• Title/Summary/Keyword: 용탈시험

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Effect of Soil Properties on Leaching of Preservative Components from CCA-treated Wood (토양 특성이 CCA 처리재로부터 방부제 성분의 용탈에 미치는 영향)

  • Jeong, Yong Gi;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.87-94
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    • 2005
  • This study was carried out to investigate the effect of soil types and soil properties on wood preservative leaching. Radiata pine (Pinus radiata Don.) sapwood stakes, which had been treated with 2.0%(w/v) CCA, were leached for 12 weeks by a common laboratory method in four different soils and for 14 days by the AWPA standard leaching method in water. The physical and chemical properties of the four soils were determined, and the percent leaching of the individual component of CCA was correlated with the various soil properties. The data show that leaching of preservative chemicals from treated wood exposed to soil is influenced by the type of soil. The preservative leaching was greater when wood was exposed to water than when the wood was in contact with water-saturated soil. The greatest chromium, copper and arsenic leaching from CCA-treated stakes were observed in the sandy loam, loam, and sand, respectively, and the least amount of leaching of CCA components occurred in the silty loam. The leaching of preservative components from treated wood is extremely complex and appears to be influenced differently by the soil properties. The extent of copper leaching from CCA treated wood appears to be related to exchangeable Mg and sum of bases. There is a reasonably good relationship between chromium leaching and exchangeable Mg, and between arsenic leaching and exchangeable K, soil Ni, Mn, Fe, Cr, or Cu content. Since this study was conducted based on laboratory leaching method using small cross-sectional dimensions; thus, data obtained from this experiment should not be used to predict leaching characteristics from commercial-size wood used in real situation. Accordingly, further studies are necessary using outdoor ground-contact leaching.

Environmental Impact Review and Improvement of Durability of Silicasol-cement Grout Material (실리카졸 약액의 환경영향성 검토 및 내구증진방안)

  • Lee, Byungho;Kim, Younghun;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.12
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    • pp.13-18
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    • 2010
  • This study was made on the fact that the environmental impact and durability of the recently developed alkali silicasol chemical grout material. The grout material used for this study was designed to understand its environmental impact and durability through the SEM, chemical resistance test, leaching test, permeability test. In order to compare with the engineering characteristics regarding alkali silicasol grout material and sodium silicate grout material. As a result of SEM, the surface and internal tissues of alkali silicasol grout material could be identified to be denser than those of sodium silicate. As a result of leaching test the adaptability was identified as grout material as it had proved to be an ecological material owing to the total amount of the element to be leached being extremely little. As a result of permeability test it is judged that it is possible to apply the silicasol to the site in the place requiring the water cut-off as the silicasol.

Leaching Characteristics of the Endocrine Disruptor-suspected Pesticides in Upland Soil (내분비계장애추정농약의 밭토양 중 용탈 특성)

  • Noh, Hyun Ho;Lee, Jae Yun;Lee, Kwang Hun;Park, Hyo Kyoung;Kyung, Kee Sung
    • The Korean Journal of Pesticide Science
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    • v.17 no.3
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    • pp.168-177
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    • 2013
  • This experiment was carried out to estimate leaching potential of thirteen endocrine disruptor-suspected pesticides in upland soils using soil columns (5 cm I.D. ${\times}$ 35 cm H.) packed with soil A (sandy loam) and soil B (loam). When 12.6 mL of water, average precipitation in Cheongju area during the period from June to August, 2001-2010, was percolated through soil column packed with soil A every day for 21 days, no pesticides were detected from leachate, with the exception of metribuzin which was detected with negligible. Also, when 2 L of water was percolated consecutively five times through soil columns packed with soil A and B, irrespective of soil types, cypermethrin, endosulfan, fenvalerate, parathion and trifluralin, which were very low water solubilities and high soil $K_{oc}s$, were not detected from leachate and were distributed mostly in the depth of 0-5 cm, representing that water solubility and soil $K_{oc}$ are major contributing factors to their leaching behavior. Despite high average leaching rates in carbaryl and methomyl, actual possibilities of ground water contamination in the agricultural environment by them would be very low, considering that the negligible amount of pesticide was percolated through a lysimeter with an undisturbed soil core simulating the field conditions, while most of pesticide was percolated through a soil column with the disturbed soil profile.

