• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.3
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• pp.255-262
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• 2020

Blended cement with fly ash and bottom ash from Circulating Fluidized Bed Combustor boiler(CFBC) burned at a low temperature, can be high heat of hydration and abnormal setting caused by higher volumn contents of Fe₂O₃, free-CaO, SO₃. In this study, the ground CFBC bottom ash powder mixed with blast furnace slag was used as substitute activator of gypsum and recycled iron slag was produced from mix and pulverized by ball mill to increase the recycling rate. The effect on compressive strength of cements with the mixture of original and hydrated bottom ash mixtures with BFS with small water, respectively, was analyzed, and it was found that the hydrated bottom ash activator was more effective in initial strength development. To improve the initial strength of blended cement, an activator mixed with a blast furnace slag and bottom ash mixing ratio of 5:95 and 10:90, respectively, the slag cement by about 6%, and it was analyzed to develop an initial strength similar to gypsum as a conventional activator.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.856-863
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• 2018

In order to investigate the re-carbonation behaviors of limestones in an oxy-circulating fluidized bed combustor (Oxy-CFBC), the re-carbonation characteristics of domestic 4 different limestone samples were analyzed in a thermogravimetric analyzer (TGA-N1000) with the higher concentration of $CO_2$. Effect of reaction temperature ($600{\sim}900^{\circ}C$) and $CaCO_3$ content (77~95%) of limestones were determined and the mass change of the CaO was observed. Under the temperature of $800^{\circ}C$, the conversion rate increased with increasing reaction temperature. However, the conversion rate decreased with increasing reaction temperature over $800^{\circ}C$. In the case of $CaCO_3$ content, the conversion was remarkably different at $870^{\circ}C$. In addition, reaction rate equations for simulating the re-carbonation of limestone by using gas solid reaction models were proposed in this study.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.417-428
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• 2021

The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MW_th Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MW_th Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m³. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO₂ concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.37-43
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• 2019

This research studied production of lightweight filling production for sink hole restoration utilizing various industrial by-products(2kinds of fly ash, petro-cokes CFBC ash, blast furnace slag fine particle). For this purpose, the mixed raw material properties(compressive strength) behaviors according to the blending ratio of industrial by-products were examined by applying the experimental design method and statistical analysis was performed using the commercial program MINITAB. Compressive strengths of industrial by-products were strongly dependent on blast furnace slag powder. Compressive strength(3days aging) was 3~11MPa depending on the amount of blast furnace slag powder used. The use of CFBC fly ash was evaluated to have the least effect on compressive strength. In addition, the compressive strength and the coefficient of permeability were measured by preparing foamed concrete for the experimental batch 1 condition in the mixture experimental design. In this case, the bulk density is 0.9 to 1.0, the apparent porosity is 30 to 50%, the compressive strength(3days old) is 1 to 2MPa, and the permeability coefficient is $10^{-2}$ to $10^{-3}cm/sec$.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.492-500
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• 2019

In this study, the effect of chemical additives on the reduction of fine particles was identified in $9.2MW_e$ commercial scale circulating fluidized bed boiler firing bituminous coal. Futhermore, a simple and effective method of fine particle collection has been developed to collect the fine particles of the boiler during fossil fuel combustion. Chemical additives were used to reduce particles below 10 PM in the flue gas, and borax solution was used as a chemical additive. In order to identify the particle behavior of PM 10 or less among the collected fine particles, it was analyzed through particle size analyzer and SEM analysis. The Borax solution tends to absorb molten mineral in the flue gas and make fine particles grow. As a result, it was analyzed that particles smaller than $10{\mu}m$ were reduced by using borax solution.

