• Title/Summary/Keyword: 온도분리

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Modelling and Simulation of H2 separation in Pd Membrane System with Co-current and Current-current Flow (병류와 향류 흐름에서 수소분리를 위한 Pd 분리막 시스템의 모델링 및 모사)

  • Yi, Yong;Noh, Seunghyo;Oh, Min
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.598-602
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    • 2010
  • In this paper, we carried out CFD modelling and simulation for the membrane system to separate H2 gas from the multi-component feed gas. The membrane system is of the annulus tubular type consisting of the external lumen side for the feed gas and the internal permeation side for the sweeping gas. The operating temperature and pressure of the lumen side inlet flow are $374^{\circ}C$ and 7 bar respectively and those of the sweeping gas are $374^{\circ}C$ and 3 bar, and considering these conditions, Pd membrane system was employed. CFD simulations were performed for the co-current flow and counter-current flow membrane system based on the flow directions between the feed and the sweeping gas. Comparisons and discussions were made for the H2 partial pressure, H2 mole fraction and H2 flux for both cases. Furthermore, we executed CFD simulations for the each case of the various inlet flow rates of the feed gas at the lumen side. Accordingly, we reviewed the effects of the flow rate and residence time on the performance of the membrane system.

Separation of Trichlorinated Hydrocarbons by ZSM-5 Zeolite Membrane (ZSM-5 제올라이트 분리막에 의한 3가 염소화합물의 투과증발 분리)

  • Lee Yong-Taek;Sim Eun-Young;Ahn Hyo-Seong
    • Membrane Journal
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    • v.16 no.2
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    • pp.159-166
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    • 2006
  • MFI(Mobil Five) structured hydrophobic ZSM-5 zeolite membrane was used for selective pervaporation of trichlorinated organic compounds(trichloromethane, trichloroethane, trichloroethylene) from their aqueous solutions. ZSM-5 zeolite membrane was hydrothermally synthesized on the inside of a porous stainless steel tube by secondary growth employing ZSM-5 seed powders. Separation factors for each binary mixtures were observed $16{\sim}66$ for trichloromethane/water, $3.3{\sim}4.6$ for trichloroethane/water and $1.4{\sim}8$ for trichloroethylene/water at the experimental conditions of the feed mole fraction from 0.0001 to 0.001 with temperature ranged $25{\sim}35^{\circ}C$.

토양으로부터 분리한 Klebsiella pneumoniae 의 pullulanase 유전자의 cloning 및 발현

  • 유주현;공인수;정용준;이정기
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 1986.12a
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    • pp.518.2-519
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    • 1986
  • 토양으로부터 분리한 질소고정균인 Klebsiella pneumoniae NFB320의 chromosomal DNA를 BamHI으로 절단하여 동일한 제한효소로 절단한 pBR322에 ligation시켜 E. coli HB101에 형질전환을 행하여 pullulanase activity를 나타내는 clone을 얻어내었다. 이 형질 전환체로부터 분리한 pullulanase 유전자가 재조합된 plasmid DNA는 약 10kb의 DNA단편을 가지고 있었으며, 재조합된 plasmid로부터 생산되는 pullulanase의 특성은 최적 활성 pH가 6.0이며, 효소의 pH안정성은 5-10이었다. 또한 형질 전환체로부터 생산되는 pullulanase의 localization,효소활성에 영향을 미치는 온도안정성 둥을 조사하였다.

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Separations of polystyrene sulfonate by dual pump field flow fractionation using UF hollow fiber membranes (듀얼펌프 중공사막 흐름 장 흐름 분회법을 사용하여 다당류(Polystyrene sulfonate)의 분리)

  • 정도연;최승렬;이승윤;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.192-194
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    • 2004
  • FFF에서 외부장은 시료의 종류에 따라 선택적으로 사용되며, 그 외부장의 종류에 따라 세부기술로 구분되어진다. 원심력(gravitational or centrifugal field)을 외부장으로 사용하는 침강장-흐름분획법(sedimentation FFF)은 지름이 0,05∼1um정도인 콜로이드 입자의 분리에 좋은 방법이다. 온도구배(thermal fradient)를 이용하는 열장-흐름분획법(thermal FFF)은 유기 고분자의 분리 및 고분자의 물성연구에 이용된다.(중략)

