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Grain growth behavior of porous Al2O3 with addition of La2O3 prepared via freeze-casting (동결주조로 성형한 La2O3가 첨가된 Al2O3 다공체의 소결 중 입자성장 거동)

  • Kim, Sung-Hyun;Woo, Jong-Won;Jeon, Sang-Chae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.6
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    • pp.231-238
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    • 2022
  • To secure the mechanical strength of porous Al2O3 ceramics, which can be utilized for filters and catalyst supports is essential for their functionality and durability. Superior mechanical strength would be obtained by tailoring the densification and grain growth during sintering. This study deals with grain growth behavior of a freeze-casted Al2O3 with addition of La2O3. In a temperature range between 1400 and 1600℃, variations of average grain size with sintering time and temperature were observed and analyzed with Gtn-G0n = kt and with k = k0exp(-Ea/RT). As a result, n value and activation energy (Ea) for grain growth were calculated as 3 and 489.09 kJ/mol, respectively. These commonly confirms retardation effect of the La addition during sintering of Al2O3 porous structure. More accurate analysis on the La effect can be followed to provide useful guidance for the selection of additives for better mechanical strength in Al2O3 porous structures.

A Web-based Monitoring of Electrical Energy Consumption and Data Analysis of Smart Farm Facilities (스마트팜 전기 사용에 대한 웹기반 실시간 모니터링 시스템 운영 및 전력사용량 분석)

  • Lee, Mu Yeol;Sim, Sojeong;Kim, Eun-jeong;Han, Young-Soo
    • Journal of Bio-Environment Control
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    • v.31 no.4
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    • pp.366-375
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    • 2022
  • The monitoring of electricity consumption using Internet of Things (IoT) technology is attracting attention as a technology to reduce operation costs of smart farms. In this study, we propose a method to apply a real-time electrical consumption monitoring system (the e-Gauge system) and utilization of the collected data real-time while a melon-producing smart farm is in operation. For this purpose, the electrical consumption data for the individual smart-farm facilities such as boilers, nutrient distribution systems, automatic controllers, circulation fans, boiler controllers, and other IoT-related utilities were collected during three months of melon cultivation period. By using the monitoring results, the electrical energy consumption pattern was analyzed as an example, and necessary considerations needed to optimally utilize the measurement data were suggested. This paper will be useful in lowering the technological implementation barriers for new researchers to build a electrical consumption monitoring system and reducing trial and errors in the usage of the generated data.

A Study on the Method of Manufacturing Lactic Acid from Seaweed Biomass (해조류 바이오매스로부터 Lactic acid를 제조하는 방법에 관한 연구)

  • Lee, Hakrae;Ko, Euisuk;Shim, Woncheol;Kim, Jongseo;Kim, Jaineung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.1
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    • pp.1-8
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    • 2022
  • With the spread of COVID-19 worldwide, non-face-to-face services have grown rapidly, but at the same time, the problem of plastic waste is getting worse. Accordingly, eco-friendly policies such as carbon neutrality and sustainable circular economy are being promoted worldwide. Due to the high demand for eco-friendly products, the packaging industry is trying to develop eco-friendly packaging materials using PLA and PBAT and create new business models. On the other hand, Ulva australis occurs in large quantities in the southern seas of Korea and off the coast of Jeju Island, causing marine environmental problems. In this study, lactic acid was produced through dilute acid pretreatment, enzymatic saccharification, and fermentation processes to utilize Ulva australis as a new alternative energy raw material. In general, seaweeds vary in carbohydrate content and sugar composition depending on the species, harvest location, and time. Seaweed is mainly composed of polysaccharides such as cellulose, alginate, mannan, and xylan, but does not contain lignin. It is difficult to expect high extraction yield of the complex polysaccharide constituting Ulva australis with only one process. However, the fusion process of dilute acid and enzymatic saccharification presented in this study can extract most of the sugars contained in Ulva australis. Therefore, the fusion process is considered to be able to expect high lactic acid production yield when a commercial-scale production process is established.

Evaluation of Usefulness and Fabrication of Femur Phantom on Quality Control of Bone Mineral Density Using 3D Printing Technology (3D 프린팅기술을 이용한 골밀도 정도관리 대퇴골 팬텀 제작 및 유용성 평가)

