• Title/Summary/Keyword: 유리조성

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Analysis of the relationship between soda-lime glass composition and viscosity calculated by Lakatos model (Lakatos 모델로 계산한 소다석회유리 점도와 조성과의 관계 분석)

  • Kang, Seung Min;Kim, Chang-sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.6
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    • pp.246-250
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    • 2022
  • An estimation method of glass viscosity using Lakatos model is one of the best way to calculate the viscosity of soda-lime glass. The glass viscosity is obtained by inputting a glass composition consisting of SiO2, Al2O3, Na2O, K2O, CaO and MgO to the Lakatos model. A series of composition of glass bottles was obtained once a month for 10 months from a soda-lime glass bottle fabrication line and isokom temperatures at the viscosity of log η = 3, 6.6, 10 and 12.3 were calculated. It was found that the isokom temperature at log η = 3 and log η = 6.6 was closely related to the value of (Si+Al)/O and 1/Na, respectively.

Changes of Fluorescent Substances and Free Amino Acids in Formed Eggs of the Silkworm(Bombyx mori) (가잠조성난의 형광물질과 유리아미노산의 변화)

  • 성수일;박광의;김주읍
    • Journal of Sericultural and Entomological Science
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    • v.20 no.1
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    • pp.11-14
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    • 1978
  • This experiment was attempted to investigate the effect of removal of suboesophageal ganglion of Bombyx mori on the changes of free amino acids and fluorescent substances by means of paper chromatography. 1. There are no differences of quantity and component of free amino acids of formed eggs in moths between treatment and control. 2. Riboflavine content of formed eggs in treated moths is less than that of formed eggs in untreated moths. 3. Fluorescent substance which appeared on Rf value 0.06 was not detected in formed eggs of treated moths but found in those of control. 4. Fluorescent substance which appeared on Rf value 0 was noted in formed eggs of treated moths but not in those of control.

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Chemical Characteristic of Glass Beads Excavated from Bakjimeure Site in Asan, Korea (아산 명암리 밖지므레 유적 출토 유리구슬의 화학적 특성)

  • Kim, Na Young;Kim, Gyu Ho
    • Journal of Conservation Science
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    • v.28 no.3
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    • pp.205-216
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    • 2012
  • 65 samples of glass bead excavated from Mahan tombs of Asan Bakjimeure site consists of 13 of potash glass group and 52 of soda glass group and soda glass is superior in numbers. When classified according to color, purple blue glass bead is accompanied potash and soda glass group whereas purple glass bead is potash glass group and red, greenish blue, green and gold foil glass bead is soda glass group. Purple blue glass bead is classified as LCA type in which the content of the stabilizer is low. Of this, the soda glass categorized as LMK type with low content of MgO and $K_2O$ is determined that natron is used as the raw material. As to red glass, the homogeneous glass is LCA-B/HMK type and the heterogeneous glass is HCLA/LMK type. Thus, each of these two types are likely to be used plant ash and natron respectively. Greenish blue and green glass depends of the type that round glass is LCA-A/LMHK type and the segmented glass is LCA-B/HMK type. The gold foil glass bead is manufactured by the purity of 19.9~22.6K gold foil and the soda glass of HCLA/LMK type. In other words, the most of the glass bead of Asan Bakjimeure site is similar to the composition of the glass confirmed in other sites of the Baekche period. On the other hand, the greenish blue and green segmented bead and some red round bead is a different chemical composition is considered that the difference in raw materials. These characteristics is expected to be an important evidence for the understanding of the trade system of the ancient glass.

Stabilization of Heavy Metals in Glasses Containing EAF Dust (전기로 분진이 첨가된 유리의 중금속 안정화 특성)

  • Eun, Hee-Tai;Kang, Seung-Gu;Kim, Yoo-Taek;Lee, Gi-Kang;Kim, Jung-Hwan
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.851-857
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    • 2004
  • The stabilizing characteristics of heavy metals in the silicate glass (SD), borosilicate glass (BD), and leadsilicate glass (PD) containing Electric Arc furnace (EAF) dust were studied by the Toxic Characterization Leaching Procedure (TCLP) test. Also, the dependence of the amount of EAF dust upon structural changes of SD, BD, and PD glasses and the TCLP results were investigated by the XRD and FT-IR spectroscopy. In the XRD results, all of SD, BD, and PD specimens containing dust up to 30 wt% were amorphous without crystallizing. In the TCLP test, the concentration of heavy metals leached from the glasses increased with the amount of EAF dust added. The SD specimen series showed the lowest heavy metal leaching and the heavy metal leachate of the PD specimens were lower than those of the BD specimens. But, the Pb leaching from the PD specimens was the highest in the PD glass composition due to the high Pb content. The value of oxygen/network former ratio could be used to compare the chemical durability within the same glass series, but not proper to do between the different glass series. Adding the EAF dust to the SD mother glass, decreased the Si-O-Si symmetry and increased the non-bridging oxygen, which weakened the structure and decreased the chemical durability of glasses. In the BD series glasses, the addition of EAF dust caused the structural changes from tetra-borate group to di-borate group and the formation of the 2-dimensional layer structure of pyre- and ortho- borate, which decreased the chemical durability of glasses. It is concluded that SD series glass among the 3 kinds of glasses is the most effective to stabilize the heavy metals of EAF dust.

