• Title/Summary/Keyword: 온도변화율

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A Study on the Water Gas Shift Reaction of RPF Syngas (RPF(Refuse plastic fuel) 합성가스의 수성가스 전환 반응 연구)

  • Roh, Seon Ah
    • Resources Recycling
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    • v.30 no.6
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    • pp.12-18
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    • 2021
  • The water-gas shift reaction is the subsequent step using steam for hydrogen enrichment and H2/CO ratio-controlled syngas from gasification. In this study, a water-gas shift reaction was performed using syngas from an RPF gasification system. The water-gas shift using a catalyst was performed in a laboratory-scale tube reactor with a high temperature shift (HTS) and a low temperature shift (LTS). The effects of the reaction temperature, steam/carbon ratio, and flow rate on H2 production and CO conversion were investigated. The operating temperature was 250-400℃ for the HTS system and 190-220℃ for the LTS system. Steam/carbon ratios were between 1.5 and 3.5, and the composition of reactant was CO : 40 vol%, H2 : 25 vol%, and CO2 : 25 vol%. The CO conversion and H2 production increased as the reaction temperature and steam/carbon ratio increased. The CO conversion and H2 production decreased as the flow rate increased due to reduced retention time in the catalyst bed.

Influence of Thermal Treatments on Germination and Internal Compositions of 'Hongro' and 'Fuji' Apple Trees during Endodormancy (내재휴면기 온도처리가 사과 '홍로' 와 '후지'의 발아와 내부물질 변화에 미치는 영향)

  • Cho, Jung Gun;Ryu, Suhyun;Lee, Seul-Ki;Han, Jeom Hwa;Jeong, Jae Hoon
    • Journal of Bio-Environment Control
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    • v.28 no.4
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    • pp.352-357
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    • 2019
  • In this study, we investigated the limit temperature range which is effective for dormancy release of 'Hongro' and 'Fuji' apples during the endodormancy period. The germination rate was 50% or more in all treatments except of 'Hongro' $-5^{\circ}C$ treatment. The germination rate of 'Fuji' was 86.3% at the temperature of $-5^{\circ}C$. The concentrations of carbohydrate and mineral components were significantly different between treatments but did not show any tendency or specific change. However, the sorbitol contents of 'Hongro' $-5^{\circ}C$ treatment were higher at 29.62 mg/g than those of 'Fuji', which was not affected for dormancy release. The results of hormone analysis showed that ABA(abscisic acid) and JA(jasmonic acid) in 'Hongro' $-5^{\circ}C$ treatment were respectively 176.48 and 15.72 ng/g. ABA, JA and SA(salicylic acid) contents in 'Fuji' apple tree were significantly lower than those of 'Hongro'. As a result of this study, the limit temperature range effective for dormancy release was different according to the varieties, and 'Hongro' did not affect with 30.3% of germination rate at $-5^{\circ}C$. However, 'Fuji' is 86.3% even at $-5^{\circ}C$ it was suggested that 'Fuji' had a chilling accumulation for dormancy release.

Estimations of Moisture Profiles During Wood Drying Using an Unsteady-State Diffusion Model (II) - Experimental Verification for Red Oak - (비정상(非正常) 상태(狀態)의 확산(擴散)모델을 이용한 수분(水分) 경사(傾斜)의 예측(豫測) (II) - 실험적(實驗的) 검증(檢證) -)

  • Park, Jung-Hwan;Smith, William B.
    • Journal of the Korean Wood Science and Technology
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    • v.24 no.3
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    • pp.37-44
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    • 1996
  • 포수상태(包水狀態)의 루부라참나무(Quercus rubra) 시험편을 3가지 등온조건(等溫條件)에서 건조한 결과를 비정상상태(非正常狀態)의 확산(擴散)모델로 추정한 결과와 비교하였다. 표면이 충분히 젖은 상태인 건조초기에는 불안정(不安定)한 확산현상(擴散現象)이 관찰되었으나, 함수율(含水率)별 건조속도의 변이를 Fick's의 확산법칙과 비교할 때 유사한 형태를 보였다. 실험에서 얻은 건조조건별 건조곡선은 확산모델의 수치해석(數値解析) 결과와 거의 일치하였으며, 같은 평위함수율(平衛含水率) 조건에서 건조온도의 증가는 목재표면 보다 내부의 함수율 변화에 더 크게 영향하여 결과적으로 낮은 온도에서의 건조조건이 목재 내의 수분경사(水分傾斜)를 급하게 하는 것으로 밝혀졌다. 본 연구를 통해 목재 건조 중의 내부에 발생하는 수분경사를 추정하는데 비정상상태의 확산모델이 모든 함수율 범위에 걸쳐 유용하게 사용될 수 있음이 밝혀졌다.

