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폐윤활유 정제기술

  • 박상도
    • Tribology and Lubricants
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    • v.10 no.2
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    • pp.20-29
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    • 1994
  • 우수한 기유와 첨가제들이 혼합된 양질의 윤활유라 할지라도 윤활유는 사용중에 차차 변질하여 그 성상이 저하하게 되는데 이와 같은 윤활유의 열화현상은 윤활유 자신이 일으키는 내부변화 즉, 화학변화와 외부적 요인에 의하여 생기는 윤활유의 오염 등에 기인하는 것으로 알려져 있다. 열화현상이 발생되면 폐윤활유는 주기적으로 교체하여야 하는데 소모성 물질이 아닌 윤활유는 국내에서 93년도 기준 년간 약 750,000 k1의 윤활유가 사용되어지고 있다. 윤활유 사용으로부터 발생된 폐윤활유는 첫째, 원유내의 윤활 성분이 10~15%인데 비하여 폐윤활유는 약 85% 이상의 윤활성분이 포함되어 있어 윤활기유의 회수율이 높으며 둘째, 폐윤활유내의 불순물은 윤활성분과는 물리화학적 성질이 달라 쉽게 분리될 수 있으며 셋째, 폐윤활유는 윤활유로서의 부적당한 물질은 이미 열화나 산화에 저거된 상태이므로 재정제가 용이하다는 장점이 있어 폐자원 재활용 측면에서 오래전 부너 관심의 대상이 되어왔다.

The Effect of Low Erucic Acid Rapeseed Oil for the Preparation of Mayonnaise on Quality Characteristics (마요네즈 제조시 품질특성에 미치는 저에루신산 유채유 혼합의 영향)

  • Kim, Jae-Wook;Son, Yang-Do;Hong, Ki-Ju;Yoo, Moo-Yeong;Jeong, Gae-Whan;Hur, Jong-Wha
    • Korean Journal of Food Science and Technology
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    • v.27 no.3
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    • pp.298-302
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    • 1995
  • This study was performed to know the availability of low erucic acid rapeseed oil (LEAR oil) for vegetable oil in commercial mayonnaise preparation. Mixed oils (blended soybean oil with LEAR oil) were prepared and mayonnaises were prepared with these oils and then compared the quality characteristics of these samples. The oxidative stability of vegetable oil with Rancimat test showed that LEAR oil was higher stability than soybean oil, and became higher with increase of LEAR oil ratio. Quality characteristics of mayonnaises with these oils showed that mayonnaise with mixed oils was preferred to that with LEAR oil itself. Furthermore, the quality characteristics of mayonnaises with mixed oils of soybean oil $(20{\sim}60%)$ plus LEAR oil $(80{\sim}40%)$ were better than those of mayonnaise with soybean oil solely.

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Oxidative Stability and Flavor Compounds of Sesame Oils Blended with Vegetable Oils (식물성유를 첨가한 참기름 혼합유의 산화 안정성과 향기 성분)

  • Joo, Kwang-Jee;Kim, Jin-Ju
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.984-991
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    • 2002
  • Oxidative stability and flavor of sesame oil blended with canola oil (Ca), corn oil (Co), and soybean oil (Sb) at ratios of 90 : 10, 70 : 30, and 50 : 50 (w/w), respectively, were evaluated. Oxidative stability of sesame oil increased with the addition of vegetable oils (10, 30, and 50% of Ca and Co, and 10% of Sb). Pyrazines, pyrroles, pyridines, and thiazoles, good contributors to the characteristic flavor of sesame oil, were also found in sesame oil blended with vegetable oil. The sensory evaluation showed that no difference was observed between sesame oil and sesame oil blended with 10% of Ca, Co or Sb, which showed higher oxidative stability.

