• Title/Summary/Keyword: 유효확산

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Characteristics of Hydrodynamic Dispersion Using a Natural Gradient Tracer Test in a Fractured Rock at the Jwacheon-dong, Busan City (부산시 좌천동 단열암반층에서 자연구배 추적자시험을 이용한 수리분산특성 연구)

  • Chung Sang-Yong;Kang Dong-Hwan;Kim Byung-Woo
    • The Journal of Engineering Geology
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    • v.16 no.3 s.49
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    • pp.245-254
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    • 2006
  • Using a natural gradient tracer test, the characteristics of hydrodynamic dispersion according to each depth of a fractured rock were studied, and the effective porosity and longitudinal dispersivity of the fractured rock were estimated. The difference of vertical hydrodynamic dispersion was identified by concentration breakthrough curves linear regression analyses of bromide concentrations according to depths versus time, and hydraulic fracture characteristics at two intervals of the monitoring well. Higher concentration and faster arrival time at GL- 18 m depth (RQD 13%, average joint spacing 2 cm, TCR 100%) than at GL- 25 m depth (RQD 41%, average joint spacing 7 cm, TCR 100%) resulted from shorter distance and more fractures. Tracer was transported through the 1 st fractures until the arrival of its peak concentration and through the 2nd fractures or matrix diffusion after the arrival of its peak concentration. The increase/decrease slopes of bromide concentration versus time were 3.46/-1.57 at GL-18 m depth and 3.l9/-0.47 at GL- 25 m depth of the monitoring well. So the faster bromide transport was confirmed at GL- 18 m depth with more fractures. The concentration increment of bromide was fitted by a Gaussian function and the concentration decrement of bromide was fitted by an exponential function. Effective porosity and longitudinal dispersivity estimated by CATTI code were 10.50% and 0.85 m, respectively.

Temperature Dependence of Oxygen Diffusivity in the PVC Film on Gold Electrode Using Steady-State Rotating Disk Electrode Technique and Modulated Electrohydrodynamic Impedance Technique (정상상태 회전원판전극(RDE) 방법과 유체역학적 요동에 의한 전기화학적(EHD) 임피던스방법을 이용한 금전극표면에 형성된 PVC 피막내 산소확산계수의 온도의존성에 대한 연구)

  • Yeon Jei-Won;Pyun Su-Il;Lee Woo-Jin;Choi In-Kyu
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.49-56
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    • 2000
  • In the present we.k, temperature dependence of oxygen diffusivity in the polyvinyl chloride (PVC) film $D_f$ formed on gold electrode was investigated using steady-state rotating disk electrode (RDE) technique and modulated electrohydrodynamic (EHD) impedance technique. Both the diffusion rate defined as the ratio of oxygen diffusivity in the PVC film to the film thickness $D_f/\delta_f$ and the time constant $\delta_f^2/D_f$ for oxygen diffusion through the PVC film were obtained from plot of the limiting current versus disk rotation speed and from filing the EHD impedance spectra experimentally measured to those theoretically calculated on the basis of the diffusion equation for mass transport through the non-conductive and porous film, respectively. By combining measured $D_f/\delta_f$ with $\delta_f^2/D_f$, we determined $\delta_f\;and\;D_f$ at room temperature separately. As temperature increased, it appeared that the $D_f$ value measured for the PVC film-covered gold RDE was enhanced more rapidly than that $D_s$ value in the solution measured for the PVC film-free gold RDE. This means that the pores glowing with increasing temperature act as effective diffusion paths within the film. The present in-situ steady-state and modulated EHD measurements prove to be effective for determining $\delta_f\;and\;D_f$, separately and at the same time the porosity of the PVC film at temperatures below glass temperature $T_g$ of the film.

