• Title/Summary/Keyword: 유해 가스

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The Study on the Synthesis of Triazole Derivatives as Energetic Plasticizer (트리아졸 계열의 에너지 가소제 합성 연구)

  • Lee, Woonghee;Kim, Minjun;Park, Youngchul
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.2
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    • pp.31-38
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    • 2016
  • Most of propellants that is used widely in the world release toxic gases such as methane gas and carbon dioxide during combustion which are noxious to the environment. This study established a synthetic process of a high nitrogen containing derivative of triazole, 4,5-bis(azidomethyl)-methyl-1,2,3-triazole (DAMTR), which can be applied as energetic plasticizer to environmental concerns. Also, the compound was characterized by NMR, IR spectroscopy, and physical properties such as glass transition temperature, melting point, decomposition temperature, density, impact sensitivity, viscosity and volatility were measured. In addition, the heats of formation (${\Delta}H_f$) and detonation properties (pressure and velocity) of DAMTR were calculated using Gaussian 09 and EXPLO5 programs.

A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions (Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구)

  • Kim, Dayoung;Hwang, Myungwhan;Woo, Insung
    • Journal of the Korea Safety Management & Science
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    • v.16 no.2
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.

UV-cut Finish of Cotton Using Polycarboxylic acid and Vitamin C (폴리카르복시산과 Vitamin C를 이용한 면섬유의 자외선 차단 가공)

  • Lee, Sang-Uk;Choi, Min-Young;You, Mi-Dum;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.30-30
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    • 2011
  • 산업화 과정에 방출된 할로겐 화합물 및 프레온 가스가 오존층을 파괴하면서 많은 양의 자외선이 지표에 도달하여 생태계에 적지 않은 영향을 끼치고 있다. 자외선은 살균, 소독작용 및 Vitamin D 합성을 위해 생명체에 필수적이지만 과다할 경우 색소침착, 피부노화, 피부암 발생, 백내장의 증가, 면역기능저하 등의 피해를 준다. 자외선은 파장 영역에 따라 UV-A(장파장 자외선), UV-B(중파장 자외선)및 UV-C(단파장 자외선)으로 나뉜다. 이 중 인체에 가장 유해한 것으로 알려진 단파장의 UV-C는 파장이 짧아 침투력이 미약해 오존층과 성층권에서 대부분 흡수되므로 생물학적으로 큰 의미는 없다. 그러나 자외선 중 UV-B와 UV-A 영역의 자외선은 인체에 영향을 가장 많이 미치므로 이들 영역의 자외선을 차단하는 것이 필요하다. Vitamin C는 아스코르브산(ascorbic acid)이라고도 불리며 미백효과, 주름 개선, 자외선 차단 및 항산화 작용을 하지만 섬유가공 시 Vitamin C는 쉽게 산화되며 세탁 내구성이 떨어지기 때문에 가교제를 필요로 한다. Vitamin C를 이용하여 자외선 차단성 섬유제품을 개발하기 위해, 포름알데히드를 유리하지 않는 폴리카르복시산 가교제 중 하나인 Citric Acid(CA)를 사용하여 고온에서 면직물에 처리했을 때 에스테르 형 가교를 형성하여 내세탁성을 가질 수 있었다. 자외선 차단 효과를 알아보기 위하여 KS K 0850 섬유제품의 자외선 차단율 및 차단지수 시험방법으로 평가하였다.

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An Analysis on Korean Mortality Structure (한국인의 사망력 구조분석)

