• Title/Summary/Keyword: 유해 gas

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Preparation of Gas Sensor from Pitch-based Activated Carbon Fibers and Its Toxic Gas Sensing Characteristics (피치계 활성탄소섬유기반 가스센서 제조 및 유해가스 감응 특성)

  • Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.193-197
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    • 2014
  • The electrode for gas sensor was prepared by using pitch-based activated carbon fibers and polyvinyl alcohol (PVA) to investigate the toxic gas sensing characteristics. The physicochemical properties of activated carbon fibers electrode for gas sensor were analyzed with SEM and BET. Toxic gases sensing property of the electrode was also identified by different toxic gases such as $NH_3$, NO and $CO_2$. The specific surface area of activated carbon fibers electrode for gas sensor was decreased by 33% owing to PVA used as a binder compared with the activated carbon fibers. However, its pore size distribution of the ACF electrode was not greatly influenced by PVA. The activated carbon fibers electrode for gas sensor responded to toxic gases by electron hopping unlike semiconductor based gas sensors. In this study, activated carbon fibers electrode was decreased to 7.5% in resistance for the NH3 gas of the 100 ppm concentration and its $NH_3$ gas sensing property was confirmed the most excellent compared with other toxic gases.

Developing the Real-Time Atmospheric Dispersion System of Hazardous Chemicals for Proactive Response (능동적 사고대처를 위한 유해화학물질의 실시간 대기확산시스템 개발)

  • Oh, Jeong-Seok;Sohn, Choong-Yeon;Hyun, Ji-I;Sung, Jong-Kyu
    • Proceedings of the Korean Information Science Society Conference
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    • 2011.06c
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    • pp.13-16
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    • 2011
  • 에너지플랜트는 위험성이 높은 유해화학물질을 취급해서 누출사고가 발생 할 가능성이 높다. 유해화학물질이 누출되어 대기 중에 확산되면 강한 유독성으로 인해 대형피해를 불러온다. 유해화학물질의 누출로 인한 대기 중의 확산피해 최소화하는 방안에는 확산 될 범위를 산출하여 적절한 사고대응조치를 취하는 것이다. 대기확산모델의 시뮬레이션을 이용한 대기확산범위 산출은 가상으로 설정 된 시나리오의 데이터를 사용자가 수동으로 입력하여 결과를 도출한다. 가상 데이터로 산출 된 결과는 정확성이 결여 될 수 있으며 실시간 대기확산범위 산출이 불가능하다. 본 연구에서는 유해화학물질의 대기확산범위를 즉각적으로 산출 할 수 있는 실시간 대기확산시스템을 설계하고 구현한다. 대기확산범위 산출에 필요한 데이터는 실시간으로 수집 된 실제 데이터를 이용한다. 실시간으로 수집된 실 데이터를 토대로 데이터마이닝기법을 통해 자율적인 누출사고를 탐지하고 누출지점을 특정 할 수 있는 지능화모듈을 설계한다. 대기확산모델은 유해화학물질의 증기운의 무게에 따라 가우시안과 SLAB모델을 이용한다. 실시간으로 산출 된 대기확산범위는 ERPG의 각 단계의 농도 기준에 근거하여 총 3단계로 구분해서 GIS맵 상의 유저인터페이스에 표현한다. 산출된 대기확산피해범위는 현장 작업자의 모바일기기로 사고와 관련 된 대응조치와 함께 신속히 전파할 수 있도록 구현해서 누출로 인한 유해화학물질의 확산사고피해 최소화를 도모한다.

A Case Study on Operation of Off-Gas Treatment System of Radioactive Waste Vitrification Facility (방사성폐기물 유리화설비의 배기가스 처리계통 운영 사례 연구)

  • Lee, Hye Hyun;Park, Kyu Won
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.249-254
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    • 2016
  • In this study, we investigated the main characteristics of off-gas generated from melting process and off-gas treatment system operation example to provide some primary data for commercial vitrification facility design. The purpose of vitrification facility operation is to treat hazardous materials in the radioactive wastes and harmful off-gas containing a variety of chemical species generated in the glass melting process. Constructing and operating vitrification facility essentially need to be licensed through safety analysis; it is very important to treat radionuclide and hazardous materials below the legal environment emissions regulation level. We must accurately understand the characteristics of off-gas and apply an appropriate off-gas treatment process accordingly. Thus, to design the appropriate off-gas treatment there must be a wide range of elements taken into account such as characteristics of waste and melter, regulation guidance of off-gas, characteristics of generated off-gas and off-gas treatment system performance assessment.

A Study on the Mortality in Oxygen and Toxic Gas Concentration According using Experimental Animals (실험동물을 이용 산소 및 유해가스 농도에 따른 치사율 연구)

  • Kim, Hyeon-Yeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.18-25
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    • 2013
  • It may occur health hazards or death by suffocation or acute poisoning in case of oxygen deficiency in ambient or exposure to harmful gas. As a part of accident prevention, we studied the change of activity and lethal dose by changing the concentration of several hazardous gas with inhalation exposure chamber and laboratory animals. We investigated the lethality and motility change during either the 4 hrs whole body exposure to oxygen, nitrogen, toluene, $H_2S$, CO and 48 recovery. As results, it is estimated that 5% oxygen concentration as lethal concentration and 5.5% as $LC_{50}$ (rat, 4 hrs) with statistics for dose-response. The results of lethality in oxygen deficient condition (approximately 6%), the lethalities were 40%, 20% with 20 ppm $H_2S$, 600 ppm CO respectively, and was not increased the lethality with 8% CO. Thus, it was confirmed that the $H_2S$, CO had influence to lethal dose, while toluene had low fluence.