Numerical Modeling of Physical Property and Electrochemical Reaction for Solid Oxide Fuel Cells (고체 산화물 연료전지를 위한 물성치 및 전기화학반응의 수치해석 모델링)

  • Park, Joon-Guen;Kim, Sun-Young;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.157-163
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    • 2010
  • Solid oxide fuel cells (SOFCs) are commonly composed of ceramic compartments, and it is known that the physical properties of the ceramic materials can be changed according to the operating temperature. Thus, the physical properties of the ceramic materials have to be properly predicted to develop a highly reliable simulation model. In this study, several physical properties that can affect the performance of SOFCs were selected, and simulation models for those physical properties were developed using our own code. The Gibbs free energy for the open circuit voltage, exchange current densities for the activation polarization, and electrical conductivity for the electrolyte were calculated. In addition, the diffusion coefficient-including the binary and Knudsen diffusion mechanisms-was calculated for mass transport analysis at the porous electrode. The physical property and electrochemical reaction models were then simulated simultaneously. The numerical results were compared with the experimental results and previous works studied by Chan et al. for code validation.

Findings from the Survey Responses by Cambodian Doctors and Patients for Telemedicine (캄보디아 환자와 의사의 원격 의료에 대한 반응 조사)

  • Yoo, Sun-gil;Oh, Dongik;Min, Sedong;Shin, Wonhan
    • Journal of Internet Computing and Services
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    • v.16 no.4
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    • pp.13-23
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    • 2015
  • In order to reduce public medical expenses as well as to provide effective medical services, telemedicine between doctors and patients is considered as an alternative to the conventional hospital visit. But the medical community has been protesting the introduction of telemedicine for the efficacy and safety reasons. Korean government has been conducting a number of pilot projects to demonstrate the efficacy and safety of telemedicine for more than 10 years. However, still the system is not yet legalized. In this study, we have conducted a telemedicine pilot project in Cambodia for one year, where telemedicine can be more freely exercised. After the project, we conducted a survey based on the 'Rogers diffusion' theory. Survey results show that both physicians and patients are positive about the relative advantage of the telemedicine. However, the complexity and high cost of the equipment used in telemedicine has been found to be a possible obstacle. In addition, we found that there is no problem for providing telemedicine services under challenged environment, such as in Cambodia.

Study of Kinetics for Removal H2S by Natural Manganese ore Sorbent (황화수소 제거를 위한 천연망간광석 탈황제의 반응 속도 연구)

  • Yoon, Yeo Il;Kim, Myung Wook;Kim, Sung Hyun
    • Clean Technology
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    • v.7 no.3
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    • pp.187-194
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    • 2001
  • The desulfurization process which belongs to the gas refining part is the unit process that eliminates $H_2S$ and COS in the coal gas formed by the coal gasification part in the integrated gasification combined cycle(IGCC). In this study, natural manganese ores were selected as the raw material of the desulfurization sorbent due to economical efficiency. Initial rates for the reactions between $H_2S$ and desulfurization sorbent using natural manganese ores were determined in a temperature range of $400{\sim}800^{\circ}C$ using a thermobalance reactor. All reactions were first order with respect to $H_2S$ and were in accord with the Arrhenius equations. When sulfidation reaction was controlled by diffusion, the temperature dependence of the effective diffusivity was given by the Arrhenius equation. Activation energies and frequency factors were obtained from the product layer diffusion coefficient of various sorbents by plotting as Arrhenius equation form.

  • PDF

Analysis Technique on Time-dependent PDF (Probability of Durability Failure) Considering Equivalent Surface Chloride Content (균등 표면 염화물량을 고려한 시간 의존적 내구적 파괴확률 해석기법)

  • Lee, Hack-Soo;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.2
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    • pp.46-52
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    • 2017
  • Recently durability design based on deterministic or probabilistic method has been attempted since service life evaluation in RC(Reinforced Concrete) structure exposed to chloride attack is important. The deterministic durability design contains a reasonable method with time effect on surface chloride content and diffusion coefficient, however the probabilistic design procedure has no consideration of time effect on both. In the paper, a technique on PDF(Probability of Durability Failure) evaluation is proposed considering time effect on diffusion and surface chloride content through equivalent surface chloride content which has same induced chloride content within a given period and cover depth. With varying period to built-up from 10 to 30 years and maximum surface chloride content from $5.0kg/m^3$ to $10.0kg/m^3$, the changing PDF and the related service life are derived. The proposed method can be reasonably applied to actual durability design with preventing conservative design parameters and considering the same analysis conditions of the deterministic method.

