• Title/Summary/Keyword: 유리조성

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Production of Foamed Glass by Using Hydrolysis of Waste Glass (I) - Hydrolysis of Waste Glass - (폐 유리의 가수 분해반응에 의한 발포유리의 제조(I) - 폐유리의 가수분해 반응 -)

  • Lee, Chul-Tae;Lee, Hong-Gil
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.519-526
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    • 2005
  • Hydrolysis of soda-lime waste glass was investigated to test the feasibility for use of waste glass as feed material in the production of foamed glass. The soda-lime glass, such as plate glass and various bottle glasses, was effectively hydrolyzed by steam and water under high pressure. The proper condition for the hydrolysis was found to be reaction temperature of $250^{\circ}C$ and reaction time of 2 h. Under this condition, the water content of hydrated glass through hydrolysis was 7.85~10.04%, allowing successful foaming process for production of foamed glass. Using Na as the modifying agent of glass was effective in the hydrolysis by water. The highest water content of hydrated glass was obtained when weight ratio of NaOH to the glass was 0.04.

Chemical Composition and Lead Isotope Ratio of Glass Beads Excavated from Eunpyeong Newtown Site (은평 뉴타운 유적 출토 유리구슬의 성분조성과 납동위원소비)

  • Kang, Hyung-Tae;Cho, Nam-Chul;Han, Min-Su;Kim, Woo-Hyun;Hong, Ji-Youn
    • Journal of Conservation Science
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    • v.25 no.3
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    • pp.335-345
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    • 2009
  • This paper presents investigations on 60 glass beads excavated from floorless tombs of Eunpyeong Newtown site to figure out composition and lead isotope ratio by SEM-EDS and TIMS, which show the difference between their compositions and Pb provenance of lead glass. The results of the composition analysis are that excavated glass are mainly divided into Potash glass($K_2O$-CaO-$SiO_2$) and Potash-lead glass($K_2O$-PbO-$SiO_2$) and the samples excavated from III-3 floorless tombs No.1005 are presumed not glass but Quartz. The transparent 9 lead glasses excavated from II-3 floorless tomb No.101 and III-3 floorless tomb No.908 seem to be manufactured by the same raw material at same site because the concentration of their compositions are well accorded with each other and deviations of them are very limited. As a result of principal component analysis(PCA), glass beads excavated are largely assort to two groups, Potash glass and Potash lead glass as well. That is, glass beads excavated from Eunpyeoung Newtown sites are quite different two types of main composition. In addition, the results of Pb provenance analysis used in lead glass confirm that most lead glass are significantly correlated with galena of northern China.

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Compositions of Fatty Acid, Free Amino Acid and Total Amino Acid of Lespedeza x chiisanensis T. LEE (지리산 싸리의 지질 구성 지방산과 유리 아미노산 및 구성 총 아미노산 조성에 관하여)

  • 김종균
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.5
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    • pp.586-591
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    • 1993
  • The compositions of amino acid in the protein and fatty acid in the lipid of Lespedeza x chiisanensis T. LEE were analyzed by HPLC and GC, respectively. The contents of crude oil and protein from the extracts were 11.13% and 5.18%, respectively. The amount of free anino acids in the protein was 443.14mg/100g, and 94.84mg/100g of essential amino acid were contained in the free amino acid. The amount of total amino acids in the protein was 3159.85mg/100g, and 1068.18mg/100g of essential amino acid were contained in the total amino acid. The compositions of fatty acid in the lipid were $C_{18\;:\;2}=45.05%,\;C_{18\;:\;3}=18.71%,\;C_{19}=14.70%,C_{18\;:\;1}=6.81%,\;C_{16}=4.35%,\;C_{16\;:\;1}=1.59%$ in order, respectively. 72.44% of unsaturated fatty acids were contained in the lipid.

