• Title/Summary/Keyword: 유기자원

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Solvent Extraction of Heavy Rare Earth Elements Using PC88A from Synthesis Solution of Low Concentration Rare Earth Solution (저농도 희토류 용액으로부터 PC88A를 이용한 중희토류의 용매추출 연구)

  • Ahn, Nak-Kyoon;Im, Byoungyong;Lee, Jieun;Park, Jae Ryang;Lee, Chan-Gi;Park, Kyung-Soo
    • Resources Recycling
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    • v.26 no.4
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    • pp.26-33
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    • 2017
  • The behavior on the solvent extraction of heavy rare earths (HRE) by using PC88A was confirmed to demonstrate the possibility of recovery on the HRE from industrial wastewater, which consist of low concentration rare earth. We verified the extraction behavior of the HRE through a change of equilibrium pH, extractant concentration and A/O ratio, and also confirmed the stripping behavior depending on the type of mineral acids. At equilibrium pH 1.0, extraction of rare earth (RE) was completed from 95% to 100%. In all extraction conditions, it tend to be extracted in order of high atomic number. When A/O ratio was 10/1, Yb and Tm were concentrated at the maximum and increased 6-fold and 3-fold compared to initial concentration, respectively. To confirm the stripping behavior of the RE, three mineral acids were applied to the organic phase and consequently rate of stripping was increased in order of $HNO_3$, $H_2SO_4$ and HCl.

A Basic Study on Non-aqueous Electrolysis of Neodymium for Room-temperature Metallurgy (상온제련을 위한 네오디뮴의 비수계 전해 기초연구)

  • Park, Jesik;Lee, Churl Kyoung
    • Resources Recycling
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    • v.27 no.4
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    • pp.29-35
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    • 2018
  • In this study, the electrochemical redox behavior of neodymium in non-aqueous electrolytes was investigated to confirm the possibility of neodymium metallurgy at room temperature. The non-aqueous electrolytes include ionic liquids such as $[C_4mim]PF_6$, $[C_4mim]Cl$, and $[P_{66614}]PF_6$, ethanol which are highly soluble in neodymium salts, and mixed electrolytes based on carbonate with highly electrochemical stability. The electrochemical redox properties of neodymium were better than those of other electrolytes in the case of the mixed electrolyte based on ethylene carbonate (EC)/di-ethylene carbonate (DEC). Ethanol was added to improve the physical properties of the mixed electrolyte. Thorough the analysis about ionic conductivity of EC/DEC ratio, ethanol content and $NdCl_3$ concentration, the best electrolyte composition was 50 vol% content of ethanol and 0.5 M of $NdCl_3$. Using cyclic voltametry and linear sweep voltametry, a current peak estimated at -3.8 V (vs. Pt-QRE) was observed as a limiting current of neodymium reduction. Potentiostatic electrolysis for 18 hours at room temperature at -6 V (vs. Pt-QRE) confirmed that metallic neodymium was electrodeposited.

Environmental Characteristics of Exochorda serratifolia S.Moore Habitats (가침박달 자생지의 환경특성)

  • Kim, Kyung-Ah;Cheon, Kyeong-Sik;Yoo, Ki-Oug
    • Korean Journal of Plant Resources
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    • v.27 no.2
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    • pp.155-173
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    • 2014
  • The habitats characteristics of Exochorda serratifolia were investigated to compile basic data for conservation and restoration. Natural habitats were located at an altitude of 1 m to 624 m above sea level with angles of inclination ranging from 2 degrees to 81 degrees. A total of 248 vascular plant taxa were identified from 37 quadrats in 16 habitats. The importance value of Exochorda serratifolia is 18.70%, and 5 highly ranked species such as Rhododendron mucronulatum (3.79%), Abelia tyaihyoni (3.27%), Euonymus alatus for. ciliatodentatus, Quercus mongolica (3.23%), and Indigofera kirilowii (2.97%) are considered to be an affinity with Exochorda serratifolia in their habitats. Species diversity was 1.03, dominance and evenness were found to be 0.15 and 0.85, respectively. Average field capacity was 24.19%, the organic matter was 8.21%, pH was 5.52, and available phosphorus was $7.71{\mu}g/g$. Correlation coefficients analysis based on environmental factors, vegetation, and soil analysis shows that the coverage of Exochorda serratifolia is correlated with field capacity and available phosphorus.