Development of 3-D Hydrodynamical Model for Understanding Numerical Analysis of Density Current due to Salinity and Temperature and its Verification (염분과 온도차에 의한 밀도류 해석을 위한 3차원 동수역학적 수치모델의 개발 및 검증)

  • Lee, Woo-Dong;Hur, Dong-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.3
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    • pp.859-871
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    • 2014
  • In order to analyze the density current due to salt and temperature difference, this study develops new numerical model (LES-WASS-3D ver. 2.0) by introducing state equation for salt and temperature and 3D advection-diffusion equation to existing 3D numerical wave tank (LES-WASS-3D ver. 1.0). To verify the applicability, the newly-developed numerical model is analyzed comparing to the experimental result of existing numerical model. In the result, it well implement the behavior and vertical salt concentration of advected and diffused seawater as well as flow velocity and temperature of the discharged warm water. This confirms the validity and effectiveness of the developed numerical model.

Factors Influencing the Market Diffusion and Marketing Strategy of WCDMA Service (국내 WCDMA 서비스의 시장확산과 마케팅전략 영향요인)

  • Kim Moon-Koo;Park Jong-Hyun;Nam Changi
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.30 no.8B
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    • pp.569-580
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    • 2005
  • In case of one of the next generation mobile telecommunication; WCDMA service, the relevant market growth is delayed by market uncertainty, lack of effective demands, rapid evolution of technology, non-existence of business strategy, lack of distinction with competitive services and killer applications. In this study we intended to analyze the influence factors of market diffusion and marketing strategy of WCDMA. For doing so, we obtained both promotion and hindrance factors for diffusing the market of WCDMA through expert survey. Also we acquired such categories as factor for adoption, willingness to pay, killer application, preferred terminal and pronising customer, which becomes the reason ifluencing on the decision of WCDMA service marketing strategy. On the basis of such results, this paper suggests the direction of deployment for marketing focusing on the strategies as customer, price, sewice, terminal provision, and positioning of WCDMA.

Characteristics of NOx Emission in a Swirl Flow in Nonpremixed Turbulent Hydrogen Jet with Coaxial Air (수소 난류 확산화염에서의 선회류에 의한 배기배출물 특성)

  • Oh, Jeong-Seog;Yoon, Young-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.3
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    • pp.275-282
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    • 2010
  • The effect of swirl flow on NOx in a nonpremixed turbulent hydrogen jet with coaxial air was studied. The swirl vane angle was varied from $30^{\circ}$ to $90^{\circ}$. The fuel jet air velocity and coaxial air velocity were varied in an attached flame region as $u_F=85{\sim}160m/s$ and $u_A=7{\sim}14m/s$. The objective of the current study was to analyze the characteristics of nitrous oxide emission in a swirl flow and to propose a new parameter for EINOx scaling. The experimental results show that EINOx decreases with the swirl vane angle and increased with flame length. Further, EINOx scaling factors can be determined by considering the effective diameter ($d_{F,eff}$) in a far field concept. The EINOx increased in proportion to the flame residence time (${\sim}{\tau_R}^{1/2.8}$) and the global strain rate (${\sim}{S_G}^{1/2.8}$).

First-Order Mass Transfer in a Diffusion-Dominated (Immobile) Zone of an Axisymmetric Pore: Semi-Analytic Solution and Its Limitations (대칭형 다공성 매질의 확산주도 영역에 관한 1차 물질이동 방정식)

  • Kim, Young-Woo;Kang, Ki-jun;Cho, Jung-ho;Kabala, Zbigniew
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4664-4670
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    • 2010
  • Comparison of the classical mobile-immobile zone (MIM) model to the derived model led to several conclusions. If the MIM model is to be applied, the initial concentration in the immobile zone has to be down-scaled by a correction factor that is a function of pore geometry. The MIM model was valid only after sufficiently long time has passed, i.e., only after the diffusion front reaches the deepest pore wall in the immobile zone. The MIM mass-transfer coefficient $\alpha$, was inversely proportional to the square of the pore depth. Also it did not depend on the mobile-zone flow velocity, contrary to the number of laboratory and field observations. The classical MIM model displayed a rapid exponential decay of immobile-zone concentration. Meanwhile at large times, the newly derived model displayed similar exponential decay. This was contrary to the mounting evidence of power-law BTC tails observed in laboratory and field settings.