• Title/Summary/Keyword: 온도-시간곡선

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An Edible Alginate Microcapsulation of Entomopathogenic Nematode, Steinernema carpocapsae (알지닌캡슐을 이용한 곤충병원선충(Steinernema carpocapsae)의 섭식유도형 제제화 기술)

  • 김용균;이승화;유용만;한상찬
    • Korean journal of applied entomology
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    • v.42 no.2
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    • pp.145-152
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    • 2003
  • Field application of the entomopathogenic nematode, Steinernema carpncapsae, is limited by its susceptibility to UV irradiation and desiccation especially at leaf spray control. This study was conducted to develop the control technique using alginate biocapsulation of the nematodes against the beet armyworm, Spodoprera exigua and the tobacco cutworm, Sp. litura that are normally infesting hosts above ground level. The alginate capsules including infective juveniles gave significant feeding toxicities to the larvae of the two lepidopteran species. The lethality followed a typical sigmoid dose-mortality pattern with increase of the nematode densities embedded in the capsules. Moisture content in the capsule was critical to the survival of the infective juveniles. More than 80% nematodes could survive above 10% moisture content remained in the capsule. Remaining moisture content within the capsule was dependent on relative humidity, ambient temperature, and capsule size, but not on citric acid reaction time during capsule formation. More than 80% of infective juveniles in the alginate capsules could survive in distilled water at 15$^{\circ}C$ for 60 days. When these nematode capsules containing welsh onion extract as another phagostimulant were applied on the 3rd instar larvae of Sp. exigua infesting peanut plants, they resulted in about 90% control efficacy. These results indicate that the alginate capsulation can be used for leaf-spray agent of the entomopathogenic nematodes as well as for improved storage purpose.

Hydrogen Electrode Performance with PTFE Bonded Raney Nickel Catalyst for Alkaline Fuel Cell (라니 니켈 촉매에 대한 알칼리형 연료전지용 수소극의 전극특성)

  • Lee, Hong-Ki;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.527-534
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    • 1992
  • Raney nickel was used as catalyst in the hydrogen electrode for an alkaline fuel cell. The hydrogen electrode manufactured with the Raney nickel catalyst which was sintered at $700^{\circ}C$ was found to have the highest electrode performance. Using the Raney nickel powder of average particle size $90{\AA}$ for the electrode, the current density which had been measured was $450mA/cm^2$ at $80^{\circ}C$ using 6N KOH solution as an electrolyte. The effects of PTFE addition were investigated with CO-chemisorption, polarization curves and Tafel slope. CO-chemisorption had shown the optimum value when the Raney nickel was mixed with 5wt% of PTFE, but from the current density and Tafel slope at porous Raney nickel electrode, the appropriate value of PTFE addition was 10wt%. Recommendable Ni and Al portion for Raney nickel was 60 : 40 and loading amount was $0.25g/cm^2$. Also the influence of pressing pressure for manufacturing catalytic layer and for junction with gas diffusion layer was examined. The morphology of catalyst surface was investigated with SEM. The influence of reactivation time and heat-treatment temperature were also studied.

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Characterization of Thermal Degradation of Polymide 66 Composite: Relationship between Lifetime Prediction and Activation Energy (폴리아미드 66 복합소재의 열 열화 특성: 수명 예측과 활성화 에너지의 상관관계)

  • Jung, Won-Young;Weon, Jong-Il
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.712-720
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    • 2012
  • Thermal degradation for glass fiber-reinforced polyamide 66 composite (PA 66) with respect of thermal exposure time has been investigated using optical microscopy, scanning electron microscopy and Fourier transform infrared spectroscopy. As the thermal exposure time was prolonged, a slight increase in tensile strength for only initial stage and afterward, a proportional decrease of tensile strength was observed. These results can be explained by the increase of crystallinity, followed by the increase of crosslinking density, chain scission and the decrease in chain mobility, due to thermal oxidation with the exposure time. Fourier transform infrared spectroscopy results showed the increase of ketone peak and silica peak on the surface of thermally exposed PA 66. In addition, the thermal decomposition kinetics of PA 66 was analyzed using thermogravimetric analysis at three different heating rates. The relationship between activation energy and lifetime-prediction of PA 66 was investigated by several methodologies, such as statistical tool, UL 746B, Ozawa and Kissinger. The activation energy determined by thermogravimetric analysis had a relatively large value compared with that from the accelerated test. This may result in over-estimating the lifetime of PA 66. In this study, a master curve of exponential fitting has been developed to extrapolate the activation energy at various service temperatures.