• Proceedings of the KSME Conference
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• 2004.11a
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• pp.1756-1760
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• 2004

Circulating Fluidized-Bed (CFB) boilers which have been operated in Korea were manufactured by the design technology of foreign leading companies. As they are not active to transfer their technology, domestic companies don't have the enough ability to design it independently yet. Doosan Heavy Industries & Construction Co. Ltd. and Korean Institute of Energy Research are trying to develop and improve the particle re-circulating device among the components of CFB boiler. Our purpose is to control the amount of particles leaving the re-circulating system by adjusting utility air and reuse the heat of circulating particles. The results of experiments with cold model system show that a fluidization state in the particle re-circulating device is very stable when the amount of utility air is supplied to its wind box with 2.29 times of minimum fluidization velocity. Also the amount of particles entering the riser don't increase linearly when the amount of utility air is supplied over 2.5 times of minimum fluidization velocity. Now we are testing its functional run with the hotstate experiment set-up.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1996.10b
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• pp.167-170
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• 1996

석탄의 고압 유동층연소는 기존의 PC 보일러보다는 저온 연소로써 NOx의 발생이 억제되며 탈황제를 동시에 주입하여 SOx 발생을 줄일 수 있는 것이 큰 잇점으로서 석탄 신에너지 개발에 유력한 시스템이다. 본 시스템에서 집진은 연소가스 중의 입자가 고온고압에서 고속으로 터빈에서 충돌될 때 일어나는 터빈의 마모, 침식, 및 부식 등을 방지하기 위하여 필수적이다. PFBC 연소기에서 연소된 가스가 정제후에 바로 가스터빈에 주입되기 때문에 PFBC의 집진은 매우 가혹한 조건이다. 뿐만 아니라 차세대에 더욱 높은 열효율 향상과 가스터빈의 수명 연장을 위하여 집진조건이 더욱 가혹해지고 엄격해질 전망이다. 그 동안 PFBC 집진의 연구가 다방면으로 진행되고 있으나 상용화를 위한 준비가 아직 갖추어지지 않았으며 모든 집진 시스템이 잠정적인 문제점을 갖고 있다. 그 중에서도 세라믹 캔들 필터는 성능이 우수하고 가장 많은 운전경험을 갖고 있기 때문에 가장 가까운 시기에 상용화에 성공할 수 있는 집진 시스템이다. 본 고에서는 세라믹 캔들필터 개발의 현황과 핵심 개발과제에 대하여 논의코자 했다.

• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.414-422
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• 2005

유럽에서 RDF기술 확산 동향과 국가별 RDF사용 현황, 각국의 RDF품질표준 및 최근 유럽공통RDF품질표준화 추진현황을 소개하고 RDF사용처별 경제성분석 내용을 소개하였다. 소각로, 시멘트공장 및 석탄화력발전소에서 RDF를 사용할 경우에 열회수량은 시멘트공장이 다소 높게 나타났고 손익평가(cost benefit balance)는 석탄화력발전소가 가장 높게 나타났다. 국내에서 가동 중인 20MW급 순환유동층 석탄화력발전보일러에서 폐플라스틱고형연료(RPF)를 혼합연소하는 기술과 염화수소 및 다이옥신 측정내용을 소개하였다. 전염소량 0.4$\sim$0.6% RPF를 2.5%혼소 시 염화수소는 10ppmv 정도로 분석되었고 다이옥신은 0.003ng-TEQ/$Sm^3$으로 거의 검출이 되지 않았다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.609-612
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• 2007

The co-combustion of coal and RPF(Refuse Plastic Fuel) mixture has been experimented in a commercially operating CFB coal boiler and the emissions such as SOx, NOx, TSP and dioxine were measured at the stack. The experimented RPF was supplied by domestic RPF company that is commercially producing RPF pellet from the wasted plastics. Up to 15% of total coal was substituted to RPF and no trouble was happened during normal boiler operation. SOx and NOx concentration was reduced about $15{\sim}20$% and TSP(Total Suspended Particle) was drastically reduced about 30% during co-combustion. Dioxine concentration at mixing ratio of 7.5% was $0.0487ng{\sim}TEQ/Sm^3$ ($O_2$, 12%) that satisfied governmental emission regulation.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.145-148
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• 2008

Fuel flexibility of CFBC boiler was examined. Combustion characteristics of low grade coal, coal sludge, coal RDF mixture and RDF were compared. The operation result of a commercial 130TPH CFBC co-generation boiler burning a low grade Chinese coal were analysed. Burning characteristics of coal/RDF mixture and coal and industrial sludge mixture were studied in a 0.1MWth scale CFBC test rig. Also RDF fuel were tested in a 8TPH CFBC test facility. Though fuel characteristics were different, the combustion modes were all very stable. The temperature were maintained in between $800-950^{\circ}C$.