• Title/Summary/Keyword: 용해 평형

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A Theoretical Performance Analysis of Small Liquid Rocket Engine for Space Vehicle Attitude Control (우주비행체 자세제어용 소형 액체로켓엔진의 이론성능 해석)

  • Kim Jeong-Soo;Park Jeong;Kim Sung-Cho;Choi Jong-Wook;Jang Ki-Won
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.196-200
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    • 2005
  • A theoretical model for the calculation of chemical equilibrium composition of propellant combustion product is briefly presented for the performance analysis of monopropellant hydrazine rocket engine. Analysis result is compared to that of test and evaluation of 1-lbf class thruster and is scrutinized primarily from the view point of ammonia dissociation fraction. Chemical equilibrium composition and average molecular weight is additionally depicted according to the variation of propellant inlet pressures and the varying nozzle area ratio. The theoretical analysis is tried as a way of derivation of design parameters for mid- and large-thrust class of monopropellant rocket engines.

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A Study on the Vibrational Characteristics of Natural Frequency with Balancing type Vibratory Conveyor Using Finite Element Methods (유한요소해석법을 이용한 평형형 진동이송기의 고유진동수 특성분석에 관한 연구)

  • Lee, Seung-Yong;Yi, Sung-Il;Kim, Chol-Ho;Choi, Yong-Jae;Choi, Woo-Chun
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.568-572
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    • 2001
  • An industrial vibratory conveyor system is devised for large-scale feeding by the low-power, using natural frequency of the system. The important thing in this system is to determine the natural frequency and to drive by it. The purpose of this study is to build up reliance on the system with changing of element parameters for vibration characteristics of balancing type vibratory conveyor by using F.E.M. modeling. For investigating the natural frequency, modal testing is performed by using impact hammer, accelerometer and LMS/Vibration Analysis System. Experimental results are compared with F.E.M results. The results of the comparisons within the errors of less than 2 percent can verify the reliability of the F.E.M. analysis of the system. Also we can verify that the characteristics of natural frequency have linearly decreased(-6%) as adding the mass($50{\sim}600kg$). We can find that controlling driving frequency is necessary for triggering the natural frequency, but natural frequency is less affected by adding the mass on the balancing weight.

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LLE of Solvent-Water-2-Propanol Ternary Systems (Solvent-water-2-propanol 삼성분계의 액-액평형)

  • Jeong, Sang-Hoon;Lee, Jin-Woo;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.653-659
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    • 1997
  • Due to the rising cost of energy, new separation processes based on extraction are becoming more attractive than before. Thus, the need for calculating and predicting liquid-liquid equilibria(LLE) compositions has very much increased. The purpose of this study is to determine the binodal curves, tie line, plait point, distribution and selectivity for the ternary systems of 2-propanol-water with methyl ethyl ketone, methyl isobutyl ketone, ethylacetate, toluene and o-xylene as solvents at $25^{\circ}C$. And those tie line data were used to examine thermodynamic consistency. The experimental tie line data were correlated with NRTL and UNIQUAC models.

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The Physicochemical Properties on the Organic, Charge Transfer Complexes under High Pressure (고압하의 전하이동착물에 대한 물성론적 연구. 사염화탄소 용액내에서의 헥사메틸벤젠과 1,3,5-트리니트로벤젠과의 전하이동착물 생성에 대한 압력과 온도의 영향)

  • Oh Cheun Kwun;Myong Ja Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.6
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    • pp.513-519
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    • 1988
  • The effect of pressure and temperature on the stabilities of hexamethylbenzene-1,3,5-trinitrobenzene charge transfer complex in carbon tetrachloride has been investigated by spectrophotometric measurements. The absorption spectra of charge transfer complexes were measured at 25, 40, $50^{\circ}C$ under 1, 200, 500, 1000, 1400 bar in this experiments. The equilibrium constants of the complex were increased with pressure and decreased with temperature rising. The absorption coefficients were increased with pressure and temperature. Change of volume, enthalpy, free energy and entropy for the formation of complexes were calculated from the equilibrium constants. The red-shift observed at a higher pressure, the blue-shift at a higher temperature and the relation between pressure and oscillator strength were discussed by means of thermodynamic fuctions.

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The Implementation of Current Compensation Controller in Driving Voltage type Converter considering the Unbalance of Reactor at the Source Side (전원측 리액터 불평형을 고려한 전압형 컨버터의 전류 보상 제어기 구현)

  • Chun Ji-Yong;Cho Yu-Hwan;Lee Geun-Hong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.5
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    • pp.413-420
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    • 2004
  • In this paper, the control algorithm of DC source device for inverter starting is proposed and the control method for compensating unbalance system source on operating time in the voltage type PWM converter with driving and regenerative faculty is suggested. The maintaining method of balancing condition for converter of AC source is used the compensating unbalanced status by current control loop. In order to solve the problem which the unbalanced system control is used to leakage transformer not equaled reactance by each phase in rectifier system. The proposed H/W and control algorithm of rectifier system is contributed to minimize of device and rising efficiency.

