• Title/Summary/Keyword: 유기물화

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Development of the On-Site Vermicomposting Unit for Sewage Sludge (하수슬러지 지렁이 퇴비화 장치개발에 관한 연구)

  • Kim, Jong-Oh;Lee, Chang-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.1
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    • pp.92-96
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    • 2003
  • The on-site sewage sludge vermicomposting equipment was designed and evaluated on the batch and continuous tests. The vermicomposting equipment was designed to consider the mechanization as well as automation. In terms of performance evaluation of equipment with continuous experiments, the highest treatment rate was found in the condition of 5mm in particle size and 10mm in e feeding height. Also, 20~25kg of earthworm per 50kg of sewage sludge was the most appropriate density of earthworm. In addition, the most effective separation of cast was found when the earthworm breeding box height was 80cm. The performance evaluation on equipment allowed the establishment of earthworm composting capacity of 2ton per a day with a size of $5{\times}3{\times}1m$ and the automatic control devices.

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Organic Matter Degradation and Nitrification Characteristics in Aerobic Digestion of Sewage Sludge (슬러지 호기성 소화공정에서의 유기물 분해 및 질산화 특성)

  • Hwang, Eung-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.865-872
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    • 2009
  • Continuous operation of aerobic sludge digestion reactor was attempted for 279 days. Anaerobic digester sludge, the target material of the experiment, was pretreated by sodium hydroxide at $40^{\circ}C$ for 120 minutes, and the pretreated sludge was fed to 5 L CSTR (continuous stirred tank reactor). Reactor performance was affected by properties of input sludge and HRT (hydraulic retention time). 6 days of HRT showed best and stable performance, and under this condition, removal rates of $NH_3$-N, SCOD, TKN, TCOD, SS, and VSS were 97.4%, 81.7%, 68.7%, 61.4%, 50.6%, and 47.0%, respectively. 73.9% of SS in anaerobic digester sludge was reduced by pretreatment and aerobic digestion. Effluent sludge had low soluble COD of 350 mg/L. This implied the sludge was stabilized and suitable for use as liquid fertilizer. Nitrification took place when HRT was higher than 4 days. $NO_3$-N concentration was as high as 658 mg/L while $NH_3$-N was as low as 20 mg/L.

A study for Solubilization and Bioavailability of Sewage Sludge Using the Complex Pre-treatment (복합 전처리를 통한 하수슬러지의 가용화 및 생물학적 유용성에 관한 연구)

  • Kang, Jung-Hyun;Lee, Hee-Soo;Lee, Tae-Jin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.35-43
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    • 2011
  • In this study, anaerobic biological decomposition were attempted after solubilization treatment of sewage sludge with the complex pre-treatment (acid/base treatment with ultrasonic radiation). Solubilization ratios were compared for ultrasonic treatment at acid or base condition. Solubilization effect of the complex pre-treatment was more effective at higher pH. Biological decomposition of complex pre-treated sludge was faster than non treated (raw) sludge, showing 10 times higher total gas production. Biological digestion of the sludge shows more biogas production. B/A ratio. which indicates hydrogen production potential, was 50% higher with complex pre-treated sludge than raw sludge but lactic acid or propionic acid were also detected during anaerobic decomposition process.

Effect of Sonification on the Ananerobic Digestion of Waste Activated Sludge(I) -Disintegration of Waste Activated Sludge Using Ultrasonic and Alkaline Pre-treatments- (초음파가 폐활성 슬러지의 혐기성 소화에 미치는 영향(I) -초음파 및 알칼리 전처리를 이용한 폐활성 슬러지의 가용화-)

  • Han, Sun-Kee;Lee, Chae-young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.1
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    • pp.96-102
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    • 2009
  • The effect of ultrasonic and alkaline pre-treatments on waste activated sludge (WAS) disintegration was investigated for improved anaerobic digestion. As WAS was treated by either methods, longer capillary suction time (CST) was required due to the break-up of cell walls, and its supernatant demonstrated increase in soluble chemical oxygen demand (SCOD), protein content and turbidity. Ultrasonic process combined with alkaline pre-treatment demonstrated higher SCOD and protein content in the supernatant as compared with ultrasonic pre-treatment only. However, the degree of disintegration (DDCOD) of WAS decreased with increasing solid concentration as both WAS disintegration methods employed simultaneously.