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Phase Separation Structure of (PVC/Liquid Crystal) Composite Membrane ((Polyvinylchloride/액정) 복합막의 상분리 구조)

  • 이미선;최성부;이한섭;박관선;김병식
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.68-69
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    • 1998
  • 1. 서론 : 고분자/액정 복합막은 액정의 높은 분자운동성이 물질의확산에 기여하여 우수한 투과성을 나타낸다. 이 막은 3차원의 망상구조를 갖는 매트릭스 고분자내에 액정이 연속상으로 안정하게 분산된 상분리 구조를 가지고 있다. 이 복합막은 그러한 상분리 구조에 기인하여 자기지지형(self support LC) 복합막이라고도 한다. 복합막 중에 액정은 탄화수소가스에 대하여 높은 선택성을 나타내어 막속으로 흡착을 촉진하고 액정물질이 결정에서 액정으로 변화는 전이온도에서 투과계수가 100-200 증가한다고 보고하였다. (생략)

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Enzyme Deactivation During Enzyme Recycling with Ultrafiltration Hollow Fibers (한외여과막을 이용한 효소재순환 시스템에서의 효소역가감소)

  • 김준석;정용섭홍석인
    • KSBB Journal
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    • v.11 no.3
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    • pp.347-352
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    • 1996
  • The enzyme deactivation in a membrane recycling system for the simultaneous saccharification and fermentation(SSF) was studied under various temperature and pressure. The optimum molecular weight cut off(MWCO) of the ultrafiltration membrane for recycling cellulase and ${\beta}$-glucosidase was 50,000. When the cellulase was recycled continuously through the membrane system, it was not deactivated. But the activity of ${\beta}$-glucosidase was decreased with an increase in operating temperature and transmembrane pressure. After 720 minutes at $42^{\circ}C$ and 24.8 psig , the activity of ${\beta}$-glucosidase was reduced by 35% of the initial activity. Such tendencies could be well explained by the results of highly induced shear at the fiber surface of membrane when temperature and transmembrane pressure became higher.

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Animal fat biodiesel separation and washing (동물성 오일 바이오디젤의 분리 및 세정 방법 연구)

  • Kim, Deogkeun;Kim, Sumgmin;Lee, Joonpyo;Park, Soonchul;Lee, JinSuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.113.2-113.2
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    • 2011
  • 동물성 오일을 이용한 바이오디젤 생산 반응 후 미반응된 메탄올과 염기촉매의 처리에 관한 연구로써 바이오디젤의 순도에 영향을 미친다. 메탄올과 염기촉매는 바이오디젤 생산 반응 후 상층인 메틸 에스터 층과 하층인 글리세롤 층에 각각 포함되어 있다. 1차적으로 각각의 층에서 메탄올을 증발하게 되며 메탄올 증발은 감압 증류 장치를 이용해 분리하게 된다. BD100을 기준으로 하여 메탄올의 함량은 0.2% 이하여야 하며 수분 함량은 0.05% 이하를 유지해야 한다. 메탄올 증발은 메탄올의 끓는 온도인 $65^{\circ}C$를 기준으로 하여 끓는점 보다 낮은 온도와 높은 온도에서 각각 증발을 실시하고 각각의 메탄올 증발 제거에 따른 FAME 함량에 미치는 영향에 대해 FAME 함량 분석을 통해 조사하였으며 메탄올 증발 후 증류수를 이용한 바이오디젤 내 잔류 촉매 및 자유 글리세린 세정 제거에 대해 조사하였다. 증류수 양과 증류수 온도 및 세정 시간에 따른 FAME 함량 변화를 알아보았으며 세정 후 증류수 증발에 따른 FAME 함량 변화에 대해서 분석을 실시하였다. 본 실험을 통해 동물성 오일을 이용한 바이오디젤 생산 후처리 공정인 메탄올 증발 및 세정, 수분 증발 공정의 최적 조건을 도출하고자 하였다.