Multiple Shoot Induction and Bulb Mass Proliferation System by in Vitro Immature Spathe Culture of Elephant Garlic (Allium ampeloprasum L.) (코끼리마늘(Allium ampeloprasum L.)의 기내 미숙총포 배양을 통한 다신초유도와 종구대량증식 시스템)

  • Kwon, Young Hee;Jeong, Jae Hyun;Lee, Jae Sun;Jeon, Jong Ok;Park, Young Uk;Min, Ji Hyun;Chang, Who Bong;Lee, Sang Young;Youn, Cheol Ku;Kim, Ki Hyun
    • Korean Journal of Plant Resources
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    • v.31 no.4
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    • pp.355-362
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    • 2018
  • This study was performed to develop the mass propagation system using tissue culture technique to supply the seeds of Elephant garlic (Allium ampeloprasum L.) which has difficulty in propagation. Immature spathe of Elephant garlic was cultured on Murashige & Skoog (MS) medium supplemented with two plant growth regulators, naphthaleneacetic acid (NAA) and kinetin. After 6 weeks of culture, the highest number of shoot (14.9/explant) was obtained when the immature spathe with 10 cm length was cultured right after harvesting. In MS medium supplemented with 2 mg/L kinetin and 0.5 mg/L NAA, the most vigorous growth characteristics was observed, the shoot number was 14.9/explant, its length was 11.3 cm, and its fresh weight was 2.5 g. When the bulblets were cultured in MS medium with 2 mg/L kinetin and 0.5 mg/L NAA, the addition of 30 mg/L adenine improved their proliferation and growth significantly, the highest bulblet formation rate (48%) was obtained. The addition of 7% sucrose also increased the bulblet formation rate at the highest frequency of 98.2%. The shoots were shown be more vigorously proliferated at the secondary subculture stage rather than primary culture stage, their propagation rate was 80% after subculture.

Identification of C3G(cyanidin-3-glucoside) from Mulberry Fruits and Quantification with Different Varieties (오디에서 C3G(cyanidin-3-glucoside)의 분리, 동정 및 계통별 함량분석)

  • 김현복;김선림
    • Journal of Sericultural and Entomological Science
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    • v.45 no.2
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    • pp.90-95
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    • 2003
  • This study was carried out to identify of C3G (cyanidin-3-glucoside) from mulberry fruits and quantify with different varieties. C3G of mulberry fruits was extracted with 1% HCl-MeOH and purified with open column (5${\times}$90cm) which filled with Amberlite IRC-50 ion exchange resin. The $\lambda$max ranges of the purified C3G on UV/vis spectrum were 516nm and 280nm. Also, molecular weight of C3G from mulberry fruits by LC-Mass was determined as 449. From above results, we concluded that anthocyanin pigment of mulberry fruits was C3G only. The cyanidin-3-glucoside (C3G) was separated and quantified by High Performance Liquid Chromatography (HPLC) system using a Nova-Pack C$\_$18/ column. Mean content of the 35 tested accessions was 0.89%. Also fruity characteristics as well as C3G content to select the desirable mulberry varieties for the production of fruit were researched and analyzed. We selected three suitable varieties such as 'Susungppong', 'Kangsun', and 'Jeolgokchosaeng(Chungpuk)'.

Development and Evaluation of Artificial Lightweight Soil Using Bottom Ash (바텀애시를 활용한 인공경량토양의 개발 및 성능 평가)

  • Kim, Chul-Min;Kim, Min-Woo;Cho, Gun-Young;Choi, Na-Rae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.252-258
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    • 2018
  • A larger energy consumption and concentration of population induced green house gas glowing and heat island effect in the urban space. Roof green system was a effect method to reduce green house gas and heat concentration in the city. Therefore, construction of this system was increasing. Most of lightweight soil used in roof green system was perlite, but this caused dust and skin disease. So it needed to develop another new lightweight soli for roof green system. Meanwhile, a thermoelectric power plant generated bottom ash as a by-product. According to previous research, bottom ash could be used for artificial lightweight soil with 60 wt% of mixing rate. But this study was proceed to develop a artificial lightweight soil using bottom ash with higher mixing rate by 65 wt% and different organic ingredients. First, physical and chemical properties of bottom ash was investigated. Then test according to landscaping design standard was proceeded for various artificial lightweight soil mix types using bottom ash, bark, compost and coco peat. As a result, the artificial lightweight soil with 65% of bottom ash, 30% of bark and 5% of compost was suitable for low and middle range of soil standard.

Solvent Extraction of Li(I) from Weak HCl Solution with the Mixture of Neutral Extractants Containing FeCl3 (FeCl3를 함유한 중성추출제의 혼합용매로 약한 염산용액으로부터 리튬(I)의 용매추출)

  • Xing, Weidong;Lee, Seah;Lee, Manseung
    • Resources Recycling
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    • v.27 no.6
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    • pp.53-58
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    • 2018
  • Solvent extraction of Li(I) from weak HCl solution was investigated by the mixture of TBP/MIBK with other neutral extractants such as Cyanex 923, TOPO and TOP. The TBP/MIBK organic phase was loaded with 0.1 M $FeCl_3$ at different HCl concentrations (1-9 M). Extraction of Li(I) from weak HCl solution is related to the stability of $FeCl_3$ in the organic mixture. As HCl concentration increased in preparing the loaded TBP phase, the stripping percentage of Fe(III) during the extraction of Li(I) became reduced and thus Li(I) could be extracted by ion exchange reaction with hydrogen ion in the organic. The concentration of TBP in the extractant mixture affected the stability of $FeCl_3$. Compared to TBP, Fe(III) was easily stripped from the loaded MIBK and thus no Li(I) was extracted by the mixture with MIBK. The nature of neutral extractant with TBP/MIBK showed little difference in the extraction of Li(I) and stripping of Fe(III).

