• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.11a
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• pp.473-474
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• 2003

최근 수 십 년간 발전소의 연소효율은 급속히 향상되어왔으나 $CO_2$, NOx 등과 같은 온실 유해가스의 제어에 관한 심각한 문제점들을 직면한 상태이다. 발전공정에서 발생되는 온실 유해가스의 저감 방법으로 매체순환식 가스 연소발전 공정이 최근에 새로운 대안으로 제시되고 있다 그러나 매체순환식 가스연소시스템 내부의 bead상 매체입자들이 입자간 혹은 입자와 반응기 벽간의 충돌과 마찰에 의하여 마모가 되게 되고, 그 결과 원하지 않는 량의 마모입자가 배출가스와 함께 배출되게 된다. 세라믹 캔들필터는 고온고압 연소공정 등에서 배출되는 가스내의 입자상 오염물질을 회수 처리하는데 효과적인 장치로써 널리 개발되고 있다. (중략)

• Journal of ILASS-Korea
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• v.23 no.4
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• pp.175-184
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• 2018

Emission characteristics of regulated (NOx, PM, CO, NMHC) and unregulated (VOCs, aldehydes, PAHs) air pollutants were investigated for diesel heavy duty buses equipped with different after-treatment systems (DPF+EGR and SCR) under urban driving cycle. The combustion temperature and the working temperature of SCR catalysts were important to make impact on NOx emissions, whereas PM emissions were low. The alkane groups dominated NMVOCs emissions, making 42.6~59.4% of sum of the NMVOCs emissions. Especially, alkane emissions of DPF+EGR-equipped vehicle included DOC had 14.9~15.5% higher than those of SCR-equipped vehicle due to low efficiency of oxidation catalyst. In the case of individual NMVOCs, n-nonane and propylene emissions highly occupied for DPF+EGR and SCR, respectively. Formaldehyde emissions among aldehydes were the highest and PAHs emissions were hardly detected except naphthalene and phenanthrene. The NMHC speciation has been shown to be the highest of the formaldehyde ranged 20.8~21.5%. The results of this study will be contributed to establish Korean HAPs emission inventory for automobile source.

• Journal of Korean Society for Atmospheric Environment
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• v.7 no.1
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• pp.73-80
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• 1991

인류가 산업발전 등으로 인해 석유등 화석연료를 사용함에 따라 대기오염은 날로 악화되어 1952년 런던스모그 같은 참사를 맞이하였고 이에 각국은 이러한 대기 오염물질을 저감하기 위하여 노력한 결과 대기 오염물질은 낮아지고 있으나 이에 반해 이산화탄소 배출량 증가에 따른 지구 온난화 현상과 오존층 파괴는 지역적인 환경문제에서 번세계적인 환경문제로 확산 전개되고 있다. 특히 산업혁명후 화석연료의 급격한 사용증가로 인한 이산화탄소 배출량 증가는 지구를 온나화시키고 수십년 후에는 환경에 심각한 영향을 주게 되는 것은 의심할 여지가 없는 것으로 이는 지구환경문제 중에서 금회 최대의 과제로 대두되게 되었다. 이에 따라 1985년 UNEP 관리 이사회를 필두로 "지구환경보전에 관한 동경회의", "대기오염 및 기후변동에 관한 노드윅 회의", "백악관회의", "휴스톤 Summit" 등에서 이 문제가 거론되기 시작하여 '90. 8월에는 스웨덴에서 온난화에 대한 과학적 인식과 대책의 메카니즘을 정하기 위한 IPCC 4차 회의가 각국 대표들이 참석한 가운데 정치, 경제, 과학의 문제로 등장하여 우리생활의 근본을 좌우할 다각적인 논의가 진행된 바 있다. 또한 미국, 영국, 일본 등 선진국들의 정상이 모이는 G7 회담 등에서 논의되고 있는 것들 중 정치적인 문제를 제외하고는 환경문제를 가장 많이 다룬다는 외신보도를 우리는 여러번 접한바 있다. 현재 국제적 환경문제로 가장 관심이 집중되고 있는 문제 중 몇가지를 소개하면 우선 <몬트리올의 정서에 의한 오존층 보호>를 들 수 있겠고, 최근 국제 협약 제정을 추진하고 있는 "지구온난화 방지에 관한 기후협약" 그리고 유해폐기물의 국제교역에 관한 "바젤협약"과 함께 새로이 제기된 "생물학적 다양성 협약"등이 거론되고 있으며, 이에 덧붙여 미국의 "자동차배출가스 규제"도 우리나라 산업에 큰 영향을 미칠 것으로 판단된다. 본 논문은 이중 대기와 관련된 오존층 보호와 지구온난화 대책에 대한 국제회의 등에서 현재까지 논의되었거나 토의될 내용에 대하여 기술하고 특히 금년부터 집중적으로 국제협상이 진행될 지구온난화 문제에 대한 최근의 국제동향 우리나라의 입장을 기술하고자 한다.

