• 한국해양학회지
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• v.26 no.3
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• pp.204-222
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• 1991

The annual cycles of plant major nutrients and dissolved oxygen in a nutrients-rich semi-enclosed coastal inlet, chinhae Bay, of the southern coast of the Korean Peninsula are first presented. The water column of the bay is stratified during summer (April-late September) and well0mixed during winter (October-March). During the summer stratification period, dissolved oxygen contents exceed 400uM in the surface but diminish to less than 50uM in the near bottom waters, which often results in an anoxic environment in the inner part of Chinhae Bay. After the breakdown of the stratification in October, dissolved oxygen concentration remains undersaturated until February. The evidence of allochthonous input of N-nutrients throughout the year is readily seen in the water column: however. crude budget calculations show that the nutrients are efficiently utilized within the bay ecosystem, and that export of the nutrients from the bay to the shelf must be negligible. There is no sign of the enrichment of the nutrients in the water column. The eutrophication phenomenon sensu stricto is not observed in chinhae Bay. Using the standing stock of dissolved oxygen and estimation of the oxygen fluxes across the air-sea boundary, a benthic oxygen respiration rate during winter is estimated conservatively at 21-24 mmol Cm/SUP -2/d/SUP -1/. this oxygen respiration rate accounts for about 20% of the total phytoplankton production in winter.

• Korean Journal of Ecology and Environment
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• v.37 no.4 s.109
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• pp.406-410
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• 2004

The alkaline phosphatase activity (APA) of two dam reservoirs and inflowing streams were measured monthly in 2000. During summer months in 2001, the vertical profiles of APA and related parameters were also examined in one of the reservoirs. The APA was relatively high during the summer season in the epilimnion while it was almost invariable in the hypolimnion. A small increase in APA was observed at just above the bottom. The APA fluctuation was independent of the concentration of soluble reactive phosphorus. It was assumed that APA is not indicative of the phosphorus availability status. An examination of size-fractionated samples suggested that APA in reservoirs was attached to particles larger than $0.4{\mu}m$, whereas in streams it existed in a dissolved form. There was a positive significant correlation between chlorophyll a concentration and APA in the photic zone. In the aphotic zone, APA correlated positively with the colony count of heterotrophic bacteria, but not with microscopic total bacterial counts.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.10
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• pp.724-729
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• 2013

Simultaneous nitrification and denitrification (SND) occurs concurrently in the same reactor under micro dissolved oxygen (DO) conditions. Anaerobic zone was applied for phosphorus release prior to an aerated membrane bio-reactor (MBR), and anoxic zone was installed by placing a baffle in the MBR for enhancing denitrification even in high DO concentration in the MBR. Phosphorus removal was tested by alum coagulation in the anaerobic reactor preceding to MBR. DO concentration were 2.0, 1.5, 1.0, 0.75 mg/L in the MBR at different operating stages for finding optimum DO concentration in MBR for nitrogen removal by SND. pH was maintained at 7.0~8.0 without addition of alkaline solution even with alum addition due to high alkalinity in the raw sewage. Both TCODcr and $NH_4^+$-N removal efficiency were over 90% at all DO concentration. TN removal efficiencies were 50, 51, 54, 66% at DO concentration of 2.0, 1.5, 1.0, 0.75 mg/L, respectively. At DO concentration of 0.75 mg/L with addition of alum, TN removal efficiency decreased to 54%. TP removal efficiency increased from 29% to 95% by adding alum to anaerobic reactor. The period of chemical backwashing of the membrane module increased from 15~20 days to 40~50 days after addition of alum.

• Journal of Wetlands Research
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• v.19 no.4
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• pp.383-392
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• 2017

In 2013, August and September(early) as summer and October and November as Fall the probe of eutrophication has been done at 22 sampling points from the entrance of Danghang Bay (Jinhae Bay) to Geosan reservoir. In Danghang Bay, total chlorophyll(TChl) concentration of summer was 3.7 times higher than that of fall, and sampling points closer to the center showed 1.8 times higher concentrations than sampling points near the fringe where fresh water encountered. Eutrophication Index(EI) exceeded 1 at all sampling points in Danghang Bay during summer and fall, and if other conditions for algae growth met there was a possibility red tide to bloom at any place. There was a tendency of EI to gradually increase moving up from the entrance of bay to the inner side during summer and fall. Especially there was a sudden increase by 2.3 times higher at sampling points of 13~22 (planned region as Madong reservoir) than at other points during fall. Nitrogen was a limiting nutrient for growth of algae during summer and fall in Danghang Bay, but phosphorus was a limiting nutrient during summer rainy season. During summer and fall, multiple linear regression analysis between EI and COD, DIN, and DIP showed a significant positive relationship and that DIP was the most effective variable. Whereas multiple linear regression analysis between TChl and COD, DIN, DIP, and DSi showed a significant positive relationship and that DIP was also the most effective variable during summer. There was no significant correlation between TChl and the other parameters during fall.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.9
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• pp.840-850
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• 2010

