• Title/Summary/Keyword: 유해시료

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Determination of Trace Elements in $PM_{2.}5/PM_{10}$ of Daejeon Region using Neutron Activation Analysis(II) (중성자 방사화분석에 의한 대전지역의 $PM_{2.}5/PM_{10}$ 농도 및 미량원소의 측정(II))

  • 문종화;박광원;김선하;정용삼
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.219-220
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    • 2002
  • 대기환경에 대한 정보의 파악은 환경연구의 기본이 된다. 유해원소 및 미량원소에 의한 환경오염과 그로 인한 인체건강에 대한 영향은 인간생활에 심각한 문제가 되므로 대기, 수질, 토양 등의 환경시료 중의 농도를 정확히 측정하는 것은 매우 중요한 일이다. 중성자방사화분석법은 핵반응을 통해 생성시킨 방사성동위원소로부터 방출되는 방사선을 검색하여 절대적으로 성분원소를 정량하는 핵분석기술(Nuclear Analytical Techniques)중의 하나로서 소량의 시료로부터 미소량원소의 비파괴, 동시다원소분석이 가능하고 분석감도($10^{-3}$-$10^{-7}$$\mu\textrm{m}$)가 탁월한 분석기술이다. (중략)

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A Study on the Investigation and Combustibles Test of Combustion in Welfare Facilities of Handicapped (장애인 복지시설의 주요가연물 조사 및 연소실험에 관한 연구)

  • Son, In-Tea;Seo, Dong-Goo;Hong, Hae-Ri;Kwon, Young-Jin
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.11a
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    • pp.314-317
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    • 2011
  • 최근 국내 장애인 복합시설의 증가와 함께 많은 사고 사례가 발생하고 있다. 하지만 장애인 시설 화재시 재실자가 장애인으로 비장애인 보다 피난 효율이 저하되어 수 많은 인재가 발생하고 있다. 따라서 장애인시설 피난 방화와 관련하여 강화된 규정이 필요하고 많은 연구가 이루어져야 할 것이다. 이에 따라 국내 장애인복합시설을 대상으로 가연물 조사와 Cone Calorimeter 실험을 통해 화재하중과 가연물 연소성상 등을 연구 분석한 결과 장애인 시설의 화재하중이 공동주택보다 높다는 것을 확인하였다. Cone Calorimeter 실험을 통해서 6개 시료 중 4개의 시료가 기준치 이상의 발열량을 보였고, 방염블라인드의 경우 Co, $CO_2$ 유해연기의 검출량이 기준치 이상으로 그 위험성을 확인 할 수 있었다.

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Determination of Trace Elements in $PM_{2.5}/PM_{10}$ of Daejeon Region using Neutron Activation Analysis(III) (중성자 방사화분석에 의한 대전지역의 $PM_{2.5}/PM_{10}$ 농도 및 미량원소의 측정(III))

  • 문종화;김선하;박광원;임종명;정용삼
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.328-329
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    • 2002
  • 대기환경에 대한 정보의 파악은 환경연구의 기본이 된다. 유해원소 및 미량원소에 의한 환경오염과 그로 인한 인체건강에 대한 영향은 인간생활에 심각한 문제가 되므로 대기, 수질, 토양 등의 환경시료 중의 농도를 정확히 측정하는 것은 매우 중요한 일이다. 중성자방사화분석법은 핵반응을 통해 생성시킨 방사성동위원소로부터 방출되는 방사선론 검색하여 절대적으로 성분원소를 정량하는 핵분석기술(Nuclear Analytical Techniques)중의 하나로서 소량의 시료로부터 미소량원소의 비파괴, 동시다원소분석이 가능하고 분석감도가 탁월한 분석기술이다. (중략)

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Pollution Characteristics of Hazardous Elements for Roadside Dust in Gwangju City, Korea (광주광역시 도로변 분진에 대한 유해원소의 오염특성)

  • Lee, Jang-Jon;Park, Young-Seog;Kim, Jong-Kyun;Han, Min-Su
    • Economic and Environmental Geology
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    • v.40 no.3 s.184
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    • pp.263-275
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    • 2007
  • The purpose of this study was to show the pollution characteristics of hazardous elements from roadside dust in the Gwangju city. We collected 47 samples from November to December in 2004 and separated four groups such as residential area, industrialized area, downtown area and heavy traffic area fer characteristics comparison on hazardous elements. Roadside dust mostly consisted of quartz, albite, microcline, muscovite in XRD analysis. Content of hazardous elements varied: As $3.4{\sim}11.9 ppm$, Cd $0.2{\sim}28.2 ppm$, Co $32{\sim}526 ppm$, Cr $25{\sim}526 ppm$, Cu $11{\sim}375 ppm$, Ni $14{\sim}247 ppm$, Pb $13{\sim}413 ppm$ and Zn $101{\sim}972 ppm$. Average contents of hazardous elements of Zn>Cu>Pb>Cr>Co>Ni>Cd. Content of hazardous elements was low in residential area, whereas that of heavy metal was much the same in both in heavy traffic area. Content of hazardous elements such as Cd, Co, Cr, Cu, Ni, Pb, Zn was found to be particularly high in industrialized area. According to these results it was possible to presume that industrialized area was affected by industry activity such as machinery, petrochemical, automobile and electronics industry. The SEM analysis, detected Pb, Cr, Ni, and Fe particles in samples of industrialized area contaminated by industry activity. The correlation coefficient table resulted from the samples of roadside dust showed that there was same direction increase of content between elements. In other words, when the content of Cd increase, Cr and Ni increase, as Cr increase, Cu and Ni increase, as Cu increase Ni increase and Pb increase Zn increase. Based on these results it was possible to predict and interpret similar contamination patterns in this study.

