• Title/Summary/Keyword: 온도분리

Search Result 2,536, Processing Time 0.034 seconds

Effect of Temperature and Velocity on the Separation of Dy/Ho by Low Pressure Liquid Chromatography (저압크로마토그래피를 이용한 Dy/Ho 분리 시 온도와 유속의 영향)

  • Park, Kye-Sung;Kim, Joon-Soo;Lee, Jin-Young;Yoon, Ho-Sung;Kim, Chul-Joo
    • Proceedings of the Korean Institute of Resources Recycling Conference
    • /
    • 2005.05a
    • /
    • pp.178-182
    • /
    • 2005
  • 본 연구에서는 추출제가 함유된 추출레진$(75{\sim}150{\mu}m)$으로 채워진 저압액체크로마토그래피를 이용하여 용리온도$(20{\sim}60^{\circ}C)$와 유속$(1.41{\sim}7.04cm/min)$에 따른 Dy와 Ho의 분리특성을 조사하였다. 용리액인 HCl의 농도는 $0.25{\sim}0.5mol/L$가 적절한 것으로 판단되며, HCl $0.5mol/L$ 이상에서는 분리효과가 거의 없었다. 일정한 용리액 농도에서 유속이 느릴수록, column의 온도가 높을수록 분리도와 해상도는 개선되었으며, 유속이 느릴수록 용리액의 소모량은 감소, 분리시간은 증가하였다. 적정조건인 용리온도 $60^{\circ}C$, 유속 7.04cm/min, HCl 0.25mol/L에서 분리도는 ${\alpha}_{Dy}^{Ho}=1.36$로 가장 높았다.

  • PDF

Preparation and characterization of MFI type Zeolite membranes on porous alumina supports (다공질 알루미나 지지체 위에 코팅한 MFI type제올라이트 분리막의 제조 및 특성 연구)

  • 정상진;김호동;김명훈;김영희;김수룡
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.11a
    • /
    • pp.110-110
    • /
    • 2003
  • 제올라이트는 다양한 유기질 분리의 촉매제 및 광학, 화학 센서, 기체 분리 등의 고기능 소재로서 크게 주목받고 있으며, 그 중 MFI type(ZSM-5, Silicalite-1) 제올라이트는 주로 석유화학공정에 주로 이용되고 있고, 분리막으로서 이산화탄소의 분리/회수 및 물/유기 혼합물의 분리 등에 대한 연구가 활발히 진행되고 있다. 본 연구에서는 분리막 제조에 유리할 것으로 판단되어지는 적합한 크기와 형상을 갖춘 나노크기의 제올라이트 분말을 수열합성법과 마이크로웨이브 합성법을 이용하여 합성하였으며, 위의 조건으로 다공질 알루미나 지지 체 위에서 알루미나/제올라이트 분리막 제조를 하는데 성공하였다. 또 한 다양한 조건(시간, 온도, 조성)에 따른 막의 두께변화와 균열발생정도를 관찰한 결과 합성시간, 건조온도에 따라서 같은 조건의 분리막 사이에서도 현격한 차이가 나타남을 알 수 있었다. 얻어진 MFI type제올라이트 분말과 분리막은 XRD, SEM, BET, TGA, FT-IR등의 분석수단을 이용하여 물성평가를 실시하였다.

  • PDF

Design and Manufacturing of Uniflow Vortex Tube (단류형 볼텍스 튜브의 설계 및 제작)

  • Lee, Byeong-Hoon;Kim, Chang-Su;Park, Sung-Young
    • Proceedings of the KAIS Fall Conference
    • /
    • 2012.05b
    • /
    • pp.662-664
    • /
    • 2012
  • 본 논문에서는 단류형 볼텍스 튜브를 설계 및 제작하였으며, 에너지 분리특성 실험을 수행하였다. 세퍼레이션 튜브의 길이 변화에 따른 에너지 분리 특성의 영향을 실험적으로 분석하였다. 세퍼레이션의 위치는 매우 중요한 성능 변수 중의 하나이며, 세퍼레이션의 길이가 길어질수록 저온측 온도차는 전체적으로 온도차가 감소하는 경향을 보이나, 고온측 온도차는 저온측에 비해 미비한 온도차를 보이고 있다.