  • 이상식
    • Korea journal of population studies
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    • v.13 no.1
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    • pp.51-80
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    • 1990
  • 한국의 사망력은 높은 수준의 성별 사망력 차이와 중년 남성의 급격한 사망력 상승을 그 구조적 특성으로 하고 있는데, 이러한 한국인 사망력 구조의 특이성은 직접적으로는 사망원인의 성별, 년령별 차별적 역활에 기인하며 간접적으로는 이들 원인의 차별성을 초래하는것으로 추정되는 경제개발기간동안의 사회, 경제 및 공공정책상의 변화 및 생활습관의 차이에서 기인된다고 보아진다. 본 연구에서는 이들 차이를 결과짓는 여러 요인들을 중심으로 한국인의 사망력 구조상에서 나타난 년령별 및 성별특성을 분석하는데 그 주요점을 두었다. 1985년 경제기획원 조사통계과에 의해 집계된 사망원인통계자료는를 활용하여 한국인의 사망력 구조의 특성을 사망원인과 관련시켜 연구분석한 결과는 다음과 같이 종합될수 있다. 첫째, 40대 이후 남성의 높은 사망력에 의거한 요인들은 뇌혈관질환, 고혈압성질환, 암질환 및 기지 심질환 및 간의 악성신생물 순으로 중요하게 나타났다. 둘째, 0세에서의 남녀간의 기득개념의 차이는 차이는 초년 또는 청년층에서의 남녀간의 사망력 차이에서 보다는 40대 이상의 중장년층에서의 남녀간의 사망력 차이에서 비롯되었으며, 뇌혈관 질환, 악성간질환 및 고혈압성 질환, 간의 악성 신생물,및 기타 심질환 및 간의 악성 신생물 질환들이 중장년층에서의 남녀간의 사망력 차이를 결정하는데 주역활을 하고 있는 것으로 나타났다. 세째, 위의 년령간의 및 남녀간의 사망력 수준의 차이를 결정짓는 주요한 사회적 간접요인들로는 첫째, 사회.경제개발과 함께 이어 병행되어온 보건정책들이 즈로 어린이 또는 여성에 편향된 결과 였으며, 둘째,환경적 요소로서 중년 남성들의 Social stress, 운동부족과 관련된 질병들과 공해, 먼지, 유해화학물 가스 등 산업재회와 관련된 질병들에 의한 사망률이 높으며, 세째, 행위적 요소로서 음주와 흡연과 관련된 질병들에 의한 중년 남성의 사망률이 높은것들로 요약될수 있다. 중년 남성의 높은 사망률은 기술적,사회적 경험이 축적된 노동력의 상실로서 국가적 손실이 크며, 고 년령층 인구의 구조적 측면에서도 성의 불균등을 초래하여 미혼 여성의 증가등 사회적인 기반문제의 주요한 요인이 되므로서 그 중요성은 지대하다고 할수 있겠다. 그러므로 이 문제는 국가적 사회적 차원에서 해결이 시급하며 그 해결책으로는 지금 까지 도외시 되어 왔던 중년 남성의 건강을 위한 프로젝트의 실지와 함께 이들에게 노출되어 왔던 운동 부족, 사회적 스트레스 및 산업재회의 해소 내지 제거에 대한 방안들이 연구 되어야 하겠다. 한편 음주 및 흡연등의 개인행위적 습관의 개선을 위한 사회 계몽활동의 추진 및 건전한 스트레스 해결책의 개발이 중요하다고 하겠다.

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Physicochemical Characteristics of CDPF according to Ash a Cleaning agent (Ash 세정제에 따른 CDPF의 물리화학적 특성)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.641-647
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    • 2017
  • In order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the physicochemical properties according to ash cleaning agents of CDPF for Diesel Engines. Penetrating agents with strong penetration into ash and a surfactant component to mix water and oil were prepared properly. The cleaning characteristics of S1 sample were good. Washcoat loss rate of S1 sample was lower by about 2.2% because of less KOH component and lower Na2SiO3 content. Washcoat loss rate of S4 sample with an added KOH and Na2SiO3 components by penetration agents was increased by about 13%. In terms of less than about 13% of CDPF's washcoat loss rate, it was able to reduce the harmful gas components.

Improment of Diesel Combustion using multiple injection under Cold Start Condition (냉시동 조건에서 디젤 연소 특성 및 연소 개선에 대한 연구)

  • Lee, Haeng-Soo;Lee, Jin-Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.711-717
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    • 2017
  • Startability and harmful emissions are the main issues in diesel engine development under cold conditions. The characteristics of combustion with multiple injection were investigated under cold start conditions. For quantitative analysis, the in-chamber pressure profile was measured and combustion visualization using direct imaging was accomplished. With multiple injection, the peak in-chamber pressure and heat release rate were increased compared to single injection. In addition, the period of flame luminosity detection was shortened using multiple injection. Combustion by main injection was improved with an increase in heat released by pilot combustion when the pilot injection quantity was increased. Finally, an increase in injection pressure also showed the possibility of combustion improvement. On the other hand, an increase of in the pilot injection quantity and injection pressure can cause an increase in harmful emissions, such as HC and CO due to wall wetting. Therefore, more sensitive calibration will be needed when applying a multiple injection strategy under cold start conditions.

