• Title/Summary/Keyword: 유효확산

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A study on the new solid planar source for high-temperature phosphorus doping of semiconductors (고온에서 반도체에 인을 도핑하기 위한 새로운 고체 판상 원료에 관한 연구)

  • 김영식;신방섭
    • Electrical & Electronic Materials
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    • v.6 no.3
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    • pp.214-219
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    • 1993
  • 고온에서 실리콘에 인을 확산시키기 위한 새로운 고체 판상 원료를 개발하였다. Source Wafer는 거품 형태의 골결을 지닌 불활성 재료에 Yttrium metaphosphate가 들어있는 구조로 되어있다. 새로운 고체 판상 원료를 사용하여 고온에서 인을 확산시켜서 재현 가능한 Sheet resistance와 깊은 Junction을 얻었다. 일련의 한 시간 도핑 결과들로부터 새로운 고체 판상 원료의 수명은 40시간 이상인 것으로 판명되었다. 1150.deg.C에서 인의 실리콘에로의 확산에 대한 유효 확산계수와 대응되는 활성화 에너지의 값을 구하였다.

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Characteristics of Contaminant Migration through Hardened Liner and Seashore Clay Considering Effective Diffusion (유효확산을 고려한 고화차수층과 해안점성토층을 통한 오염물이동 특성)

  • 장연수;홍경택
    • Journal of the Korean Geotechnical Society
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    • v.17 no.4
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    • pp.49-55
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    • 2001
  • 본 논문에서는 서해안 폐기물 매립지 하부의 점성토와 고화차수재를 재료로 수행된 확산시험 결과와 현장 조건을 적용하여 오염물이동성에 대한 수치해석을 수행하였다. 무기화합물이 하부 차수재와 원지반퇴적층으로 이동되는 일차원 이동 특성을 대상으로 하였으며 일차원 용질이동해석 프로그램 CDFD(convection-dispersion finite difference)를 현장의 비균질한 지층에 이용할 수 있도록 수정하여 적용하였다. 그 결과 원지반점성토를 통한 용질이동 메카니즘에 확산이 기여하는 정도가 50%로 매우 큰 영향을 갖고 있음을 보여주며 원지반 투수계수가 클수록 인공차수층의 필요성이 증대됨을 알 수 있었다.

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콘크리트에서의 방사성핵종 확산계수

  • 금동권;조원진;한필수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.839-844
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    • 1995
  • 처분장 구조물의 주요방벽 재료중의 하나인 콘크리트에서의 핵종확산계수를 측정하기 위하여 내부확산법을 적용하였다. 핵종은 양이온과 음이온을 대표하는 Cs 과 I 이었으며, 고체 시료는 양생된 순수시멘트 또는 시멘트와 모레를 섞은 몰타르로 물과 시멘트의 비 (W/C) 를 변화시켰다. 용액은 표준 제조방법에 따라 제조된 합성지하수이었다. Curve fitting 법을 이용한 모델과 실험의 비교로부터 핵종의 확산계수를 계산하였다. 순수시멘트의 경우 Cs 의 겉보기 확산계수는 1.7 $\times$ $10^{-12}$~1.4 $\times$ $10^{-11}$ m$^2$/sec 의 범위로 W/C 가 증가할수록 컸으며 I 는 2.9 $\times$ $10^{-14}$ ~ 1.0 $\times$ $10^{-l3}$ $m^2$/sec의 범위로 또한 W/C 에 따라 증가하였다. 몰타르의 경우 W/C 가 클수록 Cs 의 확산계수는 증가하였으나 I 에 대해서는 큰 변화를 보여주지 않았다 본 실험에서 얻어진 핵종의 유효확산계수값이 $10^{-13}$ ~ $10^{-10}$ m$^2$/sec의 범위를 갖는 것으로 보아 공극확산이 핵종확산의 지배 메커니즘임이 예상되었다.

