• Title/Summary/Keyword: 유기폐액

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Hydrogen Production from Fruit Wastes by Immobilized Cells of Enterobacter cloacae VJ-1 (Enterobacter cloacae YJ-1의 고정화세포에 의한 과일 폐기물로부터 수소생산)

  • Lee, Ki-Seok;Huh, Yang-Il;Chung, Seon-Yong;Kang, Chang-Min
    • KSBB Journal
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    • v.20 no.6
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    • pp.447-452
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    • 2005
  • The hydrogen production using immobilized cellsl was conducted using fruit wastewaters at various culture conditions. Three kinds of fruit wastewaters, melon, watermelon and pear were used. Sodium alginate was used as immobilization material. Among them, concentration of reducing sugar which was one of the main components in fruit was the highest at watermelon wastewater, and also hydrogen production was the highest as 2319.2 mL/L in it. Although hydrogen production was not much changed according to sodium alginate concentration, its production was the most at 3%(w/v). As bead size as small, hydrogen production was higher. With inspection of interior, it confirmed that the cell grew well in bead. But the addition of amino acids using as agent for metabolite production had almost no affected on hydrogen productivity. The effective range of $FeSO_4$ addition on hydrogen production were up to 1.2 g/L, and above the concentration, it inhibited the productivity. Organic acids produced during watermelon fermentation were mainly lactic acid, butyric acid, abd acetic acid; and a little of propionic acid.

Study on application of membrane for wastewater in biogas plants (BGP(Biogas Plant) 발생폐수의 분리막 적용 연구)

  • Kim, Shin-Young;Chang, In-Soung;Kim, Jang-Kyu;Yu, Myeong-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.503-503
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    • 2010
  • 국제협약에 따라 2012년부터 유기성폐기물의 해양배출이 금지됨에 따라 환경문제를 유발하는 축산분뇨, 음식물쓰레기, 농축산 폐기물 등의 처리가 곤란한 실정이다. 그러나 최근 저탄소 녹색성장으로 정부가 폐자원 에너지화에 관심을 기울이면서 위의 폐기물을 바이오가스로 전환하는 바이오가스 플랜트(Biogas Plant, BGP)의 이용이 보다 활성화 될 전망이다[1]. 이 바이오가스 처리방법에서 유기물은 메탄가스로 배출되고[2], 나머지 영양성분들(질소, 인산, 칼륨 등)은 모두 소화액에 남아있으므로[3] 이들은 친환경농업에서 필요한 액비로도 활용이 가능하며, 혐기소화 처리방법은 일반적인 가축분뇨 처리과정에서 발생되는 악취문제도 해결할 수 있는 장점 또한 가지고 있다. BGP는 유기성 폐기물에서 혐기성소화를 통해 바이오가스를 만드는 장점이 있는 반면, 가스를 만들고 남은 소화액은 액비로 활용이 가능하지만, 액비로 활용이 불가능할 경우 악성 폐수로 그 처리가 매우 까다로운 단점이 있다. 일반적인 생물학적인 폐수처리방법으로는 처리가 곤란하며, 환경기준을 맞추도록 처리하는데 많은 비용이 소요된다. 이러한 폐액처리를 위해 공정의 단순화와 높은 처리 효율[4]을 가지면서, 액비 또는 정화처리공정이 가능한 방법으로서 분리막공정이 바람직하나, BGP 발생폐액의 성상이 고농도의 오염물질을 함유하고 있어 적용이 쉽지 않다. 따라서 본 연구에서는 이를 보안할 수 있는 와류발생형 막모듈을 이용하여 Biogas Plant의 발생폐수에 대하여 분리막을 이용한 효과적인 처리공정을 개발하고 그에 따른 최적의 조건을 찾는 연구를 하고자 한다. 와류발생형 막모듈을 막과 막 사이에 와류를 발생시킴으로써 막에 전단력을 가하여 막의 가장 큰 단점인 막오염을 줄이는 방법으로 기존의 막모듈과 큰 차이가 있을 것으로 예상된다. 본 연구에서는 기존의 분리막 모듈[5]과 와류발생형 막모듈의 차이를 실험을 통해 확인하며, 막에 가해지는 압력, 막을 통과하는 유량 등의 차이를 두어 최적조건을 탐색하였다.