Growth of artificial Pb$ZrO_3$/Pb$TiO_3$ superlattices by pulsed laser deposition and their electrical properties (펄스레이져 증착법을 이용한 Pb$ZrO_3$/Pb$TiO_3$ 산화물 인공격자의 성장 및 전기적 특성)

  • 최택집;이광열;이재찬
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.54-54
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    • 2003
  • 최근 새로운 개념에 물성 구현을 위한 강유전체 산화물 인공격자의 연구가 활발히 진행되고 있다. 본 연구에서는 펄스레이져 증착법을 이용하여 산소분압 100 mTorr와 증착온도 50$0^{\circ}C$에서 LSCO/MgO 기판 위에 PbTiO$_3$(PTO) 와 PbZrO$_3$(PZO)을 주기적으로 적층하여 강유전체 산화물 인공격자를 형성하였다. 인공격자의 주기는 1~100 unitcell 까지 변화시켰다. 적층주기와 두께 변화에 따른 PZO/PTO 인공격자의 성장과 전기적 특성에 대하여 관찰하였다. X선 회절분석을 통하여 PZO/PTO 인공격자는 주기가 25 unit cell 이하의 적층구조에서 초격자의 형성으로 인한 위성피크가 관찰되었으며, 그 이하의 낮은 주기(1~10 unitcell)에서는 위성피크와 강한 (100)과 (200) 성장거동을 보였다. 높은 주기에서는 c축 성장된 PTO와 a축 성장된 PZO 각각의 성장거동을 보였다. 적층 주기가 감소함에 따라 a축 성장된 PTO와 c축 성장된 PZO가 초격자를 형성하였다. 적층주기가 감소함에 따라 유전상수와 잔류분극값이 향상되었다. 유전상수는 1 unitcell 주기에서 800정도의 값을 보였고, 잔류분극값은 2 unitcell 주기에서 2Pr=38.7 $\mu$C/$\textrm{cm}^2$ 정도의 가장 큰 값을 나타냈다. 적층주기가 2 unitcell에서 두께가 감소함에 따라 유전상수가 감소하였고, 20 nm 까지 분극반전에 의한 capacitance-voltage 특성곡선의 이력 현상(강유전성)을 관찰하였다. 이러한 산화물 인공초격자에서의 유전상수와 잔류분극값의 향상에 대하여 논의 할 것이며, 임계크기효과 관점에서 나노사이즈(50 nm~5 nm)에서 인공초격자의 전기적 분극의 안정성에 대하여 또한 논의 할 것이다.소수성 가스의 경우70% 이상 향상되었음을 알 수 있었으며, 본 연구를 통해 광분해를 이용한 스크러버가 기존설비의 장.단점을 충분히 보완 가능한 환경 설비임을 확인할 수 있었다. duty로 구동하였으며, duty비 증가에 따라 pulse의 on-time을 고정하고 frequency를 변화시켰다. dc까지 duty비가 증가됨에 따라 방출전류의 양이 선형적으로 증가하였다. 전압을 일정하게 고정시키고 각 duty비에서 시간에 따라 방출전류를 측정한 결과 duty비가 높을수록 방출전류가 시간에 따라 급격히 감소하였다. 각 duty비에서 방출전류의 양이 1/2로 감소하는 시점을 에미터의 수명으로 볼 때 duty비 대 에미터 수명관계를 구해 높은 duty비에서 전계방출을 시킴으로써 실제의 구동조건인 낮은 duty비에서의 수명을 단시간에 예측할 수 있었다. 단속적으로 일어난 것으로 생각된다.리 폐 관류는 정맥주입 방법에 비해 고농도의 cisplatin 투여로 인한 다른 장기에서의 농도 증가 없이 폐 조직에 약 50배 정도의 고농도 cisplatin을 투여할 수 있었으며, 또한 분리 폐 관류 시 cisplatin에 의한 직접적 폐 독성은 발견되지 않았다이 낮았으나 통계학적 의의는 없었다[10.0%(4/40) : 8.2%(20/244), p>0.05]. 결론: 비디오흉강경술에서 재발을 낮추기 위해 수술시 폐야 전체를 관찰하여 존재하는 폐기포를 놓치지 않는 것이 중요하며, 폐기포를 확인하지 못한 경우와 이차성 자연기흉에 대해서는 흉막유착술에 더 세심한 주의가 필요하다는 것을 확인하였다. 비디오흉강경수술은 통증이 적고, 입원기간이 짧고, 사회로의 복귀가 빠르며, 고위험군에 적용할 수 있고, 무엇보다도 미용상의 이점이 크다는 면에서 자연기흉에 대해 유용한 치료방법임에는 틀림이 없으나 개흉술에 비해 재발율이 높고 비용이 비싸다는 문제가 제기되고 있는 만큼 더 세심한 주의와 장기 추적관찰이 필요하리라 사료된

