• Title/Summary/Keyword: 유기물화

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Radiocarbon for Studies of Organic Matter Cycling in the Ocean (방사성탄소를 이용한 해양 유기탄소 순환 연구 동향)

  • Hwang, Jeomshik
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.17 no.3
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    • pp.189-201
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    • 2012
  • Radiocarbon is a powerful tool for studies of carbon cycling in the ocean. Development of measurement technology of accelerator mass spectrometry has enabled researchers to measure radiocarbon even in specific compounds. In this paper, a brief introduction on radiocarbon measurement and reporting of radiocarbon data is provided. Researches that used radiocarbon measurements on bulk organic matter, organic compound classes, and specific organic compounds are reviewed. Examples include works to understand the cycling of particulate and dissolved organic matter, biochemical composition of particulate organic matter, post-depositional transport of sedimentary organic matter, selective incorporation of fresh organic matter by benthic organisms, chemoautotrophy by archaea, and sources of halogenated chemical compounds found in marine mammals.

Treatment Efficiency Evaluation of Integrated Two-Phase Pilot-Scale Anaerobic Digestion Using Food Waste Leachate (Pilot Scale 일체형 2상 혐기성소화에서의 음폐수 처리효율 평가)

  • Song, Hancheul;Kim, Dongwook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.2
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    • pp.51-58
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    • 2016
  • In the Integrated Two-Phase Anaerobic Digestion (ITPAD) process, acid and methane fermentation take place in one reactor, which has advantages to cope with organic load variation and reduce foot-print required, compensating disadvantages of Conventional Separated Two-Phase Anaerobic Digestion (CSTPAD). In the present work, organic matter degradation efficiency and biogas generation amount and other performance parameters of the ITPAD fed with food waste leachate were analyzed. In addition, feasibility study on the ITPAD method was performed by comparing its digestion efficiency with that of the CSTPAD. Organic matter alteration and biogas generation of the integrated method were examined for approximately 130 days based on the 5ton/day scaled pilot plant. Experiment results revealed that organic matter removal rate was 80% for mean food waste leachate input amount of $4.1m^3/day$. The biogas generation rate was $63.0m^3$ per ton of food waste leachate input, corresponding to the input VS amount of $0.724m^3/kg-VS_{added}$, and methane content of generated biogas was approximately 61.3%. The ITPAD has a comparable or higher organic matter removal efficiency compared to the conventional separated two-phase anaerobic digestion method. Consequently, the ITPAD method has a great need to commercialize a food waste leachate treatment technology against highly concentrated organic waste leachate.

Geochemical Evaluation and Characterization of the Shale Gas Resources (셰일 가스 자원의 지화학적 평가 및 특성화)

  • Lee, Young-Joo
    • Economic and Environmental Geology
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    • v.46 no.4
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    • pp.359-373
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    • 2013
  • Shale is considered as a source rock for conventional oil and gas exploration and development because shale is fine-grained detrital sedimentary rock which can preserve the organic matter better. Shale has a good sealing capacity for the petroleum trap due to its low permeability. Commercial recoveries of gas from shale in the North America based on the development of technologies of horizontal drilling and hydraulic fracturing reveal that shale also function as a effective reservoir rock. Geochemical techniques to evaluate generation potential of the hydrocarbons from organic matter in the source rocks can be applied for the exploration of the shale gas resources. To evaluate shale gas resources, it is important to understand various geochemical processes and shale characteristics controlling generation, storage and estimation of shale gas reserves. In this paper, the generation mechanism of the oil and gas from organic matter is reviewed, and geochemical techniques which can be applied for the evaluation and characterization of shale gas are introduced.

