• Title/Summary/Keyword: 원자력연구소

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A Study on the Radiolytic Synthesis of PVBC-grafted ETFE Films and Their Quaternarization with Diamines for the Preparation of Anion Exchange Membranes (음이온 교환막 제조를 위한 염화비닐벤질 고분자가 그라프트된 ETFE 필름의 방사선 합성과 디아민류와의 4차 아민화에 관한 연구)

  • Ko, Beom-Seok;Sohn, Joon-Yong;Nho, Young-Chang;Shin, Junhwa
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.179-184
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    • 2011
  • In this study, several anion exchange membranes were successfully prepared by radiation grafting of vinylbenzyl chloride (VBC) monomer onto a polyethylene-co-tetrafluoroethylene (ETFE) film and subsequent quaternarization with diamins such as 1,4-diazbicyclo[2,2,2]octane, N,N,N',N'-tetramethyl-1,3-diaminopropane, N,N,N',N'-tetramethyl-1,6-diaminohexane, and trimethylamine. The anion exchange capacities of the prepared membranes were determined by using acid-base titration method. The cross-sectional morphology of the membranes was studied by using SEM instrument. The cross-sectional distribution patterns of the grafted polymers with anion exchange functional groups were also studied by EDX analysis.

Preparation and Characterization of Microorganism Fermentation Celluose as Hydrogel by Radiation Crosslinking (방사선 가교에 의한 미생물 발효 셀룰로오스 하이드로겔의 제조 및 특성)

  • Lim, Youn-Mook;Park, Jong-Seok;Gwon, Hui-Jeong;Nho, Young-Chang;Kim, Sung-Ho;Choi, Young-Hun;Lee, Sun-Yi;Chong, Moo-Sang
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.113-118
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    • 2011
  • Hydrogels from a mixture of poly(N-vinylpyrrolidone) (PVP), ${\kappa}$-carrageenan and microorganism fermentation celluose were prepared by $^{60}Co$ gamma-ray irradiation. PVP and ${\kappa}$-carrageenan were mixed with the different ratios. Microorganism fermentation celluose were added to the mixture of PVP and ${\kappa}$-carrageenan to evaluate the effect of microorganism fermentation celluose on the gel strength. The gel strength of the hydrogel was evaluated for application of a wound dressing. The results showed that gelation and gel strength were increased with increasing the content of the microorganism fermentation celluose.

Characteristics and Effects of Radiation Treatment on Wood Pulping Process (목재 펄프 제조 공정에서의 방사선 효과 및 특성)

  • Won, So Ra;Shin, Hye Kyoung;Jeun, Joon Pyo;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.5 no.3
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    • pp.227-230
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    • 2011
  • Pulps were separated from wood chips using an Electron beam irradiation (EBI) treatment without a NaOH-AQ (anthraquinone) treatment for cooking. The methods were based on a hot water treatment after EBI and two-step bleaching processes. Chemical compositions and FT-IR spectroscopy demonstrated that the content of lignin and hemicellulose in the bleached wood pulps treated with various EBI dose decreased with an increase of EBI doses. Specifically, the lignin in the bleached with pulps treated at 600 kGy of EBI dose was almost completely removed. Moreover, TGA analysis showed that a thermal stability increased with increasing the content of cellulose but the lignin decomposed slowly over the wide region.

Establishment of γ-irradiation-induced Hematopoietic Tissue Damage Model in ICR Mice (ICR 마우스에서 감마선 조사로 유도된 조혈조직 손상 모델 확립)

  • Kang, Jung Ae;Rho, Jong Kook;Jang, Beom-Su;Chung, Young-Jin;Park, Sang Hyun
    • Journal of Radiation Industry
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    • v.7 no.1
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    • pp.55-59
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    • 2013
  • Ionizing radiation causes the massive generation of reactive oxygen species, resulting in cellular and tissue damage. The present study was performed to evaluate ${\gamma}$-irradiation induced cellular damage in ICR mice. The mice were divided into four groups with ten mice in each group. Group 1 served as an unexposed control group. Groups 2, 3, and 4 were exposed to 3, 5, and 7 Gy of ${\gamma}$-radiation, respectively. Five mice per group were sacrificed 1 and 7 days after ${\gamma}$-radiation. Exposure to ${\gamma}$-irradiation resulted in hematopoietic damage in a dose-dependent manner when compared with the unexposed control group, which featured a significantly decreased spleen index. However, the exposed mice showed no significant differences in their serum AST, ALT and in the histopathological change of their liver. These results suggest that ${\gamma}$-irradiation is a good tool to prepare a hematopoietic damage model. This animal model can be employed to study the hematopoietic efficacy of biologically active compounds.

Effects of Natural Plant Extracts and Gamma Rays on Lactobacillus Isolated from Korean Traditional Raw Rice Wine (천연 식물추출물과 감마선이 막걸리에서 분리한 유산균에 미치는 영향 연구)

  • Nam, Ji-young;Kim, Jae-Hun;Lee, Ju-Woon;Kim, Jin Kyu
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.319-323
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    • 2010
  • Recently, Korean traditional raw rice wines (RRW) have received attention because they are a nutritious food with health properties. But the rapid deterioration of fermented RRW is one of the serious problems for brewing and marketing in the world beyond Korea. The goal of this study was to develop a way to enhance the quality and to lengthen the period of circulation of the RRW. A lactic acid bacterium was isolated from RRW. It was identified as Lactobacillus fermentum (98%) based on its biochemical properties, and 16S rRNA sequence. Treatments of RRW with gamma radiation and green tea extracts reduced the bacterial population except for yeasts and Lactobacillus in the RRW. This result suggested that the natural plant extracts and catechin products can be used as an effective natural storage agent.

