate system with varying temperature and pressure conditions and occupancies of $SF_6$ and $H_2$, which cannot be easily tuned experimentally. We observe that stability of H2 enclathrated in the hydrate structure more affected by the occupancy of $SF_6$ molecules and temperature than pressure, which ranges from 1 to 100 bar.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.711-711
• /
• 2009

Global warming has been widely recognized as a serious problem threatening the future of human beings. It is caused by the buildup in the atmosphere of greenhouse gases, such as carbon dioxide, methane, hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF6). Particularly, SF6 has extremely high global warming potential compare to those of other global warming gases. One option for mitigating this greenhouse gas is the development of an effective process for capturing and separating these gases from anthropogenic sources. In general, gas hydrates can be formed under high pressure and low temperature. However, SF6 gas is known to form hydrate under relatively milder conditions. Therefore, technological and economical effects could be expected for the separation of SF6 gas from waste gas mixtures. In this study, we carried out morphological study for the SF6 hydrate crystals to understand its formation and growth mechanisms. The observations were made in high-pressure optical cell charged with liquid water and SF6 gas at constant pressure and temperature. Initially SF6 hydrate formed at the surface between gas and liquid regions, and then subsequent dendrite crystals grew at the wall above the gas/water interface. The visual observations of crystal nucleation, migration, growth and interference were reported. The detailed growth characteristics of SF6 hydrate crystals were discussed in this study.

• Journal of Korean Society for Atmospheric Environment
• /
• v.27 no.1
• /
• pp.1-15
• /
• 2011

Korea Global Atmosphere Watch Center (KGAWC), which is located in Anmyeondo and, belongs to the Korea Meteorological Administration (KMA), measures sulfur hexafluoride ($SF_6$) in every hour since 2007. In this study, $SF_6$ observed in 2007 are discussed. A gas chromatograph-electron capture detector (GC-ECD) with pre-cooled device is applied during the observation, and produced data are qualified by means of periodic calibration with $SF_6$ standard gas made by Korea Research Institute of Standard and Science (KRISS). $SF_6$ has been greatly paid attention since Kyoto protocol because of its high global warming potential(GWP) with 22,200 times of $CO_2$ in the period of 100 years. It is a man-made compound and has been usually used for gas insulation since 1970s and for etching process in the information technology-based industry since 1990. Average mixing ratio of $SF_6$ in 2007 was 6.65 pmol/mol at Anmyeondo. According to the GAW report published in 2008, average mixing ratio of $SF_6$ in the atmosphere is continuously growing. At present, the average mixing ratio of $SF_6$ in the atmosphere is known to be approximately 6.25 pmol/mol at global observatory. $SF_6$ value in Anmyeondo shows 0.40 pmol/mol greater than that of the Mauna Loa observatory in 2007.

• Membrane Journal
• /
• v.19 no.3
• /
• pp.244-251
• /
• 2009

In this research the polyethersulfone hollow fiber membrane was used to separate Sulfur Hexafluoride ($SF_6$) which is the one of the six greenhouse gases from Air ($N_2$). The effects of the non-solvent (Acetone, Ethanol) type, air-gap and post-treatment (surface silicon coating) were investigated by the structure and performance of the membranes. The structure change of the membrane was examined by scanning electron microscope. The single gas permeation using $N_2$, $SF_6$ through the membrane surface coated with silicon showed maximum 7.64 perm-selectivity improved 3.4 times.