합성유의 개발 동향

  • 김광민
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1992.06a
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    • pp.21-59
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    • 1992
  • 1980년대에 접어들면서 반합성유, 합성유가 산업전반에 광범위하게 적용되기 시작하였으며 많은 화학회사들이 꾸준히 성장하는 합성유 추세에 대해 관심을 가지게 되었다. 또한 광유와 합성유의 가격차가 생각보다는 크지 않다는 이유로, 광유와 합성유를 혼합하면 좀더 경제적일 수 있다는 판단하에 꾸준히 개발되고 있는 추세이다. 좀더 구체적으로 말하면, 1980-1985년 사이에는 예상보다는 성장율이 저조하였다. 그 이유는 합성유 또는 반합성유 판매로부터 이익을 얻으려는 수많은 윤활유 제조사들이나, 기계제조업체, 소비자들에게 어떤 합성유가 가장 경제적이며 우수한 것인지에 대한 접합성을 놓고 치열한 경쟁을 벌였기 때문이다. 제품별 합성유 현황을 좀더 자세히 알기 위해서는 우선 합성기유에 대한 이해가 필요하다.

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The Study on the Oxidative Stability of Mixed Rapeseed oil with Palm oil (팜유 혼합유채유의 산화안정성에 관한 연구)

  • 현영희;안명수
    • Korean journal of food and cookery science
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    • v.9 no.4
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    • pp.317-322
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    • 1993
  • Two kinds of simple and interesterfying mixed rapeseed oil were prepared according to add 30%, 50% and 70% of coconut and palm oil, then the physicochemical propecties such as the tedency of oxidation, foaming activity were Investigated. The initial AV and POV of interesterifyung mixed rape-seed oils were higher than those of simple mixed oils, but the tendencies of oxidation were similar. The intial value of IV interesterfied rapeseed oils was added in simple mixed rapeseed oil, Induction period were increased about 2.4~4 times. Induction period of intereterifyng mixed oils added palm ell increased about 2~3.2 times. While the foaming Buantity of interesterifing mixed rapeseed oils with palm oil were lower about 28~40% than those of the simple mixed rapeseed oils.

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심해 침몰유조선 잔존유 회수작업 종료절차에 대한 합리성 증대방안

  • Gang, Gwang-Gu;Sim, Yu-Taek;Gang, Sin-Yeong
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2013.10a
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    • pp.29-31
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    • 2013
  • 유조선이 화물유 탱크 내 유류를 적재한 채 국내 연안 해저면에 침몰하는 경우 화물유 탱크 내 적재유가 유출되어 대형 오염사고로 연결될 가능성이 있으므로 화물유 탱크 내 적재유는 신속하고 안전하게 제거 되어야만 한다. 심해 수중작업 특성상 이러한 잔존유 회수작업 완료 후 화물유 탱크 내 잔존유 제거상태의 직접적 확인은 매우 곤란하므로 회수작업 종료 기준 및 절차는 매우 중요하다. 이에 따라, 국내에서 실제 이루어 진 제1유일호 및 제3오성호, 경신호 잔존유 작업사례에 적용된 회수방법에 따른 종료절차를 비교분석하여, 향후 국내 연안에 침몰되는 유조선 잔존유 회수작업에 적용 가능한 합리적 표준 작업종료 절차를 제시하였다.

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The Study on the Thermal Oxidation of Mixed Rapeseed Oil with Coconut and Palm Oil (혼합 유채유의 가열산화에 관한 연구)

  • 현영희
    • The Korean Journal of Food And Nutrition
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    • v.15 no.4
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    • pp.342-349
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    • 2002
  • Rapeseed oil is easily oxidized due to the high contents of unsaturated fatty acid such as linoleic acid and linolenic acid. For stability of rapeseed oil oxidation, a special process is required. Two kind of simple and interesterifying mixed rapeseed oil were prepared according to add 30%, 50% and 70% of coconut oil and palm oil. Sample oils were heated at 180${\pm}$5$^{\circ}C$ for 5, 10, 15, 20, 25, 30 and 35 hours. Then the physicochemical properties such as the tendency of oxidation were investigated. The initial AV and POV of interesterifying mixed rapeseed oil were higher than those of simple mixed oil. But the tendency of oxidation were similar. While oxidation rate of similar and interesterifying mixed rapeseed oils with coconut oil and palm oil were lower about than those of rapeseed oil.

