• Title/Summary/Keyword: 유리 전이

Search Result 1,238, Processing Time 0.028 seconds

Fatty Acid Composition of Lipids obtained from Korean Soybean Varieties (한국산 콩의 품종별 지방질의 지방산 조성)

  • Yoon, Tai-Heon;Im, Kyung-Ja;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
    • /
    • v.16 no.4
    • /
    • pp.375-382
    • /
    • 1984
  • The fatty acid compositions of lipids from five local varieties and three imported varieties of soybean were determined. Total and free lipids of the samples were extracted with chloroform-methanol mixture (2:1, v/v) and ethyl ether, respectively. The ether-extracted samples were extracted again with water saturated n-butanol to obtain bound lipids. The average percent contents of the lipid fractions were 21% (total), 18% (free), and 3.3% (bound). The results indicated that seven fatty acids (10:0, 12:0, 14:0, 16:0, 17:0, 20:0 and 22:0) were identified as minor fatty acids for all the varieties examined in this study. The relative contents of 18:2 were the highest (50.1-59.7%) in all the lipid fractions, and the contents in total and free lipids were in-fluenced by the local varieties. Little difference in fatty acid composition was noted between the total and free lipids of the samples. Total and free lipids contained more 18:1 (about 10%) and less 16:0 (about 40%) and 14:0 (about 34%) than did the bound lipids. The relative percent contents of 18:3 in the total, free and bound lipids were on average 8.9, 9.0, and 7.3 percents. The content in the total lipids of Gwanggyo varieties showed the highest level (11.1%), and in the bound lipids of Eundaedoo varieties the lowest (6.0%). In case of the total and free lipids, those varieties which showed higher relative contents of 18:1 generally had lower relative contents of 18:2 and 18:3.

  • PDF

Correction for Na Migration Effects in Silicate Glasses During Electron Microprobe Analysis (전자현미분석에서 발생하는 규산염 유리 시료의 Na 이동 효과 보정)

  • Hwayoung, Kim;Changkun, Park
    • Korean Journal of Mineralogy and Petrology
    • /
    • v.35 no.4
    • /
    • pp.457-467
    • /
    • 2022
  • Electron bombardment to silicate glass during electron probe microanalysis (EPMA) causes outward migration of Na from the excitation volume and subsequent decrease in the measured X-ray count rates of Na. To acquire precise Na2O content of silicate glass, one should use proper analytical technique to avoid or minimize Na migration effect or should correct for decreases in the measured Na X-ray counts. In this study, we analyzed 8 silicate glass standard samples using automated Time Dependent Intensity (TDI) correction method of Probe for EPMA software that can calculate zero-time intercept by extrapolating X-ray count changes over analysis time. We evaluated an accuracy of TDI correction for Na measurements of silicate glasses with EPMA at 15 kV acceleration voltage and 20 nA probe current electron beam, which is commonly utilized analytical condition for geological samples. Results show that Na loss can be avoided with 20 ㎛-sized large beam (<0.1 nA/㎛2), thus silicate glasses can be analyzed without TDI correction. When the beam size is smaller than 10 ㎛, Na loss results in large relative errors up to -55% of Na2O values without correction. By applying TDI corrections, we can acquire Na2O values close to the reference values with relative errors of ~ ±10%. Use of weighted linear-fit can reduce relative errors down to ±6%. Thus, quantitative analysis of silicate glasses with EPMA is required for TDI correction for alkali elements such as Na and K.