  • Da-Yeong, Hong;Jeong, Lee;Jun-Ho, Lee;Jae-Won, Mun;Han-Saem, Oh;Yu-Won, Jeong;Seong-Hyun, Jin;Jong-Min, Hong;In-Ja, Lee
    • Journal of radiological science and technology
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    • v.46 no.1
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    • pp.1-8
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    • 2023
  • As the demand for bone mineral density testing increases in Korea, which is close to an aging society, it is necessary to evaluate the repeatability of equipment such as femur phantom other than l-spine for more accurate diagnosis. However, in clinical practice, it is often not possible to proceed such evaluation due to insufficient quality control conditions. Therefore, this study is to evaluate the usefulness of the femur phantom after fabricating the same using 3D printing technology. The femur phantom was output using GlowFill filament and FDM 3D printing type. Each phantom was repeatedly scaned 20 times to compare whether the existing l-spine phantom and the fabricated femur phantom were suitable as a phantom for quality control. Each time the seven researchers took three times, the location of the femur phantom was readjusted, and then scanned to confirm the error between the researchers. As a result of conducting repeatability evaluation using femur phantom, the coefficient of variation rate was 2%, which was within the minimum precision tolerance of 2.5%. The reproducibility between the researcher was also found to be suitable as the average coefficient of variation was 0.031 and the coefficient of variation rate was 3.1%, which was within the minimum precision error range of 5%. In conclusion, it is considered that the prospective attitude and usefulness of the femur phantom fabricated by 3D printing in clinical practice will be sufficient.

Ionomer Binder in Catalyst Layer for Polymer Electrolyte Membrane Fuel Cell and Water Electrolysis: An Updated Review (고분자 전해질 연료전지 및 수전해용 촉매층의 이오노머 바인더)

  • Park, Jong-Hyeok;Akter, Mahamuda;Kim, Beom-Seok;Jeong, Dahye;Lee, Minyoung;Shin, Jiyun;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.25 no.4
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    • pp.174-183
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    • 2022
  • Polymer electrolyte fuel cells and water electrolysis are attracting attention in terms of high energy density and high purity hydrogen production. The catalyst layer for the polymer electrolyte fuel cell and water electrolysis is a porous electrode composed of a precious metal-based electrocatalyst and an ionomer binder. Among them, the ionomer binder plays an important role in the formation of a three-dimensional network for ion conduction in the catalyst layer and the formation of pores for the movement of materials required or generated for the electrode reaction. In terms of the use of commercial perfluorinated ionomers, the content of the ionomer, the physical properties of the ionomer, and the type of the dispersing solvent system greatly determine the performance and durability of the catalyst layer. Until now, many studies have been reported on the method of using an ionomer for the catalyst layer for polymer electrolyte fuel cells. This review summarizes the research results on the use of ionomer binders in the fuel cell aspect reported so far, and aims to provide useful information for the research on the ionomer binder for the catalyst layer, which is one of the key elements of polymer electrolyte water electrolysis to accelerate the hydrogen economy era.

Gas Hydrate Phase Equilibria of $CO_2+H_2$ Mixture in Silica Gel Pores for the Development of Pre-combustion Capture (연소 전 이산화탄소 회수기술을 위한 실리카겔 공극 내에서의 이산화탄소+수소 혼합가스 하이드레이트의 상평형)

  • Kang, Seong-Pil;Jang, Won-Ho;Jo, Wan-Keun
    • Clean Technology
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    • v.15 no.4
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    • pp.258-264
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    • 2009
  • Thermodynamic measurements were performed to show the possibility of recovering $CO_2$ from fuel gas (the mixture of $CO_2$ and $H_2$) by forming gas hydrates with water where water was dispersed in the pores of silica gel particles having nominal 100 nm of pore diameter. The hydrate-phase equilibria for the ternary $CO_2+H_2$+water in pores were measured and $CO_2$ concentrations in vapor and hydrate phase were determined under the hydrate-vapor two phase region at constant 274.15 K. It was shown that the inhibition effect appeared due to silica gel pores, and the corresponding equilibrium dissociation pressures became higher than those of bulk water hydrates at a specific temperature. In addition, direct measurement of $CO_2$ content in the hydrate phase showed that the retrieved gas from the dissociation of hydrate contained more than 95 mol% of $CO_2$ when 42 mol% of $CO_2$ and balanced Hz mixture was applied. Compared with data obtained in case of bulk water hydrates, which showed just 83 mol% of $CO_2$ where 2-stage hydrate slurry reactor was intended to utilize this property, the hydrate formation in porous silica gel has enhanced the feasibility of $CO_2$ separation process. Hydrate formation as not for slurry but solid particle makes it possible to used fixed bed reactor, and can be a merit of well-understood technologies in the industrial field.