Changes of Microbial Activity and Physicochemical Environment during Composting of Papermill Sludge in a Pilot Plant (제지슬럿지의 퇴비화 과정 중 미생물활성 및 이화학적 환경변화)

  • Chung, Young-Ryun;Chung, Man-Hoon;Han, Shin-Ho;Oh, Say-Kyun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.3 no.2
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    • pp.79-89
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    • 1995
  • Changes of microbial activity and physicochemical environment during composting of papermill sludge(PMS) in the pilot plant equipped with an agitated bed reactor were monitored for establishing the efficient composting system. Microbial activity determined as the evolution of $CO_2$ increased for the first 10 days after introduction of PMS to the reactor and decreased thereafter. Population changes of microorganisms in the reactor-PMS were not typical as in windrow system. The ratio of thermophilic bacteria to mesophilic bacteria, however, increased slowly even 23 days after introduction. Temperature of PMS increased rapidly from the first day and reached $62^{\circ}C$ at 7 days after introduction and decreased slowly thereafter. The acidity of PMS was pH 6.8 initially, increased to pH 8.0 after 7 days and decreased to pH 7.4 after 23 days. Redox potential(Eh) of PMS was -320mV at the beginning of composting, but it was increased with time to reach -15mV after 23 days composting. However, Eh of PMS pre-sterilized before measurement was average 50mV, regardless of composting periods indicating the major role of microorganisms during composting process. Water content of PMS was 67% initially and decreased to about 50% after 23 days composting in the reactor. Less than 13 days-old compost inhibited growth of radish in the container mixture with bed soil. Based on statistical analysis of microbial and physicochemical parameters of PMS during composting, an equation was developed for determining compost maturity. A number of experiments using various organic wastes are required before application of the formular to the practical use.

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Continuous Mediated Electrochemical Oxidation of Ethylene Glycol by Co(III)/Co(II) and Fe(III)/Fe(II) Redox Systems (Co(III)/Co(II) 및 Fe(III)/Fe(II) 산화환원계에 의한 에텔렌글리콜의 연속 매개전해 산화)

  • Kim, Ik-Seong;Park, Seung-Cho
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.635-640
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    • 2005
  • Mediated electrochemical oxidation (MEO) is an aqueous process which oxidizes organics electrochemicallly at low temperatures and pressures. The useful process can be used to treat mixed wastes containing hazardous organics. This paper have studied MEO of ethylene glycol (EG) in nitric acids by Fe(III)/Fe(II) and Co(III)/Co(II) system. It investigated current density, supporting electrolyte concentration, hydraulic retention time, removal efficiency of EG by MEO. Removal efficiency of EG by MEO was superior in Co(III)/Co(II) redox system than Fe(III)/Fe(II) redox system, where MEO removal efficiency was 100 percent. In case of EG, the reactions were fast and good yields of carbon dioxide formation was observed.

A Study on the Biosorption Process for Organic and Nutrient Removal from the Wastewater (생흡착을 이용한 하수의 유기물, 질소, 인제거에 관한 연구)

  • Kim, Hyun-Kab;Park, Ju-Seok;Chung, Hyung-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.470-479
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    • 2004
  • The experimental conditions and relationships between parameters such as organic matter, aeration volume, aeration time, and precipitation time for the effective treatment of domestic wastewater were investigated. With the batch systems, the adsorption amount of unit microbe was measured with the change of MLSS concentration, precipitation time, and aeration amount. Theoretical adsorption amount of microbes was then numerically formulated by use of a SPSS multiple analysis as follows: $$Y=-0.0106(X_1)+0.07310(X_2)+42.705(X_3)+62.700$$ In this study, the amount of organisms to be removed in the range of MLSS concentration 2,000~4,500 mg/l were examined. In order to investigate the optimal condition of nitrification, the upper water in the biosorption stage was used as the initial experiment water. The results showed that the C/N ratio was 1.5 and the reaction time for the optimal nitrification was 1.5 hr. When the adsorption efficiency for microbe biosorption was 66%, the optimum denitrification efficiency was 83.3%. When the optimum parameters obtained from the batch experiment were applied to the lab-scale operation, the total retention time from the flow-in to flow-out was 10 hours and the removal efficiency was 93.8% for $COD_{cr}$ and 80.9% for TN. For the full-scale operation, the total retention time was 9.0 hours and the removal efficiency was 94.4% for BOD, 89.6% for $COD_{cr}$, 88.0% for TN, and 86.2% for TP.

Effects of Rice Straw Application on Barley Growth and Grain Yield in Paddy Field (답리작 보리 재배시 볏짚 시용 효과)

  • 임시규;김정태;김병주;홍순표;서득용;김완석
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.1
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    • pp.49-55
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    • 1997
  • For the labor-saving cultivation of barley in rice-barley double cropping system in paddy field, a series of expriments on the effect of rice straw application were carried out at the National Yeongnam Agricultural Experiment Station from 1992 to 1993. The affection of phenol compounds released from fresh rice straw could be lessened when seeded under rice straw in the soil and that made emergence rate increase by 11%, compared with that on application on the rice straw. Although utilization of rice straw as an organic material caused the poor growth of barley in early stage, it could be enhanced the culm breaking strength. On this reason, affected by rice straw, grain yield was increased from 8% in common barley and up to 20% in malting barley. The more nitrogen, CaO$_2$2 and SiO$_2$ applied, the more decomposition of rice straw accelerated from 2% to 6.9%. On the application of rice straw as an organic material in malting barely cultivation, the content of crude protein was decreased while 1,000-grain-weight and grain assortment was increased.