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The Effect of Spreading Gain Control on a CDMA Slotted ALOHA System (CDMA슬롯ALOHA시스템에서 확산 이득 제어의 영향)

  • 도미선;박중신;강지은;이재용
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.26 no.12B
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    • pp.1665-1676
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    • 2001
  • The effect of spreading gain control on the throughput of a CDMA slotted ALOHA system is considered. Mobile users transmit packets over a shared channel, and the packets transmitted in the same time slot over the shared channel act as simultaneous access interference (SAI). When using spread-spectrum signal, a CDMA slotted ALOHA channel achieves high probability of capture due to the property of high title resolution, and the bit rate of user information is determined by spreading gain. When the SAI level gets larger, the high value of spreading gain enhances the packet throughput by increasing the probability of a successful packet transmission, while it degrades the of the effective throughput by reducing the user information bits carried within a packer. To solve the problem, we investigated the effect of the capture probability and the SAI level on these system throughputs, and evaluated the throughput performance of the system for each spreading gain control scheme. The results showed that the maximum effective throughput could be achieved with an unified method despite the variation of the SAI level by deriving an optimal value of the spreading gain according to 171e system states.

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A Study on Moisture Transport of Artificial Lightweight Concrete (인공경량골재 콘크리트의 수분이동 특성에 관한 연구)

  • Lee, Chang Soo;Choi, Sang Hyun;Park, Jong Hyok;Kim, Young Ook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4A
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    • pp.373-384
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    • 2009
  • For the first step on the quantitative evaluation of shrinkage reduction and differential shrinkage analysis of lightweight aggregate concrete, this study sets the moisture transport model of concrete by pre-absorbed water of porous lightweight aggregates and measured effective moisture diffusion coefficient, moisture capacity, degree of humidity supply and degree of humidity consumption by water binder ratio and aggregate type. The effective moisture diffusion coefficient in steady state caused by humidity difference between inside and outside of concrete had low value as low water-binder ratio. And in case of same water-binder ratio, effective moisture diffusion of mixtures used normal aggregates were lower than those used lightweight aggregates. To determine moisture store capability of concrete - moisture capacity, moisture contents were measured in 9 humidity conditions. As a result moisture contents of mixtures used lightweight aggregates was higher than mixtures used normal aggregates in all humidity conditions. This study measured lightweight aggregates' degree of humidity supply that applicable to normal atmospheric environment (above RH 50%) and made it quantitatively. Also amount of moisture release was set as a exponential function that represents a clear trend proportion to time and inverse proportion to humidity of the surroundings. As the result of measurement about degree of moisture consumption inside concrete following the internal consumption caused by cement hydration self-drying, it was showed that rapid decrease of humidity, around 10%, at early ages (7~10 days) when water-binder ratio is 0.3 and slow decrease around 5% and 1% when water-binder ratio is 0.4 and 0.5.

Diffusion of Phenol in Apples (사과 내에서 페놀의 확산)

  • Park, Hyeon Ju;Choi, Dong Ho;Chung, Kyong-Hwan;Song, Yo Soon;Seo, Gon
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.572-578
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    • 2006
  • The accumulation of phenol in apples was measured by exposing them to phenol vapor at $25^{\circ}C$. The effective diffusivities of phenol in the rind and flesh of apples were estimated by comparing the experimentally determined fractional uptake curve with the simulated ones based on a consecutive diffusion model in the rind and flesh. Phenol was detected in the flesh of apples after 5 day exposure due to its slow diffusion in the rind. The consecutive diffusion model of phenol in apples simulated well the measured fractional uptake curve when the effective diffusivities of phenol in the rind and flesh were assumed to be $5.0{\times}10^{-13}m^2/s$ and $1.5{\times}10^{-10}m^2/s$, respectively.