The present study was attempted to find the effects of structural properties of phosphorus on the water quality of Gyehwa reservoir in Saemangeum. Relationship of phosphorus fractions between water and sediment properties was closely examined, and a few types of phosphorus were found from the sample sediment as : Saloid-P, Al-P, Fe-P, Ca-P, Red-P and Occd-P. Saloid-P (1.4%), Al-P (0.5%), Fe-P (39.8%), Ca-P (56.6%), Red-P (0.4%), Occd-P (1.3%) were extracted in a mass basis from the sediment of Gyehwa reservoir. Approximately more than 97% of phosphorus were calcium related phosphorus (Ca-P, 56%) and iron bound phosphorus (Fe-P, 39.8%). The Fe-P closely relates with water quality of T-N (r=0.761, p<0.05), $NO_3$-N (r=0.754, p<0.05), $NH_4$-N (r=0.728, p<0.05), T-P (r=0.774, p<0.05) and $PO_4$-P (r=0.767, p<0.05) while the Ca-P did not show any consistent dependency on the water quality. On the other hand, the correlation of Ca-P with $P_2O_5$ was high with r=0.783 (p<0.05) in the sediment. The Fe-P was affected significantly on the Ignition Loss (r=0.569, p<0.05), T-N (r=0.715, p<0.05) and T-P (r=0.983, p<0.01). In the research of correlation between phosphorus fraction and heavy metals in the sediment, Ca-P did not show any specific relationships with heavy metals. The Fe-P showed a significant correlation with As (r=0.817, p<0.01), Cu (r=0.793, p<0.05), Cd (r=0.786, p<0.05), Zn (r=0.738, p<0.05), so that it can be stated that the presence of Fe-P may implicate the volume of various metallic elements.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.276-277
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• 2007

본 논문에서는 미량의 세포를 포함한 용액 내에서 세포의 산소호흡량을 측정하기 위해 FEP(Fluorinated Ethylene Propylene)를 멤브레인으로 사용한 Clark-type 센서를 제안하였다. 제안된 Clark-type 센서는 3-전극 시스템을 구성하는 유리 기판, 산소를 선택적으로 투과 시키는 FEP 멤브레인과 세포를 담을 수 있는 PDMS reservoir로 구성된다. 산소 센서의 3-전극 시스템에서 작업 전극과 상대 전극으로는 Au, 기준 전극으로는 Ag/AgCl을 사용하였다. 기준 전극은 Ag 전극을 0.1M KCl/Tris-HCl 용액에서 chlorination하여 표면에 AgCl이 형성되도록 하였고, OCP(Open Circuit Potential) test를 수행한 결과 2시간 동안 안정적인 OCP 특성을 보여 좋은 내구성을 가짐을 확인하였다. 또한, 산소 유무에 따른 cyclic voltammetry 그래프의 차이를 확인하고, amperometry로 감도 및 반응 시간, 선형성을 측정/분석하였다. 제작된 산소 센서는 40초의 90% 반응 시간과 0.994의 아주 좋은 선형 상관계수를 보여주었다.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.7 no.3
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• pp.171-180
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• 2002

The temporal and spatial distributions of phosphorus have been investigated in the Gomso Bay, Korea. TP, PIP, TOP and DIP in sediment were found 548.8mg P kg$^{-1}$ , 426.1mg P kg$^{-1}$ , 122.6mg P kg$^{-1}$ , and 0.217mg P kg$^{-1}$ , respectively with a decreasing order of PIP>TOP>DIP. Any temporal or spatial trend has not been found on the distribution of TP in the sediment, except the high TP values near the mouth of Julpo-chun. We found seasonal patterns high TOP(28.90% of TP) and low TIP(71.10% of TP) in August, but low TOP(15.63% of TP) and high TIP(84.38% of TP) in November. There were three times higher DIP concentration in August than in November. Such case is probably not only due to the enhanced supply of DIP directly from the decomposition of organic matter from overlying water in summer, but also the released phosphate from the adsorbed particulate matter such as PIP under the low pH and Eh conditions at the subsurface layers of the sediment induced by the active microbial respiration of increased organic materials in summer. Primarily, the source of phosphorous from municipal sewage strongly influenced the early stage of the distribution of all the phosphorous in the Gomso tidal flat. Notwithstanding, through the processes of diagenesis in sediment, water temperature and organic contents probably functioned as the key parameters to control the temporal distributions of TOP, TIP and DIP in the Gomso tidal flat.

