• Title/Summary/Keyword: 원자력학회지

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Fabrication of Electrospun Si-Zr-C Fibers by Electron Beam Irradiation (전자선 조사를 이용한 전기방사된 Si-Zr-C 섬유의 제조)

  • Seo, Dong Kwon;Jeun, Joon Pyo;Kim, Hyun Bin;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.4 no.3
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    • pp.265-269
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    • 2010
  • Silicon-based non-oxide ceramic carbide fiber is one of the leading candidate ceramic materials for engineering applications because of its excellent mechanical properties at high temperature and good chemical resistance. In this study, polycarbosilane(PCS) and zirconium butoxide were used as a precursor to prepare polyzirconocarbosilane (PZC) fibers. A polymer solution was prepared by dissolving PCS in zirconium butoxide (50/50 wt%). This solution was heated at $250^{\circ}C$ in a nitrogen atmosphere for 2 hour with stirring, and then dried in a vacuum oven for 48 hour. PZC fibers were fabricated using an electrospinning technique. The fibers were irradiated with an electron beam to induce structural crosslinking. Crosslinked PZC fibers were heat treated at $1,300^{\circ}C$ in a nitrogen atmosphere. The microstructures of PZC fibers were examined by SEM. Chemical structures of PZC fibers were examined by FT-IR and XRD. Thermal stability of PZC fibers was investigated by TGA.

Preparation and Characterization of Microorganism Fermentation Cellulose as Hydrogel Wound Dressing (미생물 발효 셀룰로오스를 이용한 상처 치료용 하이드로겔의 제조 및 특성)

  • Kim, Mi-Yeong;Lim, Youn-Mook;Lee, Jong-Dae;Song, Sung-Gi;Gwon, Hui-Jeong;Park, Jong-Seok;Nho, Young-Chang;Kim, Sung-Ho;Choi, Young-Hun;Lee, Sun-Yi
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.365-372
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    • 2010
  • Irradiation has been recognized as a highly suitable tool to aid in the formation of hydrogel. The radiation process has various advantage, such as easy process control and the lack of necessity for initiators and crosslinker. In this study, the hydrogel containing the citrus fermentation gel for the wound healing were successfully synthesized. The strength of hydrogel was increased as a function of a increasing the concentration of citrus and the irradiation doses. In addition, this hydrogel have been evaluated by the cytotoxicity and animal experiment.

The Characterization of Crosslinked SPEEK Based Ion Exchange Membranes Prepared by EB Irradiation Method (전자선을 이용해 가교된 SPEEK 기본 물질로 하는 이온 교환막의 특성 분석)

  • Song, Ju-Myung;Shin, Junhwa;Sohn, Joon-Yong;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.151-157
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    • 2011
  • Crosslinked SPEEK/PVDF membrane were prepared by EB radiation method with various contents of PVDF. The prepared membranes were subjected to a comparative study of proton exchange membranes for fuel cell appreciations. The crosslinked SPEEK/PVDF membranes were characterized by using DMA, DSC and SAXS. The DMA data indicate that the ionic modulus values and cluster $T_g$ decrease with increasing PVDF content. Thus, it was suggested that the number of clustering in the crosslinked membranes can be reduced with increasing PVDF content. The DSC results were shown that the degree of crystalline of the membrane increased with increasing PVDF content. The morphology of the crosslinkied membranes was shown that with increasing PVDF content, the number of crystalline domain of the SPEEK/PVDF membranes increased but ionic aggregation of the membranes decreased. The water uptake behavior, ionic exchange capacity (IEC) and proton conductivity were decreased with increasing PVDF content. The overall findings suggest that the crosslinked membranes offer the possibility for improving the performance of PEMFC, provided that the membranes have thermal and hydration stability.

Mechanical Properties of Radiation-Curing Vinyl Ester Resin (방사선 경화 비닐에스터 수지의 기계적 특성 연구)

  • Shin, Bum-Sik;Jeun, Joon-Pyo;Kim, Hyun Bin;Kang, Phil-Hyun
    • Journal of Radiation Industry
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    • v.4 no.1
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    • pp.19-23
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    • 2010
  • Vinyl ester (VE) resins, introduced in the late 1960s, have made large strides in reinforced plastics applications as adhesive and matrix materials on their appropriate mechanical performance characteristics in the glassy state. Generally, VE resins are a group of dimethacrylate resins based on bisphenol A type epoxy resin. They exhibit easy handling properties as well as good resistance to most chemical agents due to their mechanical and thermal properties. In this study, the effects of curing methods of vinyl ester resins on gel contents, flexural strength and dynamic mechanical properties were investigated. Thermal curing (room temperature, $80^{\circ}C$) and electron beam curing were used to crosslink a VE resin/styrene complex (65/35 wt%) with methyl ethyl ketone peroxide (MEKPO) as a catalyst and an 8 wt% cobalt naphthenate in styrene solution as a accelerator. For the samples, gel contents as well as flexural strength and dynamic mechanical properties were characterized and compared by soxhlet apparatus, universal testing machine (UTM) and dynamic mechanical analysis (DMA). As a result, the electron-cured VE resin was confirmed as a better condition than those for gel contents, flexural strength and dynamic mechanical properties, respectively.