A Study on Durability and Impermeability of Environmentally Friendly Inorganic Ground Injection Material (환경 친화적인 무기질계 지반주입재의 내구성 및 차수효과에 관한 연구)

  • Chun, Byungsik;Kang, Hyoungnam;Do, Jongnam;Lim, Jooheon
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.6
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    • pp.113-119
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    • 2006
  • Recently, the ground injection method using water glasses as one of the main resources and the products of these constructions have basic problems in terms of the method of constructions for the permanent foundation reinforcement and stopping leakage of water because they have some serious problems such as durability, compressive strength, injectant eluviation and so forth even though they are still used to stop leakage of water in the temporary structures. The purpose of this study is to demonstrate the strength characteristic and environment friendliness of NDS method by unconfined compressive strenth test, permeability test, length change test, leaching test, and assessment of environmental impact in comparison water glass type material. The test results show that NDS method has significant improvement of strength, permeability, volume change, and leaching. An assessment of environmental impact also demonstrates that the NDS material is environmentally friendly.

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A Study on the Application and Grouting Effects of Akali-Silicasol Grout Material from Field Test (현장시험을 통한 알칼리성 실리카졸 주입재의 적용성 및 주입효과에 대한 연구)

  • Kim, Younghun;Lee, Jinkyu;Yang, Hyungchil;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.8
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    • pp.5-13
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    • 2012
  • This research have investigated the application and the injection effect of the alkaline silicasol grouting materia (which is) recently developed. To compare the engineering characteristics of the alkaline silicasol which is formed with 3D-gel and the sodium silicate, it have studied the strength and environmental effects through the laboratory test, and field application was investigated with a review of the injection effect and waterproof through the field test. As a result of the laboratory test, unconfined compression strength of alkaline silicasol was 5 times more than sodium silicate. As a result of the leaching test, a total amount of the eluviated elements was very small, it considered the environment-friendly material. As a result of the field test, considerable reduction of the coefficient of permeability at the hydraulic layer was confirmed, and it could secure that the coefficient of permeability showed a lower than standard value of $10^{-5}cm/sec$.

Strength Characteristics of Geo-polymer Grout (지오폴리머계 그라우트재의 강도 특성)

  • Lee, Jonghwi;Kim, Seonju;Cha, Kyungsub;Kim, Sunkon;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.4
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    • pp.53-59
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    • 2012
  • In this study, strength and durability of a geo-polymer grout material(HIT) was investigated through unconfined compression strength tests(UCS)), scanning electron microscope(SEM), elution tests, and surface observations. UCS tests showed high initial strength and rapid continuous strength increments when compared to labile wasser glass(LW) and space grouting rocket system (SGR) grout materials, which showed strength reduction after 28 days. The higher strength was also reflected in SEM results which showed calcium silicate hydroxide(C-S-H) gels of the dense hydrate range, indicating higher strength and durability. Additionally, elution tests and grout surface observations showed HIT was in good condition and the decrease in weight was minor when under water for six months. LW and SGR showed the grout surface to be constricted and lower durability due to higher weight increase. These results and observations show HIT to be better suited for coastal structural applications than LW and SGR in long terms of strength and durability.

A Study Of Practical For Eco-Grouting Materials (친환경 그라우팅 재료를 통한 현장 적용성 연구)

  • Moon, Kim-Hak;Jang, Kyung-Jun;Hur, Won;Hur, Hyung-Suk
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1253-1257
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    • 2010
  • 그라우팅은 건설공사에서 지반의 갈라진 틈이나 공동, 공극 등에 적절한 충전재를 압력을 이용하여 주입하는 것으로, 굴착공사 시 누수방지와 불안정한 지반의 보강을 위하여 광범위하게 사용되고 있다. 가장 많이 사용되고 있는 그라우팅 주입재의 재료로는 물유리계를 주재료로 사용하는 약액주입공법이 많이 사용되어지고 있다. 기존의 물유리계 재료를 사용할 경우 발생하는 용출현상 및 강도저하를 보완하기 위하여 가소성을 부과한 무기질계 재료ECG(Eco Clean Grouting)를 사용하여, 강도 및 내구성이 우수하고 주입재의 용출 현상이 발생하지 않아 환경오염 문제가 거의 없는 영구적인 차수 및 보강에 적합한지와 친환경적 특성을 확인한다. 본 연구는 가소성 무기질계 재료인 ECG(Eco Clean Grouting)재료를 사용하여 현재 많이 사용되는 재료인 물유리계 재료로 일축압축강도, 체적변화, 내구성 평가, 투수시험, 어독성 시험, 용탈시험등을 수행하여 비교 분석 하였다. 일축압축 시험결과 재령 28일 강도는 ECG가 물유리재료에 비해 크게 발현되었고, 내화학성시험 결과 ECG의 길이변화율이 거의 없는 것으로 내화학성에서 강점을 보였다.