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Impact on Habitat Changes by Restoration of Low-Flow Channel using Physical Habitat Simulation (물리서식처 모의를 통한 저수로 물길 조성이 서식처 변화에 미치는 영향)

  • Choi, Jong Geun;Kim, Jong Joo;Choi, Heung Sik
    • Proceedings of the Korea Water Resources Association Conference
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    • 2019.05a
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    • pp.107-107
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    • 2019
  • 하천은 과거부터 현재까지 인간의 삶에 있어서 중요한 공간이며 환경적, 생태적으로도 중요한 가치를 지니고 있다. 특히, 하천은 물과 흙으로 이루어져 있기 때문에 수생물이 살아갈 수 있는 독특한 생태 서식처 공간을 제공한다. 국내에서는 1980년대 말부터 하천환경의 개선 및 복원에 대해 관심과 인식을 높이고 공감대를 형성하여 훼손된 하천을 원래 모습으로 되돌리는 사업을 수행하였다. 이러한 하천복원사업이 하천에 서식하는 수생물의 어떠한 영향을 주는지 분석하기 위해 최근에는 다양한 물리서식처 분석이 수행되고 이를 통해 각종 복원계획을 수립하고 있다. 하천복원사업을 통한 생태유량 재산정, 보 철거의 영향, 다양한 복원기법을 통한 수생물에 미치는 영향 파악 등을 들 수 있다. 그러나 이러한 기존 연구들은 하천복원사업으로 인한 수리특성과 수생 서식처의 변화를 살펴보는 간접적인 영향에 대한 내용이었다. 그러나 직접적으로 영향을 미치는 하도의 단면을 재설계하고 다양한 복원기법을 적용하여 그 영향을 파악하는 연구도 수행되어야 할 것으로 판단된다. 본 연구는 수리학적으로 유리한 저수로 물길 조성 및 다양한 저수로 조성기법의 적용을 통해 우점종의 서식처에 미치는 영향에 대해 원주천을 대상으로 물리서식처 분석을 수행하였다. 대상구간은 원주천 중 상류에 위치한 900 m 구간으로, 대상 어종은 원주천의 중 상류에 서식하는 우점종인 참갈겨니를 목표로 하였다. 수리분석과 서식처분석은 각각 River2D 모형과 서식처 적합도 모형을 사용하였다. 서식처 적합도 모형에 사용된 서식처 적합도 곡선은 Gosse (1982)의 방법을 이용하여 구축하였으며, 수심, 유속, 기층을 모두 고려하여 물리 서식처 분석을 수행하였다. 저수로 물길 복원 조성을 위하여 수리학적으로 유리한 저수로 단면으로의 복원 및 거석, 여울/소 구조, 단면의 확폭을 통해 기존 자연형 하천과는 다른 복원을 조성하였다. 수리학적으로 유리한 저수로 물길 복원을 조성한 결과를 이용하여 물리서식처 분석을 수행하였을 때, 기존 자연하천인 현상태 대비 약 37% 가중가용면적이 악화되는 것으로 나타났다. 그러나 수리학적으로 유리한 저수로 단면의 설계 조건에서 거석, 여울/소 구조 및 단면의 확폭의 복원을 수행하였을 때 서식처가 최소 약 3%에서 최대 21%까지 가중가용면적이 향상되었다.

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Studies on Chemical Composition of Raspberry (Free Amino Acids, Non-Volatile Organic Acids and Sugar) (나무딸기의 화학적(化學的) 성분(成分) 조성(組成)에 관한 연구(硏究) (유리아미노산, 유기산 및 유리당))

  • Joo, Kwang-Jee
    • Journal of Nutrition and Health
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    • v.11 no.3
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    • pp.21-24
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    • 1978
  • In order to estimate the chemical composition of Raspberry (IR Crataegifalius), the free amino acids were analyzed by amino acid autoanalyzer, and organic acids contents were determined by gas chromatography and the free sugars were detected by paper chromatography. The results obtained were as follows: 1) The free amino acids found in Raspberry were 18 kinds of them, especially, all essential amino acids were showed, and lysine was abundant among them, consequently it was found that the composition of amino acids in Raspberry is more superior than those of the other fruits. 2) The organic acids in Raspberry were found citric acid, tartaric acid, malic acid and fumaric acid. It was found that the quantity of the organic acids was less than those of other common fruits. 3) Sugar such as glucose, fructose, maltose and mannose were detected by paper chromatography.