농업용 폐비닐 열분해 파생물질의 조성분석과 유해성 평가

  • 신혜순;강주연;김미경;정기화;심성훈
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.151-151
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    • 2003
  • 토양에 방치된 농업용 폐비닐은 거의 분해가 되지 않으며, 수분과 공기의 유통을 차단하고 토양 내 미생물들의 흐름을 막아 토양을 더욱 황폐화시키게 된다. 불법적인 소각 때는 산불의 위험에다 다이옥신, 염소 및 염화수소가스 등을 배출해 대기오염을 유발시킨다. 폐비닐을 열분해과정으로 처리하여 아주 작은 입자로 미분쇄하고 겔상태로 용융된 원료물질속으로 완전히 균일하게 혼합하여 골재로 활용하는 과정에서 가스상과 액상의 여러 가지 중간생성물질이 발생하게 되며, 농약의 살포에 의한 잔류농약 둥 인체에 유해가능한 요소들이 있을 수 있다. 본 연구에서는 개발공정이나 제품에서 인체에 영향을 미칠 수 있는 물질에 대하여 유해성을 평가하고 용응 겔 및 가스와 오일에 함유된 화학성분을 분석하였기에 보고하고자 한다 시험동물의 혈액생화학적 검사에서는 농업용 폐비닐물질 및 열분해 파생물질의 혈청 Cholesterol, 혈청 Alanine aminotranseferse와 Aspartate aminotransferse, Albumin 수치, LDH, Glucose, Uric acid, A/C 비 등의 생화학적 활성도를 측정한 결과들에서는 농업용 폐비닐물질을 투여한 시험군에서 나타난 결과와 비교하여 열분해 파생물질을 투여한 시험군에서 나타난 결과가 감소된 통계결과를 보였다. 이 결과들은 농업용 폐비닐물질을 투여한 시험군보다 열분해 파생물질을 투여한 시험군의 외부독성물질 투여에 의한 생체독성의 영향과 생체에 가해진 스트레스강도가 작았음을 의미하는 것이다. 잔류농약분석에서는 시료로부터 농약을 추출하는 용매추출과정, 시료추출물 중 공존하는 방해성분을 제거하는 정제과정, 폐비닐물질 및 열분해 파생물질 성분을 100mg/kg 이상군의 투여 후 시험동물의 부검시 모든 투여군에서 독성소견이 인정되지 않았다. 이와 같은 결과로 열분해 및 연소과정에서 발생하는 파생물질의 분석결과를 응용하여 대기오염을 방지하고 인체 유해물질을 차단하는 공해 방지 설계의 기초자료를 제안하고자 한다.

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A study on the screening of toxic materials by HPTLC and GC/MS (HPTLC 및 GC/MS를 이용한 유해화학물질의 스크리닝에 관한 연구)

  • Park, Sung-Woo;Jang, Seong-Gil;Park, You-Sin;Lee, Jin-Hoon;Lee, Sang-Ki;You, Jae-Hoon;Kim, Dong-Hwan;Jin, Kwang-Ho;Kim, Ki-Wook;Kim, Yu-Na;Lho, Dong-Seok
    • Analytical Science and Technology
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    • v.13 no.1
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    • pp.108-120
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    • 2000
  • To perform an effective screening for toxic materials of forensic interest detected in high profile criminal case in biological and environmental samples, we tried to construct a searchable computerized database using HPTLC(High Performance Thin Layer Chromatography) and GC/MS. Retardation factor($R_f$) values and UV spectral data of HPTLC were investigated for 160 pesticides, 34 chemicals and 39 explosives of standard grade. The data were compiled in a library. We also analyzed 112 pesticides, 31 chemicals and 17 explosives and 57 volatile organic compounds(VOCs) by GC/MS. The data for RT and characteristic mass ions were also compiled in a library.

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Study on the storage stability of allyl chloride and carbon disulfide in tedlar bags (테들라 백에서의 알릴클로라이드와 이황화탄소 보존성 연구)

  • Lee, Jinseon;Kim, Kijoon;Yoon, Junheon;Cho, Seokyeon
    • Analytical Science and Technology
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    • v.26 no.6
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    • pp.381-386
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    • 2013
  • The sixty nine chemicals that are closely linked to chemical accident are designated as the substances requiring preparation for accidents and managed for public health under the Toxic Chemicals Control Act. In this study, storage stability of allyl chloride (AC) and carbon disulfide (CD), which are highly inflammable and volatile in tedlar bags, was studied for gaseous chemicals sampling. Storage stability was studied considering storage temperature ($2^{\circ}C$, $25^{\circ}C$), chemical concentration (low conc. ppm, high conc. ppm) and storage time (0, 48, 96, and 144 hr). Also, the stability of bags containing one type of chemical substance and the bags containing a mixture of chemicals was compared against each other. As a result, two chemicals showed decreasing storage stability based on storage time. Also two chemicals presented statistical significance of concentration and mixing type.

