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A Study of Accelerated Corrosion Test and Chloride Penetration Analysis with Artificial Seawater Immersion Condition (인공해수 침지조건에 따른 부식촉진시험과 염화물침투해석에 대한 연구)

  • Park, Sang-Soon;Jeong, Ji-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.1
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    • pp.93-100
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    • 2014
  • Steel reinforcement buried in concrete structure in submerged zone does not easily become corroded due to lack of dissolved oxygen. For that reason, accelerated corrosion test in submerged state is performed with an electrochemical method, which is not suitable for actual corrosion mechanism and makes it difficult to find relevance with long-term behavior. In this study, accelerated corrosion test was performed with the temperature and chloride concentration as main variables in order to establish a method for accelerated corrosion test in submerged zone. Corrosion was determined by the result of reinforcement corrosion monitoring based on galvanic potential measurement and half-cell potential method. The accelerated corrosion test result showed that temperature had the most dominant influence. To determine the chloride content, chloride concentration by depth in the test sample was measured. With the same conditions, chloride penetration interpretation was performed by DuCOM, a FEM durability interpretation program. Also, a test was performed to measure dissolved oxygen according to soaking conditions of artificial seawater, which was used for verifying the validity of the accelerated corrosion test result.

Electrode Properties of Thin Film Battery with LiCoO2 Cathode Deposited by R.F. Magnetron Sputtering at Various Ar Partial Pressures (R.F. 마그네트론 스퍼터링을 이용한 LiCoO2 양극활물질의 Ar 증착분압에 따른 박막전지 전극 특성)

  • Park, H.Y.;Lim, Y.C.;Choi, K.G.;Lee, K.C.;Park, G.B.;Kwon, M.Y.;Cho, S.B.;Nam, S.C.
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.37-41
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    • 2005
  • We investigated the electrochemical properties and microstructure on the various argon deposition pressure $(P_{Ar})$ and the low annealing temperature $(400^{\circ}C)$ of $LiCoO_2$ cathodes, which deposited by R.F. magnetron sputtering. The microsuucture and composition of Lico02 thin film was changed as a function of $P_{Ar}$. The capacity and electrochemical properties were improved with Ph of $LiCoO_2$ thin films. The cycling reversibility and stability of thin film batteries were measured by cyclic voltammetry and the constant current charge-discharge. The physical properties of cathode films were analyzed by ICP-AES, XRD, SEM and AFM for composition, crystallization and surface morphology.

A Study on Software Development and Legal Regulation (소프트웨어 개발과 법적규제)

  • Kim, Hyung-Man
    • Journal of Digital Convergence
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    • v.9 no.5
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    • pp.11-20
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    • 2011
  • Internet users and copyright holder have been at the center of a severe legal dispute because file-sharing soft (P2P) through Napster aggravates the violation of copyright as well as takes on the world. Though it is natural that we should hold users a criminal penalty for the illegal use of various computer programs, I think that if the supply of a computer program is generally within a circle of development act, program developer ought not to hold users criminally liable for the unintended illegal act of users. Two main issues are addressed in this work: (i) the basis and validity of legal responsibility and condemnation that appear in the precedent set as to P2P in America, Japan, and Korea. (ii) the necessity of both scientific technology development and efficient legal regulation of copyright holder. For this purpose, software development and legal regulation are reviewed analyzed from viewpoint of the criminal law.

Atmospheric Effects on Growth Kinetics and Electronic Properties of Passive Film of Aluminum in Borate Buffer Solution (Borate 완충용액에서 알루미늄의 산화피막의 생성과정과 전기적 성질에 대한 대기의 영향)

  • Kim, Younkyoo
    • Journal of the Korean Chemical Society
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    • v.60 no.3
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    • pp.169-176
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    • 2016
  • In a borate buffer solution, the growth kinetics and the electronic properties of passive film on aluminum were investigated, using the potentiodynamic method, chronoamperometry, and multi-frequency electrochemical impedance spectroscopy. The corrosion of aluminum was heavily influenced by the degree of oxygen concentration because of the increasing reduction current. The oxide film formed during the passivation process of aluminum has showed the electronic properties of n-type semiconductor, which follow from the Mott-Schottky equation. It was found out that the passive film (Al(OH)3) of Al formed in the low electrode potential changes to Al2O3 while the electrode potential increases. The growth kinetics data as measured by chronoamperometry suggests a mechanism in which the growth of the film of Al2O3 is determined by field-assisted transport of ions through the film.

A Study on Correlation Between Accelerated Corrosion Test and Long-term Exposure Test According to the Temperature Condition (온도조건에 따른 철근부식 촉진시험과 장기폭로시험의 상관성에 관한 연구)

  • Park, Sang-Soon;So, Byung-Tak
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.203-208
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    • 2016
  • In this study, to clarify the differences rebar corrosion beginning, through the actual corrosion accelerated test in corrosion time and laboratory test chamber of the structure of the marine environment results in both environments, it is an object of correlation coefficient derived. The accelerated corrosion test was carried out by two case, I.e., one is $20^{\circ}C$ of low temperaure codition(case 1), and the other is $65^{\circ}C$ of high temperaute codition(case 2). Whether corroions occurs, it was measures using half-cell potential method. The results indicated that case 2 is to acclerate the corrosion of rebar about 1.7~1.8 times as compared with case 1, thenthe corrosion of rebar embadded in concrete occurred according to the order of OPC60, FA, BS, OPC35. Correlation coefficient between acclerated corrosion test and long-term exposure test, case 1 is 2.45 to 2.94, and case 2 is 4.37~4.99.