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A Study on the Calibrate Method of Volumetric Moisture Content Measuring Sensor(CS616) (TDR(Time Domain Reflectometry) 방식의 함수센서 (CS616) 보정방법에 관한 연구)

  • Cho, Myung-Hwan;Kim, Hong-Man;Jee, Kee-Hwan;Park, Joo-Young
    • 한국방재학회:학술대회논문집
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    • 2010.02a
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    • pp.89.1-89.1
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    • 2010
  • 본 연구는 토양의 함수비를 측정하기 위하여 TDR(Time Domain Reflectometry, 시간영역 광전자파 분석기) 방식의 함수센서(CS616)에 대한 올바른 보정시험을 제안하기 위하여 피복두께, 센서간 간섭 영향, 온도의 영향 및 다짐율 변화에 대한 실내 시험을 수행하였다. 시험 결과 피복두께, 센서간 간섭 영향 및 온도의 영향은 체적함수비의 크기에 미치는 영향은 크지 않은 것으로 나타났으며, 오히려 보정시험시 정확한 체적함수비 조건을 유지하는 것이 중요할 것으로 사료된다. 또한 보정시험을 수행할 때 다짐율까지 고려한 시험을 수행하는 노력에 비하여 얻어지는 체적함수비의 정확도의 크기는 다짐율과 주기를 고려하여 얻어진 회귀식을 살펴보면 주기에 비하여 상대적으로 영향이 작은 것으로 사료된다.

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Correlation between Strain and Dielectric properties in Paraelectic $ZrTiO_4$ Thin Films ($ZrTiO_4$상유전 박막의 Strain과 유전 특성 상관성 고찰)

  • 김태석;오정민;김용조;박병우;홍국선
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.108-108
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    • 2000
  • 급증하는 무선통신 정보수요는 특히, 고주파대역 (300NHz-300GHz)에서 사용되는 공진기, 필터, 발진기 등과 같은 소자의 품질향상을 요구하고 있다. 고주파용 유전체 중 ZrTiO4 는 $\alpha$-PbO2 계열의 사방정구조를 갖고 있는 유전체로서 높은 유전율 ($\varepsilon$=40)과 높은 품질계수 (Q=1/tan$\delta$=4700 at 7GHz)를 갖고 있고, Sn 첨가시 0ppm/$^{\circ}C$의 공진주파수 온도계수를 얻을 수 있다고 보고되어 있다. 본 연구에서는 약 110$0^{\circ}C$ 이상에서 안정한 상으로 존재하는 ZrTiO4를 저온에서 증착하여 준안정한 상태로 결정화되게 한후, 유전손실 (tan$\delta$)과 유전율($\varepsilon$)을 측정하였다. 또한 증착온도와 열처리과정에 따른 박막의 us형 (Strain) 정도의 변화를 X-선 회절결과로부터 분석하였으며 이를 측정된 유전특성 값과 비교하였다. ZrTiO4 박막은 DC magnetron reactive sputter로 Zr과 Ti 타겟으로부터 high phosphorous doped Si (100) 기판위에 증착하였다. 압력은 4mTorr로 유지하고 박막의 화학양론적 조성비를 맞추기 위해 각 타겟에 가해지는 power는 Zr/Ti=500W/650W로 고정하고, 반응가스의 비율을 Ar/O2=17sccm/3.5sccm으로 유지하여 박막내에 인입되는 산소량을 제어하였다. 증착 직후와 열처리 후의 박막특성을 비교하기 위해 증착온도를 상온에서부터 $600^{\circ}C$까지 변호시키고 증착후 각각의 시편을 80$0^{\circ}C$ 산소분위기에서 2시간동안 열처리하여 시편을 준비하였다. 박막의 상형성 여부와 결정성변화는 $ heta$-2$\theta$X-선 회절법을 사용하여 조사하였고, EPMA를 이용하여 박막의 조성을 확인하였다. 유전특성의 측정을 위해 백금 상부전극을 증착한 후, impedance analyzer를 이용하여 100kHz 영역에서의 유전손실을 측정하고, 측정된 정전용량과 박막의 두께로부터 유전율을 계산하였다. ZrTiO4 박막은 증착온도 20$0^{\circ}C$ 이상에서 결정성을 보이기 시작했으며, 열처리 이후에는 상온에서 비정질이었던 시편이 $650^{\circ}C$ 이상의 온도에서 결정화되기 시작하였다. 증착온도에 따라 유전손실은 0.038에서 0.017 정도로 감소하는 경향을 나타냈으며, 각각 열처리에 의해서 0.034, 0.005 정도로 다시 감소하였다. 박막의 유전율은 약 35 정도의 값을 나타내었으며 X-선 회절 data로부터 분석한 박막의 변형은 증온도에 따라 7.2%에서 0.04%로 감소하였고 이 이경향은 유전손실은 감소경향과 일치하였다.