Plasma resistance of Bi-Al-Si-O and Bi-Al-Si-O-F glass coating film (Bi-Al-Si-O와 Bi-Al-Si-O-F 유리 코팅막의 플라즈마 저항성)

  • Sung Hyun Woo;Jihun Jung;Jung Heon Lee;Hyeong-Jun Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.34 no.4
    • /
    • pp.131-138
    • /
    • 2024
  • In this study, the microstructure and plasma resistance characteristics of 35Bi2O3-15Al2O3-50SiO2 (BiAl SiO) and 35Bi2O3-7.5Al2O3-50SiO2-7.5AlF3 (BiAlSiOF) glass layers coated on sintered alumina substrates were investigated according to the sintering conditions. The coated layers were formed using the bar coating method and then sintered at a temperature in the range of 700~900℃, which corresponds to the temperature before and after the hemisphere forming temperature, after a debinding process. The plasma resistance of the two coated glasses was approximately 2~3 times higher than that of the quartz glass, and in particular, the BiAlSiOF glass film with F added showed higher plasma resistance than BiAlSiO. It is thought to be due to the effect of suppressing the reaction with fluorine gas by adding fluorine to the glass. When the sintering time was increased at 700℃ and 800℃, the plasma resistance of both glasses improved, but when the sintering temperature was increased to 900℃, the plasma resistance decreased again (i.e., the etching rate increased). This phenomenon is thought to be related to the crystallization behavior of both glasses. The change in plasma resistance depending on the sintering conditions is thought to be related to the appearance of Al and Bi-rich phases.

CdSe/ZnS 양자점 전계발광소자에서 전하수송층인 Zinc Tin Oxide의 비저항이 소자의 발광 특성에 미치는 영향

  • Yun, Seong-Ryong;Jeon, Min-Hyeon;Lee, Jeon-Guk
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2011.10a
    • /
    • pp.44-44
    • /
    • 2011
  • Unipolar 구조의 양자점 발광소자는 소자에 주입되는 전자로 구동 가능하게 설계되어 bipolar 구조와 달리 직류뿐만 아니라 교류로도 구동이 가능하다. 소자의 구조는 패턴된 ITO 유리기판 위에 Radio frequency magnetron sputter로 성장시킨 투명한 금속산화층 사이에 콜로이드로 분산된 양자점이 포함되어 있다. 본 연구에서는, 전하 수송층으로 사용되는 Zinc Tin Oxide (ZTO)가 전압 인가 시 발생하는 과부하로 인해 낮은 전계발광(electroluminescence, EL)특성이 나타나는 문제점이 있다. 이를 해결하고자 ZTO층의 비저항과 EL특성 사이의 관계를 알아보고, ZTO의 비저항 값을 변화시키기 위해 sputter 공정 중 인가 전력과 작업압력, 산소 분압 등의 성장 조건을 변화시켰다. ZTO의 조성비에 따른 비저항 및 전기적 특성을 홀 측정 장비로 측정하였다. 인가전력이 낮고 작업압력이 낮을수록 비저항 값이 낮았으며, 그에 따라 소자의 동작전압이 낮아지고 EL특성 또한 우수하게 나타났다.

  • PDF

Comparison of Agronomic Traits According to Plant Types before Wintering in Malting Barley Lines (맥주맥의 월동전 초형에 따른 주요 형질의 비교)

  • 천종은
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.36 no.1
    • /
    • pp.12-16
    • /
    • 1991
  • So as to compare the differences of major agronomic traits according to fall plant types, two cultivars and eight lines which were derived from the same pedigree, were planted and analyzed. The heading and mature times, and culum length of erect plant types were earlier or longer, but the spike number per ㎡ and yield were smaller than the those of prostrate types. Also, 1000 grain weith, assortment rate and light penetration rate in erect types were greater than in prostrate types. The heading time was positively correlated with mature time and yield, but negatively correlated with culum length, 1000 grain weight, assortment rate and light penetration rate. Yield was negatively correlated with light penetration rate. If the lines with prostrate types in fall season, fast regrowth after wintering and rapid elongation of stem were bred and selected, it will be of great benefit in the area requiring sever winter hardiness.

