• Analytical Science and Technology
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• v.7 no.2
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• pp.233-236
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• 1994

To evaluate the emulsion stability indices of W/O emulsion system, we developed the simple and sensitive "VOLUMETRIC METHOD". This technique involved the first step of homogenizing the milk fat-water system with Ultra-turrax T25, then the volume of the added water phase was measured immediately. After quiescent incubation in test tubes at room temperature for a desired storage time, the bottom volume of the separated water layer was measured. And then "emulsion stability index(ESI)" was calculated by the following equation : $ESI=(1-V_s/V_a){\times}100$, where $V_a$ means the volume of the added water in the W/O emulsion and $V_s$ represents the volume of the separated water in the W/O emulsion for a desired storage time. The emulsion stability indices of W/O emulsion system at sorbitan trioleate, span 60, and tween 20 were $95.4{\pm}1.8$, $56.1{\pm}2.8$, and $41.6{\pm}2.2$ respectively. Furthermore, the differences between "VOLUMETRIC METHOD" and "Titus et al method" were less than 5.0 of ESI Value.

• Journal of ILASS-Korea
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• v.9 no.3
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• pp.29-34
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• 2004

To investigate characteristics and micro-explosion of single-droplets of emulsified fuel, water is mixed with diesel oil by using ultrasonic energy fuel feeding system. The fuel characteristics is analysed through H-NMR spectrum and micro-explosion phenomena of the emulsified fuel is also investigated. The life times of droplets of conventional diesel fuel, ultrasonic energy added diesel fuel and emulsified fuel we obtained additionally. According to this study, the micro-explosion phenomena of single-droplets happen in atmospheric pressure condition, a curve form of emulsified fuel's life tim is different from diesel fuel's one and the change of chemical structures is a cause of ultrasonic-energy-added diesel fuel effect.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2000.11a
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• pp.91-98
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• 2000

The fuels of water-in-oil emulsion have a potential of reducing PM(Particulate Matter) and NOx emissions, and increassing combustion efficiency in the furnaces and the burners. For making the most of the beneficial of the secondary atomization due to the microexplosion, the water droplets distributed in the oil must have the optimal sizes. The purpose of this paper is to investigate the water droplet size distribution characteristics of the different types of the static mixers. For analysing the size distribution characteristics efficiently, image analysis system was constructed and an appropriate image processing algorithm was developed. Two kinds of static mixers: Kenics type and RF type, were tested. As a results, RF type static mixer shows a better characteristics in the mean drop sizes, particularly in the condition of high water content.

• Journal of ILASS-Korea
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• v.10 no.3
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• pp.9-16
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• 2005

To investigate spray and combustion of emulsified fuel of W/O type, we mixed water with light oil by using ultrasonic energy adding system. We measured the SMD of sprayed droplet to find atomization characteristics of emulsified fuel with using the Malvern 2600D system. Major parameters are the weight ratio of water($0{\sim}30%$ by 10%) in emulsified fuel injection pressure(lobar), and the measurement distance($10{\sim}100mm$ by 10mm). Combustion visualizing system is made up commonly used boiler system and digital camera 1/500s to investigate combustion phenomena. As a result, the more water contents increased, the more SMD increased. The water particle of emulsified fuel made short flame in continuos spray combustion phenomena because of micro explosion.

• Journal of Advanced Marine Engineering and Technology
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• v.25 no.4
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• pp.904-911
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• 2001

The fuels of water-in-oil emulsion have a potential of reducing PM(Particulate Matter) and NOx emissions, and increasing combustion efficiency in the furnaces and the burners. For making the most of the beneficial of the secondary atomization due to the microexplosion, the water droplets distributed in the oil must have the optimal sizes. The purpose of this paper is to investigate the water droplet size distribution characteristics of the different types of the static mixers. For analysis the size distribution characteristics efficiently, image analysis system wes constructed and an appropriate image processing algorithm was developed. Two kinds of static mixers: Kenics type and RF type, were tested. As a results, RF type static mixer shows a better characteristics in the mean drop size, particularly in the condition of high water content.