A Study on the Monitoring Criteria of Disaster Signs for Early-warning System based on Multiple Hazardous Gas Sensor (복합 유해 가스 센서 기반의 조기 경보 시스템을 위한 재난 전조 감시 기준에 관한 연구)

  • Han, Kyusang;Park, Sosoon;Yoon, En Sup
    • Journal of the Korean Institute of Gas
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    • v.17 no.2
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    • pp.28-35
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    • 2013
  • The number of large and complex buildings is growing and they are usually concentrated in metropolitan cities. There is a possibility in such buildings that a small accident can expand to a massive disaster since their scale and complexity. To deal with this issue, a research on gas sensors which can detect multiple gases and early-warning systems has been conducted. Proper criteria or standards are necessary for effective application and operation of such sensor-based disaster monitoring system. In this study, we have proposed the alarm criteria of concentration of hazardous gases for the detection and the alarm release. For each alarm level, systematic disaster response plans consist of responsive actions and information delivery have been prepared. These disaster monitoring criteria can help the detection of hazardous gas-related disaster in the early stage of accident and the provision of appropriate emergency responses.

Design of JESS-based Inference Rule for the Monitoring of Harmful Gas (유해가스 모니터링을 위한 JESS 기반 추론규칙의 설계)

  • Ahn, yoon-ae
    • Proceedings of the Korea Contents Association Conference
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    • 2010.05a
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    • pp.396-398
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    • 2010
  • 밀폐된 공간으로 이루어진 작업장은 여러 가지 유해가스가 많이 발생된다. 이로 인해 환기가 불충분한 작업공간에서는 산소결핍 및 유해가스로 인한 건강장해와 인화성 물질에 의한 화재, 폭발 등의 위험이 존재한다. 따라서 유해가스 정보를 작업장 내의 센서를 통해서 실시간으로 모니터링하고, 위험으로부터 작업자의 안전을 보장할 수 있는 모니터링 시스템이 필요하다. 특히, 상황에 맞는 의사결정이 가능하도록 하기 위해 상황인식 시스템의 도입이 필요하다. 이 논문에서는 작업장의 유해가스 정보를 모니터링하기 위한 추론 규칙을 JESS를 기반으로 설계한다.

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Study of Toxic Gas Removal Characteristics by Chemical Analysis of Essential Oil using SPME Method (SPME법을 이용한 식물정유 성분분석을 통한 유해가스 제거 특성연구)

  • 박영규
    • KSBB Journal
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    • v.19 no.3
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    • pp.231-235
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    • 2004
  • This paper was investigated to clarify the possibility of ammonia gas removal by essential oil. First of all, the chemical analysis was peformed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil react with ammonia by neutralization and their reaction mechanism was elucidated. Based on their chemical neutralized reaction, the removal efficiencies of ammonia gas were studied to derive the optimal conditions in the scrubber tower such as optimal temperature and pH. The experimental result shows that the removal efficiency of ammonia gas was achieved over 98 % by the misty aerosol dispersion of scrubber tower.

A System on Air Dispersion System for Toxic Gas on Energy Plant Environment (에너지 플랜트 환경에서 독성가스를 위한 대기확산 시스템에 관한 연구)

  • Oh, Jeong-Seok;Sohn, Choong-Yeon;Sung, Jong-Gyu
    • Proceedings of the Korea Information Processing Society Conference
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    • 2011.04a
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    • pp.1074-1077
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    • 2011
  • 국내외 대규모 산업시설은 유해물질과 직 간접적으로 밀접하게 관련되어 유해물질 누출사고는 막대한 물적, 인적 피해를 발생시키며 누출물질, 저장시설, 대기 상태에 따라 유해물질 확산 속도 및 범위가 다르기 때문에 이를 예측하는 대기확산 시스템이 필요하다. 또한 기존의 대기확산 시스템은 산업시설 구조물 설계 단계에서 안전성을 확인하는 시뮬레이션용으로 사용되었기 때문에 누출사고 발생 시 즉각적인 처리와 대응이 어려우며 전문적 지식수준의 사용자 입력을 요구한다. 본 논문은 에너지 플랜트 환경의 특수성과 효율성을 고려하여 운영 중인 시설에 적용 가능한 대기확산 시스템 연구를 목적으로 한다. 이를 위하여 신속하고 효율적인 대기확산 모델을 선정 정의하고 융통성 있는 대기확산 시스템의 구성요소를 컴포넌트화하여 구현하였으며 사고 발생 시 빠르게 피해범위를 예측할 수 있는 실시간 대기확산 시스템 설계 방안을 제시하였다.

Development of Confined Plasma Source for Hazardous Gas Treatment (유해가스 처리를 위한 Confined Plasma Source 개발)

  • Yoon, Yongho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.3
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    • pp.135-140
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    • 2020
  • Since the process gas that is essential in the semiconductor process is a harmful gas, it is an essential task to solve it in an environmentally friendly manner. Currently, the cleaning technology used in the semiconductor process is mostly a wet cleaning based on hydrogen peroxide developed in the 1970s, and the SC-1 cleaning liquid for removing particles on the surface uses a mixture of ammonia and hydrogen peroxide. Therefore, environmental problems are caused, and economic problems caused by excessive water use are also serious. For this reason, the products developed through this study are used to decompose the process harmful gas from the chamber outlet into a harmless gas before entering the vacuum pump, or by incineration and the gaseous components are deposited on the pump. I want to solve the problem. In this paper, CPS (Confined Plasma Source) is proposed to save environment and improve productivity by replacing harmful gases (N2, CF4, SF6⋯., Etc) which are indispensable in semi-contamination process with innocuous gases or incineration with plasma, to study.