  • PDF

무기물 색변환층을 사용한 무기물/유기물 유기발광소자의 발광 메커니즘

  • Jeong, Hwan-Seok;Kim, Seok-Hyeon;Chu, Dong-Cheol;Kim, Tae-Hwan;Gwon, Myeong-Seok
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.122-122
    • /
    • 2010
  • 백색 유기발광소자를 제작하기 위한 여러 가지 유기물층을 사용할 때 제작공정이 어려워지고 유기발광소자의 발광 효율이 저하되고 색안정성이 나빠지는 문제점이 있다. 본 논문에서는 Zn2SiO4:Mn 무기물 형광체를 사용한 유무기 혼성 유기발광소자를 제작하고 발광 메카니즘을 조사하였다. 색변환층으로 사용되는 Zn2SiO4:Mn 형광체는 졸겔 방법을 사용하여 형성하고 비이클용액 및 열처리 공정을 사용하여 유리기판 위에 도포하였다. 형성된 Zn2SiO4:Mn 형광체 층에 대하여 X선 회절측정한 결과는 형광체내의 Zn 이온이 도핑된 Mn 이온에 대체되었음을 보여준다. 제작된 진청색 OLED의 전계발광 스펙트럼은 461 nm 에서 peak 을 나타내고 Zn2SiO4:Mn 무기물 형광체는 470 nm에서 여기 되어 Mn 이온의 4T1-6A1 전이에 의하여 527 nm에서 발광을 한다. Zn2SiO4:Mn 무기물 형광체를 사용한 유기발광소자의 전계발광스펙트럼에서 나타나는 527nm peak 은 Zn2SiO4:Mn 무기물의 색변환에 의해 나타난 결과로서 제작된 유기발광소자에서 발광된 빛을 청색에서 녹색으로 변환한 결과이다. Zn2SiO4:Mn 무기물 색변환층을 사용하여 제작된 무기물/유기물 유기발광소자의 발광 메카니즘은 전계발광스펙트럼 및 광루미네센스 스펙트럼 결과를 기초로 설명하였다. 이 결과는 녹색 무기물 형광체를 진청색 유기발광소자와 결합하여 제작된 유기발광소자의 발광색을 조절할 수 있음을 보여주었다.

  • PDF

Morphology and Tensile Properties of Polyimide/Polyamideimide Composites from Different Polyimide Precursors (Polyimide 전구체에 따른 Polyimide/Ppolyamideimide 복합체의 형태학 및 인장 특성)

  • 김진봉;최윤희;임병탁;박준상
    • Polymer(Korea)
    • /
    • v.25 no.2
    • /
    • pp.160-167
    • /
    • 2001
  • The various compositions of polyimide (PI)/polyamideimide (PAI) composites were prepared by heat treatment of the solvent cast PI precursors/PAI blends. The optical micrographs showed that a good compatibility was observed between poly(amic acid) (PAA) and PAI, but in the case of PAME/PAI mixtures, a phase separation apparently occurred due to the absence of ionic and/or H-bonding forces. Regardless of PI precursors, the similar tensile properties were observed. The tensile modulus of the composites were higher than that of the neat polyimide. The X-ray diffraction patterns of the composites showed that the chain rearrangement of PI was increased due to the plasticizing effect of PAI, which has lower glass transition temperature than that of PI, during thermal imidization process.

  • PDF

The Taste Compounds of Fermented Squid, Loligo kobiensis (꼴뚜기젓의 정미성분(呈味成分))

