• Title/Summary/Keyword: 용해도 상수.

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Plasma Polymerized Styrene for Gate Insulator Application to Pentacene-capacitor (유기박막트랜지스터 응용을 위해 플라즈마 중합된 Styrene 게이트 절연박막)

  • Hwang, M.H.;Son, Y.D.;Woo, I.S.;Basana, B.;Lim, J.S.;Shin, P.K.
    • Journal of the Korean Vacuum Society
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    • v.20 no.5
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    • pp.327-332
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    • 2011
  • Plasma polymerized styrene (ppS) thin films were prepared on ITO coated glass substrates for a MIM (metal-insulator-metal) structure with thermally evaporated Au thin film as metal contact. Also the ppS thin films were applied as organic insulator to a MIS (metal-insulatorsemiconductor) device with thermally evaporated pentacene thin film as organic semiconductor layer. After the I-V and C-V measurements with MIM and MIS structures, the ppS revealed relatively higher dielectric constant of k=3.7 than those of the conventional poly styrene and very low leakage current density of $1{\times}10^{-8}Acm^{-2}$ at electric field strength of $1MVcm^{-1}$. The MIS structure with the ppS dielectric layer showed negligible hysteresis in C-V characteristics. It would be therefore expected that the proposed ppS could be applied as a promising dielectric/insulator to organic thin film transistors, organic memory devices, and flexible organic electronic devices.

Phosphate Adsorption Characteristics of Zirconium Mesostructure Synthesized under Different Conditions (지르코늄 메조구조체의 합성조건 변화에 따른 인 흡착 특성)

  • Lee, Seung-Hak;Lee, Kwan-Yong;Lee, Sang-Hyup;Choi, Yong-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.583-587
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    • 2006
  • In this study, the phosphate adsorption characteristics of zirconium mesostructures synthesized under different conditions were estimated. X-ray diffraction analysis, phosphate adsorption isotherm test and kinetic test was performed for the zirconium mesostructures synthesized at different inorganic/surfactant molar ratio and with different surfactant templates. The test results were analyzed with adsorption models. From this work, it was found that at the inorganic/surfactant molar ratio of 1/0.50($0.013{\cdot}Zr(SO_4){_2}:0.068{\cdot}surfactant:5.55{\cdot}H_2O$), the meso-pores in the material could be most uniformly and clearly formed and thus the adsorption capacity and reaction rate of material could be maximized. And the pore size in the mesostructure increased with the chain length of surfactant template used, and maximum phosphate adsorption amount and reaction rate could be achieved with the zirconium mesostructure synthesized with the surfactant template of dodecyltrimethylammonium bromide.

Purification and Characterization of Cholesterol Oxidase Produced by Streptomyces polychromogenes IFO 13072. (Streptomyces polychromogenes IFO 13072가 생산하는 Cholesterol Oxidase의 정제 및 효소학적 특성)

  • 김현수;성림식;이경화;이용직;이인선;유대식
    • Microbiology and Biotechnology Letters
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    • v.30 no.2
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    • pp.142-150
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    • 2002
  • Streptomyces polychromogenes IFO 13072 was used as a strain producing cholesterol oxidase(EC 1.1.3.6). The conditions of cholesterol oxidase production were investigated. The optimum composition of medium for production of the enzyme was 1% dextrin, 0.5% casamino acid, 0.1% $KH_2$PO$_4$, 0.5% $NaNO_3$ and 0.05% $MgSO_4$(pH 7.3). The enzyme was purified specifically by cholesterol affinity column chromatography with a yield of 23.2%. The purified enzyme showed a single polypeptide on SDS-PAGE and the molecular weight was estimated about 52,000 daltons. The optimum pH and temperature of the cholesterol oxidase were pH 7.0 and $37^{\circ}C$, respectively. The enzyme was stable in the range of pH 6.0~7.0 and $25^{\circ}C$. The cholesterol oxidase activity was strongly inhibited by metal ions such as $Hg^{2+}$ and $Fe^{2+}$ and inhibitors such as dithiothreitol, mercaptoethanol and isonicotinic acid. The Michaelis constant(Km) for the cholesterol was found to be 25 mM by Lineweaver-Burk plot analysis.

Evaluation of Biodegradation Kinetic in Biological Activated Carbon (BAC) Process for Drinking Waste Treatment : Effects of EBCT and Water Temperature (정수처리용 생물활성탄 공정에서 Halonitromethanes (HNMs)의 생물분해 동력학 평가 : EBCT 및 수온의 영향)