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Characteristics of methane production for treatment of brewery wastewater using anaerobic filter (혐기성 필터를 이용한 맥주 폐수 처리에서 메탄 생산 특성)

  • Choi, Young-Ki;Choi, Suk Soon;Chung, Hyung Keun;Jeong, Tae-Young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.29-34
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    • 2011
  • In the present work, the anaerobic filter was used to treat the high concentration of organic wastewater which was produced in the beer production process. During the whole operation periods, wastewater treatment with methane production was effectively performed. The average removal efficiencies of BOD, CODcr, SS, TN and TP were 61.4, 60.9, 31.4, 70.7 and 70.0 %, respectively. Also, methane content in the total gas and methane production amount were 68.8 % and $0.08{\sim}0.77m^3CH_4/kgCOD$, respectively. As a consequence, the practical anaerobic digestion technology developed in this study showed a feasibility of an effective method to treat brewery wastewater with enhancing the methane productivity.

Recovery of Silver from the Spent Solution Generated from Electrochemical Oxidation of Radioactive Wastes (放射性 폐기물의 전기화학적 분해 폐액으로부터 銀의 回收)

  • 문제권;정종훈;오원진;이일희
    • Resources Recycling
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    • v.10 no.5
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    • pp.22-28
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    • 2001
  • Recovery of silver in the spent solution generated from MEO(Mediated Electrochemical Oxidation) process, which is a process to decompose radioactive organic mixed wastes at low temperature, was performed using chemical method. Silver nitrate in 5M nitric acid solution could be completely recovered as AgCl by using 1% excess of the stoichiometric HCl equivalents. Then, AgCl was transformed to Ag metal by reduction reaction with hydrogen peroxide under alkaline media. The optimum pH for the reduction to silver metal was found to be in the range of 12.8∼13.0.

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Characterization of Kraft Lignin by 13C-Nuclear Magnetic Resonance Spectroscopy (13C-NMR에 의한 크라프트 리그닌의 특성)

  • Lee, Beom-Goo;Hwang, Byung-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.17 no.4
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    • pp.44-56
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    • 1989
  • To recover much residual lignin from the black liquor of kraft pulp. the black liquor was extracted and purified with many organic solvents. Many kinds of lignins were isolated from each fraction obtained and the characteristics of these lignins investigated by $^{13}C$-NMR spectroscopy. If M$\ddot{o}$rck's method was compared with Kirk's method. M$\ddot{o}$rck's method was better than Kirk's method because the particular signals of each lignin occur more in the former than m the latter. Especially the $^{13}C$-NMR spectrum of the MCS fraction identifies with those of other researchers. The experiment that the kraft lignin from Pinus densiflora S. et Z. found in Korea was investigated by $^{13}C$-NMR spectroscopy was performed first in Korea.

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Technology Trends of Metal Recovery from Wastewater (폐수(廢水) 중(中) 유가금속(有價金屬) 회수기술(回收技術) 동향(動向))

  • Hwang, Young-Gil;Kil, Sang-Cheol;Kim, Jong-Heon
    • Resources Recycling
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    • v.22 no.3
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    • pp.91-99
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    • 2013
  • Steel industry which has been accomplishes the base of our country economy, automobile and electronic industry are taking charge of the role, whose electroplating is important. Large amount of wastewater and various metal salts, including hazardous materials was generated from the electroplating pre-treatment, plating, washing and post-plating. Currently, the general wastewater follows in the environmental law and neutralization after controlling, sludge where the various metal is mixed reclaims below multiple regulative and trust it is controlling. The sludge which includes the gas price metal reclaims in the field and trust it controls. a reclamation price of land it is insufficient but and the control expense holds plentifully and it loses the gas price metal which is valuable. Consequently, The research regarding to recover a gas price metal actively from this waste water, it is advanced. A new method to recover valuable metals from electroplating wastewater synthesis of metal sulfides using topical methods utilizing iron oxidizing bacteria, reagent of sulfides and solvent extraction using an organic solvent, such as the development of the law to recover these metals and metal sulfides of wastewater using selective recovery have been studied. By using these wastewater treatment method under frequency above 95%, it has been obtained the valuable metal from the wastewater, where the metal ion of Fe, Cu, Zn and Ni complexes was mixed. As we discuss the wastewater, which has been discharged from electroplating process, it is important and will be applied to the resources of metal in the urban mine.

