• Title/Summary/Keyword: 용액형

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Solution-Processed Fluorine-Doped Indium Gallium Zinc Oxide Channel Layers for Thin-Film Transistors (용액공정용 불소 도핑된 인듐 갈륨 징크 산화물 반도체의 박막 트랜지스터 적용 연구)

  • Jeong, Sunho
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.3
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    • pp.59-62
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    • 2019
  • In this study, we have developed solution-processed, F-doped In-Ga-Zn-O semiconductors and investigated their applications to thin-film transistors. In order for forming the appropriate channel layer, precursor solutions were formulated by dissolving the metal salts in the designated solvent and an additive, ammonium fluoride, was incorporated additionally as a chemical modifier. We have studied thermal and chemical contributions by a thermal annealing and an incorporation of chemical modifier, from which it was revealed that electrical performances of the thin-film transistors comprising the channel layer annealed at a low temperature can be improved significantly along with an addition of ammonium fluoride. As a result, when the 20 mol% fluorine was incorporated into the semiconductor layer, electrical characteristics were accomplished with a field-effect mobility of $1.2cm^2/V{\cdot}sec$ and an $I_{on}/_{off}$ of $7{\times}10^6$.

An Experimental Study on Hydrodynamic Behavior of a Slender Cylinder Falling in a Viscoelastic Fluid (점탄성 유체내에서 낙하하는 원통형 미소체의 거동에 관한 실험적 연구)

  • 주용기
    • The Korean Journal of Rheology
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    • v.4 no.1
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    • pp.25-34
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    • 1992
  • 저속으로 낙하하는 원통형 미소체의 유체역학적 거동에 대하여 점탄성 유체의 비 뉴우튼 성질의 영향에 관해서 연구가 수행되었다. 원통형 미소체의 직경 및 직경에 대한 길 이의 비 (Aspect Ratio)의 영향에 관해서도 또한 고찰하였으며 본 실험에서는 뉴우튼 유체 로서 99.5%의 글리세린용액과 점탄성 유체로서 1,000 wppm 의 polyacyla-mide(Separan AP-273) 수용액이 각각 사용되었다. 낙하하는 미소체의 Aspect Ratio가 증가할수록 무차원 최종속도는 뉴우튼 유체내에서 보다 점탄성 유체내에서 그증가속도가 더욱 커짐을 보였다. 뉴우튼 유체 내에서 낙하하는 원통형 미소체의 마찰저항 계수는 실험데이타로부터 계산된 값과 이론치가 비교적 잘일치하나 점탄성 유체에 관한 마찰저항 계수는 본 실험의 결과치와 무한히 긴 원통형 미소체에 대한 기존연구의 이론값과는 상당한 차이가 있음을 알수 있었 다, 이는 점탄성 유체내에서 수직으로 낙하하는 원통형 미소체의 저항계수가 k(즉 용기의 직경에 대한 미소체 직경의 비), power-law index 레이놀즈수 뿐아니라 aspect ratio를 포함 하는 새로운 관계식이 도출되어야 함을 분명히 보여주고 있다.

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Effects of mineralizer and concentration on the morphology of the $CaTiO_3$ powders prepared by hydrothermal method (수열법에 의한 $CaTiO_3$분말 합성 시 광화제와 농도가 입자형상에 미치는 영향)

  • 정항철;서동석;이종국
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.6
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    • pp.329-334
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    • 2002
  • The $CaTio_3$powder with perovskite structure was synthesized by mixing anatase $TiO_2$and $Ca(OH)_2$powders as starting materials, and KOH or NaOH as mineralizer, followed by hydrothermal method. The change of crystal structure, particle shape and size of the synthesized $CaTiO_3$powder was investigated with kind and concentration of mineralizer. It was found that the spherical particles of 0.7 $\mu$m were obtained when using 1N KOH and the hexahedrons particles of 3$\mu$m were obtained for the case of using 10 N KOH. With increasing KOH concentration, the particle shape was changed from sphere to hexahedrons and its size also increased. When using 1 N NaOH, the powder was consisted of 0.5~1 $\mu$m particle in size, whereas hexahedrons of 1~4 $\mu$m and whiskers more than 10$\mu$m in size was obtained for the 10 N NaOH solution. With increasing NaOH concentration, the particle shape was varied from hexahedrons to whiskers, showing the similar result with the KOH case. It was confirmed from EDS analysis that Na element, which was detected in hexahedrones was not contained in the whiskers.

Micromachined pH Sensor Using Open Well Structures (개방형 우물 구조를 이용한 마이크로머신형 pH 센서)

  • Kim, Heung-Rak;Kim, Young-Deog;Jeong, Woo-Cheol;Kim, Kwang-Il;Kim, Dong-Su
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.4
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    • pp.347-353
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    • 2002
  • A structure of a glass electrode-type pH sensor for measuring any concentration of $H^+$ in an aqueous solution was embodied with bulk micromachining technology. Two open well structures were formed, and a reference electrode was secured by the Ag/AgCl thin film in the sloped side of the etched structure. A sensitive membrane of an indicator electrode for generating a potential by an exchange reaction to $H^+$ was made with a glass containing Na 20% or more finely so that its thickness might be $100{\mu}m$ or so, and then it was bonded to one pyramidal structure. A liquid junction for a current path was formed by filling an agar in the anisotropically etched part of the Si wafer, which had a size of $50{\mu}m{\times}50{\mu}m$, and then bonded it to the other. After complete fabrication of each part, it was filled with a 2M KCl reference solution and encapsulated the sensor structure with a cold expoxy. The potential value of fabricated pH sensor was about 90mV/pH in the standard pH solutions.