An Analytical Study on Precedents of Emotional Child Abuse at Daycare Centers of Korea : Focusing on Emotional Abuse Type, Issues, and Preventive Measures (국내 어린이집의 아동학대 판례 분석 연구 : 정서적 학대 유형, 쟁점 사안 및 예방대책을 중심으로)

  • Youn, Ki-Hyok
    • Journal of Convergence for Information Technology
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    • v.7 no.5
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    • pp.157-167
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    • 2017
  • This study aims to establish measures to prevent emotional abuse by analyzing court precedents related to emotional abuse at daycare centers of Korea. For this, ten precedents of first trial and four precedents of appellate trial related to emotional abuse were analyzed in depth. In the results of study, there were diverse types of emotional abuse at daycare centers such as assaulting(hitting head, face, and buttocks with hands and feet), throwing things, neglecting, forcefully feeding food, stopping mouth with handkerchief and wet tissue, skipping meals, and showing scary images. And the main issues of precedents included the matter of justifiable act as circumstances precluding wrongfulness, and the matter of applying the joint penal provision. Based on such results, the measures to prevent emotional abuse at daycare centers were suggested.

A Study on the Variation of Runoff and Travel Time in Urban Stream due to Watershed Development (유역개발에 따른 도시하천에서의 유출량 및 도달시간 변화에 관한 연구)

  • 서규우;배덕효
    • Water for future
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    • v.29 no.3
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    • pp.207-216
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    • 1996
  • The subject research attempts to evaluate the variations of total runoff volume, peak flow, and travel time depending on the urbanhization, return periods and rainfall patterns under the situations that the preparation of a large residential site at the lowland areas of the downstream of Dongsu stream in Bupyung-Gu, Incheon city is progressed and the area will be eventually fully developed. The ILLUDAS model was used for the runoff analyses based on 3 differend steps of urbanization and 4 different types of Huff's quantile according to rainfall patterns is Huff's 4 quantile, Huff's 2 quantile, Huff's 3 quantile and Huff's 1 quantile. Under the 80 and 90 % of urbanization to the 70% of urbanization, the mean increasing ratio of total runoff volume for each case is 3.5 and 5.5 %, that of peak flow is 4.2 and 8.8%, and the mean decreasing ratio of travel time is 4.4 and 10.1%, respectively. The mean increasing ratio of total runoff volume according to the return periods is 3.0 and 5.4%, that of peak flow is 3.9 and 8.0% under the same conditions of urbanization.

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Analysis on Load of Non-point Source from Sewage Treatment Districts in Nakdong River (낙동강 유역 내 하수처리구역의 비점 배출 부하량 분석)

  • Shin, Hyun Suk;Kim, Mi Eun;Kim, Jae Moon;Jang, Jong Kyung
    • Journal of Korea Water Resources Association
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    • v.48 no.9
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    • pp.695-709
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    • 2015
  • The inflow of nonpoint pollution sources due to sustainable development and urbanization is gradually increasing and causes a diversity of water pollution. There are lots of difficulties to find a solution as the problems related to variation of hydrological and natural phenomenon. A differentiated method to estimate the nonpoint pollution sources has been proposed using rainfall and characteristics of urbanization and observed data from sewage treatment districts in the study. The types of nonpoint pollution sources on an assumption of combined sewer system have been classified as three types which are inflow of rainfall, bypass of sewage treatments, and combined sewer overflows from a river. Three types for estimation of nonpoint pollution sources applied more accurately to generate a amount of nonpoint pollution loads. This study is expecting a wide application for effective water resource management on TMDL (total maximum delivery load) unit watershed and sewage treatment districts.

A Suggest on the Reclassification and Performance Criteria of Construction Material in Korean Public Procurement - Based on the Law of Purchasing Policy for Market Support of Small and Medium Business - (공공공사 직접구매 조달품목 재분류 및 성능기준 제안)

  • Yang, Jinkook;Choi, Yongho;Lee, Eunha;Lee, Sangbeom
    • Korean Journal of Construction Engineering and Management
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    • v.15 no.3
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    • pp.31-37
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    • 2014
  • "The Law of purchasing policy for market support of small and medium business" was legislated to support small and medium industry by expanding purchase and revised consistently for the activation. And then the government made the public construction direct purchase compulsory about design items designated by president on small and medium business based on this law. However, secureing quality, tardiness and field material staff's heavy duty were arisen from approximately 120 direct market purchase items. The legislative intent of law is in accord with Win-Win growth between major company and small and medium business. However material staff who works in the field based on this law has difficulties with material securing quality, JIT(Just In Time), cost push. This study reclassified procurement items of "the direct market purchase system" reasonably and then suggested performance criteria for evaluation. The suggested result will contribute to vatalize the direct market purchase system.

Recovery of Metallic Lithium by Room-Temperature Electrolysis: I. Effect of Electrode Materials (상온(常溫) 전해법(電解法)에 의한 리튬 금속(金屬)의 회수(回收): I. 전극물질(電極物質)의 영향(影響))

  • Lee, Jae-O;Park, Jesik;Lee, Churl Kyoung
    • Resources Recycling
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    • v.21 no.6
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    • pp.45-50
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    • 2012
  • The room-temperature electrodeposition of metallic lithium was investigated from ionic liquid, 1-methyl-1-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13TFSI) with lithium bis (trifluoromethanesulfonyl)imide (LiTFSI) as a lithium source. Cyclic voltammograms on gold working electrode showed the possibility of the electrodeposition of metallic lithium, and the reduction current on a gold electrode was higher than the value on platinum and copper. The metallic lithium could be electrodeposited on the gold electrode under potentiostatic condition at -2.4 V (vs. Pt-QRE) and was confirmed by analytical techniques including XRD and SEM-EDS. The dendrite-typed electrodeposits were composed of a metallic lithium and a alloy with gold substrate. And any impurity could be detected except for trace oxygen introduced during handling for the analyses.