• Journal of ILASS-Korea
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• v.9 no.3
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• pp.22-28
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• 2004

This study is concerned about the characteristics of ultrasonic-energy-added W/O type emulsified fuel. The distilled water was mixed with diesel oil by using ultrasonic energy fuel feeding system and then the SMD of sprayed droplets was measured to find out atomization characteristics of emulsified fuel by using the Malvern 2600 system. The capacitance value was measured to verify stability of the same specimen by using the digital LCR meter, EDC1630 additionally. The main results are as follows; 1) The more measuring distance increases between one hole nozzle tip and analyser bearm, the more SMD increases. 2) The more water content increases, the more capacitance value increases depending on the time. Main Parameters of the study are the amount of water content $0{\sim}30%$ by 5% in emulsified fuel, and the measurement distance, $20{\sim}140mm$ by 10mm or 20mm between nozzle tip and analyser beam.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.9
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• pp.945-951
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• 2012

A water emulsion fuel can be used to reduce soot and NOx emissions simultaneously because it has a lower combustion temperature and better fuel atomization owing to the evaporative latent heat and microexplosion of water. Moreover, it can be used without making special modifications to conventional diesel engines. Therefore, this fuel has attracted considerable research attention. In addition, lower-grade fuels are being considered for use in conventional engines because of an increase in oil prices. In this study, we investigated the combustion and exhaust characteristics of MDO (marine diesel oil), which has a lower grade than common diesel oil, and ME (MDO water emulsion) under various test conditions in an automotive diesel engine.

• Applied Chemistry for Engineering
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• v.28 no.2
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• pp.186-192
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• 2017

In this study, water in oil (W/O) emulsion fuel was prepared with surfactant mixture of OIMS90 and NP12 by varying ratio of water to bunker-C oil, surfactant concentration and composition, emulsification time, stirring intensity, temperature and mixing time. Diesel engine performance and exhaust emissions were measured and analyzed with prepared emulsified fuel and compared with those measured using bunker Coil. The results indicated that bunker C emulsion fuel stabilized by surfactant mixture of OIMS90 and NP12 is efficient in reducing emissions of particulate matter, $NO_2$, CO, $CO_2$ and $SO_2$. The biggest reduction in exhaust emission was achieved by using emulsion fuel prepared by OIMS90/NP12 = 4 : 6, 500 ppm of total surfactant concentration and 10% water content at $80^{\circ}C$. Boiler efficiency test measured with emulsion fuel showed excellent energy efficiency compared with bunker C oil.

• Korean Journal of Food Science and Technology
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• v.35 no.3
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• pp.423-428
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• 2003

Stabilities of W/O emulsions containing eugenolchitosan (EuCs) prepared from chitosan and eugenol were compared to determine the optimal conditions for the ratio of water (core phase) to corn oil (continuous phase), the concentration of EuCs, storage temperature, and the extent of homo-mixing. The optimal ratio of water to corn oil was 2:3 (w/w). The effects of EuC concentrations, and singular vs. binary system of emulsifiers on the storage stability of the emulsion were investigated with EuCs and polyoxyethylene sorbitan monolaurate. The emulsion was stable, showing more than 95% emulsion stability index (ESI) value, when the concentration of EuCs was more than 0.18% (w/v). ESI value of binary emulsifier system was almost equal to that of singular emulsifier system at the concentration of 0.18% (w/v). At this singular emulsifier system, the W/O emulsion formed by EuCs had ESI value of 100%. The optimal concentration of EuCs was determined as 0.18% (w/v). The highest stability of the emulsion was obtained from the homo-mixing at 11,000 rpm for 10 sec and the storage temperature ranging $25{\sim}65^{\circ}C$. EuCs produced from this study was mutagenecity-negative on Ames test and contained no heavy metal ions.