  • PDF

Nonlinear optical behavior of binary mixture protein and water near the phase separation temperature (상분리 온도 근방에서 섞임체 단백질-물의 비선형 광학적 특성)

  • 조창호;김태균;서영석
    • Korean Journal of Optics and Photonics
    • /
    • v.8 no.6
    • /
    • pp.461-465
    • /
    • 1997
  • The 3rd order nonlinear optical susceptibility was measured through the self-induced ellipse rotation. The phase separation temperature increases with the increase of salt and it decreases with the increase of glycerol.

  • PDF

Isolation of Major Microflora Bacillus coagulans from Rice Bran (쌀겨발효로부터 분리된 우점종 미생물 Bacillus coagulans의 분리)

  • Lee, Sang-Han;Park, Po
    • Food Science and Preservation
    • /
    • v.17 no.1
    • /
    • pp.165-168
    • /
    • 2010
  • It is known that temperature during solid fermentation using rice bran is increased upto 60-70 degree. To investigate the major microflora regarding temperature maintenance of rice bran bathing, we first isolated predominant microbes using various media by a limiting dilution method. The RNA of isolated strains were purified and sequenced. The rRNA sequencing revealed that the selected strains were similar to Bacillus coagulans according to their taxonomical relationships. Together, these results indicate that Bacillus coagulans is a major kind of microflora during solid fermentation using rice bran.

A Study on Separation of $N_2-SO_2$ Mixed Gas by Polymer Membranes (고분자막을 이용한 $N_2-SO_2$ 혼합기체의 분리에 관한 연구)

  • 김성준;민병렬;이태희
    • Membrane Journal
    • /
    • v.2 no.2
    • /
    • pp.135-143
    • /
    • 1992
  • Separation of $N_2-SO_2$ mixed gas by polymer membranes, SEPA-97(CA), TFC, and FT-30 membrane, was investigated by varying pressure and temperature. The permeability coefficients and the separation factors of mixed gases were measured, and the influence of various factors on the gas permeability characteristics and separation performance were investigated. The range of pressure was 0.1~1.0 MPa, and that of temperature was 283~303 K. The experimental results showed that the permeability coefficients and the separation factors were increased with an increase in pressure, but they were deereased with increasing temperature. Among the examined membranes, FT-30 possessed the best gas-separating characteristics.

  • PDF

Temperature Effect on the Retention Behavior of Sugars in Ion Exchange Chromatography (이온 교환 크로마토그래피에서 온도가 당의 체류 특성에 미치는 영향)

  • Kim, Jin-Il;Lee, Chong-Ho;Koo, Yoon-Mo
    • Korean Chemical Engineering Research
    • /
    • v.43 no.6
    • /
    • pp.722-727
    • /
    • 2005
  • Dow99Ca350 (Dowex monosphere 99Ca/350 separation resin), MFG-220, and Finex CS-10GC are ion-exchange resins, and primarily used to separate sugars, and all of these resins have poly styrene DVB backbone, and sulfonyl group. These resins are already used to separate sugars continuously at sugar industry at constant temperature. These resins are used in experiments for understanding temperature effect on retention or adsorption behavior. Using Dow99Ca350, swelling test, porosity test, pulse test, and frontal analysis at various temperatures were performed. In the cases of MFG-220, and Finex CS-10GC, the effect of temperature variation was verified by pulse test. The experimental results are shown that Dow99Ca350, MFG-220, and Finex CS-10GC, which are commercial resins for sugar separation, are stable to temperature variation because the maximum change of retention time of fructose, and glucose are 1.76, and 3.37% respectively.