정향 추출물이 시판 식용유의 가열산화 억제에 미치는 영향

  • 박상일;문주수;이옥환;손종연
    • Proceedings of the Korean Society of Food and Cookery Science Conference
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    • 2003.10a
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    • pp.83-83
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    • 2003
  • 대두유, 올리브유 및 채종유에 대한 정향추출물(clove extract)의 항산화 효과를 알아보고자 대두유, 올리브유 및 채종유에 정향추출물을 0.02%의 농도로 첨가한 후 180$\pm$2$^{\circ}C$에서 48시간동안 가열산화 시키면서 산가(acid value) 및 공액이중산가(conjugated diene value)를 측정하였다. 대두유, 올리브유, 채종유의 초기 산가는 0.13, 0.75, 0.11이었으며, 가열산화 후 0.52, 1.31, 0.51로 증가하였다. 또한 대두유, 을리브유, 채종유의 초기 공액이증산가는 0.57, 0.43, 0.35에서 가열산화 후 1.93, 1.04, 1.08으로 대두유보다 채종유나 올리브유의 산화안정성이 높았다. (중략)

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Characteristics of Cow Milk and Goat Milk Yogurts Fermented by Streptococcus thermophilus LFG Isolated from Kefir (Kefir에서 분리한 Streptococcus thermophilus LFG를 이용한 우유 및 산양유 요구르트의 품질 특성)

  • Lim, Young-Soon;Lee, Si-Kyung
    • Food Science of Animal Resources
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    • v.33 no.6
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    • pp.787-795
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    • 2013
  • This study was carried out to investigate the characteristics of goat and cow milk yogurts containing high-exopolysaccharide fermented by Streptoccous thermophilus LFG isolated from kefir. The pH of cow milk yogurt was higher than that of goat milk yogurt. The contents of lactic acid was greater in goat milk yogurt (743.9-1043.8 mg/100 g) than in cow milk yogurt (441.6-709.9 mg/100 g). The numbers of survival lactic acid bacteria were the greatest in goat milk yogurt fermented by Str. thermophilus LFG. Viscosity was greater in cow and goat milk yogurts cultured by Str. thermophilus LFG than in yogurts by Str. thermophilus TH3. Syneresis of yogurt fermented by Str. thermophilus LFG was 9.6-16.1% and 28.2-31.8% in yogurt fermented by Str. thermophilus TH3 after 10 d storage at $4^{\circ}C$. Flavor compounds identified from goat milk were acetone, ethylbutanoate, ethyl-3-methylbutyrate, ethyl-2-butenoate and ethylhexanoate, and those from cow milk were ethylbutanoate, acetone, 2-heptanone and acetoin. Flavor compounds detected from goat milk and cow milk yogurts were acetic acid, butanoic acid, butanol, diethylcarbinol, acetone, diacetyl, decane, 2-methyl-3-pentanone, hexanal, 2-heptanone, acetoin, benzaldehyde, dimethyldisulfide, and dimethyltrisulfide. In sensory evaluation, overall preference and texture values were higher in goat milk yogurt fermented by Str. thermophilus LFG than in cow milk yogurts and the yogurt fermented by mixed culture resulted in the highest score.

내연기관용 윤활유의 고온 열안정성 연구

  • 김영운;정근우;조원오;김종호;심주섭
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1995.06b
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    • pp.47-47
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    • 1995
  • 자동차 엔진이 소형화, 고성능화됨에 따라 윤활유 또한 저점도화, 고성능화 되고 있다. 따라서, 오일 소비량이 적고 열안정성이 우수한 윤활유가 요구되는데, 본 연구에서는 광유계 윤활기유의 여러가지 첨가제를 혼련하여 에너지 절약형 윤활유를 제조하였는바, 윤활유 첨가제가 고온 열안정성에 미치는 영향을 조가하였다.

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