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Characteristics and Classification of Red Brown Glass Beads Excavated in Korean Peninsula (한반도에서 출토된 적갈색 유리구슬의 특성 및 유형 분류)

  • Kim, Na-Young;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.29 no.3
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    • pp.279-286
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    • 2013
  • It is characterized and classified as the type of red brown glass beads to compare the chemical composition and manufacturing technique on the 141 samples in 12 sites of the Three Kingdom Period analyzed until now. It can be divided into three types according to the chemical composition of stabilizers(CaO & $Al_2O_3$) and soda raw materials(MgO & $K_2O$) on the red brown glass beads except one sample. Type I of high alumina glass is identified as the most common types that is 78.6 % of the distribution ratio at analytical samples and is excavated the most from ruin sites. In contrast, type II, 13.6 % of distribution ratio at analytical samples, is about 5 % CaO and $Al_2O_3$, MgO and $K_2O$ at around 1.5 % is similar to the composition of plant ash glass. Type III is that the content of CaO is higher than $Al_2O_3$ and the content of MgO and $K_2O$ is below 1.5 %. It is the same as the composition of natron glass and its share is the lowest as 7.9 %. Of these, type III is divided into two types according to the content of MgO and $K_2O$. It is identified that manufacturing technique of type I and II is drawing and type III is casting method with microscopic investigations. Type II and III is estimated that raw materials is different because is confirmed in the majority of ruins in spite of the fact that distribution ratio is very low. So, red brown glass beads distributed in Korea Peninsula are divided into three types of glass culture.

A Characteristics on the Ancient Glass Beads Excavated from the Site of Hapgang-ri in Sejong, Korea (세종 합강리 유적 출토 고대 유리구슬의 특성 연구)

  • kim, Eun a;Kim, Gyu Ho;Kang, Ji Won;Yun, Cheon Su
    • Journal of Conservation Science
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    • v.36 no.5
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    • pp.405-420
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    • 2020
  • A convergence research was conducted on glass beads excavated at the ruins of Hapgang-ri, Sejong, using the archeology and conservation approach. The period of appearance of Jugu Towangmyo in the ruins of Hapgang-ri can be estimated to begin in the late 2nd century; for Jugu Towangmyo No. 15, the period spans from the late 2nd to early 3rd century. Form, color, and manufacturing techniques of complete glass beads were examined, and the cross-sections and chemical composition of 16 samples were observed. Based on these analyses, the glass beads were divided into blue, purple, and red colors. The blue-colored beads could be further sub-divided based on their gloss and brightness; in contrast, the red-colored beads were highly uniform with regard to these parameters. Based on the stripe and bubble arrangement on the surface of the glass beads, their drawing technique was identified. Traces of heat treatment or polishing were observed at the ends of the beads. According to their chemical composition, the 16 samples were classified into 3 potash glass and 13 soda glass groups; in the latter, the properties of the stabilizers were divided according to the blue and red bead colors. The stabilizers of the red beads are unique in that they allow the distinction among beads excavated in other areas in South Korea owing to their compositional differences. Colorants in blue- and red-colored beads are cobalt (containing MnO), and copper and iron, respectively.

Dissolution Properties of K2O-CaO-MgO-SiO2-P2O5 Glasses (K2O-CaO-MgO-SiO2-P2O5계 유리의 제조 및 용출특성)

  • 이용수;윤태민;강원호
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1132-1137
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    • 2003
  • For the application of environment conscious glass-fertilizer, dissolution characteristics of phosphate glass was investigated. In 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/ glass system, the compositions were designed according to variation of CaO & MgO contents, and glass formation region was confirmed. From the glass composition, the confirmed glasses were investigated to figure out thermal and dissolution properties. It was detected that glass transition & softening temperature of the glasses increased with increasing MgO contents. The dissolution properties of the glasses was affected by CaO and MgO content ratio.