  • Lee, Eung-Ho;Sung, Nak-Ju
    • Korean Journal of Food Science and Technology
    • /
    • v.9 no.4
    • /
    • pp.255-263
    • /
    • 1977
  • Fermented squid, Loligo kobiensis, is widely used and occupies an important position in foods of this country. But no study on its taste compounds has been reported. This study was attempted to establish the basic data for evaluating taste compounds of fermented squid. The changes of such compounds during fermentation as free amino acids, nucleotides and their related compounds, TMAO, TMA and betaine were analysed. The sample was prepared with 20% salt content and fermented at a controlled temperature of $15{\pm}3^{\circ}C$. ADP, AMP and inosine tended to degrade rapidly while hypoxanthine increased more than four times as compared with raw sample at 91 day fermentation. In the free amino acid composition of fresh squid, abundant amino acids were proline, taurine, alanine, arginine, serine, glutamic acid, lysine, glycine, leucine and valine in order. Such amino acids like phenylalanine, methionine, tyrosine, isoleucine, and histidine were poor. In squid extract, proline and taurine were dominant holding 40.2% and 32.0% of total free amino acids respectively. The total free amino acid nitrogen in fresh squid was 33.6% of its extract nitrogen. The changes of free amino acid composition in the extract of squid during fermentation was not observed. In the extract of fermented product, abundant amino acids were proline, leucine, lysine, serine, arginine, alanine, valine, isoleucine, phenylalanine, methionine and glycine in order. Glutamic acid and histidine were poor and taurine and tyrosine were trace in content. The increase of total free amino acids during 63 day fermentation reached approximately wore than 1.8 times as compared with that of raw sample and than decreased slowly. The amount of betaine increased more than 1.2 times as compared with that of raw sample during 91 day fermentation. TMA increased while TMAO decreased during fermentation. The amount of TMAO nitrogen in 91 days fermented squid was 402.4mg% on moisture and salt free base. Betaine and TMAO known as sweet compounds were abundant in fermented squid. It is supposed that these compounds could also play a role as important taste compounds of fermented squid. It is concluded that the major taste compounds of fermented squid were amino acids like proline, leucine, serine, lysine, arginine, alanine and betaine. Other compounds such as valine, isoleucine and TMAO and hypoxanthine could also not be excluded as taste supporters in fermented squid.

  • PDF

Delayed Detection of a Penetrating Tracheal Foreign Body (수상 후 10년이 지나 발견된 기관 내 이물질)

  • Jang, Woo-Sung;Kim, Young-Tae;Kim, Joo-Hyun;Kang, Chang-Hyun
    • Journal of Chest Surgery
    • /
    • v.40 no.5 s.274
    • /
    • pp.384-387
    • /
    • 2007
  • The finding of a tracheal penetrating injury that's caused by a foreign body is rare in adulthood. A 42-year-old man had experienced penetrating trauma due to a glass fragment 10 years ago. He presented with blood tinged sputum and dyspnea on exertion, and this had developed 1 year previously. Chest CT scan and bronchoscopy revealed a foreign body crossing the tracheal lumen and the object arose from outside of the trachea; this was all associated with airway edema. We removed the foreign body, which was a 5cm length of glass fragment, and we repaired the tracheal defect using a simple primary suture. The postoperative course of the patient was uneventful and he is now being followed up at the outpatient department; he has had no additional symptoms.

The Comparison between Anterolateral Thigh Free Flap and Radial Forearm Free Flap in Partial Glossectomy Defect - An Evaluation of Donor Site Morbidity and Functional Outcome (유리 전외측 대퇴부 피판과 유리 요측 전박피판을 이용한 설재건 시공여부 및 기능적 결과 비교)

  • Cho, Sang Hyun;Lee, Won Jai;Lew, Dae Hyun;Tark, Kwan Chul
    • Archives of Plastic Surgery
    • /
    • v.34 no.3
    • /
    • pp.330-335
    • /
    • 2007
  • Purpose: The purpose of this study is to evaluate the functional outcome and donor site morbidity of anterolateral thigh free flap(ALT) compared to Radial forearm free flap(RFFF) for the reconstruction of partial glossectomy defect. Methods: 5 ALT free flap (group I) were attempted for partial glossectomy patients. We compared patients undergone ALT flap with those(n=11) of similar size defect reconstructed with RFFF (Group II). Rating scales for articulation and swallowing function were applied and donor site morbidity have been evaluated. Results: The scales for speech function showed no difference between the two groups (average score; group I - 6.4, group II - 6.45). Swallowing function also showed no difference between the two groups(average score; Group I - 6.6, Group II - 6.27). ALT group had one patient with donor site morbidity(numbness). All of the RFFF patients(11/11) complained and suffered from hypertrophic scar, retraction, numbness or hyperpigmentation on forearm donor site. Based on our study, ALT free flap is comparable to that of RFFF in terms of functional assessment in tongue reconstruction. Conclusion: Considering the donor site morbidity, ALT flap is to be valuable to reconstruct partial glossectomy defect.