• Title/Summary/Keyword: 유황전지

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Electrochemical Properties of PVdF Gel Polymer Electrolyte with Plasticizer for Lithium/sulfur Battery (리튬 유황 전지용 PVdF 겔 고분자 전해질의 가소제에 따른 전기화학적 특성 평가)

  • Ryu, Ho-Suk;Kim, Jong-Seon;Kim, Dong-Ju;Kim, Dong-Yeon;Kim, Ic-Pyo;Ahn, Hyo-Jun;Kim, Ki-Won;Ahn, Jou-Hyeon;Lee, Gun-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.10 no.3
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    • pp.213-218
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    • 2007
  • In order to find out proper PVdF gel polymer electrolyte for Li/S battery, we investigated PVdF gel polymer electrolytes with various glyme type plasticizer such as polyglyme, tetraglyme, triglyme. The organic solvents as triglyme, tetraglyme, polyglyme (Mn = 250, 500) has different chain length of ethylene oxide(EO) in solvent of glyme system. ionic conductivity decreased as increasing chain length of EO in plasticizers. Ionic conductivity of PVdF gel electrolyte with tetraglyme, triglyme, polyglyme (Mn = 250, 500) at room temperature was $5{\times}10^{-4},\;3{\times}10^{-4},\;6{\times}10^{-5},\;3{\times}10^{-5}\;S/cm$, respectively. Li/S cell with PVdF gel polymer electrolyte using tetraglyme plasticizer had low interfacial resistance and the highest initial discharge capacity of 1232 mAh/g of active sulfur, which was about 70% utilization of theoretical value.

Development of portable DMFC systems (휴대용 직접 메탄올 연료전지 시스템 개발)

  • Moon, Go-Young;Kim, Hyuk;Yoo, Hwang-Chan;Noh, Tae-Geun;Lee, Won-Ho
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.46-53
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    • 2007
  • Direct Methanol Fuel Cell, DMFC is a potential power source for portable IT application. DMFC works at low temperature ($<100^{\circ}C$) without fuel processing. Methanol has high energy density, fuel economy, and easiness to handle. This paper focuses high efficient catalyst to increase utilization in the electrode, new membrane reducing methanol crossover, new material parts, and optimization of system integration. Lightweight and small-sized DMFC based on new materials, efficient stack, and improved system control will be applied to the 50W prototype system for the notebook computer.

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A Study on the Temperature Distribution Characteristics of NAS Battery Module (NAS 전지 모듈의 온도 분포 특성에 관한 연구)

  • Heo, Doo-Sang;Yi, Chung-Seob;Jeong, Hyo-Min;Chung, Han-Shik
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.4
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    • pp.1-6
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    • 2012
  • This paper addresses the issue of Renewable Energy for Electricity Storage device is one of the NAS (Sodium-Sulfur) battery will be about the module. For safety reasons, not the actual battery cells using a dummy cell in the module's operating temperature setting to examine the characteristics of the insulation vacuum of the wall temperature and external temperature changes measured over time. Upper and lower boundaries of the wall vacuum insulation characteristics cotton C intervals over time, average $5^{\circ}C$, but the temperature is rising, 4C section with little temperature change did not occur. On the other hand, about $3^{\circ}C$ in section 4D, and it was confirmed that the temperature rises. Wall vacuum insulation characteristics over time to look at the experiments and measurements are described.

A Study on High Efficiency Power Conditioning System for Safety Operation of PEMFC_type Fuel Cell Generation System (고분자전해질형 연료전지 발전시스템의 안전운전을 위한 고성능 전력변환기에 관한 연구)

  • Kwak Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.57-61
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    • 2006
  • Fuel cells are direct current (DC) power generators. They generate electricity through an electrochemical process that converts the energy stored in a fuel directly into electricity. Fuel cells have many benefits, which produce no particulate matter, nitrogen or sulfur oxides. And they have few moving parts and produce little or no noise. When fueled by hydrogen, they yield only heat and water as byproducts. Their wide application can reduce our dependence on fossil fuels and foreign sources of petroleum. This paper is studied on a high efficiency power conditioning system (PCS) applied to the proton exchange membrane fuel cell (PEMFC) generation system. This paper is designed to a novel PCS circuit topology of high efficiency. Some experimental results of the proposed PCS is confirmed to the validity of the analytical results.