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유기 EL 디스플레이의 개요, 재료 및 연구 동향

  • 박준영
    • Electrical & Electronic Materials
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    • v.15 no.12
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    • pp.3-10
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    • 2002
  • 유기 전계발광 소자는 발광성 유기화합물을 양극과 음극사이에 형성한 후 전기적으로 여기시켜 그 발광을 이용하는 디스플레이로 1960년도에 처음 전기 적 발광현상이 안트라센 물질에서 처음 보고되었다[1]. 그 후 1987년에 코닥(Kodak)사의 Tang에 의해 적층형 유기 전계발광 소자가 처음 연구되어 소개된 후 실용화를 목표로 활발히 연구되기 시작하였으며[2], 1990년도 들어서는 유기물 재료 중에 전도성 고분자형 재료의 전기적 발광현상이 영국의 케임브리지 대학에서 보고되어 고분자형 유기 전계발광 소자연구가 진행되기 시작하였다[3]. 유기 전계발광 디스플레이는 평판 디스플레이의 한 종류로서 저전압 구동, 박형, 자체발광에 인한 고인식성 및 넓은 시야각, 빠른 응답속도 등의 많은 장점을 갖고 있어 현재 널리 사용되는 액정 디스플레이의 결점을 해결해줄 수 있는 차세대 디스플레이로 최근 들어 매우 높은 관심을 받고 있으며 연구개발 또한 가장n 활발한 분야로 알려져 있다 현재는 저분자형 유기물을 사용하는 저분자 유기 전계발광 소자와 전도성 고분자를 사용하는 고분자 유기 전계발광 소자가 전자발광 디스플레이 연구의 두 분야로 경쟁하면서 연구가 진행되고 있다. 이에 1990년도 후반부터 디스플레이로의 연구가 일본에서부터 활발히 진행되면서 수동형 (Passive Matrix) 구동의 유기 EID가 일본의 Pioneer,한국의 삼성 SDI등에 의해서 상업화되었다. 현재는 카오디오나 핸드폰 등에 이미 채용이 되고 있으며 일반인들이 쉽게 볼 수 있는 디스플레이로 바뀌어가고 있다. 또한 향후 중대형 디스플레이로 상업화하기 위하여 일본의 Sony, Sanyo, Toshiba, 한국의 삼성 SDI 등에서 능동구동 유기 EL (Active Matrix OLED (AM OLED))를 경쟁적으로 개발하고 있다. (그림 1 참조)유기 ELD는 이와 같이 빠른 속도로 발전하고 있으며, 향후 몇 년 내에 우리 주변의 일상적 인 디스플레이로 등장할 것으로 판단된다. 본 보고서에서는 현재 실용화가 급속히 진전되고 있는 유기 전계발광 디스플레이의 소자구조, 발광기구. 소자특성, 각종 재료, 풀컬러화 기술, 구동방법등에 대한 기술개요와 국내외 기술동향에 대하여 소개하고자 한다.

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Advanced Treatment of Wastewater Using Symbiotic Co-culture of Microalgae and Bacteria (미세조류와 박테리아의 공생 배양을 이용한 하폐수 고도처리)

  • Mujtaba, Ghulam;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.27 no.1
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    • pp.1-9
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    • 2016
  • The co-culture system of microalgae and bacteria enables simultaneous removal of BOD and nutrients in a single reactor if the pair of microorganisms is symbiotic. In this case, nutrients are converted to biomass constituents of microalgae. This review highlights the importance and recent researches using symbiotic co-culture system of microalgae and bacteria in wastewater treatment, focusing on the removal of nitrogen and phosphorus. During wastewater treatment, the microalgae produces molecular oxygen through photosynthesis, which can be used as an electron acceptor by aerobic bacteria to degrade organic pollutants. The released $CO_2$ during the bacterial mineralization can then be consumed by microalgae as a carbon source in photosynthesis. Microalgae and bacteria in the co-culture system could cooperate or compete each other for resources. In the context of wastewater treatment, positive relationships are prerequisite to accomplish the sustainable removal of nutrients. Therefore, the selection of compatible species is very important if the co-culture has to be utilized in wastewater treatment.