Manufacturing of Ni-63 Sealed Source for Betavoltaic Battery Using the Small-scale Electroplating Device (소형 전기도금장치를 이용한 베타전지용 Ni-63 밀봉선원 제작)

  • Kim, Jin Joo;Choi, Sang Mu;Son, Kwang Jae;Hong, Jintae
    • Journal of Radiation Industry
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    • v.11 no.3
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    • pp.173-179
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    • 2017
  • The small-scale electroplating device was designed and fabricated for Ni-63 sealed source (foil type) with a high specific activity needed for production of betavoltaic battery. The condition of Ni electroplating was optimized by using fabricated electroplating device to establish a Ni-63 electroplating condition on the Ni foil. The results showed that the optimum surface morphology and thickness of Ni deposit was obtained for 1,758 seconds at a current density of $15mA{\cdot}cm^{-2}$ with 0.5% tween 20. Radioisotope Ni-63 electroplating was implemented under established condition. The radioactivity of Ni-63 sealed source was calculated to $28mCi{\cdot}cm^{-2}$, and the thickness of Ni-63 deposit was about $2.4{\mu}m$.

Property of CdTe/CdS Solar Cells on Gamma-irradiation (방사선에 대한 CdTe/CdS 태양전지 특성 검토)

  • Kim, Ji-Yoo;Kim, Hwa-Jung;Park, Hae-Jun;Ha, Jang-Ho
    • Journal of Radiation Industry
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    • v.8 no.1
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    • pp.17-22
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    • 2014
  • In this study, we prepared CdTe/CdS solar cells using a thermal vacuum evaporation method. In particular, $CdCl_2$ treatment was attempted using this same method at $400^{\circ}C$ for 30 min. The prepared CdTe/CdS solar cells were investigated using Fouier transform infrared spectrometry (FTIR), field emission scanning electron microscopy (FE-SEM), and a solar simulator system including light absorption properties, morphological properties, and power conversion efficiency (PCE). In addition, we investigated the gamma-irradiation treatment at dose rates of 0 Gy, 500 Gy, 1 kGy, 10 kGy, and 30 kGy. The characteristics of gamma-irradiation treatment were studied based on the same method described above. In particular, it showed increased values as 0.826% higher than the non-irradiation of 0.448% from PCE analysis.

Screening for Soybean Pod Borer(Grapholitha glycinivorella Matsumura) Resistant Lines in Korean. Native Soybean Collections (재래종 대두의 콩나방 피해율에 관한 연구)

  • Kwon, S.H.;Ryu, J.;Kim, J.R.;Chung, K.H.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.22 no.2
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    • pp.93-97
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    • 1977
  • The rate of damaged soybean seeds by pod borer averaged 7.4% with the range of 1.2%-21.3% and tended to be higher in the lines with hairy pods comparing to those with hairless pods. The susceptibility of pod borer was negatively correlated with the pod setting date. while was not significantly affected by the weather conditions during the pod setting period.

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Evaluating the Application of Portable Safety Equipment in Nuclear Power Plants using Multi-unit PSA (다수기 PSA 기반 원자력 발전소 이동형 안전 설비 활용성 평가)

  • Jae Young Yoon;Ho-Gon Lim;Jong Woo Park
    • Journal of the Korean Society of Safety
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    • v.38 no.3
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    • pp.110-120
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    • 2023
  • Following the Fukushima accident, portable equipment employed as accident mitigating systems have been installed and operated to reduce core damage and large early release frequencies. In addition, the establishment of an accident management strategy has gained importance. This study investigated the current status of portable equipment including the international portable equipment FLEX (diverse and flexible coping strategies), and domestic portable equipment multi-barrier accident coping strategy (MACST). Research on optimal utilization of MACST remains insufficient. As a preliminary study for establishing an optimal strategy, sensitivity studies were conducted to facilitate the priority of use on portable equipment, number of portable equipment, and dependency of operator actions based on a multi-unit probabilistic safety assessment model. The results revealed the conditions that reduced the multi-unit and site conditional core damage probabilities, indicating the optimal strategy of MACST. The results of this study can be used as a reference for establishing an optimal strategy that utilizes domestic safety equipment in the future.

Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation (방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구)

  • Lee, Sun-Young;Song, Ju-Myung;Sohn, Joon-Yong;Shin, Junhwa
    • Journal of Radiation Industry
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    • v.6 no.2
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    • pp.171-176
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    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

Considerations on Screening for the Input Data of the Biosphere Model in the Radioactive Waste Disposal Facility (방사성폐기물 처분시설에서 생태계 모델의 입력데이터 선정에 대한 고찰)

  • Mi-Seon Jeong;Dong-Kuk Park;Soo-Gin Kim;Kang-Il Jung
    • Journal of Radiation Industry
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    • v.17 no.2
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    • pp.209-217
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    • 2023
  • The biosphere has important function in the safety assessment of a radioactive waste disposal facility. A biosphere model in the safety assessment needs various input data that contain significantly inherent uncertainties. This paper reviews the effects of the input data on the radiological impact assessment from main radionuclides such as 14C and 99Tc in the biosphere model. In addition, it is confirmed that the safety criteria is met, when the conservative input data for the intake rate, soil to plant concentration ratio, and distribution coefficients of the radionuclides are applied and probabilistic analysis are conducted in the biosphere model. Nevertheless, it is required to generate site-specific input data for the confidence building and reduce excessive conservatism in the biosphere model.