  • Son, Hee-Jong;Kang, So-Won;Yoom, Hoon-Sik;Ryu, Dong-Choon;Cho, Man-Gi
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.7
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    • pp.404-411
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    • 2015
  • In this study, the effects of empty bed contact time (EBCT) and water temperature on the biodegradation of 9 halonitromethanes (HNMs) in biological activated carbon (BAC) process were investigated. Experiments were conducted at three water temperatures ($10^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$) and three EBCTs (5, 10 and 15 min). Increasing EBCT and water temperature increased the biodegradation efficiency of HNMs in BAC column. Dibromochloronitromethane (DBCNM) and tribromonitromethane (TBNM) showed the highest biodegradation efficiency, but chloronitromethane (CNM) and dichloronitromethane (DCNM) were the lowest. The kinetic analysis suggested a pseudo-first-order reaction model for biodegradation of 7 HNMs at various water temperatures and EBCTs. The pseudo-first-order biodegradation rate constants ($k_{bio}$) of 7 HNMs ranged from $0.0797{\sim}0.7657min^{-1}$ at $10^{\circ}C$ to $0.1245{\sim}1.8421min^{-1}$ at $25^{\circ}C$. By increasing the water temperature from $10^{\circ}C$ to $25^{\circ}C$, the biodegradation rate constants ($k_{bio}$) were increased 1.6~2.4 times.

Magnetic Properties of Both Ni-W and (Ni-3%W)-Cu Textured Substrates for ReBCO Coated Conductor (고온초전도 박막선재용 Ni-$W_{xat.%}$ 및 (Ni-$W_{3at.%}$)-$CU_{xat.%}$ 이축배향 금속 기판들의 자기적 특성)

  • Song, K.J.;Kim, T.H.;Kim, H.S.;Ko, R.K.;Ha, H.S.;Ha, D.W.;Oh, S.S.;Park, C.;Yoo, S.I.;Joo, J.H.;Kim, M.W.;Kim, C.J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.28-29
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    • 2006
  • The magnetic properties of a series of both annealed and as-rolled Ni-$W_y$ alloy tapes with compositions y = 0, 1, 3, and 5 at.%, were studied. To compare with Ni-W alloys, the magnetic properties of a series of both annealed and as-rolled $[Ni_{97at.%}W_{3at.%}]_{100-x}Cu_x$ alloy tapes with compositions x = 0, 1, 3, 5 and 7 at.%, were studied, as well. Both the isothermal mass magnetization M(H) of a series of samples, such as both Ni-W and [Ni-W]-Cu alloy tapes, at different fixed temperatures and M(T) in fixed field, were measured using a PPMS-9 (Quantum Design). The degree of ferromagnetism of Ni-$W_y$ alloys have reduced as W-content y increases. Both the saturation magnetization $M_{sat}$ and Curie temperature $T_c$ decrease linearly with W-content y, and both $M_{sat}$ and $T_c$ go to zero at critical concentration of $y_c$ ~ 9.50 at.% W. The effect of Cu addition on both the saturation magnetization $M_sat$ and Curie temperature $T_c$ decrease linearly with Cu-content x in $[Ni_{97at.%}W_{3at.%}]_{100-x}Cu_x$ alloy tapes with compositions x = 0, 1, 3, 5, and 7 at.%. The results confirm that [Ni-W]-Cu alloy tapes can have much reduced ferromagnetism as Cu-content x increases.

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Current Status and Perspectives of Weed Science in Asia-Pacific Area (아시아·태평양지역의 잡초연구 동향과 전망)

  • Lee, In-Yong;Kim, Jin-Won;Kim, Sang-Su;Yoo, Hong-Jae;Hwang, In-Seong;Lee, Kye-Hwan;Cho, Nam-Gyu;Lee, Dong-Guk;Hwang, Ki-Hwan;Won, Ok Jae;Jia, Weiqiang;Ko, Young-Kwan;Choi, Jung-Sup;Yeom, Hyun-Suk;Park, Kee Woong
    • Weed & Turfgrass Science
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    • v.6 no.4
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    • pp.292-305
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    • 2017
  • This paper provides the current status of weed science and prospects for the development of weed science based on the research trends presented at the 26th Asian Pacific Weed Science Conference in 2017. Approximately 458 researchers from 25 countries, including Korea, participated in the conference and presented 325 papers in 20 research areas. Major research topics were herbicide resistance, herbicide use, herbicide development, weed ecology, allelopathy, weed management, and exotic weeds. Particularly, there were many presentations and interesting to researchers about the development and use of new herbicides, such as florpyauxifen-benzyl ester, triafamone, fenquinotrione, and tolpyralate. Development of new herbicide formulations and spray methods were suggested as a solution for the population decline in rural area and low labor quality especially in Asia and Pacific regions. In future weedy rice and exotic weeds will be a serious problem in this area so we need to cooperate to make good technical and practical solutions.