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The Effects of the Nano-sized Adsorbing Material on the Electrochemical Properties of Sulfur Cathode for Lithium/Sulfur Secondary Battery (나노 흡착제가 Li/S 이차전지용 유황양극의 전기화학적 특성에 미치는 영향)

  • Song, Min-Sang;Han, Sang-Choel;Kim, Hyun-Seok;Ahn, Hyo-Jun;Lee, Jai-Young
    • Journal of Hydrogen and New Energy
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    • v.13 no.4
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    • pp.259-269
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    • 2002
  • A battery based on the lithium/elemental sulfur redox couple has the advantage of high theoretical specific capacity of 1,675 mAh/g-sulfur. However, Li/S battery has bad cyclic durability at room temperature due to sulfur active material loss resulting from lithium polysulfide dissolution. To improve the cycle life of Li/S battery, PEGDME (Poly(ethylene glycol) dimethyl ether) 500 containing 1M LiTFSI salt which has high viscosity was used as electrolyte to retard the polysulfide dissolution and nano-sized $Mg_{0.6}Ni_{0.4}O$ was added to sulfur cathode as additive to adsorb soluble polysulfide within sulfur cathode. From experimental results, the improvement of the capacity and cycle life of Li/S battery was observed( maximum discharge capacity : 1,185 mAh/g-sulfur, C50/C1 = 85 % ). Through the charge-discharge test, we knew that PEGDME 500 played a role of preventing incomplete charge-discharge $behavior^{1,2)$. And then, in sulfur dissolution analysis and rate capability test, we first confirmed that nano-sized $Mg_{0.6}Ni_{0.4}O$ had polysulfide adsorbing effect and catalytic effect of promoting the Li/S redox reaction. In addition, from BET surface area analysis, we also verified that it played the part of increasing the porosity of sulfur cathode.

Trend on the Recycling Technologies for Spent Batteries by the Patent and Paper Analysis (특허(特許)와 논문(論文)으로 본 폐전지 재활용(再活用) 기술(技術) 동향(動向))

  • Shin, Shun-Myung;Joo, Sung-Ho;Kim, Soo-Kyung;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.21 no.4
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    • pp.16-25
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    • 2012
  • There are several kinds of batteries such as zinc-air battery, lithium battery, Manganese dry battery, silver oxide battery, sodium-sulphur battery, lead acid battery, metal hydride secondary battery, nickel-cadmium battery, lithium ion battery, alkaline battery, etc. These days it has been widely studied for the recycling technologies of the used battery from view points of economy and efficiency. In this paper, patents and published papers on the recycling technologies of the used battery were analyzed. The range of search was limited in the open patents of USA (US), European Union (EU), Japan (JP), Korea (KR) and SCI journal articles from 1972 to 2011. Patents and journal articles were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journal articles were analyzed by the years, countries, companies, and technologies.

Discharge Properties of Sodium-sulfur Batteries at Room Temperature (상온용 나트륨/유황전지의 방전 특성)

  • Kim, T.B.;Ahn, H.Y.;Hur, H.Y.
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.193-197
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    • 2006
  • The sodium/sulfur(Na/S) battery has many advantages such as high theoretical specific energy(760Wh/kg), and low material cost based on the abundance of electrode material in the earth. It has been reported that the electrochemical properties of sodium/sulfur cell above $300^{\circ}C$, utilized a solid ceramic electrolyte and liquid sodium and sulfur electrodes. A lot of researches have been performed in this field. Recently, Na/S battery system was applied for electricity storage system for load-leveling. One of severe problems of sodium/sulfur battery was high operating temperature above $300^{\circ}C$, which could induce the explosion and corrosion by molten sodium, sulfur and polysulfides. In order to develop sodium battery operated at low temperature, sodium ion battery has been studied using carbon anode, and sodium oxides cathodes. However, the energy densities of the sodium ion batteries were much lower than high temperature sodium/sulfur cell. In this study, the sodium/sulfur battery with 1M $NaCF_3SO_3$ is tested at room temperature. The charge-discharge mechanism was discussed based on XRD, DSC, SEM and EDS results.