The effects of aqueous extracts of plant roots on germination of seeds and growth of seedings (식물근의 추출물질이 종자발아 및 유식물의 생장에 미치는 영향)

  • Chan-Ho Park
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.4 no.1
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    • pp.1-23
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    • 1968
  • This study aimed at contributing to the improvement of cropping systems after finding out the effects of excrements and components of crop root influence on other crops as well as themselves. The following forage crops suitable for our country were selected for the present study. Aqueous extracts of fresh roots, aqueous extracts of rotting roots and aqueous solutions of excrements of red clover, orchard grass and brome grass were studied for the effects influencing the germination and growth of seedlings of red clover, ladino clover, lespedeza, soybean, orchard grass, Italian ryegrass, brome grass, barley, wheat, sorghum, corn and Hog-millet. In view of the possibility that the organic acid might be closely related to the excrements and components of crop root connected with soil sickness, the acid components of three species of roots were analysed by paper chromatography and gas chromatography method. The following results were obtained: 1. Effects of Aqueous Extracts of Fresh Roots : Aqueous extracts of red clover: The extracts inhibited the growth of seedlings of the ladino clover and lespedeza and also inhibited the development of most crops except that of sorghum among the Graminaceae. Aqueous extracts of orchard grass: The extracts promoted the seedlings growth of red clover and soybean, while it inhibited the germination and growth of orchard grass. There were no noticeable effects influencing other crops while it inhibited the growth of barley and Hog-millet. Aqueous extracts of brome grass: There was no effect on Italian ryegrass but there was an inhibiting effect on the other crops. 2. Effects of Aqueous Extracts of Rotting Roots : Aqueous extracts of red clover: The extracts promoted the seedling growth of red clover. But it reflected the inhibiting effects on other crops except sorghum. Aqueous extracts of orchard grass: The extracts promoted the growth of red clover, ladino clover, soybean and sorghun, while it inhibited the germination and rooting of barley and Hog-millet. Aqueous extracts of brome grass: The extracts gave the promotive effects to the growth of red clover, soybean and sorghum, but caused inhibiting effects on orchard grass, brome grass, barley and Hog-millet. 3. Effects of Aqueous Solutions of Excrements : The aqueous solution of excrements of red clover reflected the inhibition effects to the growth of Graminaceae, while the aqueous solutions of excrements of orchard grass and Italian ryegrass caused the promotive effects on the growth of red clover. 4. Results of Organic Acid Analysis : The oxalic acid, citric acid, tartaric acid, malonic acid, malic acid and succinic acid were included in the roots of red clover as unvolatile organic acid, and in the orchard grass and brome grass there were included the oxalic acid, citric acid, tartaric acid and malic acid. And formic acid was confirmed in the red clover, orchard grass and brome grass as volatile organic acid. In consideration of the results mentioned in above the effects of excrements and components of roots found in this studies may be summarized as follows. 1) The red clover generally gave a disadvantageous effect on the Graminaceae. Such trend was considered chiefly caused by the presence of many organic acids, namely oxalic, citric, tartaric, malonic, malic, succinic and formic acid. 2) The orchard grass generally gave an advantageous effect on the Leguminosae. This may be due to a few kinds of organic acid contained in the root, namely oxalic, citric, tartaric, malic and formic acid. Furthermore a certain of promotive materials for growth was noted. 3) As long as the root of brome grass are not rotten, it gave a disadvantageous effect on the Leguminosae and Graminaceae. This may be due to the fact that several unidentified volatile organic acid were also included besides the confirmed organic acid, namely oxalic, citric, tartaric, malic and formic acid. 5. Effects of Components in Roots to the Soil Sickness : 1) It was considered that the cause of alleged red clover's soil sickness did not result from the toxic components of the roots. 2) It was recognized that the toxic components of roots might be the cause of soil sickness in case the orchard grass and brome grass were put into the long-term single cropping. 6. Effects of Rooted Components to the Companion Crops in the Cropping System : a) In case of aqueous extracts of fresh roots and aqueous excrements (Inter cropping and mixed cropping) : 1) Advantageous combinations : Orchard grass->Red clover, Soybean, Italian ryegrass->Red clover, 2) Disadvantageous combinations : Red clover->Ladino clover, Lespedeza, Orchard grass, Italian ryegrass, Fescue Ky-31, Brome grass, Barley, Wheat, Corn and Hog.millet, Orchard grass->Lespedeza, Orchard grass, Barley and Hog-millet, Brome grass->Red clover, Ladino clover, Lespedeza, Soybean, Orchard grass, Brome grass, Barley, Wheat, Sorghum, Corn and Hog-millet, 3) Harmless combinations : Red clover->Red clover, Soybean and Sorghum, Orchard grass->Ladino clover, Italian ryegrass, Brome grass, Wheat, Sorghum and Corn, Brome grass->Italian ryegrass, b) In case of aquecus extracts of rotting roots(After cropping) : 1) Advantageous combinations : Red clover->Red clover and Sorghum, Orchard grass->Red clover, Ladino clover, Soybean, Sorghum, and Corn, Brome grass->Red clover, Soybean and Sorghum, 2) Disadvantageous combinations : Red clover->Lespedeza, Orchard grass, Italian ryegrass, Brome grass, Barley, Wheat, and Hog-millet Orchard grass->Barley and Hog-millet, Brome grass->Orchard grass, Brome grass, Barley and Hog-millet, 3) Harmless combinations : Red clover->Ladino clover, Soybean and Corn, Orchard grass->Lespedeza, Orchard grass, Italian ryegrass, Brome grass and Wheat Brome gass->Ladino clover, Lespedeza, Italian ryegrass and Wheat.