• Journal of the Korean Wood Science and Technology
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• v.48 no.2
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• pp.253-266
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• 2020

This study selected three types of agglomerated wood charcoal (Agglomerated wood charcoal with charcoal powder, Carbonized wood briquette, Ignition-type of perforated charcoal) that are in circulation in Korea among fuel-type wood products and analyzed the fuel characteristics, harmful substance content, and emissions of air pollutants generated by combustion. The first results showed that charcoal-grilled carbon, which is the raw material of charcoal, produced higher CO than saw-billed carbon. The second result is that the emission standards of air pollutants generated by the combustion of molded wood coal are not up to the emission standards of nitrogen oxides and sulfur oxides in the entire product, compared with the emission criteria of the atmospheric environment preservation method (based on 2019, carbon monoxide: 200 ppm, nitrogen oxides, 150 ppm sulfur oxides: 100 ppm), but the carbon dioxide moulding and carbon dioxide levels were not up. Based on the analysis of combustion gas generated during combustion derived from this study, future research is needed for comparing with the emission standards of pellets, which are wood products for fuel, among the existing biomass burning standards and for reducing carbon monoxide generated during incomplete combustion of agglomerated wood charcoal.

• Journal of Korea Ship Safrty Technology Authority
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• s.27
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• pp.15-24
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• 2009

최근 IMO에서는 온실가스 배출을 규제화 하고자 하는 동향이 있으며 조만간 선박에서 온실가스 배출의 규제가 실현될 것으로 예상된다. 선박에서 배출되는 온실가스는 CO$_2$가 대부분을 차지하고 있으며 세계경제상황에 따른 영향이 고려되지만 지속적으로 증가추세에 있는 CO$_2$를 감소시키기 위한 아국의 대처방안이 필요한 시점이다. 또한 향후 발효될 EEDI를 소개하고 결과적으로 GHG를 저감시키기 위한 방안인 선형개선, 폐열회수시스템, 친환경연료사용기관, SEMP 등에 관한 내용을 다루어 보았다. 이 보고서에서는 GHG를 비롯한 NOx, SOx 및 PM과 같은 유해배출물질을 Top Down방식으로 평가함으로써 선박에서 기인하는 대기오염물질 관련 국내정책 및 해운산업의 장기적인 발전전략에 유용하게 사용될 것으로 기대한다.

• Journal of Korean Society of Transportation
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• v.33 no.4
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• pp.357-367
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• 2015

This study aims to propose integrated management strategies based on the relationship between co-benefits and total benefits of greenhouse gases and air pollutant emissions for establishing a transport and environmental policy. The results show that the integrated management of the following policies: 'Car Free Day' and 'Early Scrapping of Decrepit Diesel Vehicle', which are used for reducing reduce gasoline and diesel, can together reduce both PM and $CO_2$ emissions and increase total benefits. In addition, the integrated management of 'Car Free Day' with environment policies and 'Congestion Charge' with environment policies simultaneously controls the three factors which influence emissions, including travel volume, travel speed and emissions factor, and was found to be effective in terms of co-benefits. This study reduces both air pollutants, which are harmful to health, and greenhouse gas emissions, which influence climate change, and improves the efficiency of policy through the integrated management of policies.

• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.607-618
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• 2017

Harmful air pollutants are exhausted from the various industrial facilities including the coal-fired thermal power plants and these substances affects on the human health as well as the nature environment. In particular, nitrogen oxides ($NO_x$) and sulfur dioxide ($SO_2$) are known to be causative substances to form fine particles ($PM_{2.5}$), which are also deleterious to human health. The integrated system composed of selective catalytic reduction (SCR) and wet flue gas desulfurization (WFGD) have been widely applied in order to control $NO_x$ and $SO_2$ emissions, resulting in high investment and operational costs, maintenance problems, and technical limitations. Recently, new technologies for the simultaneous removal of $NO_x$ and $SO_2$ from the flue gas, such as absorption, advanced oxidation processes (AOPs), non-thermal plasma (NTP), and electron beam (EB), are investigated in order to replace current integrated systems. The proposed technologies are based on the oxidation of $NO_x$ and $SO_2$ to $HNO_3$ and $H_2SO_4$ by using strong aqueous oxidants or oxidative radicals, the absorption of $HNO_3$ and $H_2SO_4$ into water at the gas-liquid interface, and the neutralization with additive reagents. In this paper, we summarize the technical improvements of each simultaneous abatement processes and the future prospect of technologies for demonstrating large-scaled applications.

• Resources Recycling
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• v.11 no.6
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• pp.3-11
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• 2002

Recently, waste printed circuit board (PCB) has significantly increased in its amount due to the rapid development of electronic industries. Since several kinds of noxious materials and also valuable metals are contained in it, the waste PCB is in an urgent need of recycling for the dual purposes for the prevention of environmental pollution and recovery of valuable resources. Also, the catalyst which equipped in the exhaust pipes of automobiles to reduce emission of air pollutants contains precious met-als so that their recovery from the waste auto-catalysts is required. In this study, the recovery of valuable metals from waste PCB and auto-catalyst by arc furnace melting process has been investigated, which is known to be very stable and suitable f3r less production of pollutants due to its high operating temperature. The effect of the kind of flux on the recovery of precious metals was examined by using quicklime, converter slag, and copper slag as the flux. In addition, the influence of direct and alternating current and the applying direction of direct current has been investigated. It was observed that using converter or copper slag as a flux was more desirable for a higher efficiency in the precious metal recovery compared with quicklime. For the effect of current, application of direct current taking the bottom as a negative pole generally showed a better efficiency for the extraction of valuable metals from waste PCB, which was also observed for the case of waste auto-catalyst. The average recovery of precious metals from both wastes by arc furnace melting process was very high, which was up to in the range of 95～97%.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.651-656
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• 2005

Toluene, which is emitted from textile process, is considered as an important hazardous air pollutant. In this study, the catalytic activity of transition metal oxides(Cu, Mn, V, Cr, Co, Ni, Ce, Sn, Fe, Sr, Cs, Mo, La, W, Zn)/${\gamma}-Al_2O_3$ catalysts was investigated to carry out the complete oxidation of toluene. The metal catalysts were characterized by XRD-ray diffraction), FE-SEM(Field Emission Scanning Electron Micrograph), BET(Brunauer Emmett Teller) method and TPR(Temperature Programmed Reduction). Among the catalysts, Cu/${\gamma}-Al_2O_3$ was highly promising catalyst for the oxidation of toluene. From the BET results, it seems that the catalytic activity is not correlated to the specific surface area. XRD results indicated that most of catalysts exist as amorphous phase. From the FE-SEM results, it was observed that copper on ${\gamma}-Al_2O_3$ surface was well dispersed among catalysts. The catalytic activity for the toluene oxidation could be explained with that metal oxide catalyst was dispersed well over supports and was attributed to reduction activity in surface of catalysts.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.702-708
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• 2018

Volatile organic compounds (VOCs), as a significant air pollutant, is generated mainly from the burning of fossil fuels, building materials using painting, etc. The inhalation of a certain amount of VOCs can be deleterious to human health, e.g., headaches, nausea and vomiting. In addition, it can also cause memory loss and even increase the rate of leukemia. Therefore, as one of the methods for reducing VOCs in air, polyacrylonitrile/fly ash (PAN/FA) composite nanofibrous membranes were fabricated by electrospinning. To observe their VOCs adsorption capacity, the morphological structure of PAN/FA nanofibrous mats was investigated by field emission scanning electron microscopy (FE-SEM), and the VOCs (chloroform, benzene, toluene, and xylene) adsorption capacity of PAN/FA membranes were tested by gas chromatography/mass spectrometry (GC/MS). The results indicated that the PAN nanofiber containing 40 wt. % FA powder had the smallest fiber diameter of 283 nm; they also showed the highest VOCs adsorption capacity compared to other composite membranes.