The Effects of Temperature and Pressure on the Diffusion of Phenol in Apples (사과 내에서 페놀의 확산에 대한 온도와 증기압의 영향)

  • Park, Hyeon-Ju;Lee, Ki-Won;Chung, Kyong-Hwan;Song, Yo-Soon;Seo, Gon
    • Korean Journal of Environmental Agriculture
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    • v.26 no.1
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    • pp.69-76
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    • 2007
  • The accumulation curves of phenol in the flesh of apples were measured at $5^{\circ}C$, $25^{\circ}C$ and $40^{\circ}C$ when they were exposed to phenol vapor, The effective diffusivities of phenol at the rind and flesh were determined by comparing its experimentally obtained accumulation curves with simulated ones. The simulation was carried out by the non-steady state diffusion rate equation. The diffusion model assumed the consecutive diffusion of phenol at the rind and flesh of apples. The detection time of phenol in the flesh of apples was shortened with increasing temperature, and it accumulated amount also increased rapidly. The estimated effective diffusivity of phenol at the rind of apples increased with temperature as like $1.1{\times}10^{-13}\;m^2/s$ at $5^{\circ}C$, $1.4{\times}10^{-13}\;m^2/s$ at $25^{\circ}C$ and $2.2{\times}10^{-13}\;m^2/s$ at $40^{\circ}C$, but those at the flesh of apples were invariant as $1.5{\times}10^{-10}\;m^2/s$ at this temperature range. The effect of temperature on the diffusivity of phenol was small, but the increase of the vapor pressure of phenol with temperature accelerated the penetration of phenol at the rind, resulting in the rapid accumulation at the flesh of apple.

One-dimensional Analytical Solutions for Diffusion from a Low-permeability Layer (1차원 해석해를 이용한 저투수성 매체에서의 확산에 관한 연구)

  • Jang, Seonggan;Yang, Minjune
    • Economic and Environmental Geology
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    • v.53 no.1
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    • pp.11-21
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    • 2020
  • One-dimensional analytical solutions were used for forward and back diffusion of trichloroethylene (TCE) and tetrachloroethylene (PCE) in a single system with high- and low-permeability layers. Concentration profiles in a low-permeability layer, diffusive fluxes at the interface between the high- and low-permeability layers, and contaminant persistence in the high-permeability layer due to back diffusion were simulated with a comparison of semi-infinite and finite analytical solutions. In order to validate the analytical solutions used in this study, the results of one-dimensional analytical solutions developed by Yang et al. (2015) were compared with Nash-Sutcliffe model efficiency coefficient (NSE). When compared with Yang et al. (2015), the analytical solutions used in this study showed good agreements (NSE = 0.99). When compared with semi-infinite analytical solutions, TCE and PCE concentration profiles in the low-permeability layer, the diffusive fluxes, and the contaminant tailings of the high-permeability layer were underestimated. In order to determine the appropriate analytical solutions based on the effective diffusion coefficient, the thickness of the low-permeability layer, and the diffusion time in the TCE and PCE contaminated site, a term of dimensionless diffusion length (Zd) was used. If the Zd is less than 0.7, the semi-infinite solutions can be used to simulate accurate concentration profiles in low-permeability layers. If the Zd is greater than 0.7, the reliability of simulations may be improved by using the finite solutions.

Modeling the effect of mass transfer on the kinetics of fructo-oligosaccharide production by immobilized cells (고정화 세포에 의한 Fructo-oligosaccharides 생산 반응메카니즘에서 물질전달 영향에 대한 수학적 모델)

  • 윤종원;전영중이민규송승구
    • KSBB Journal
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    • v.8 no.3
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    • pp.266-271
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    • 1993
  • The effective diffusion coefficients of glucose, sucrose and fructo-oligosaccharides in Ca-alginate gel beads at high concentration of sucrose solutions were investigated at $50^{\circ}C$. A mathematical model for the kinetics of fructo-oligosaccharide production using immobilized cells was proposed and compared with experimental results varying the bead size, the substrate concentration and the bead ratio. Very low values of diffusion coefficients ranging $1.2-7.6\times10^{-7}\textrm{cm}^2$/sec were obtained, and the predicted results were in good agreement with experimental ones in all cases tested.

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