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Rapid Determination of Ginsenosides Rb1, Rf, and Rg1 in Korean Ginseng Using HPLC (HPLC를 이용한 고려인삼 중 진세노사이드 Rb1, Rf 및 Rg1의 신속분석 방법 개발)

  • Hong, Hee-Do;Choi, Sang-Yoon;Kim, Young-Chan;Lee, Young-Chul;Cho, Chang-Won
    • Journal of Ginseng Research
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    • v.33 no.1
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    • pp.8-12
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    • 2009
  • A simple gradient HPLC method for rapid determination of major ginsenosides ($Rg_1$ and $Rb_1$) and unique ginsenoside (Rf) of Korean ginseng (Panax ginseng C.A. Meyer) was developed. Within 50min, three ginsenosides have been separated and identified on $\mu$-Bondapak $C_{18}$ column ($3.9{\times}300\;mm$, $10{\mu}m$) with gradient elution using water and acetonitrile as a mobile phase. The method was validated in terms of linearity, accuracy, and precision. The correlation coefficients ($r^2$) for calibration curves of ginsenosides were over 0.9997. The developed HPLC method was successfully applied to the analysis of ginseng samples and the recoveries of ginsenosides were in the range of $101.1{\sim}115%$ with RSD<3.2%. The developed method could be used for rapid evaluation of the ginsenosides $Rg_1$, $Rb_1$, and Rf.

Estimation of Ammonia Stripping Condition for Adequate Aerobic Liquid-Composting of Swine Manure (돈분뇨의 적합한 호기성 액비화를 위한 암모니아 탈기조건 설정)

  • Son, Bo-Kyoon;Gang, Seong-Gu;Jo, Eun-Ju;Kim, Shin-Do;Lee, Chang-Ju;Kim, Jeong-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.2
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    • pp.73-79
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    • 2006
  • Aeration is the most important and indispensable operation unit for the treatment of swine manure using aerobic liquid-composting process. The composting of swine manure depends on biological treatment process, but the highly concentrated ammonia nitrogen is required a pretreatment to expect the appropriate efficiency of the biological treatment process. In this study, pilot experiments have been carried out to estimate of the fit condition about ammonia stripping process as a pretreatment to aerobic liquid- composting. pH adjustment with $Ca(OH)_2$ was economically superior to use of NaOH and optimum pH of ammonia stripping was 12.3, ammonia nitorgen was rapidly removed as pH were increased at $$35^{\circ}C$$. When air stripping is performed before aerobic liquid-stripping, a high initial pH is required for complete ammonia removal and is additional effects such as organic substances, phosphorus, turbidity, and color removal. Stripping process was very efficient in the pretreatment of highly concentrated ammonia nitrogen for composting of swine manure. Emission rate of gaseous ammonia was $0.5355mole\;s^{-1}$ at initial time and $0.0253mole\;s^{-1}$ at finitial time. The fit condition of ammonia stripping in this study were at the temperature of $$35^{\circ}C$$, and the pH of 12.3 during 48 hours.