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Studies on the Leaching of the Constituents In Paddy Soil -II. Effects of Organic Matter (논 토양성분의 용탈에 관한 연구 -II. 논 토양성분의 용탈에 미치는 유기물(有機物)의 영향(影響))

  • Kim, Kwang-Sik;Kim, Yong-Woon
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.2
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    • pp.162-167
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    • 1983
  • These studies were carried out to investigate the effects of organic matter on the leaching of chemical constituents in paddy soil. Rice plants were cultured in paddy soil to which rice straw and compost were applied and then chemical properties of percolated water were analysed. The results were as follows: In the paddy soil cultured with rice plants, the pH value of soil was higher in the compost plot than in the rice straw plot. The leaching of iron, managanese, calcium, magnesium and phosphate was increased by cultivation of rice plant, but that of potassium, ammonium, and silica was decreased. When rice straw was applied in the paddy soil, the leaching of iron, managanese, phosphate and silica was increased during the growing periods, while that of calcium, magnesium, potassium and ammonium was increased by application of compost.

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Leaching and Adsorption of Flupyrazofos(KH-502) in the Soil (Flupyrazofos(KH-502)의 토양 중 용탈 및 흡착)

  • Yang, Jae-E;Cho, Boo-Yeon;You, Kyoung-Youl
    • Korean Journal of Environmental Agriculture
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    • v.16 no.1
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    • pp.72-79
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    • 1997
  • Adsorption, leaching, and retention of the Flupyrazofos(KH-502), a new active ingredient for insecticide, in the soils under laborarory and field conditions were investigated to provide the basic data for the safety use and to assess a secondary impact of this insecticide on soil and water environments. A significant power function relation was found between the adsorbed KH-502 and time, representing that 45% of the added KH-502 was adsorbed within 30 min. but a quasiequilibrium was reached after 6 to 12 hr with a slower adsorption. Adsorption phenomena followed th first-order kinetics and time required for 50% adsorption was 5.8 hr. The equilibrium adsorption isotherm was explained by the Freundlich equation and was classified as S-type. The amounts of KH-502 leached through the soil column (C) as compared to initial conc. ($C_0$) were very low and these relative concentrations ($C/C_0$) were 0.073 and 0.017 in SL and CL soils, respectively. The residual conc. of KH-502 in the surface soil was comparatively low and decreased with time. Half-lives of KH-502 in the surface soil was comparatively low and decreased with time. Half-lives of KH-502 under the field conditions were estimated to be 20 and 18 days in the SL and CL soils, respectively. The KH-502 cone, transported to the subsurface soils was extremely low. These results demonstrate that KH-502 has a low pollution risk potential to the surrounding environment as far as it is used following the recommended guideline.

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Evaluation of Soil Contamination by Copper Depleted from ACQ-Treated Wood (ACQ 방부처리목재로부터 용탈된 구리에 의한 토양오염 평가)

  • Ra, Jong-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.4
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    • pp.504-510
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    • 2015
  • This research was performed to evaluate soil contamination caused by copper depleted from ACQ-treated wood. Three years after the exposure of ACQ-treated wood in the field test sites, soil samples around the treated wood were collected and analyzed for the copper amount and distribution through soil. Soils around the deck posts installed in five different neighborhood parks located in Chonnam and Gyeongnam were investigated for copper contents. The results of the field test showed that the amount of copper leached from the end surface of treated wood buried under soil was more than 1.5 times the copper amount leached from the lateral surfaces, and the mobility of copper was very restricted in soil. The copper contents of soil within 10 cm from the treated deck posts installed in the parks showed to be less than 500 mg/kg, which are the limit values of the 2nd region set up by enforcement regulation of soil environment conservation act. The distribution ranges of copper in soil from the treated wood set up in the field test sites seemed to be much wider than those from deck posts, which may explained by the fact that the retentions of the treated samples used in the field test sites were much higher than those of the deck posts.