A Study on the Automatic Seam Tracking of Triangular Wave Form (삼각파 형태의 용접선 자동추적에 관한 연구)

  • Bae Cherl-O;Kim Hyun-Su;Ahn Byong-Won
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.2 s.25
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    • pp.151-155
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    • 2006
  • In these days, welding is the most commonly used metallic connection technology and also is the fundamental production technology of the modem industrial, which is used in various areas of the industrial fields, such as shipbuilding, automobiles, airplanes and plant facilities. However welding process produces strong light, electric currents, and fume gases etc., and the welding automation is not so easy compared to the other works of manufacturing industries which produce the standardized products in large quantities. So it is difficult to weld and detect the all kinds of seams automatically by a specific sensor. In this paper the sensor applying strain gauges is used to detect the seams of triangular wave form. With the auto carriage having the sensor we proposed the experiment to weld and track the seam automatically.

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Evaluation on th e Wear Fit and Activity of Emergency Escape Breathing Devices for Ship Accidents (선박사고용 호흡구난장비의 착용성 및 활동성 평가 연구)

  • Noh, Jae-Hyeon;Park, Yong-Hwan
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.79-84
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    • 2019
  • The use of emergency escape breathing devices (EEBD) is strongly required to protect against toxic gas or flooding caused by ship fires or accidents. Recently developed domestic EEBD products only satisfy the basic performance requirements, but no wear fit and activity performance evaluation has been done for real usage. In this study, the global level test requirements for wear comfort and activity of EEBDs were developed and the open and closed type of domestic EEBD products were evaluated. Poor visibility, longer wear time, breathing resistance, and hose obstruction in an open type and canister obstruction, weight unbalance, and an invisible black breathing bag in the closed type EEBD were estimated to be the main problems that need to be improved.

A Study on the development of Explosion-proof type's the terminal box of the ventilator with the control of wind volume and operating time (풍량 및 운전시간 제어 방폭 배풍기 인버터 단자함 개발에 관한 연구)

  • Yoo, DongJoo
    • Journal of Convergence for Information Technology
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    • v.8 no.6
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    • pp.187-192
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    • 2018
  • This thesis is about the study of inverter terminal boxes in a explosion proof type exhaust fan that can control wind volume and operating time. In Korea, there is no ventilator to adjust the amount of wind and operating time when working in poor conditions. The purpose of the project is to create a explosion terminal box that can control the operating time and wind speed of a suitable explosion ventilator in hazardous environments. The two explosion-proof switches allow the operation time to be driven 1 hour, 3 hours and continuous time, and the speed of the induction motor rotation was set in 3 stages at 2000 rpm, 2600 rpm and 3000 rpm to control the volume. The tested motor used a half-horsepower barrier three-phase induction motor and a full-bridge inverter to set the desired flow rate and operating time.

Effective Removal of Gaseous BTEX Using VPB During Treatment of Briny Produced Water (VPB를 이용한 효율적인 Gas 상태의 BTEX 제거에 관한 연구)

  • Kwon, Soondong
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.167-177
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    • 2011
  • Billions of barrels of briny produced water are generated in the United States every year during oil and gas production. The first step toward recovering or reusing this water is to remove the hazardous organics dissolved in the briny produced water. Biological degradation of hazardous volatile compound could be possible regardless of salinity if they were extracted from briny water. In the current work, the effectiveness of a vapor phase biofilter to degrade the gas-phase contaminants (benzene, toluene, ethylbenzene and xylenes, BTEX) extracted from briny produced water was evaluated. The performance of biofilter system responded well to short periods when the BTEX feed to the biofilter was discontinued. To challenge the system further, the biofilter was subjected to periodic spikes in inlet BTEX concentration as would be expected when it is coupled to a Surfactant-Modified Zeolite (SMZ) bed. Results of these experiments indicate that although the BTEX removal efficiency declined under these conditions, it stabilized at 75% overall removal even when the biofilter was provided with BTEX-contaminated air only 8 hours out of every 24 hours. Benzene removal was found to be the most sensitive to time varying loading conditions. A passive, granular activated carbon bed was effective at attenuating and normalizing the peak BTEX loadings during SMZ regeneration over a range of VOC loads. Field testing of a SMZ bed coupled with an activated carbon buffering/biofilter column verified that this system could be used to remove and ultimately biodegrade the dissolved BTEX constituents in briny produced water.