Performance Based Evaluation of Concrete Strength and Freeze-Thaw Resistance from Wind Speed - Sunlight Exposure Time Effect (풍속과 일조시간에 따른 콘크리트의 강도 및 동결융해 저항성 성능중심평가)

  • Kim, Tae-Kyun;Choi, Seung-Jai;Choi, Ji-Hun;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.49-58
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    • 2017
  • The phenomena that we experience in everyday life such as snow, rain, wind, and temperature are referred to as weather, and the average state of atmospheric phenomena that occur over a long period of time in a specific region is referred to as climate. In addition, significant variation of climate compared to the average state is referred to as climate change. Concrete structures can have various problems when exposed to elements. Among the problems, the freeze-thaw problem due to extreme climatic factors such as heavy rain and snowfall has become a particularly significant issue recently. The concrete that has been subjected to repeated freeze-thaw rather than too high or low temperature shows serious degradation of durability, and the performance of structures with degraded performance is difficult to recover. Therefore, in this study, concrete durability performance with respect to freeze-thaw from curing conditions change due to wind speed and sunshine exposure time. Concrete freeze-thaw experiment are performed. using wind speed and sunlight exposure time. Also, performance based evaluation through the satisfaction curve based on the freeze-thaw test results are performed.

Design and Evaluation of a Microcomputer-based Vacuum Drying System for Shiitake Mushrooms (마이크로컴퓨터 시스템을 이용한 표고버섯의 감압건조에 대한 연구)

  • Choi, Jae-Yong;Kim, Kong-Hwan;Chun, Jae-Kun
    • Korean Journal of Food Science and Technology
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    • v.19 no.6
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    • pp.550-555
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    • 1987
  • Strain gauges attached on the Bourdon tube and load cell were used as the sensors for measuring the vacuum pressure in drying chamber and the weight loss of Shiitake mushrooms respectively. The vacuum drying system was interfaced further with the Bear II microcomputer. The interface devices used were built with such IC chips as MC 6821, ADC 0809, SN 74244 and SN 7424. The relationship between readings of vacuum gauge (P, mmHg) and digital outputs (D) from the microcomputer was represented by P =3.08 D-13.4875(r=0.9999). The weights of drying sample (W) were also related with the digital outputs (D) by W=0.4076 D-6.4762 (r=0.9999). During the vacuum drying of Shiitake mushrooms. the data on pressure and weight were recorded at regular intervals using an acquisition program on the microcomputer system. The Page model was fitted well to the drying data of Shiitake mushrooms. resulting in the following empirical equations : $(M-M_e)/(M_o-M_e)=\exp(-0.1569t^{1.0048})$ at 400 mm Hg up to 14 hours and $(M-M_e)/(M_o-M_e)=\exp(-0.1385_t^{1.2688})$ at 600 mm Hg up to 8 hours.

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Effect of Vanadium Addition on the Cavitation Erosion Resistance of Fe-Cr-Ni-Si-C Hardfacing Alloy (Fe-Cr-Ni-Si-C계 경면처리 합금의 Cavitation Erosion 저항성에 미치는 Vanadium 첨가의 영향)