Effect of Temperature, pH and Sugars on Kinetic Property of Maillard reaction (당의 종류, pH 및 온도가 마이야르 반응속도에 미치는 영향)

  • Chun, Young-Hye;Kim, Chong-Kun;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.18 no.1
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    • pp.55-60
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    • 1986
  • The effects of temperature (70-$100^{\circ}C$), pH (3-8) and various sugars were investigated on the reaction rate, activation energy and z-value of Maillard reaction of 0.8m sugar and 0.8m glycine mixture. The sugars compared were glucose, fructose, lactose and sucrose, and the reaction was evaluated by absorbances at 278nm for pyrazine compounds and at 400nm for brown pigments. Fructose-glycine mixture showed a faster initial reaction rate than that of glucose-glycine, which was reversed by the order of glucose > fructose > lactose > sucrose after 10 hrs of reaction at pH 5.8 and $100^{\circ}C$. Generally, higher activation energy was required for forming pyrazines than that of brown pigment development. The highest z-value was obtained for lactose-glycine mixture, followed by glucose or fructose-glycine which had almost same z-value. The reaction rate was little affected by the pH change in the range of 4-6, while pH < 3 and pH 6-8 caused a significant increase in the rates.

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Evaluation of Surface Condition and Food Solution on the Color Stability of Dental Restoration Materials (표면 상태와 용액에 따른 치과용 수복재료의 색안정도 평가)

  • Woo, Hee-Sun;Kim, Hyo-Jin;Jun, Soo-Kyung
    • The Journal of the Korea Contents Association
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    • v.19 no.4
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    • pp.359-367
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    • 2019
  • For this study, specimens were prepared using five types of composite resin and resin-reinforced glass ionomer Fuji II LC, and 29 days precipitation was done in four kinds of solution, which were soy sauce, gochujang, wine, and distilled water. Ten specimens for each coloring sample were divided into two groups, one those surfaces was polyester film and the other with 1200-grit abrasive paper, and 20 specimens per materials. Color change (${\Delta}{\ast}ab$) in the colored specimens is measured in 2days, 7days, 14days and 29days using spectrophotometer (CM-2600d, Konica, Minolta, Ramsey, NJ). All values were considered significant when P<0.05. 1. Each material is discolored over time under the influence of different storage solutions. 2. In soy source, among the specimens polished with polyester film, color change was observed in resin-modified glass ionomer Fuji II LC, prodigy and compomer F-2000 on day 2. Meanwhile, Fuji II LC showed noticeable color change in specimens prepared with 1200-grit sandpaper on day 2, which was followed by flowable resin on day 7. 3. On day 2, there was a color change with the specimens of flowable resin, resin-modified glass ionomer Fuji II LC and Prodigy among the hybrid specimen in the groups of polyester film in gochujang.

An Experimental Study on Absorber with Spiral Tube in Absorption Heat Pump (흡수열펌프에서 나선형 관이 설치된 흡수기의 실험적 연구)

  • Min, Byong-Hun
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.71-75
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    • 2010
  • The efficient performance of absorber is of great importance for the absorption heat pump cycle. The experimental study of absorber with spiral tube of tangential feeding of liquid phase has been investigated using methanol-glycerine as a working fluid. The effect of change in absorber operating conditions was analyzed to improve the performance. The increase in solution flow rate and cooling flow rate positively affects the absorber performance while an increse in the solution concentration negatively affects the absorber performance. The results showed that mass absorption flux was in the range of $0.2{\sim}0.6kgm^{-2}sec^{-1}$, the solution heat transfer coefficient between 1.6 and $4.2kwm^{-2}K^{-1}$, the absorber thermal load from 0.9 to 1.5kw and the mass transfer coefficient from 0.9 to 1.7 m/sec.

A Study on Heat Transfer Characteristics for Removal of Absorption Heat in Absorption Process of Ammonia-Water Bubble Mole (암모니아-물 기포분사형 흡수과정에서의 흡수열 제거를 위한 열전달 특성 연구)

  • Lee, Jae-Cheol;Lee, Ki-Bong;Chun, Byung-Hee;Lee, Chan-Ho;Ha, Jong-Joo;Kim, Sung-Hyun
    • Clean Technology
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    • v.7 no.4
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    • pp.273-280
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    • 2001
  • An absorber is a major component in the absorption refrigeration systems and its performance greatly affects the overall system performance. In this study, experimental analyses on heat transfer characteristics for removal of absorption heat in ammonia-water bubble mode absorber were performed. Heat transfer coefficients were estimated as the variations of input gas flow rate, solution flow rate, temperature, concentration, absorber diameter and height, and input flow direction. The increase of gas and solution flow rate affects positively in heat transfer. However, the increase of solution temperature and concentration affects negatively. Moreover, under the same Reynolds Numbers, countercurrent flow is superior to cocurrent flow in heat transfer performance. In addition, from these experimental data, empirical correlations which can explain easily the characteristics of heat transfer are derived.

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Dissolution Conditions of Solid Radioactive Wastes Generated from NPP for the Analysis of Radionuclides Using a Closed-vessel Microwave Acid Digestion System (원전 발생 고체 방사성폐기물 내 핵종 분석을 위한 극초단파 산분해 장치를 이용한 용액화 조건)

  • 표형열;이정진;전종선;이창헌;지광용
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.158-166
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    • 2004
  • The optimal conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, active charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes were used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added the simulated radioactive wastes were over 94%. As an effective pre-treatment, the proposed microwave acid digestion conditions concerning the chemical trait of each radioactive waste are expected to be generally applied to above-mentioned radioactive wastes from nuclear power plant hereafter.

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