Preparation and Characterization of Microorganism Fermentation Cellulose as Hydrogel Wound Dressing (미생물 발효 셀룰로오스를 이용한 상처 치료용 하이드로겔의 제조 및 특성)

  • Kim, Mi-Yeong;Lim, Youn-Mook;Lee, Jong-Dae;Song, Sung-Gi;Gwon, Hui-Jeong;Park, Jong-Seok;Nho, Young-Chang;Kim, Sung-Ho;Choi, Young-Hun;Lee, Sun-Yi
    • Journal of Radiation Industry
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    • v.4 no.4
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    • pp.365-372
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    • 2010
  • Irradiation has been recognized as a highly suitable tool to aid in the formation of hydrogel. The radiation process has various advantage, such as easy process control and the lack of necessity for initiators and crosslinker. In this study, the hydrogel containing the citrus fermentation gel for the wound healing were successfully synthesized. The strength of hydrogel was increased as a function of a increasing the concentration of citrus and the irradiation doses. In addition, this hydrogel have been evaluated by the cytotoxicity and animal experiment.

The Characterization of Crosslinked SPEEK Based Ion Exchange Membranes Prepared by EB Irradiation Method (전자선을 이용해 가교된 SPEEK 기본 물질로 하는 이온 교환막의 특성 분석)

  • Song, Ju-Myung;Shin, Junhwa;Sohn, Joon-Yong;Nho, Young-Chang
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.151-157
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    • 2011
  • Crosslinked SPEEK/PVDF membrane were prepared by EB radiation method with various contents of PVDF. The prepared membranes were subjected to a comparative study of proton exchange membranes for fuel cell appreciations. The crosslinked SPEEK/PVDF membranes were characterized by using DMA, DSC and SAXS. The DMA data indicate that the ionic modulus values and cluster $T_g$ decrease with increasing PVDF content. Thus, it was suggested that the number of clustering in the crosslinked membranes can be reduced with increasing PVDF content. The DSC results were shown that the degree of crystalline of the membrane increased with increasing PVDF content. The morphology of the crosslinkied membranes was shown that with increasing PVDF content, the number of crystalline domain of the SPEEK/PVDF membranes increased but ionic aggregation of the membranes decreased. The water uptake behavior, ionic exchange capacity (IEC) and proton conductivity were decreased with increasing PVDF content. The overall findings suggest that the crosslinked membranes offer the possibility for improving the performance of PEMFC, provided that the membranes have thermal and hydration stability.

Property of CdTe/CdS Solar Cells on Gamma-irradiation (방사선에 대한 CdTe/CdS 태양전지 특성 검토)

  • Kim, Ji-Yoo;Kim, Hwa-Jung;Park, Hae-Jun;Ha, Jang-Ho
    • Journal of Radiation Industry
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    • v.8 no.1
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    • pp.17-22
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    • 2014
  • In this study, we prepared CdTe/CdS solar cells using a thermal vacuum evaporation method. In particular, $CdCl_2$ treatment was attempted using this same method at $400^{\circ}C$ for 30 min. The prepared CdTe/CdS solar cells were investigated using Fouier transform infrared spectrometry (FTIR), field emission scanning electron microscopy (FE-SEM), and a solar simulator system including light absorption properties, morphological properties, and power conversion efficiency (PCE). In addition, we investigated the gamma-irradiation treatment at dose rates of 0 Gy, 500 Gy, 1 kGy, 10 kGy, and 30 kGy. The characteristics of gamma-irradiation treatment were studied based on the same method described above. In particular, it showed increased values as 0.826% higher than the non-irradiation of 0.448% from PCE analysis.

X-Ray Diffraction Studies of Uranyl Hydrolysis Precipitates Synthesized in Neutral to Alkaline Aqueous Solutions

  • 박용준;표형렬;김원호;전관식
    • Bulletin of the Korean Chemical Society
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    • v.17 no.10
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    • pp.925-929
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    • 1996
  • Uranyl hydrolysis precipitates were obtained by increasing pH value of aqueous uranyl solution in the range of neutral to alkaline pH value and their phase transformation during the solubility experiment under various conditions has been examined. The precipitates formed in the hydrolysis reaction of uranyl ion had a layered structure such as a meta-schoepite phase, a schoepite structure, or a mixed phase of meta-schoepite and schoepite. Phase transformation between them was strongly dependent on the pH value at which the precipitate was formed. The distance between the layers in meta-schoepite or schoepite phase was ∼7.35 Å, and it was increased with the pH value at which the precipitate was synthesized as well as the pH values of the aqueous solution. The phase transformation from a meta-schoepite to schoepite was fast for the precipitates formed at low pH values, however, it was not the case for the precipitates formed at high pH values. A small difference of pH value in aqueous solution gave a great change on its solubilities near pH 9.7, because a layered structure of the precipitates became amorphous above that pH value. Greater solubility for the precipitate formed at higher pH value can be explained from the fact that the precipitates formed at low pH value had a better crystallinity and also that the precipitates formed at higher pH value has a slower rate of crystallization.

Studies on Purple Seed Stain (Cercospora kikuchii) of Native Soybean Collections (재래종대두의 자반병 감염에 관한 연구)

  • Kwon, S.H.;Ou, J.H.;Kim, J.R.;Song, H.S.
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.22 no.1
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    • pp.11-15
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    • 1977
  • Natural infection of purple stain seemed to be higher in early maturing lines comparing to late maturing group. It was positively correlated with length of the period from flowering to maturity and significantly associated with weather conditions during the maturing period.

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