• Title/Summary/Keyword: 유황화합물

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Separation and Identification of Polycyclic Aromatic Compounds in Pyrolysis Products of Cellulose and Lignin (셀룰로오스와 리그닌의 열분해 생성물중의 여러고리 방향족화합물의 분리와 동정)

  • Park, Nae-Joung;Lee, Milton L.
    • Journal of the Korean Chemical Society
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    • v.28 no.4
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    • pp.244-250
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    • 1984
  • Separation and identification of the polycyclic aromatic compounds (PAC) from pyrolysis products of cellulose and lignin were performed using a combination of acid-base solvent partitioning and silicic acid column chromatography with fused-silica capillary column gas chromatography/ mass spectrometry. Sixteen PAC were positively identifited by retention indices and mass spectra data. Both materials produced the same kinds of PAC. But lignin produced much more PAC than cellulose. Almost no highly carcinogenic heterocyclic PAC containing nitrogen and sulfur were produced.

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Quality Characteristics of Onions Applied with Methylsulfonylmethane (MSM) during Cultivation (양파 재배 중 식이유황 methylsulfonlymethane 처리가 양파의 품질 특성에 미치는 영향)

  • Kwon, Eunjin;Ryu, Dayeon;Surh, Jeonghee
    • Korean Journal of Food Science and Technology
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    • v.45 no.2
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    • pp.213-220
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    • 2013
  • Two types of onions cultivated with different methods of sulfur application (designated as S-1 and S-2) were examined for their physicochemical and sensory properties, and then compared with onions without sulfur application as a control. During cultivation, dietary sulfur methylsulfonylmethane (MSM) was sprayed on the leaves twice starting at 2 months before harvest, with one month intervals for S-1. For S-2, the MSM was applied once onto surface soils before sowing, and then once again on the leaves at 2 months before harvest. Thiosulfinate, a major sulfur-containing compound in onions, increased in the order of control, S-1, and S-2, without noticeable differences in the strength of spicy hot taste and flavor. The S-2 onions demonstrated a total reducing capacity three times higher than control and S-1 did. It indicates that the application of sulfur would positively affect the quality of onions under the condition where sufficient time is given for soil mineralization.

윤활유 첨가제의 화학적 성질과 윤활작용과의 관계

  • 강석춘
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1988.06a
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    • pp.12-27
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    • 1988
  • 첨가제는 기유인 탄소와 수소로 된 유기화합물과 함께 존재하면서 윤활기능을 높여 주는 것으로써 유황, 염소와 인을 주요성분으로 하고 있다. 비록 이들 첨가제의 화학적 구조와 반응에 따라 윤활기능 및 역할을 체계적으로 연구하는 것은 매우 복잡하고 때로는 불가능 하지만 가능한 범위에서 화학적 관계와 윤활작용의 상호관계를 살펴보기로 한다.

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윤활유 첨가제의 화학적 성질과 윤활작용과의 관계

  • 강석춘
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.15-27
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    • 1988
  • 첨가제는 기유인 탄소와 수소로 된 유기화합물과 함께 존재하면서 윤활기능을 높여주는 것으로써 유황, 염소와 인을 주요 성분으로 하고 있다. 비록 이들 첨가제의 화학적 구조와 반응에 따라 윤활기능 및 역할을 체계적으로 연구하는 것은 매우 복잡하고 때로는 불가능하지만 가능한 범위에서 화학적 관계와 윤활작용의 상호관계를 살펴보기로 한다.

Effect of catalyst poison agents on the hydrogenation of soybean oil (촉매독이 대두유의 경화에 미치는 영향)

  • Lee, Sur-Koo;Kim, Chang-Sik
    • Applied Biological Chemistry
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    • v.36 no.2
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    • pp.93-98
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    • 1993
  • The purpose of this study is to determine the physicochemical properties in soybean oil during the hydrogenation by addition of phosphorus compounds and sulfur compounds is increased in soybean oil, decreased oleic acid and increased linoleic acid and stearic acid contents were found. When the sulfur compounds content is increased, solid fat content is increased at $10.0^{\circ}C$ and $21.1^{\circ}C$ and gradually decreased at $33.3^{\circ}C$ and $37.8^{\circ}C$. Higher melting point in hydrogenated soybean oil is observed on addition of phosphorus compounds compared to addition of sulfur compounds. When the sulfur compounds content is increased, conditions of selective hydrogenation are observed. Lead and arsenic are detected at a concentration of 0.01 ppm in a few kinds at each step of the refining process of soybean oil.