Heavy Metal Analysis of Inhabitants from City of the Seoul, Korea (서울지역 거주 성인 모발의 유해 중금속 함량 분석)

  • Im, Eun-Jin;Ha, Byung-Jo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.35 no.1
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    • pp.27-32
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    • 2009
  • Human hair is an excretory system for trace metals and thus metal content in human hair can reflect the body status. The investigation of trace elements in human hair has been correlated with the diagnosis of various diseases as well as the monitoring of deficiency statues in nutrition. Many chronic diseases may be related to mineral status, some may be related to toxic mineral. Hair samples were collected from 120 inhabitants of the city of Seoul, Korea. In this study the concentrations of 10 elements (Hg, Pb, Cd, Al, As, U, Bi, Sb, Ba, Be) in hair were determined by inductively coupled plasma mass spectroscopy (ICP-MS). The conclusions showed that people in Seoul, Korea were affected by some kinds of toxic minerals. The Hg concentrations of male are higher than those of female and reference range. The mean concentration of Sb was higher in the female than male and reference range. In age distribution, the mean concentration of Hg was in 40's are higher than 20's and 30's and reference range. The concentrations of Al were the highest in the 20's. After analyzing, we concluded that a compounded treatment should be conducted, which considers the variety of factors related to detoxification.

Diversity and Mycotoxin Production of Aspergillus flavus in Stored Peanut (저장 땅콩에서 분리된 Aspergillus flavus의 다양성 및 독소생성능)

  • Choi, Jung-Hye;Nah, Ju-Young;Lee, Mi-Jeong;Lim, Su-Bin;Lee, Theresa;Kim, Jeomsoon
    • The Korean Journal of Mycology
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    • v.49 no.3
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    • pp.303-313
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    • 2021
  • Peanuts in storage were estimated for mycotoxigenic fungi and mycotoxins. Peanut samples collected from storages in Gochang were mainly contaminated with Fusarium (17.2±28.0%), Penicillium (12.4±28.0%), and Aspergillus (8.0±7.6%). Other genera, including Talaromyces, Rhizopus, Rhizoctonia, Trichocladium, Clonostachys, Mucor, Chaetomium, Trametes, Epicoccum, and Humicola, were also found. Although aflatoxins were not detected in the peanut samples, 29 strains of Aspergillus flavus were identified using molecular marker genes. Among them, 17 selected isolates produced aflatoxins in solid culture media ranging from 0.61-187.82 ㎍/kg. All of them could produce both aflatoxin B1 and B2 and some (n=5) produced additional G1, G2, or both. This study is the first report that A. flavus stains obtained from Korean stored peanut are aflatoxigenic.

Monitoring of Pathogenic Bacteria, Heavy Metals, and Pesticide Residues in Commercial Edible Dry Flowers (시판 23종 꽃차의 유해세균, 중금속 및 잔류농약 평가)

  • Lee, Yun-Seo;Lee, Dong-Hee;Hwang, Eun-Kyung;Sohn, Ho-Yong
    • Journal of Life Science
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    • v.32 no.6
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    • pp.438-446
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    • 2022
  • Some flowers have a high sensual appeal owing to their unique shape, color, smell, and taste and have been used as functional food and oriental medicine. Recently, edible dry flowers (EDFs) have attracted social attention as noble sources of functional teas. In this study, for the risk assessment of EDFs, pathogenic bacteria, heavy metals, and pesticide residues were monitored in 23 types of commercial EDF. No Enterobacteria spp. and Listeria spp. were found in all EDF products. However, common aerobic bacteria (3.24~3.85 Log CFU/g) were found in EDF, namely, Pueraria lobata, Chamaemelum nobile, Acacia decurrens, Rhododendron mucronulatum Turcz, Oenothera lamarckiana, Brassica napus, and Prunus serrulata. Staphylococcus aureus was found in 11 and Salmonella sp. was found in 8 of the 23 EDFs. Considering the cold extraction of EDF for tea and beverages, the regulation of pathogenic bacteria in EDFs is necessary. No heavy metals such as Pb, Cd, Co, Cr, Cu, Ni, and As were found in all EDFs, except the dry flower of Hemerocallis fulva, which contained Pb at 0.08 ppm. Different pesticides and fungicides were found in EDFs, but their concentrations were very low (0.01~0.08 ppm) and below the maximal residue level. Only the dry flower of Chrysanthemum morifolium had a high content of chlorpyrifos (0.215 ppm), which is long-lasting pesticide. Our results suggest that the establishment of EDF regulations for pesticide residue, culture separation between edible and garden flowers, and guidelines for preventing pathogenic microbial contamination are necessary.