Naturopathic Effects of Arthritis, Frozen Shoulder and Lumbago Using the Qi-Therapy (관절염, 오십견 및 요통에 대한 기(氣)치유 효과)

  • Kim, Munki;Lee, Hyung Hoan
    • Journal of Naturopathy
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    • v.8 no.2
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    • pp.53-62
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    • 2019
  • Purpose: To investigate the healing effect of 21 patients with chronic back pain, shoulder pain, and knee arthritis by a Qigong. Methods: The study performed by hand injection of a Soojung Qi-therapy. Results: Ten patients (47.6%) had low back pain, eight (38%) had frozen shoulders, and three (14.3%) had knee arthritis. Satisfaction after five times of the Qi-healing was 72% in those who returned to normal and 14% in those who improved. When the maximum pain level set at 5.0, the difference between before and after healing was 3.33 in arthritis subjects, 3.75 in fifty shoulder subjects, and 3.80 in low back pain. In general, the degree of pain decreased as the number of healings increased. In particular, even after the first healing, the pain reduction of the subjects was high in arthritis, frozen shoulders, and low back pain. That is, there was a possibility of controlling pain with only one Qi-healing. Conclusions: Soojung Qi-therapy is one of the natural healing treatments because it reduces fast pains and accessible to handling anytime and anywhere. Conclusions: With Qi-therapy, arthritis, frozen shoulder, and lumbago patients almost recovered to their original shape. Therefore, Qi-therapy regarded as one of the useful natural healing therapies.

Quantum Efficiency Measurement and Analysis of Solar Cells (태양전지의 양자효율 측정 및 분석)

  • Youngkuk Kim;Donghyun Oh;Jinjoo Park;Junsin Yi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.4
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    • pp.351-361
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    • 2023
  • The purpose of this paper is to help those who research and develop solar cells in university laboratories and industrial sites understand the most basic and important quantum efficiency measurement and analysis method in analyzing solar cell performance. Starting with the definition of quantum efficiency, we calculate the theoretical current density according to the band gap of the solar cell material from the solar spectrum, along with a detailed introduction to the measurement and analysis methods, and measure and analyze the theoretical current density and quantum efficiency. We discuss in depth how to analyze the performance of solar cells through Quantum efficiency measurement and analysis of solar cells is a very useful method that can give intuition to solar cell performance analysis as it can analyze solar cells according to depth (front emitter, bulk, rear surface). Students and researchers who study solar cells with a deep understanding of theoretical current density and quantum efficiency measurement analysis are expected to use it as a basis for analyzing solar cell performance.

A Nonlinear Truss Finite Element Model for Structures with Negative Poisson Effect Accompanied by Tensile Buckling (인장 좌굴 현상을 수반하는 음의 포아송 효과를 가지는 구조물 해석을 위한 비선형 트러스 유한요소 모델)

  • Tae-Wan Kim;Jun-Sik Kim
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.36 no.3
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    • pp.193-201
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    • 2023
  • In this study, a nonlinear truss finite element is developed to analyze structures with negative Poisson effect-induced tensile buckling. In general, the well-known buckling phenomenon is a stability problem under a compressive load, whereas tensile buckling occurs because of local compression caused by tension. It is not as well-known as classical buckling because it is a recent study. The mechanism of tensile buckling can be briefly explained from an energy standpoint. The nonlinear truss finite element with a torsional spring is formulated because the finite element has not been reported in the literature yet. The post-buckling analysis is then performed using the generalized displacement control method, which reveals that the torsional spring plays an important role in tensile buckling. Structures that mimic a negative Poisson effect can be constructed using such post-buckling behaviors, and one of the possible applications is a mechanical switch. The results obtained are compared to those of analytical solutions and commercial finite element analysis to assess the validity of the proposed finite element model. The numerical results show that the developed finite element model could be a viable option for the basic design of nonlinear structures with a negative Poisson effect.

Hybrid Structural Health Monitoring of Steel Plate-Girder Bridges using Acceleration-Impedance Features (가속도-임피던스 특성을 이용한 강판형교의 하이브리드 구조건전성 모니터링)

  • Hong, Dong-Soo;Do, Han-Sung;Na, Won-Bae;Kim, Jeong-Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1A
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    • pp.61-73
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    • 2009
  • In this paper, hybrid health monitoring techniques using acceleration-impedance features are newly proposed to detect two damage-type in steel plate-girder bridges, which are girder's stiffness-loss and support perturbation. The hybrid techniques mainly consists of three sequential phases: 1) to alarm the occurrence of damage in global manner, 2) to classify the alarmed damage into subsystems of the structure, and 3) to estimate the classified damage in detail using methods suitable for the subsystems. In the first phase, the global occurrence of damage is alarmed by monitoring changes in acceleration features. In the second phase, the alarmed damage is classified into subsystems by recognizing patterns of impedance features. In the final phase, the location and the extent of damage are estimated by using modal strain energy-based damage index method and root mean square deviation (RMSD) method. The feasibility of the proposed hybrid technique is evaluated on a laboratory-scaled steel plate-girder bridge model for which hybrid acceleration-impedance signatures were measured for several damage scenarios. Also, the effect of temperature on the accuracy of the impedance-based damage monitoring results are experimentally examined from combined scenarios of support damage cases and temperature changes.