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Liquid-Liquid Equilibrium for the Quaternary System Water + Tetrahydrofuran + Butyl Acetate + Isoamyl Alcohol Mixture at 298.15 K and Atmospheric Pressure (1 atm 298.15 K에서 4성분 Water+Tetrahydrofuran+Butyl Acetate+Isoamyl Alcohol 계의 액-액평형)

  • Kim, Young-Kyu;Ok, Dong-Seok;Park, Dong-Won
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.632-637
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    • 2010
  • Liquid-liquid equilibrium data for the quaternary system water +tetrahydrofuran + butyl acetate + isoamyl alcohol mixture were measured at 298.15 K and atmospheric pressure. Binodal curves, tie-lines, distribution, and selectivity for the quaternary system have been determined in order to investigate the effect of using binary solvents, butyl acetate and isoamyl alcohol, on extracting tetrahydrofuran from aqueous solution. In addition, these experimental tie-line data were also compared with the values predicted by the UNIFAC model. For the quaternary system, an average root-mean-square deviation for the system in 75/25, 50/50, and 25/75 mass ratios as mixed solvents are(3.35, 5.21 and 5.65) %, respectively.

Stability Evaluation Methods of Agricultural Reservoir by Field Monitoring (현장계측에 의한 농업용저수지 제체의 안정관리기법)

  • Lee, Dal-Won;Oh, Beom-Hwan
    • Korean Journal of Agricultural Science
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    • v.30 no.2
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    • pp.164-174
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    • 2003
  • This study was performed to suggest a rational method for the stability evaluation of agricultural reservoir in the very soft ground. The stability methods for agricultural reservoir was used to compare and analyze with various condition by limit equilibrium method. The behavior of settlement-displacement obtained by field monitoring system was used to compare and analyze with various stability methods, and to investigate the applicability of the methods for stability evaluation of agricultural reservoir. The horizontal displacement was abruptly increased when physical properties of soft clay reached its maximum values and therefore, the values of these properties could be used to the fundamental data for stability evaluation. The evaluation of the stability of agricultural reservoir was suggested to use the inclination of curve rather than critical line.

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A Research on a Cross Post-Distortion Balanced Linear Power Amplifier for Base-Station (기지국용 Cross Post-Distortion 평형 선형 전력 증폭기에 관한 연구)

  • Choi, Heung-Jae;Jeong, Hee-Young;Jeong, Yong-Chae;Kim, Chul-Dong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.11
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    • pp.1262-1270
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    • 2007
  • In this paper, we propose a new distortion cancellation mechanism for a balanced power amplifier structure using the carrier cancellation loop of a feedforward and post-distortion technique. The proposed cross post-distortion balanced linear amplifier can reduce nonlinear components as much as the conventional feedforward amplifier through the output dynamic range and broad bandwidth. Also the proposed system provides higher efficiency than the feedforward. The capacities of power amplifier and error power amplifier in the proposed system are analyzed and compared with those of feedforward amplifier. Also the operation mechanisms of the three kind loops are explained. The proposed cross post-distortion balanced linear power amplifier is implemented at the IMT-2000($f_0=2.14\;GHz$) band. With the commercial high power amplifiers of total power of 240 W peak envelope power fer base-station application, the adjacent channel leakage ratio measurement with wideband code division multiple access 4FA signal shows 18.6 dB improvement at an average output power of 40 dBm. The efficiency of fabricated amplifier Improves about 2 % than the conventional feedforward amplifier.

Development of CCPP(Calcium Carbonate Precipitation Potential) calculating program for corrosion control of drinking water distribution system (상수도관 부식방지를 위한 CCPP(Calcium Carbonate Precipitation Potential) 산정 프로그램 개발)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.1
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    • pp.170-175
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    • 2008
  • In this study, we developed the CCPP calculating program, which is a kind of index and can determine whether calcium carbonate would precipitate or not in pipe line of water distribution system. Through 9 complicated procedures, CCPP can be calculated. Assuming pH of equilibrium as a first trial, compare the right-hand-side result with left-hand-side result. If the percentage difference between the two results is less than a prescribed tolerance, the initial assumption for the assumed equilibrium pH is adequate. If the difference is too large, make a different assumption and repeat until a result within the prescribed tolerance is achieved. Plugging the intermediate results into the final equation, we could compute the CCPP. Using Fortran and Visual Basic languages, we developed the program. As a result of application of the program, the water quality of intaking water of Han River is highly corrosive by the index of CCPP.

Impregnation of Ibuprofen on MCM-41 using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 MCM-41에의 Ibuprofen 함침)

  • Kim, Hong-Lyong;Kim, Jung-Teag;Chun, Jae Kee;Lee, Seok Hee;Hong, Seong-Soo;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.248-253
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    • 2006
  • In order to develope an efficient drug delivery system, experimental researches on the supercritical impregnation of ibuprofen onto mesoporous silica, MCM-41,and its drug release characteristics were performed. Supercritical carbon dioxide was adapted as an alternative solvent as it is harmless and able to avoid defects of organic solvents in drug manufacturing processes. The procedure was composed of three steps, that is, as hydrothermal synthesis of MCM-41, supercritical impregnation of ibuprofen onto MCM-41 and release of impregnated ibuprofen. Supercritical impregnation reached equilibrium within 2 h for all cases of this research and the amount of equilibrium impregnation increased with solubility of ibuprofen in supercritical carbon dioxide. Release profiles of impregnated ibuprofen showed a similar behavior for all MCM-41 with different impregnated ibuprofen.