The Commercialization Ways of Wellness Tourism and the Problems of Healing Tourism in Gangwon Province Model (강원도형 치유관광의 과제 및 웰니스 상품화 방안)

  • Kim, Sang-Yoon
    • Journal of the Korea Convergence Society
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    • v.10 no.7
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    • pp.317-323
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    • 2019
  • Amid the recent growing social demand for wellness culture and healing tourism, I, through a literature survey and case study, reviewed the conditions of healing tourism in Gangwon-do as a destination of healing tourism, and examined the development project of Gangwon-do type healing tourism and commercialization of the wellness perspective. According to the survey, it was found that the Yeongdong area in Gangwon Province had excellent healing-based conditions in virtue of abundant natural resources, but it was found that it was necessary for local governments to cooperate in order to prevent overlapping investments and create synergy effects by connecting with one another as development contents or business items of healing tourism projects overlap or remain in the planning stage. In the case of Goseong-gun, which was reviewed as the main site, it has high potential as a silver-healing tour and if the County seeks a wellness merchandising strategy for each healing tourism target based on a therapy program linked with local specialized resources, and effectively links and specializes regional strengths in Gangwon-do's Yeongdong region, it is expected to become a regional success story of operating the development of the local tourism for silver and health-oriented tourists.

Biochemical Methane Potential Analysis for Anaerobic Digestion of Marine Algae (해조류의 혐기소화를 위한 메탄생산퍼텐셜 분석)

  • Lee, Jun-Hyeong;Kim, Tae-Bong;Shin, Kook-Sik;Yoon, Young-Man
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.23-33
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    • 2020
  • Marine algae(Macro algae) are easily bio-degradable, and by-products are available as feed and fertilizer. The biomass of marine algae has higher CO2 absorption capacity than the wood system, and is highly valuable in use due to its fast growth speed and wide cultivation area without special cost for raw material production. In 2018, Marine algae production was 1,722,486ton, such as Saccharina japonica, Undaria pinnatifida and Porphyra tenera, the large amounts of by-products have been generated in the food processing facilities for commercialization. In this study, Saccharina japonica, Undaria pinnatifida were collected in the south coast region and Porphyra tenera was collected in the west coast region. The theoretical methane potential and biochemical methane potential(BMP) were analyzed, and Modified Gompertz model and Parallel first order kinetics model were adopted for the interpretation of the cumulative methane production curves. The theoretical methane potential of Saccharina japonica, Undaria pinnatifida and Porphyra tenera were 0.393, 0.373 and 0.435 N㎥/kg-VS, respectively. BMP obtained by the Modified gompertz model 0.226, 0.227, and 0.241 N㎥/kg-VS for Saccharina japonica, Undaria pinnatifida and Porphyra tenera, respectively. And BMP obtained by the Parallel first order kinetics model were 0.220, 0.243, and 0.240 N㎥/kg-VS for Saccharina japonica, Undaria pinnatifida and Porphyra tenera, respectively.

Estimation of Characteristics Treatment for Food Waste with Blast Volume and Preheating of Air using Bio-Drying Process (Bio-drying 공법 활용 공기 투입 및 예열에 따른 음식물류 폐기물 분해 특성 평가)

  • Park, Seyong;Lee, Wonbea
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.15-25
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    • 2022
  • In this study, the efficiency of treatment of moisture and organic matter in food waste was analyzed according to the air blast volume and preheating using the bio-drying method. Te mount of air blast volume and preheating were determined by the evaluation of temperature and CO2 during food waste treatment using the bio-drying method. As a results, the increase in the air blast volume increased the moisture removal efficiency and removal rate, but, lowered the temperature inside the bio-drying by the decease in microbial activity. In order to maintain the activity of microorganisms, it was estimated that it was necessary to inject an appropriate air blast rate according th the properties of the food waste. In this study, the injection of air blast volume at 15L/min was optimal. It was evaluated that the organic matter and water removal rates according to the presence or absence of air preheating, the organic matter removal rate and water removal rate increased by 3-5% when air preheating was not performed. Also, there was no internal aggregation caused by the generation of condensate inside the bio-drying. Therefore, for effective bio-drying of food waste, it is necessary to maintain an appropriate air blast volume to maintain microbial activity, and it is considered that injection through preheating of air is required.