Effect of Nitrogen and Potassium Fertilizer Types on Growth Responce of Onions Under Continuous Cropping (양파의 연작지(連作地)에서 질소(窒素) 및 가리비종별(加里肥種別) 생육반응(生育反應))

  • Shin, Bog-Woo;Yoo, Chul-Hyun;Lee, Sang-Bog;Joeng, Ji-Ho;Han, Sang-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.3
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    • pp.271-276
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    • 1998
  • This experiment was carried out to investigate the changes on nutrient uptake and yields of onion when it was applied with urea and ammonium sulfate as nitrogen fertilizer types; potassium chloride and potasssium sulfate as potassium fertilizer types and lime requirement and phosphorus absorption coefficient controlled 5% as soil improvement index. The variety of onion used was CheonJuHwang and the soil used was Yonggye series in the Jeonnam Muan area. The amounts of N, P and K uptake were higher in the mixed application plot of ammonium sulfate and potassium sulfate than in the plot of urea or potassium chloride. The sulfate content of soil was higher in the period of plant growth than in the harvest stage. The sulfate content of plant was highest in the harvest stage and this content was higher in the stem and in the leaf than in the bulb. The sugar content of onion was 7.43~8.23 Brix content was higher in the large bulb than in the small bulb. The weight of dry matter and the rate of good quality were high in the mixed application plot of ammonium sulfate and potassium sulfate, so the yield of onion was increased 2~6% compared with control.

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Formation of Alunite and Schwertmannite under Oxidized Condition and Its Implication for Environmental Geochemistry at Dalseong mine (산화환경하에서 명반석, 슈베르트마나이트의 형성특징과 환경지구화학적 의미: 달성광산)

  • 추창오;이진국;조현구
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.1
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    • pp.37-47
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    • 2004
  • Sulfates such as alunite and schwertmannite formed under oxidation condition play a important role in geochemical processes taken place at waste dumps and a creek from Dalseong mine, Daegu. Water chemistry shows pH decreases from upstream toward downstream creek, mainly due to formation of schwertmannite that is the most abundant phase along the creek. The removal of Al from the creek is preferentially attributed to formation of Al-bearing minerals and Al-sulphates. Among them, alunite is the most important Al-sink phase that occurs at higher pH than $pK_1$, Al hydrolysis constant. With high saturation index, alunite formed at the creek has a spherical form, commonly associated with schwertmannite. Secondary minerals formed on the surface of altered or weathered surfaces of heavy metals from the wasted dump that underwent severe oxidation, where alunite has characteristic habits which are spheric, radiating, and botrytis-like aggregates. Natroalunite occurs in association with alunite, or as mixtures of both of them. Because the pH decreases with distance due to formation of schwertmannite, although total contents of dissolved ions slowly lessen at least in the AMD, it is expected that the minerals precipitated at the creek can be exposed to subsequent dissolution, which may induce possible environmental problems.

Synthesis and Rietveld Refinement of the Cathode Material $LiFePO_4/C$ for Rechargeable Lithium Batteries (리튬 2차전지용 양극소재 $LiFePO_4/C$의 합성 및 리트벨트 구조분석)

  • Hwang, Gil-Chan;Choi, Jin-Beom;Kim, Jae-Kwang;Ahn, Jou-Hyeon
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.1
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    • pp.63-72
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    • 2009
  • Carbon-coated lithium iron phosphate ($LiFePO_4/C$) composites are synthesized by the modified mechanical activation method (modified MA process) and studied by the Rietveld structural refinement. Rietveld indices of $LiFePO_4/C$ indicate good fitting with $R_p=8.14%,\;R_{wp}=11.1%,\;R_{exp}=9.09%,\;R_B=3.88%$, and S (GofF, Goodness of fit) = 1.2, respectively. $LiFePO_4/C$ with a space group Pnma shows a = 10.3229(3)${\AA}$, b = 6.0052(2) ${\AA}$, c = 4.6939(1) ${\AA}$, and V = 290.98(1) ${\AA}^3$ in dimension, indicating good agreements with those of previous works. Synthetic powders are nano-sized ($65{\sim}90nm$) homogeneous particles with high purity. Thus the modified MA method will be an efficient process to get a high quality cathode material for commercial lithium batteries.

Analysis of Central Place Hierarchy Change in Daejeon Metropolitan City (대전광역시 중심지 위계 변화 분석)

  • Kim, Sang-Soo;An, Sang-Hyun;Shin, Young-Chul;Kim, Houng-Tae
    • Journal of the Korean Association of Geographic Information Studies
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    • v.11 no.3
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    • pp.23-33
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    • 2008
  • This study was performed to determine the central place hierarchy in Daejeon metropolitan city by examining its central place systems for the existing central place analyses through formation of urban spatial structure and GIS method. The central place structure and hierarch for the year of 2000 and 2005 were analyzed by using the model of W. K Davis modified, in which $1km{\times}1km$ GRID was applied. The analysis results showed the establishment of one CBD(existing center of Eunghaeng-dong and Sunhwa-dong) and two Subcenters (tourist resort of Yusung-dong and administrative center of Dunsan-dong) in Daejeon metropolitan city for the year of 2000. For the year of 2005, established were two CBD(existing center of Eunghaeng-dong and Sunhwa-dong and administrative center of Dunsan-dong) and two Subcenters (tourist resort of Yusung-dong and bus-terminal of Yongjeon) in Daejeon metropolitan city. The analysis results are expected to play a pivotal role in supporting the urban spatial policies in near future.

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