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Isolation and Enzymatic Characterization of Bacteria from Livestock Manure (축산분뇨에서 분리한 세균의 동정 및 효소학적 특성)

  • 김진선;정소선;이준석;최미영;서승염
    • Korean Journal of Microbiology
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    • v.37 no.3
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    • pp.214-220
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    • 2001
  • To develop the effective composting system, we isolated bacteria that have the abilities to degrade organic matters such as cellulose, carbohydrate, protein and lipid during the compositing of livestock manureAmong 24 strains, 6 bacteria have all the enzymatic activities of protease, amylase, cellulase and lipase.These microorganisms were identified as Corynebacterium varibilis, Bacillus spp., Pseudomonas spinosa,Acetobacter calcoaceticus and Athrobacter cumminsii All the enzymes produced by the bacteria showedactivities at the broad pH range and the maximal activities were obtained at $60^{\circ}C$. It seemed that after theincrease of temperature caused by fermentation of livestock manure, the enzymes started to degrade the rawmaterials, which are added for the control of humidity. However cellulase activity was maximum at $37^{\circ}C$,suggesting that the cellulase-producing bacteria work at an early stage of livestock manure fermentation toprovide the organic material for the growth of other bacteria. The production of the enzymes were growth-associated and maximal activities appeared at the early stationary phase of growth.

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Antipathogenic Activity of Bacillus amyloliquefaciens Isolated from Korean Traditional Rice Wine (막걸리로부터 분리된 Bacillus amyloliquefaciens 균주의 항균 활성)

  • Sim, Hyunsu;Kim, Myoung-Dong
    • Microbiology and Biotechnology Letters
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    • v.44 no.1
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    • pp.98-105
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    • 2016
  • The presence of bacterial strains showing antagonistic activity to common pathogens found in a variety of fermented foods in Korea was explored. A bacterium inhibiting the growth of pathogens such as Aspergillus terreus (KCTC6178), A. flavus (KCTC6984), Staphylococcus aureus (KCCM12214), Escherichia coli O157:H7 (KCCM40406), Bacillus cereus (KCTC1012), Cryptococcus neoformans (ATCC208821), Salmonella typhimurium (ATCC19430), and Listeria monocytogenes (KCTC3569) was isolated from Makgeolli, a Korean traditional rice wine. The strain showing high antipathogenic activity was identified as B. amyloliquefaciens based on the nucleotide sequence of the 16S ribosomal RNA gene. Compared with B. amyloliquefaciens KCTC1660, whose genome has been sequenced, the isolate exhibited significantly low activities of starch-degrading enzymes and high resistance to high temperature and low pH.

Separation of Neodymium from NdEeB Permanent Magnetic Scrap (NdFeB계 영구자석 스크랩으로부터 네오디뮴의 분리회수)

  • Yoon Ho-Sung;Kim Chul-Joo;Lee Jin-Yeung;Kim Sung-Don;Kim Joon-Soo;Lee Jae-Chun
    • Resources Recycling
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    • v.12 no.6
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    • pp.57-63
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    • 2003
  • In this study, the separation of neodymium was investigated from NdFeB permanent magnet scrap. Decomposition and leach-ing process of NdFeB permanent magnet scrap by oxidation roasting and sulfuric arid leaching were examined. Neodymium could be separated from iron by double salt precipitation using sodium sulfate. The optimum conditions established for decom-position and leaching are as follows: oxidation roasting temperature is $500^{\circ}C$ for sintered scrap and $700^{\circ}C$ for bonded scrap, concentration of sulfuric acid in leaching solution is 2.0 M, leaching temperature and time is $50^{\circ}C$ and 2 hrs, and pulp density is 15%. The leaching yield of neodymium and iron was 99.4% and 95.7% respectively. The optimum condition for separation of neodymium by double-salt precipitation was 2 equivalents of sodium sulfate and $50^{\circ}C$ The yield of neodymium was above 99.9%.