A study on the Material and Characteristics of Glass Beads from Oc Eo Site, Vietnam (베트남 옥 에오(Oc Eo) 유적 출토 유리구슬의 재질 및 특성 연구)

  • Kim, Gyu Ho;Yun, Ji Hyeon;Kwon, Oh Young;Park, Jun Young;Nguyen, Thi Ha
    • Korean Journal of Heritage: History & Science
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    • v.49 no.2
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    • pp.158-171
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    • 2016
  • The observation and analysis results of 9 glass bead samples collected from Oc Eo site in Vietnam, an outport of the ancient port city Funan in East Asia, are as follows. The type of glass beads is round, the colors are reddish brown, greenish blue, green, black and purplish blue, and the chemical composition is soda glass group. This means that they are similar in type, color and chemical compositions to glass beads from the ancient Korean peninsula. There are limitations in data because the glass beads are not from excavation investigation but from earth surface investigation. But it is significant that similar making technique and chemical composition are being observed in both the glass beads from Oc Eo and those of Korea. According to "Nihon Shoki" Kinmeiki, Baekje king sent Funan's goods and 2 slaves to Japan in 543. It is clear that there were direct or indirect exchanges between Baekje and Funan. The possibility has grown that glass beads could be included among goods.

Comparison of Free Amino Acids and Nucleotides Content in the Olive Flounder Paralichthys olivaceus Fed with Extruded Pellet (건조 배합사료로 사육한 넙치 어육의 유리아미노산 및 핵산 관련 성분의 비교)

  • Jang, Mi-Soon;Park, Hee-Yeon;Kim, Kang-Woong;Kim, Kyoung-Duck;Son, Maeng-Hyun
    • Food Science and Preservation
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    • v.18 no.5
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    • pp.746-754
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    • 2011
  • This study analyzed the taste components of dorsal muscle and fin muscle collected from olive flounder cultured with extruded pellet (EP) compared with those of olive flounder cultured with raw fish moist pellet (MP) as a control. The olive flounder in this study were cultured for 10 months with either the formulated extrude pellets (FEP), commercial extruded pellets (CEP) or the MP feed, and the average weight was 1.15 kg. The major nucleotides and related compounds in the dorsal muscles of the fish fed with MP, CEP and FEP diets were AMP and IMP. The fin muscle of the olive flounder contained the largest amounts of IMP($5.91{\mu}mol/g$). The K value of the dorsal muscle in olive flounder fed with MP, CEP and FEP showed 9.63%, 9.83% and 5.84%, respectively. The free amino acids in the dorsal muscle of olive flounder showed significantly differences in the composition depending on the feed, but the distribution of free amino acids showed similar patterns. Among free amino acids, taurine showed the highest content in all the experimental groups, and the asparagine and citrulline contents were significantly higher in the groups fed with CEP and FEP than in the group fed with MP. The significant differences were observed in the contents of specific free amino acids in dorsal muscle and fin flesh depending on the feed for cultured olive flounder.

A Characteristic Analysis of Glass Beads in Geumgwan Gaya, Korea (I) (금관가야 유리구슬의 특성 분석 (I))

  • Kim, Eun A;Lee, Je Hyun;Kim, Gyu Ho
    • Journal of Conservation Science
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    • v.37 no.3
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    • pp.232-244
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    • 2021
  • This study examined the physical attributes and heat treatment characteristics of glass beads excavated from the Gimhae area, which is the location of Geumgwan Gaya. This enabled classification of surface characteristics of the beads based on the investigation of the color, size, and shape. The glass beads were classified into eight color systems, with purplish-blue beads as the representative color. Bead size was categorized into three types depending on the outer diameter and how it increased over time. Bead shapes were categorized as round, tubular, or doughnut-shaped based on the inner diameter and length, with round being the typical shape. According to the degree of heat treatment, there are three types of cross-section for glass beads that are manufactured by the drawing technique, most of which are the HT-III type. In addition, it is estimated that the heat treatment technology has more considerable effects than other methods. Through non-destructive analysis, the chemical composition was obtained and categorized as flux, stabilizer, and colorant. Analysis confirmed the presence of 63 and 9 pieces in the potash and soda glass groups, respectively. Overall findings from the study highlighted a correlation between the chemical composition and the external factors such as color, size, shape, and manufacturing technology of glass beads recovered from Geumgwan Gaya, revealing characteristics related to that time and region.

