• Title/Summary/Keyword: 용융금속

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A Study on Molten Salt Electrorefining of Uranium Metal Using Low Carbon Steel Cathode (저 탄소강 음극을 사용한 금속우라늄의 용융염 전해정련에 관한 연구)

  • Yang, Y.S.;Kang, Y.H.;Hwang, S.C.
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1119-1123
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    • 1999
  • In this paper, electrorefining of uranium metal was studied to develop pyrometallurgical processing technology in molten salt system. The reaction between uranium metal and $CdCl_2$ was taken about 3 hours and the uranium metal deposits were obtained in the form of dendrite grown on the cathode surface in every electrotransport experiment. The shapes of dendrite were changed according to the applied voltages. Current efficiency was decreased with the increase of current density. Deposition rate was not changed after 6 hours and its maxium was obtained at $100{\sim}150mA/cm^2$ of current density and about 75 rpm of stirring speed, respectively. Also, the current efficiency was increased with decrease of the pitch of spiral groove curved on cathode.

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Corrosion Protection of Steel by Applying a Zn-Sn Metal Spray System (Zn-Sn 합금을 이용한 강구조물의 금속용사공법 방식성능평가 연구)

  • Ryu, Hwa-Sung;Jeong, Dong-Geun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.6
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    • pp.505-513
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    • 2014
  • The purpose of this study is to evaluate the corrosion protective properties of a Zn-Sn metal spray method according to the contents of Zn and Sn by a CASS test and the electrochemical theory. In the experiment, the CASS test and the electrochemical test were conducted to investigate the corrosion protective property of the Zn-Sn Metal Spray system, the Zinc galvanizing system, and the heavy duty coating system. As a result, it was confirmed that the Zn-Sn (65:35) Metal Spray system had very high corrosion protective property through the electrochemical characteristic as comparison with the other anti-corrosion systems and was very effective to prevent steel products from corrosion.

나트륨-콘크리트 반응 연구 현황

  • 배재흠;민병훈;김수만;최종현;조병렬;김태준;황성태
    • Nuclear Engineering and Technology
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    • v.28 no.2
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    • pp.216-227
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    • 1996
  • 액체금속로의 안전설계 및 안전해석에 있어서 고려되어야하는 용융나트륨과 콘크리트 반응의 특성, 그리고 이들 반응의 모델을 조사 분석하였고 액체금속로 개발 선진국들의 나트륨-콘크리트 반응연구 현황을 검토 분석하였다. 그리고 나트륨-콘크리트 반응은 매우 복잡하여 액체금속로 개발 선진국에서 이의 반응 연구를 꾸준히 진행시키고 있고 액체금속로의 안전설계 및 안전운전을 위하여 보다 완벽한 반응모델을 개발하고자 노력하고 있어 우리나라에서 액체금속로 개발을 추진하기 위한 앞으로의 나트륨콘크리트 연구방향을 제시하였다.

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Physical and Chemical Characteristics of Cast-Iron Factory (주물 주강 공정에서 발생되는 분진의 물리화학적 특성에 관한 연구)

  • 안정언;전기준;박영옥;정용원
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.273-274
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    • 2002
  • 주물작업은 용융된 금속을 미리 준비한 주형에 부어 원하는 형태의 주물을 만드는 금속성형작업으로서, 철(iron)만을 이용한 주철주물, 강(steel)을 이용한 주강주물 여러 가지 비철금속을 이용한 비철주물으로 대별할 수 있다 주물공업은 경공업, 중공업 분야를 막론하고 전 산업분야의 기초가 되는 소재산업으로서 기계 덴 재료공업 등 산업 전반에 미치는 영향은 지대하다. (중략)

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플라즈마 토치를 이용한 비가연성 모의 방사물 용융실험

  • 조천형;문영표;송명재
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.403-408
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    • 1998
  • 비가연성 방사성 폐기물로 발생되는 물질은 큰크리트, 유리, 석고, 철재류, 토사류 및 원자력발전소 계통에서 발생하는 필터류 등이며, 이들 폐기물 중 금속류를 제외한 물질들의 성분은 SiO$_2$가 60%이상, CaO 3~12%, $Al_2$O$_3$ 10% 미만으로 일반 유리의 성분과 유사하다. 따라서 이들 비가연성 방사성 폐기물을 최적의 흔합비로 용융하였을 경우 안정한 유리질의 고화체를 생성시킬 수 있다. 본 연구에서는 시료별로 조성이 다른 비가연성 모의 폐기물을 플라즈마 토치(60kW)와 용융로 등이 장착된, 시스템에서의 용융 실험을 통해 약 20%정도의 부피 감용효과가 있음을 밝혀냈고, 생성된 웅융 고화체에 대한 침출실험을 통하여 EPA의 규제치를 안정적으로 만족하는 건전성을 확인하였다.

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A Study on the Droplet Formation of Liquid Metal in Water-Mercury System as a Surrogate of Molten Salt-Liquid Metal System at Room Temperature (용융염-액체금속 계의 대용물인 물-수은 계에서 액체금속 액적의 생성에 대한 연구)

  • Kim, Yong-il;Park, Byung Gi
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.165-172
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    • 2018
  • As an approach for estimation of the droplet size in the molten salt-liquid metal extraction process, a droplet formation experiment at room temperature was conducted to evaluate the applicability of the Scheele-Meister model with water-mercury system as a surrogate that is similar to the molten salt-liquid metal system. In the experiment, droplets were formed through the nozzle and the droplet size was measured using a digital camera and image analysis software. As nozzles, commercially available needles with inner diameters (ID) of 0.018 cm and 0.025 cm and self-fabricated nozzles with 3-holes (ID: 0.0135 cm), 4-holes (ID: 0.0135 cm), and 2-holes (ID: 0.0148 cm) were used. The mercury penetration lengths in the nozzles were 1.3 cm for the needles and 0.5 cm for the self-fabricated nozzles. The droplets formed from each nozzle maintained stable spherical shape up to 20 cm below the nozzle. The droplet size measurements were within a 10% error range when compared to the Scheele-Meister model estimates. The experimental results show that the Scheele-Meister model for droplet size estimation can be applied to nozzles that stably form droplets in a water-mercury system.

Pyro-Electrochemical Reduction of a Mixture of Rare Earth Oxides and NiO in LiCl molten Salt (LiCl 용융염에서 NiO를 혼합한 희토류 산화물의 파이로 전해환원 특성)

  • Lee, Min-Woo;Jeong, Sang Mun
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.379-384
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    • 2017
  • An electrochemical reduction of a mixture of NiO and rare earth oxides has been conducted to increase the reduction degree of rare earth oxides. Cyclic voltammetry (CV) measurement was carried out to determine the electrochemical reduction behavior of the mixed oxide in molten LiCl medium. Constant voltage electrolysis was performed with various supplied charges to understand the mechanism of electrochemical reduction of the mixed oxide as a working electrode. After completion of the electrochemical reduction, crystal structure of the reaction intermediates was characterized by using an X-ray diffraction method. The results clearly demonstrate that the rare earth oxide was converted to RE-Ni intermetallics via co-reduction with NiO.