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Microbial Conversion of Organic Wastes for Production of Biogas and Algal Biomass (바이오가스와 균체단백질 생산을 위한 유기질 폐기물의 미생물 전환 연구)

  • 권순찬;김진상
    • KSBB Journal
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    • v.8 no.5
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    • pp.438-445
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    • 1993
  • Raw cow manure was treated by a 4-step integrated system with phase separation anaerobic digestion and algal culture. When the first methane fermentation was performed by the effluent from the acid fermenter with retention time of 4 days, the elrerage blogas production rate was 977m1/1 culture/day Gas productivity compared to conventional single-stage anaerobic digestion increased up to 31.4%. As the 2nd methane fermenter was fed by the effluent from the first methane fermenter with 4 days of retention time, average amount of 428m1/1 culture/day of biogas was produced. The reduction rate of COD in the effluent from the acid fermenter, the 1st and the 2nd methane fermenter were 71.8%, 42.6% and 24.0% respectively. Finally, we examined algal treatment process for the effluent from the 2nd methane fermenter. A semi-continuous culture of Chlorella sp. PSH3 was conducted by feeding the effluent with retention time of 10days. In this process, the production rate of algal biomass and COD reduction rate were averaged 1.8g/1 culture/day(2.8$\times$106 cells/ml) and 73%, respectively. Through the 4-setp treatments, the total chemical oxygen demand was reduced from 51,300ppm to 85ppm. Therefore, the reduction rate of total chemical oxygen demand reached about 99.8%. The results indicate that the integrated system could be applicable for treatment of organic wastes, concurrently producing biogas and algal biomass.

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고효율 자외선/광촉매 시스템을 이용한 고농도 유기성 폐수처리

  • Jeong, Hyo-Gi;Kim, Jung-Gon;Kim, Si-Uk
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.272-276
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    • 2005
  • Food wastewater derived from three-stages methane fermentation system showed high concentrations of sCOD, T-N and $NH_{3}-N$. To treat the organic wastewater, the optimal operating conditions for high efficiency $UV/TiO_{2}$ photocotalytic system have been investigated. In the first process, wastewater was pre-treated with $FeCl_{3}. The optimum pH and concentration for coagulation were 4.0 and 2000 mg/L, respectively. Through this process, 52.6% of $COD_{cr}$ was removed. The second process was $UV/TiO_{2}$ photocatalytic reaction. The optimum conditions for the operation of $UV/TiO_{2}$ photocatalytic system developed in this lab have been studied. In this process, CODcr was removed from 2890 to 184 mg/L and T-N was removed from 2496 to 914 for 24 hours, respectively.

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Anaerobic Digestion of Distillery Wastewater in a Two-phase UASB System (이상 UASB 공정을 이용한 주정폐수의 혐기성소화)

  • Shin, Hang Sik;Bae, Byung Uk;Paik, Byung Cheon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.4
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    • pp.185-192
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    • 1990
  • A two-phase UASB system was operated for high-rate treatment of concentrated distillery wastewater. The phase separation was obtained by adjusting pH in each reactor. When influent SS concentration was 4.1/g/l, the first phase UASB reactor was effectively operated up to the loading rate of 16.5kg $COD/m^3.day$, producing 3.9g HAc/l.day. In the methanogenic UASB reactor, loading rate up to 44kg $COD/m^3.day$ could be applied while removing 80% of influent COD with a specific gas production of 16.5 l/l. day. After the formation granular sludge in both reactors, it was possible to maintain the appropriate pH in the first phase only by recirculating the effluent from methanogenic phase without the addition of alkaline chemicals.

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