• Journal of Korean Society of Forest Science
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• v.89 no.1
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• pp.55-64
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• 2000

This study was carried out to analyze the characteristics of pH and electrical conductivity(EC) at each stand and soil depth by the artificial acid rain sprinkling in the upper watershed of Mt. Palgong and furthermore to clarify the relationships between forest soil and water purification function. The results obtained in the experimental sites of Quercus acutissima and Larix leptolepis were summarized as follows ; 1. The average soil pH at each soil layer(0~5cm, 0~10cm, 0~20cm in depth) were 4.8, 4.3 and 4.5 for the Quercus acutissima soil and 5.15, 5.19 and 5.21 for the Larix leptolepis soil. The soil pH of Larix leptolepis stand was higher than that of Quercus acutissima stand. In addition, the deeper soil depth was, the higher soil pH was. 2. The soil solution pH of Larix leptolepis stand was higher than that of Quercus acutissima stand. It was due to the high soil pH of Larix leptolepis stand itself and the difference of humus layer thickness. 3. It took time to show the pH buffer capacity of forest soil after application of artificial acid rain in the forest soil. The pH value of soil solution in each experimental site was maximum at this time and then did not increase pH value any more. 4. Soil solution EC increased slowly with pH 3.0 treatment, but it decreased slowly with pH 5.0 treatment over time. It was assumed that the amount of the leached cation and the ions leading buffer action changed at the stands with ranges of acidity treatment. 5. From the trend of soil solution EC at each soil depth, it seemed that the water buffer capacity of the forest soil increased as the soil depth increased.

• Korean Journal of Environmental Agriculture
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• v.34 no.4
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• pp.274-281
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• 2015

BACKGROUND: A lasting release of low levels of persistence chemicals including pesticides and pharmaceuticals into river has a bad influence on aquatic ecosystems and humans. The present study monitored pesticide residues in the Yeongsan and Seomjin river basins and their tributaries as a fundamental study for water quality standard of pesticides.METHODS AND RESULTS: Nine pesticides(aldicarb, carbaryl, carbofuran, chlorpyrifos, 2,4-D, MCPA, methomyl, metolachlor, and molinate) were determined from water samples using SPE-Oasis HLB(pH 2) and LC/MS/MS. Validation of the method was conducted through matrix-matched internal calibration curve, method detection limit(MDL), limit of quantification(LOQ), accuracy, precision, and recovery. MDLs of all pesticides satisfied the GV/10 values. Linearity(r²) was 0.9965- 0.9999, and a percentage of accuracy, precision, and recovery was 89.4-113.6%, 3.1-14.0%, and 90.8-106.2%, respectively. All pesticides exclusive of aldicarb were determined in the river samples, and there was a connection between the positive monitoring results and agricultural use of the pesticides.CONCLUSION: Monitoring outcomes of the present study implied that pesticides were a possible non-point pollutant source in the Yeongsan and Seomjin river basins and tributaries. Therefore, it is required to produce and accumulate more monitoring results on pesticides in river waters to set water quality standards, finally to preserve aquatic ecosystems.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.11
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• pp.613-625
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• 2017

For two agricultural reservoirs that are rented for fishing spots, benthic nutrient fluxes experiment were performed two times with two sediments from fishing-effective zone and one sediment from fishing-ineffective zone using laboratory core incubation in oxic and anoxic conditions. During benthic nutrient fluxes experiment, the changes in DO, EC, pH, and ORP in the supernatant were not significantly different between fishing-effective zone and fishing-ineffective zone, and were similar to the sediment-hypolimnetic diffused boundary layer in agricultural reservoir. Except for $NO_3{^-}-N$, more benthic nutrient fluxes of $NH_4{^+}-N$, T-P, and $PO{_4}^{3-}-P$ from sediment to hypolimnetic was measured in anoxic than in oxic conditions (p<0.05). As the DO concentration in hypolimnetic decreases, the microorganism-mediated ammonification is promoted, the nitrification is suppressed, and finally the $NH_4{^+}-N$ diffuses out from sediment to hypolimnetic. Also, the diffusion of T-P and $PO{_4}^{3-}-P$ from sediments to hypolimnetic is accelerated through the dissociation of the phosphorus bound to both organic matters and metal hydroxides. The difference in the benthic nutrient diffusive fluxes between fishing-effective zone and fishing-ineffective zone was not statistically significant (p>0.05). Therefore, it was found that fishing activities did not increase the benthic nutrient diffusive fluxes to a statistically significant level. Due to the short fishing activities of 10 years and the rate-limited diffusion of the laboratory core incubation, the contribution of fishing activities on sediment pollution is estimated to be low. No significant correlation was found between the total amount of nutrients in sediment and the benthic nutrient diffusive fluxes in both aerobic and anaerobic conditions. Therefore, nutrients input from various nonpoint sources of watersheds are considered to be a more dominant factor rather than fishing activities in water quality deterioration, and both aeration and water circulation in hypolimnetic were required to suppress the anoxic environment in agricultural reservoirs.