Fabrication of Pb Free Solder Glass for Electronic Packaging Application (전자 패키징용 Pb Free 저융점 유리의 제조)

  • 최승철;이창식;유재륜;정경원
    • Journal of the Korean Ceramic Society
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    • v.38 no.7
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    • pp.628-633
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    • 2001
  • 전자 패키징에 적용 가능한 저융점 유리 중에서 납성분이 포함되어 있지 않는 Bi계 유리의 연구를 행하였다. 기판과의 일체화를 위한 유리의 응용으로, 소자와의 반응 억제와 열응력 완화를 위해 유리의 저융점화 및 열팽창계수를 제어하였다. 본 연구에서 제조된 Bi계 유리는 DTA와 TMA의 열분석을 통해 5$50^{\circ}C$ 부근에서 연화점이 있고, 열팽창계수는 7.52~12.09$\times$$10^{-6}$/$^{\circ}C$의 범위였으며, 비유전율은 9~13이었다. 본 연구의 납성분을 포함되어 있지 않는 유리조성은 우수한 내산성을 나타내었다.

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Lipids and Fatty Acid Composition of Free and Bound Lipids in Barley Grain (보리의 유리(遊離) 및 결합지질(結合脂質)의 조성에 관한 연구)

  • Kim, Hyun-Ku;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.382-387
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    • 1982
  • Lipids and fatty acid composition of free and bound lipids isolated from four barley varieties were studied. The average content of purified free and bound lipids were 1.57% and 0.48%, respectively. The average contents of neutral lipids, glycolipids and phospholipids in the free and bound lipids contain 81.1% and 16.4%, 11.4%, and 6.8%, 6.7% and 75.5%, respectively. Among the neutral lipids in both free and bound lipids, triglycerides were the predominant with free fatty acids, monoglycerides, diglycerides, free sterol esters being present as minor components. Linoleic, oleic, palmitic and linolenic acid were the principal fatty acids in both free and bound lipids. And fatty acid composition of lipid classes in free and bound lipids were determined.

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The Study on Physical Properties and Applicability of Material of Polyamide-66/Glass Fiber Blends Composition to the Eyewear Frame (Polyamide-66/Glass fiber 블렌드 조성물의 물리적 특성 및 안경테 소재로써의 적용성에 관한 연구)

  • Son, Jin-Young;Lee, Ji-Eun;Choi, Kyung-Man;Bae, Yu-Hwan;Kim, Ki-Hong
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.4
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    • pp.365-371
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    • 2013
  • Purpose: In this study, we evaluated the physical and thermal properties of the compositions made by blending glass fiber (GF) of different contents into glass fiber polyamide-66, and investigated if the compositions applying to the glasses frame to replace the TR-90, which is polyamide-12 resin used as an injection-type spectacle frame material. Methods: To investigate the characteristics change of polyamide-66 (PA-66) compositions with the change of the content of glass fibers, we produced a composition of the content by using a twin-screw extruder. The mechanical strength of the composition production was measured and coating properties as well as cutting processability were evaluated. We evaluated the applicability of the glasses frame by comparison the results of new compositions with characterizations of traditional TR. Results: For the results of the characterization of Polyamide-66/GF composition, we found that the higher increase of content of the glass fiber, the less mold shrinkage rate, and the mechanical strength was increased. Tensile strength increased from $498kg/cm^2$ for 0 wt% of the content of the glass fibers to $849kg/cm^2$ for 30 wt% of the content of the glass fibers. As a result of a coating evaluation, the strength of coating was 4B in the GF 5wt% and 5B, which was extremely good coating characteristics, in the over than GF 5 wt%. Conclusions: In case that 30 wt% of the glass fiber was blended, the mechanical strength was greatly improved, the hardness was increased, injection temperature increased due to increase of the viscosity, and the flow mark of the product may occur. The paint coating of PA-66 blended with glass fiber was all excellent. With general evaluating physical properties and workability properties it was determined that around 10 wt% of the content of the glass fibers was possible to apply a spectacle frame.