Experimental Study on the Energy Separation of the Vortex Tube for EGR Cooler (EGR Cooler 대체용 Vortex Tube의 에너지 분리 현상에 관한 실험적 연구)

  • Kim, Chang-Su;Park, Sung-Young
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.11 no.1
    • /
    • pp.55-60
    • /
    • 2010
  • Vortex tube is the device that can separate small particles from the compressed gas, as well as compressed gas into hot and cold flow. Due to energy separation ability, a vortex tube can substitute for an EGR cooler of the automotive engine. In this study, experimental approach has been performed to analyze the energy separation characteristics of the vortex tube. Energy separation characteristics of the vortex tube has been tested for supply pressure, cold-out pressure, and hot-out pressure. As increasing supply pressure, energy separation effect increased. Maximum temperature exists about 0.85 of the cold-out-flow-ratio, and minimum exists about 0.35. Hot-out temperature of the vortex tube is affected by the hot-out and cold-out pressure. However, for the given conditions, cold-out temperature is independent of exit pressure change. The results from this study can be used for the basic design parameter of the EGR cooler substitute of an automotive engine.

Reevaluation of Isolation and Identification of Gram-positive Bacteria in Kimchi (김치에 서식하는 Gram 양성세균의 분리 및 동정의 재평가)

  • 임종락;박현근;한홍의
    • Korean Journal of Microbiology
    • /
    • v.27 no.4
    • /
    • pp.404-414
    • /
    • 1989
  • Attempts were made to isolate and identify Gram-positive or lactic acid bacteria in Kimchi fermentation. Species diversity depended on isolation media and temperatures, and diversity tended to be reduced with decrease of temperature. MRS and KM (natural medium prepared from Kimchi materials) were suitable respectively for isolation and present number of species. Identification of isolates was performed by dichotomous identification schemes arranged on the basis of Bergey's manual of Systematic Bacteriology (1986). Gram-positive bacteria isolated at different temperatures (5, 15, $25^{\circ}C$) were 5 species of Leuconostoc, 4 species of Streptococcus, 3 species of Pediococcus, 2 species of Bacillus and 18 species of Lactobacillus. Species with high frequency of appearance were Lactobacillus plantarum, Streptococcus raffinolactis, Leuconostoc mesenteroides subsp. mesenteroides at $25^{\circ}C$, L. plantarum, Lactobacillus fructosus, L. mesenteroides subsp. mesenteroides at $15^{\circ}C$ and L. mesenteroides subsp. mesenteroides, Leuconosotoc paramesenteroides, Lactobacillus maltaromicus at $15^{\circ}C$. In general, Kimchi fermentation was achieved by Lactobacillus spp. (59.7% frequency) at $25^{\circ}C$ and Leuconostoc spp. (65.2% frequency) at $5^{\circ}C$. Pediococcus cerevisiae and Streptococcus faecalis which have been so far known as bacteria of Kimchi fermentation were not isolated.

  • PDF

Temperature Effect on the Retention Behavior of Sugars and Organic Acids on poly (4-vinylpyridine) Resin (PVP 분리 수지에서 온도에 따른 당과 유기산의 체류 특성 변화)

  • Kim, Jin-Il;Lee, Chong-Ho;Koo, Yoon-Mo
    • Korean Chemical Engineering Research
    • /
    • v.44 no.1
    • /
    • pp.35-39
    • /
    • 2006
  • This study was performed to understand temperature effect on retention behavior of fructose and glucose as sugars and lactic acid and acetic acid as organic acids on poly (4-vinylpyridine) resin. The pulse tests were performed to understand temperature effect on retention time of sugars and the results were not shown large change. As it was able to predict with PVP resin not to be used for sugar separation generally, the results were shown poor resolution for separation of sugars and temperature effect on the resolution change of sugars also was not large. On the other hand, in the case of organic acids on PVP resin, the pulse tests were shown temperature effect on the retention behavior was very large. So, the frontal analyses were performed to understand quantitative adsorption behavior of organic acids at 35 and $65^{\circ}C$. These adsorption characteristics of organic acids with PVP resin system can be used to preparative chromatographic process such as SMB (simulated moving bed).