Comparison of Flower Thinning Efficiency of Lime-sulfur on Korean Major Pear (Pyrus pyrifolia Nakai) Cultivars (석회유황합제 처리에 의한 국내 주요 배 품종별 적화 반응 비교)

  • Byeong Hyeon Yun;Ji Hae Jun;Il-Sheob Shin;Hyun Ran Kim;Kang Hee Cho;Jae Hoon Jeong;Se Hee Kim;Sang-Yun Cho;Sewon Oh
    • Korean Journal of Plant Resources
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    • v.37 no.1
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    • pp.62-70
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    • 2024
  • Fruit thinning rate and characteristics were investigated for three years on seven promising pear (Pyrus pyrifolia Nakai) cultivars, which were treated by lime-sulfur as an eco-chemical thinning substance. Lime-sulfur was treated twice at the second and third days after full bloom by cultivar. Most of pear cultivars were significantly thinned by lime-sulfur compounds. Especially 'Whangkeumbae', 'Supergold' and 'Hanareum' exhibited high flower thinning rates, 41.5%, 40.1% and 39.9%, respectively. As weather conditions at the lime-sulfur treatment, insolation and cloud amount were correlated with flower thinning rate but not significant (r = 0.49 and r = -0.45, respectively). These results suggest that lime-sulfur is suitable for reducing labor force for flower thinning of Korean pears but flower thinning effects of lime-sulfur can vary depending on other factors such as environmental conditions. This information will provide useful data for low labor force cultivation of Korean pear cultivars.

Trend on the Recycling Technologies for the used Lithium Battery by the Patent Analysis (특허(特許)로 본 폐리튬전지 재활용(再活用) 기술(技術) 동향(動向))

  • Sohn, Jeong-Soo;Shin, Shun-Myung;Kang, Kyung-Seok;Choi, Mi-Jeong
    • Resources Recycling
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    • v.16 no.3 s.77
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    • pp.50-60
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    • 2007
  • There are several kinds of battery such as zinc-air battery, lithium battery, Manganese dry battery, silver oxide battery, mercury battery, sodium-sulphur battery, lead battery, nickel-hydrogen secondary battery, nickel-cadmium battery, lithium ion battery, alkaline battery, etc. These days it has been widely studied for the recycling technologies of the used battery from view points of economy and efficiency. In this paper, patents on the recycling technologies of the used lithium battery were analyzed. The range of search was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1986 to 2006. Patents were collected using key-words searching and filtered by filtering criteria. The trends of the patents was analyzed by the years, countries, companies, and technologies.

Trend on the Recycling Technologies for the used Manganese Dry Battery by the Patent Analysis (특허(特許)로 본 폐망간전지 재활용(再活用) 기술(技術) 동향(動向))

  • Shon, Jeong-Soo;Kang, Kyung-Seok;Han, Hye-Jung;Kim, Tae-Hyun;Shin, Shun-Myung
    • Resources Recycling
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    • v.17 no.2
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    • pp.76-84
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    • 2008
  • There are several kinds of battery such as zinc-air battery, lithium battery, manganese dry battery, silver oxide battery, mercury battery, sodium-sulphur battery, lead battery, nickel-hydrogen secondary battery, nickel-cadmium battery, lithium ion battery and alkaline battery, etc. These days it has been widely studied for the recycling technologies of the used battery from view points of economy and efficiency. In this paper, patents on the recycling technologies of the used manganese dry battery were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) from 1986 to 2006. Patents were collected using key-words searching and filtered by filtering criteria. The trends of the patents were analyzed by the years, countries, companies, and technologies.