Adsorptive Removal of Hazardous Organics from Water with Metal-organic Frameworks (금속-유기 골격체(Metal-organic Frameworks)를 활용한 물로부터의 유해 유기물의 흡착 제거)

  • Seo, Pill Won;Song, Ji Yoon;Jhung, Sung Hwa
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.358-365
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    • 2016
  • Removing hazardous materials from water resources is very important for efficient utilization of the resources, and adsorptive removal is regarded as a competitive technology when good adsorbents with high capacity/selectivity are available. Metal-organic framework (MOF), composed of both organic and inorganic (metallic) species, have been tried for various adsorptions because of huge surface area/pore volume, well-defined pore structure, and facile functionalization. In this review, we summarized technologies on adsorptive removal of hazardous organics from water mainly using MOFs as adsorbents. Instead of reporting high adsorption capacity or rate, we summarized mechanisms of interaction between adsorbates (organics) and adsorbents (MOFs) and methods to modify or functionalize MOFs for effective adsorptions. We expect for readers of this review to understand needed characteristics of adsorbents for the adsorptive removal, functionalization of MOFs for effective adsorption and so on. Moreover, they might have an idea on storage and delivery of organics via understanding of the mechanism of adsorption and interaction.

Effect of Mechanical Mixing Intenstiy on Composting (교반강도가 퇴비화에 미치는 영향)

  • Hwang, Seon-Suk;Hwang, Eui-Young;Namkoong, Wan
    • Journal of the Korea Organic Resources Recycling Association
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    • v.3 no.2
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    • pp.47-57
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    • 1995
  • The purpose of this study was to investigate the effect of mechanical mixing intensity on composting. The major parameters investigated were the mixing intensity and initial moisture content. Laboratory scale composting reactors with mixing equipment were used in this study. Wastes used for the study were raw nightsoil sludge, nightsoil sludge after vacuum evaporation treatment and pig manure. When moisture contents were 60% and 63%, amount of organic material degraded in the continuous mixing reactors was higher than that in the intermittent mixing reactors. Compost produced from reactors with continuous mixing had better texture than that obtained from reactors with intermittent mixing. When moisture content was 68%, organic waste was kneaded rather than mixed in the continuous mixing reactors. Amount of organic material degraded in the continuous mixing reactors also was lower than that in the intermittent mixing reactors.

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Experimental Study of the mechanism of methane generation under various organic conditions on Lake or Reservoir (호소 환경 조건에 따른 메탄 발생 기작 정량화 실험 연구)

  • Bang, Young Jun;Lee, Sung Woo;Kim, Dong Hyun;Lee, Seong Oh
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.173-173
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    • 2022
  • 유기 퇴적 오염물은 다양한 형태로 호소 바닥에 축적되어 호소 환경 및 생태계에 악영향을 미치고 있으며 메탄가스와 같은 온실가스의 발생을 유발한다. 또한, 수력 산업, 관개, 이·치수 등 다양한 목적에 의해 수체의 형성이 활발하게 이루어지면서 하천 및 호소에 의한 탄소유출을 전지구적 탄소순환에 적극적으로 포함시켜야 한다는 필요성이 증가하고 있다. 따라서 하천 및 호소에서 발생하는 다양한 생지화학적 반응에 의한 메탄 발생 메커니즘 파악은 유역의 중요한 환경평가 지표를 나타내며 탄소 순환을 이해하는데 매우 중요하다. 수온, 수심, 유기물 조건에 따른 하천 및 호소의 메탄 발생을 분석한 연구들이 선행되었으나 생지화학적 특성을 정리하고 이에 따른메탄 발생을 정량화한 연구들은 거의 없는 상황이다. 본 연구는 호소 내 메탄을 발생시키는 기작을 판별하기 위해 수온과 호소 환경과 유사한 TOC(총유기탄소)와 TP(총인) 조건과 같은 유기물 조건을 설정하여 BMP Test를 수행하였다. 반응수조에서 발생한 가스를 포집한 후 GC(Gas Chromatograpghy) 분석을 통해 메탄 생성량을 산출하였고, 유기물 조건에 따라 이론적인 메탄 생성량 대비 실제 발생한 메탄 생성량을 나타내는 생분해도를 산출하여 호소 환경별 주요 기작에 따른 가스 발생을 정량화 하였다. 실험 결과 수온에 가장 큰 영향을 받았으며, 수온에 따라 TP, TOC 순으로 메탄 발생의 영향성을 확인하였다. 향후에는 호소 환경에서의 유기물 조건을 반영하기 위해 입도비, 점착성/ 비점착성 조건, 수체의 높이 조건을 포함한 추가 실험을 수행하고 메탄수율을 정량화하여 호소 내 유기퇴적물에 대한 생지화학적 및 수환경 영향 평가 기법 개발이 가능할 것으로 기대한다.