  • 김경오;김준기;장세기;김선진;강성군
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.11a
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    • pp.72-72
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    • 1998
  • 원자력발전소 1차계통내 밸브의 경면처리(hardfa따1잉에 사용되는 재료는 $90~343^{\circ}C$의 고온과 높은 접촉응력 그리고 급격한 압력변화가 일어나는 환경에서 사용되기 때문에 내마모성과 내식성 그리고 cavitation erosion 저항성이 우수한 Co계 Stellite 합금이 현재 사용되어진다. 그러나 Co가 원력발전소 1차계통의 방사선장을 형성하는 주요 원소로 알려지면서 S Stellite 합금을 대체할 수 있는 Fe계 경면처리용 합금을 개발하려는 연구가 진행되고 있다. 현재 Fe계 경면처리용 합금의 개발은 적절환 팝금원소를 첨가하여 적충결함에너지를 낮춤 으로써 전위의 교차슬립을 억제하여 표면을 경화시키고, 소성변형을 억제하여 마모저항성을 향상시키려는 방법으로 연구가 진행되고 있다. 본 연구에서는 Fe-Cr-Ni-Si-C 합금에 Fe계 합금의 적충결함에너지를 감소시키는 것으로 알려진 vanadium을 0, 1, 2wt%첨가하여 첨가량의 변화가 cavitation erosion 저항성에 미치 는 영향을 조사하였다. Cavitation erosion 실험은 초음파를 이용하여 미세한 기포를 발생시키는 vibratory type으로 A ASTM G-32 규격에 따라 제작된 실험장치를 이용하여 $25{\pm}2^{\circ}C$의 온도의 증류수 속에 잠긴 상태에서 실시하였다. 시면은 지름 16mm, 두게 7mm의 버턴형태로 vanadium 첨가량을 변화시킨 조성을 아크 용융 방법을 이용하여 제작하였으며 hom끝단부에 부착하여 cavitation e erosion 저항성 살험을 하였다. 시편의 cavitation erosion 실험시간에 따른 무게감소량을 측 정하였으며 cavitation erosion 시킨 시편의 표면을 SEM으로 관찰하였다.겨지는 열전달 매체액 과 신규 부식억제제가 적용된 시스템 등 객관적으로 확인된 부식억제제 시스랩에 대 하여 다양한 평가 방법을 동원 비교분석하고자 하였다. 실험은 KSM 2142에 의한 무게감량법, 분극곡선 측정에 의한 $E_P$(공식개시전위), $E_R$(재부동태화전위) 측정, 시간에 따른 자연전위 변화 측정 빛 이때의 부식속도(선형분극법), 인위적인 피막 파괴 전,후 의 전위 변화 및 부식속도 측정법에 의한 국부부식 발달 저지능 등을 평가하여 각 실험결과를 비교분석하여 보았다. 수록 민감하여 304 의 IGSCC 와 매우 유사한 거동을 보인다. 본 강연에서는 304 와 600 의 고온 물에서 일어나는 IGSCC 민감도에 미치는 환경, 예민화처리, 합금원소의 영향을 고찰하고 이에 대한 최근의 연구 동향과 방식 방법을 다룬다.다.의 목적과 지식)보다 미학적 경험에 주는 영향이 큰 것으로 나타났으며, 모든 사람들에게 비슷한 미학적 경험을 발생시키는 것 이 밝혀졌다. 다시 말하면 모든 사람들은 그들의 문화적인 국적과 사회적 인 직업의 차이, 목적의 차이, 또한 환경의 의미의 차이에 상관없이 아름다 운 경관(High-beauty landscape)을 주거지나 나들이 장소로서 선호했으며, 아름답다고 평가했다. 반면에, 사람들이 갖고 있는 문화의 차이, 직업의 차 이, 목적의 차이, 그리고 환경의 의미의 차이에 따라 경관의 미학적 평가가 달라진 것으로 나타났다.corner$적 의도에 의한 경관구성의 일면을 확인할수 있지만 엄밀히 생각하여 보면 이러한 예의 경우도 최락의 총체적인 외형은 마찬가지로 $\ulcorner$순응$\lrcorner$의 범위를 벗어나지 않는다. 그렇기 때문에도 $\ulcorner$

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A Study on the Characteristics of Coffee Ground(CG)-RDF by Using Different Drying Method (건조법에 따른 커피박 고형연료의 특성 고찰 연구)

  • Kim, Sang-bin;Ha, Jin-wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.451-457
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    • 2019
  • In this study, the characteristics of coffee grounds were reviewed by making them from solid fuel through heat-drying and oil-drying method. The differences in the higher calorific power by each dried sample were compared. And industrial analysis using the thermogravimetric analyzer was considered for applicability to organic waste and oily samples. Before and after drying, the surface of the specimen was observed with SEM equipment and the ingredients were measured through the EDS equipment. As a result, no other hazardous substances, such as heavy metals, were measured. Next, The differences between thermal decomposition and combustion reactions were considered through the TG and DTG curves. As a result, it is that the oil-dried coffee grounds is longer to burn than the heat-dried coffee grounds. Finally, the combustion gases emitted through the thermogravimetric analyzer were collected and the carbon monoxide and carbon dioxide performed qualitative and quantitative analysis using GC over time.