• Journal of Korean Society of Water and Wastewater
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• v.33 no.1
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• pp.9-16
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• 2019

The algal blooms in stagnant streams and lakes have caused many problems. Excessive algae leads to disturbance of ecosystem and overload of water treatment processes. Therefore, phosphorus(P), source of algal blooms, should be controlled. In this study, a filtration trench has been developed to convert dissolved phosphorus into hydroxyapatite(HAP) so that it could be crystallized on the surface of 'phosphorus removal granular material'; and residual particulate phosphorus could be removed by additional precipitation and filtration. The front and rear parts of filtration trench consisted of 'phosphorus removal granular material contact bed' and 'limestone filtration bed', respectively. As a result of the column test using phosphorus removal granular material and limestone serially, $PO_4-P$ was removed more than 90% when EBCT(empty bed contact time) of the contact bed was over 20 minutes; and T-P represented 60% of removal efficiency when total EBCT was over 1.5 hours. The results of column tests to figure out the sedimentation characteristics showed that more than 90% of particulate phosphorus could be removed within 24 hours. It was necessary to optimize the filtration part in order to increase removal efficiency of T-P additionally. Also, it was confirmed through the simulation of Visual MINTEQ that most of particulate phosphorus in the column tests is the form of HAP. Based on the results of the study, it could be suggested that the design parameters are over 0.5 hour of EBCT for phosphorus removal granular material contact bed and over 1.5 hours of EBCT for limestone filtration bed.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.1
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• pp.63-72
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• 2020

Dissolved hexavalent uranium can exist in the form of several different chemical species. Furthermore, species distributions depend on the pH value of the aqueous solution. Representatively, UO₂²⁺, UO₂OH⁺, (UO₂)₂(OH)₂²⁺, and (UO₂)₃(OH)₅⁺ species coexist in solutions at acidic and circumneutral pH values. When amorphous silica particles are suspended in an aqueous solution, the dissolved chemical species are easily adsorbed onto silica surfaces. In this study, it was examined whether the species distribution of the adsorbed U(VI) on a silica surface followed that of the dissolved U(VI) in an aqueous solution. Time-resolved luminescence spectra of three different dissolved species (UO₂²⁺, UO₂OH⁺, and (UO₂)₃(OH)₅⁺) and two different adsorbed species (≡SiO₂UO₂, ≡SiO₂(UO₂)OH^-, or ≡SiO₂(UO₂)₃(OH)^5-) were measured in the pH range 3.5-7.5. The spectral shapes of these chemical species were compared by changing the pH value; consequently, it was confirmed that the species distribution of the adsorbed U(VI) species was different from that of the dissolved U(VI) species.

• Journal of the Korean Society for Marine Environment & Energy
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• v.3 no.4
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• pp.65-75
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• 2000

The roles of environmental factors affecting on heterotrophic bacterial distribution at Hangam Bay and Masan Bay in which occurred frequently red tide, during June to November 1996 were investigated. The aquatic environment of Masan Bay and Haengam Bay showed difference in the contents of inorganic nutrients. Haengam Bay may be defined as nitrogen limited aquatic environment. On the other hand, Masan Bay appeared to the appropriate N/P molar ratio of mean 15.9 during the periods of study. By the results of simple regression, chlorophyll a showed significant correlation with precipitation (r=0.813, P<0.05) and phosphorus (r=0.846, P<0.05) at Haengam Bay, but not showed significant correlation with parameters at Masan Bay. The heterotrophic bacteria showed significant correlation with many environmental parameters at Masan Bay (Precipitation, r=0.990, P<0.01 : NO₃-N, r=0.901, P<0.05 : Dissolved inorganic nitrogen, r=0.899, P<0.05 ; N/P molar ratio, r=0.952, P<0.05 : Salinity, r: -0.934, P<0.05) than Haengam Bay (SiO₃-Si, r=0.960, P<0.01). By the results of multiple regression, the chlorophyll a was varied with only 2 factors in Masan Bay (R²=0.100) and 3 factor in Haengam Bay (R²=0.903). The major factor which affected to chlorophyll a was SiO₃-Si (R²%=67.8) in Masan Bay, and -N/P (R²%=37.6) in Haengam Bay. The heterotrophic bacteria were varied with 4 factors in Masan Bay (R²=100) and 2 factor in Haengam Bay (R²%=0.878). The major factor, which affected to heterotrophic bacteria, was SiO₃-Si (R²%=42.3) and salinity (R²%=32.1) in Masan Bay, and SiO₃-Si (R²%=76.3) in Haengam Bay. Resultingly, the influx of freshwater in Masan and Haengam Bay was enriched in inorganic nutrients, and plays an important role in the change of heteroterophic bacteria and chlorophyll a during early summer to autumn.