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Application of Electron Beam for Accelerating Composting of Sewage Sludge (하수슬러지 퇴비화촉진을 위한 전자빔의 응용)

  • Kang, Ho;Shin, Kyung-Sook;Jeong, Ji-Hyun;Schuchardt, Frank
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.2
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    • pp.62-70
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    • 2010
  • A feasibility test for accelerating composting of sewage sludge irradiated with electron beam(3kGy) was investigated. Dried wood chip and leaves were used as a bulking agent and carbon source, respectively. The test variables included changes in temperature, organics and nutrients, and bioactivities from experimental and control composters. Results indicates that the temperature rose up to $60^{\circ}C$ within 1 day and maintained high temperature above $50^{\circ}C$ for more than 5 days in the irradiated sludge cake composter. It resulted in the fast degradation of organics during the initial 5 days, showing that approximately 70% of total amount of carbon degraded within 20 days was destroyed. It is likely that the composting of electron beam irradiated sludge cake is able to reduce it's maturing period significantly.

Effect of Influent COD Fraction on Nitritation from Wastewater and Piggery wastewater (유입수 유기물 성상이 반류수와 가축분뇨 아질산화 반응에 미치는 영향)

  • Gil, Kyun-Gik;Im, Ji-Yeol
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.2
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    • pp.185-192
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    • 2011
  • BNR process is an effective method to remove high strength nitrogen included in wastewater and piggery wastewater. There have been many former studies about the induction of nitritation which have many advantages than full nitrification and the impacting factors on nitritation. Especially, it is reported that organic matter has a relation with nitritation. In this study, laboratory sacle reactor was operated using effluent of anaerobic digester, piggery wastewater and anaerobic digester effluent of piggery wastewater. After analyzing the operating results, the impact of organic matter on nitritation was analyzed by classified COD fractions. It was showed that nitritation is affected by organic matter especially by Ss. In conclusion, organic matter should be managed not just as a single gross parameter but in a classified form.

Advanced Characterization Techniques of Organic Matter in Aqueous Solutions (물 속 유기물의 고도 특성 분석)

  • Shon, Ho Kyong;Vigneswaran, Saravanamuthu;Kandasamy, Jaya;Kim, Jong Beom;Kim, Jong-Ho
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.1-14
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    • 2011
  • Water is the most precious resource to human being, but it is polluted by different organic compounds. Organic matter (OM) in aqeous solutions is one of the important parameters of concern for human and environmental impact, and thus, it is essential to better characterize specifically targeted organic matter in aggregated and individual level of concentrations. This review presents different analytical tools and protocols to investigate detailed properties and characterization. Physical, chemical and biological aspects of OM are envisaged in terms of traditional and advanced measurement methods.

Nitrogen Removal in Flat-Panel Air-Cathode Microbial Fuel Cell according to Various Inoculum Sources and Organic Concentration (식종원 및 유기물 농도 변화에 따른 평판형 외기환원전극 미생물 연료전지의 질소 제거)

  • Park, Younghyun;Yu, Jaecheul;Nguyen, Thi Hien;Lee, Taeho
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.12
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    • pp.635-640
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    • 2016
  • Although microbial fuel cell (MFC) can produce electricity from organics in wastewater, nitrogen removal is required for application of process for wastewater treatment plant. This study developed flat-panel air-cathode MFCs (FA-MFCs) comprised of two large separator electrode assemblies (SEAs) and evaluate total nitrogen removal according to three inoculum sources and pre-nitrification acclimation. The nitrification efficiencies were >99% regardless of inoculum sources under the phase for pre-nitrification acclimation. The total nitrogen removal efficiencies of FA-MFCs without pre-nitrification acclimation were the highest at the low organic conditions (<300 mg-COD/L) under the phase for nitrification and denitrification. The increase of organic concentration influenced the total nitrogen removal efficiency, positively. The organics were removed >95% but were not used for heterotrophic denitrification totally. This study suggests that application of FA-MFC system for wastewater treatment can allow the simultaneous removal of organic and nitrogen compounds, although this affects the low electricity production.