• Title/Summary/Keyword: 원소분석

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Fluorescence Signal Analysis of Mixed Rare Earth Elements by Nonlinear Fitting Method (비선형 Fitting법에 의한 희토류 혼합물의 형광신호 분석)

  • Kim, Dukhyeon;Shin, Jangsoo;Song, Kyuseok;Cha, Hyungki;Lee, Jongmin
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.41-45
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    • 1995
  • To analyze mixed rare earth elements quantitatively a nonlinear fitting method was applied to laser induced fluorescence signals. Mixed flourescence signal of two elements, Sm and Eu were resolved independently and determined the concentration of these two elements simultaneously. It was found that detection limit for each element in the mixture was sub-ppb level which was the same as that of the single element sample. Additionally it was found that lifetimes of Sm and Eu extracted from the nonlinear fitting method is the same as in the single element cases.

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Physical Characteristic Analysis of Municipal Solid Waste for Estimation of Gasification Pretreatment Condition (가스화용 전처리 조건예측을 위한 생활폐기물의 물리적 특성 분석)

  • Yoon, Youngsik;Lim, Yongtaek;Park, Sunam;Gu, Jaehoi;Im, Nakjun;Han, Haengseok
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.171.1-171.1
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    • 2011
  • 폐기물의 처리방법은 중간처리와 최종처리로 구분되며, 중간처리의 방법으로는 고형화, 생물학적 처리(소화), 화학적 처리(중화/침전/추출), 자원화 및 재활용, 소각/열분해용융/가스화 등이 있다. 최종처리 방법으로는 매립, 해양투기 등이 있으며, 과거에는 폐기물의 처리 방법으로 최종처리가 많이 이용되었으나 현재에는 지속가능한발전의 이념아래 폐기물의 자원화, 청정에너지의 생산 등을 이유로 전처리 기술이 많이 보급되고 있는 추세이다. 남원시에서 발생되는 생활폐기물은 2010년 통계에 따르면 하루 평균 약 43돈에 이르고 있으며, 매립지의 사용연수를 연장하기 위한 중간처리 방법이 검토되고 있다. 생활폐기물의 가장 일반적인 중간처리 방법으로는 소각, 열분해용융, 가스화 등이 적용될 수 있으며, 이와 같은 열적처리는 폐기물의 감용 및 감량 효율이 높은 중간처리 방법에 속한다. 이러한 열적처리를 위해서는 폐기물의 물리적 특성에 대한 조사 및 검토가 가장 먼저 선행되어야 하며, 본 연구에서는 남원시에서 발생되는 생활폐기물의 성상분류, 삼성분분석, 원소분석, 발열량분석 결과를 통해 가스화에 적합한 전처리 조건을 예측하였다.

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Indoor Air Quality Pollution of PM2.5 and Associated Trace Elements Affected by Environmental Tobacco Smoke (환경담배연기로 인한 실내공기 중 PM2.5 및 미량성분 오염 특성)

  • Lim, Jong-Myoung;Lee, Jin-Hong
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.5
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    • pp.317-324
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    • 2014
  • Environmental tobacco smoke (ETS) samples were collected separately in mainstream and side-stream smoke using a self-designed smoking machine, and a total 40 of PM2.5 was collected with low volume air sampler at indoor environments with and without ETS in Daejeon, Korea. About 20 trace elements including toxic metals like As, Cr, Mn, Se, V, and Zn were determined in PM2.5 and ETS samples by instrumental neutron activation analysis (INAA). It is found that the emission factors of K, Cl, Na, and Al were much higher than those of toxic elements for both mainstream and side-stream smoke. The average concentration of PM2.5 was enriched by 1.5 times at smoking area ($58.7{\pm}18.1{\mu}g/m^3$) than at smoking free area ($38.6{\pm}12.7{\mu}g/m^3$). The concentration ratio of each element between smoking and smoking free area were ranged from 1.1 to 6.0 except Cu (1.0); especially, Ce (6.0), La (5.2), K (2.3), and Co (2.0) showed higher ratio, which suggests that the ETS is one of the possible increasing factors of PM2.5 and elemental concentration at indoor environment.

Stable Isotopic Reconstructions of Diets in Joseon Dynasty Using Human Remains from Myeongam-ri Site, Asan (조선시대 회곽묘 출토 인골의 안정동위원소 분석을 통한 아산 명암리 피장자의 식생활 복원)

  • Kang, Soyeong;Kim, Yun-Ji;Cho, Eun Min;Kim, Sue Hoon
    • Korean Journal of Heritage: History & Science
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    • v.49 no.4
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    • pp.38-51
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    • 2016
  • This study reports on human dietary reconstruction of Joseon Dynasty using stable isotope analysis. The stable carbon and nitrogen isotope values were measured of bone collagen extracted from 25 human bones from archaeological site in Myeongam-ri, Asan. Average values of ${\delta}^{13}C$ and ${\delta}^{15}N$ are $-19.7{\pm}0.5$‰(n=23) and $9.6{\pm}1.1$‰(n=23), respectively. The isotopic data indicates that Myeongam-ri individuals consumed $C_3$ plants mainly and assumed of dietary resourced from a terrestrial animal protein. Previous isotopic studies of the Joseon era suggested that dietary composition of Joseon population was not influenced by region and burial type. Also comparison of the isotopic results of male and female from double burials showed sex-dependent dietary patterns among individuals living in the same circumstances.

A Study on the Correction of Spectral Line Overlaps for the Determination of Rare Earth Elements by X-Ray Fluorescence Spectrometry (X-선 형광분광법에 의한 희토류원소 분석에서 스펙트럼선 겹침 방해의 보정에 관한 연구)

  • Young-Man Kim;Young-Sang Kim;Yoon-Chang Park;Chong-Wook Lee
    • Journal of the Korean Chemical Society
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    • v.30 no.6
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    • pp.538-547
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    • 1986
  • The 8 rare earth elements were determined in the monazite concentrates by X-ray fluorescence spectrometry. The spectral line overlapping interferences from the other elements were investigated and the correction methods of interferences were studied using line overlap coefficients. The coefficients were calculated from the ratios of the intensities measured at the diffracted angle (2${\theta}$) of the analytical lines of other elements to the intensity of pure rare earth oxide. The coefficients were used to correct the line overlaps by a regression analysis. The linearities of calibration curves from the corrected intensities were remarkably improved, and their standard deviations were decreased. The analytical results agreed with that of the inductively coupled plasma(ICP) spectrometry within an allowable error range.

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