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Effect of Ultrasonic Irradiation on On-board Fuel Analyzed Using Gas Chromatography/Mass Spectrometry (GC/MS를 이용한 선박연료유에 대한 초음파조사 효과 분석)

  • Choi, Jung-Sik
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.6
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    • pp.890-897
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    • 2021
  • Since the enforcement of strict regulations on marine fuel oil sulfur content, demand for Low Sulfur Fuel Oil (LSFO) has been increasing. However, as LSFO properties vary greatly depending on the supply timing, region, and supplier, LSFOs can experience problems with sludge formation, blending compatibility, and stability once mixed into storage tanks. This study investigates using ultrasound cavitation effects to improve the quality of LSFOs in storage tanks. For marine gas oil (MGO), the results showed that the relative ratio of high molecular weight compounds to those of low molecular weight decreased after ultrasonic irradiation, due to cavitation-induced cracking of chemical bonds. For marine diesel oil (MDO) and blended oil, a small increase in the relative abundance of low weight molecular compounds was observed after treatment. However, no correlation between time and relative abundance was observed.

Antitumor Effect of Young Radish Kimchi Prepared with Young Radish Cultivated in the Soil Containing Sulfur on Sarcoma-180 Tumor Cells Transplanted Mice (유황처리 열무로 제조한 열무김치의 Sarcoma-180 암세포에 대한 고형암 성장 억제효과)

  • Kong, Chang-Suk;Bak, Soon-Sun;Rhee, Sook-Hee;Kil, Jeung-Ha;Rho, Chi-Woong;Hwang, Hae-Jun;Kim, Nak-Ku;Park, Kun-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.10
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    • pp.1520-1524
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    • 2005
  • Young radishes (YR, yeolmu in Korean) were cultivated in the soil with and without sulfur. Young radish kimchi-general (YR kimchi-G) was prepared with YR commonly cultivated in the soil without sulfur. Young radish kimchl-sulfur (YR kimchi-S) and young radish kimchi-sulfur with lime mortar (YR kimchi-SL) were prepared with the YR cultivated in the soil with sulfur an4 sulfur added lime mortar on it respectively. Antitumor effects of methanol extracts from the YR kimchis were investigated in sarcoma-180 tumor cell transplanted mice. The solid tumor growth was significantly inhibited by the YR kimchi-SL prepared with YR grown in the soil with sulfur (p < 0.05). The treatment of the methanol extracts from YR kimchi-S and -SL increased the glutathione S-transferase activities and glutathione contents in the livers, compared to thlose of YR kimchi-G and the control. One of the antitumor effects by the YR kimchis was due to the increased the glutathione levels and the glutathione S-transferase activity which is phase 2 enzyme. These results also suggested that the antitumor effects of YR kimchi can be enhanced by using YR cultivated differently in the presence of sulfur that can help to produce sulfur-containing compounds in YR.

ISOLATION AND IDENTIFICATION OF LACTOBACILLUS SALIVARIUS INHIBITING THE FORMATION OF ARTIFICIAL PLAQUE AND THE PRODUCTION OF VOLATILE SULFUR COMPOUNDS (치태 형성과 휘발성 유황화합물 생성을 억제하는 Lactobacillus salivarius의 분리 및 동정)

  • Kim, Mi-Hyung;Choi, Nam-Ki;Kim, Seon-Mi;Oh, Jung-Suk;Yang, Kyu-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.32 no.2
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    • pp.344-356
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    • 2005
  • There are normal inhabitants doing medically useful functions in the body. There are many kinds of bacteria performing specific functions in the oral cavity. Two strains of lactic acid bacteria were isolated from inhabitants of caries-free children's oral cavity, which inhibited the formation of artificial plaque by Streptococcus mutans and the production of volatile sulfur compounds by anaerobic bacteria. The isolates were identified by the test using API 50 CHL medium kit and 16S rDNA partial sequencing. 1. Two isolates were Gram-positive bacilli and produced hydrogen peroxide. 2. When Streptococcus mutans was cultured in the media, the mean weight of formed artificial plaque on the orthodontic wires was $124.4{\pm}30.4\;mg$, whereas being reduced to $5.2{\pm}2.0mg$ and $10.6{\pm}6.6mg$ in the media cultured with Streptococcus mutans and each isolate, respectively (p<0.05) 3. The number of viable cells of Streptococcus mutans was $3.4{\times}10^9$ per ml in the cultured solution, whereas those of Streptococcus mutans in the combined culture with each of isolates were $4.6{\times}10^8\;and\;2.4{\times}10^8$ per ml. 4. The optical density was 1.286 in the supernatant of Fusobacterium nucleatum after vortexing for 30minutes, whereas in the supernatant of combined Fusobacterium nucleatum and each isolate, they were reduced to 0.628 and 0.497, which the percentages of coaggregation between them were 29.4% and 57.8%, respectively 5. The optical density of Fusobacterium nucleatum precipitate was 1.794 in the culture media containing cysteine and $FeSO_4$, being reduced to 1.144 and 0.915 in the coaggregated precipitates of Fusobacterium nucleatum and each isolate. The optical density of Porphyromonas gingivalis precipitate was 1.932 in the culture media, being reduced to 1.170 and 1.266 in the coaggregated precipitates of Porphyromonas gingivalis and each isolate. 6. When two isolates were tested with API 50 CHL medium kit, those were identified Lactobaciallius salivarius and Lactobaciallius delbrueckii subsp. lactis. 7. The similarity values of 16S rDNA sequence between each of isolates and Lactobaciallius salivarius subsp. salicinius were 99.60% and 99.73%, respectively, meaning that isolates were Lactobaciallius salivarius subsp. salicinius. These results indicated that two strains isolated from caries-free children's saliva, which inhibited the formation of artificial plaque and the production of volatile sulfur compounds, were identified as Lactobaciallius salivarius subsp. salicinius.

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Effect of the Photolysis rate and Initial concentration for the Pollutants on modelled Ozone concentration (반응속도상수와 오염물질의 초기 농도가 오존농도 예측에 미치는 영향)

  • 이화운;김유근;원경미;김희정
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.422-423
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    • 1999
  • 최근 저유황 연료유의 공급과 청정연료의 사용 등으로 인해 1차 오염물질은 점차 줄어드는 추세에 있는 반면, 늘어나는 자동차와 급속한 산업화로 산업시설에서 배출되는 질소산화물과 탄화수소류, 휘발성 유기화합물(VOC) 등이 복잡한 광화학 반응을 통해 2차 오염물질을 생성함으로 대기오염의 문제가 심각하다.(중략)

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A Study on the Chemical Odor Reduction Methodology of Paper-mill Sludge (제지슬러지 발산악취의 화학적 제거 방법에 관한 연구)

  • 노태목;김학민;이승현;김선태
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.217-218
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    • 1999
  • 최근 들어 경제의 발전과 생활수준이 향상됨에 따라 악취는 소음과 함께 환경분야에 많은 민원을 야기하고 대기오염물질의 하나로 인식되고 있다. 특히 유황계 화합물을 대표하는 악취물질인 황화수소는 무색의 기체로써 부패한 계란 냄새가 나고 역치농도(Threshold Odor Value)가 0.00047ppm$_{v}$ 로 매우 낮은 농도에서도 취기를 감지할 수 있는 것으로 알려져 있다. 이러한 성질을 갖는 황화수소는 석유 화학공업이나 제지공업, 폐수처리장 그리고 폐기물 처리장 등에서 많이 발생하고 있다.(중략)

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