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$[Li_{1-5x}Nb_{5(x-y)}Mg(or Zn)_{5y}]Nb_{1-4x+3y}O_3$단결정의 결합 및 물성에 관한 연구

  • 김기현;심광보;오근호
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.129-133
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    • 1997
  • 본 연구에서는 LiNbO$_3$ 단결정 소재의 광손상에 대한 저항성을 향상시키는 첨가물로 잘 알려져 이쓴 MgO 및 ZnO를 첨가하여 육성한 조화용융조성(congruent melting composition)의 LiNbO$_3$ 단결정의 domain 구조는 이들 dopants를 첨가함에 따라 single domain에서 ring 형태의 주기적인 domains으로 변화함을 확인하였고, 첨가된 이온이 domain 형성에 미치는 영향을 전자현미경(SEM-WDS)으로 관찰하였다. 또한, 육성한 [Li1-5xNb5(x-y)Mg(or Zn)5y]Nb1-4x+3yO3 단결정들의 유전율(전이온도) 변화 및 광학적 특성[광투과율, 굴절률]을 측정하여 undoped LiNbO$_3$단결정과 비교하였다. 첨가물을 첨가함에 따라 전이온도는 약 20~3$0^{\circ}C$정도 증가하였으며, 10-3 order의 굴절률 변동치를 나타내었다. 또한, 육성된 결정들의 투과율은 대체로 70~80%를 나타내었고, 첨가물을 첨가함에 따라 흡수단과 OH- 흡수 band는 단파장쪽으로 각각 약 5~10nm, 40nm이동됨을 확인하였다. 이는 LiNbO$_3$단결정의 광손상 저항성이 향상되었음을 간접적으로 보여주는 결과이다.

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Relation the Role of Wathe in withering and Mechanical Properties of Some Leafy Vegetables -1. Effect of Withering on Viscoelastic Properties of Spinach and Leek- (엽채류(葉菜類)의 조위(凋萎)와 역학물성(力學物性) -1. 조위(凋萎)와 물성변화(物性變化)-)

  • Kong, Jai-Yul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.15 no.3
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    • pp.286-293
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    • 1986
  • The purpose of this study was to investigate the effect of withering on mechanical properties for optimizing the condition of transportation and storage of fresh leafy vegetables which they would be easily able to be suffered the physical damage. Experimental material used were spinaches and leeks which were easily apt to be withered. The breaking stress, elastic modulus and viscosity were measured in the range of temperature $3{\sim}37^{\circ}C$ and water content $70{\sim}95%$ by the four element model, being used the creep tester made by author. As a result of this study, while water content was decreased, breaking stress was increased. The elastic modulus and viscosity of the specimens were not influenced on temperature, but on water content. In reversibility test of the withering, the appearance, water content and elastic modulus of the specimens were completely recovered to the initial freshness, but the viscosity was not.

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Analysis of Thermal Heat Island Potential by Urbanization Using Landsat-8 Time-series Satellite Imagery (Landsat-8 시계열 위성영상을 활용한 도심지 확장에 따른 열섬포텐셜 분석)

  • Kim, Taeheon;Lee, Won Hee;Han, Youkyung
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.36 no.4
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    • pp.305-316
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    • 2018
  • As the urbanization ratio increases, the heat environment in cities is becoming more important due to the urban heat island. In this study, the heat island spatial analysis was calculated and conducted for analysis of urban thermal environment of Sejong city, which was launched in 2012 and has been developed rapidly. To analyze the ratio and change rate of urban area, a multi temporal land cover map (2013 to 2015 and 2017) of study area is generated based on Landsat-8 OLI/TIRS (Operational Land Imager / Thermal Infrared Sensor) satellite imagery. Then, we select an TIR (Thermal Infrared) band from the two TIR bands provided by the Landsat-8, which is used for calculating the heat island potential, through the accuracy evaluation of the brightness temperature and AWS (Automatic Weathering Station) data. Based on the selected band and surface emissivity, land surface temperature is calculated and the estimated heat island potential change is analyzed. As a result, the land surface temperature of the high ratio and change rate of urban area was significantly higher than the surrounding area around $3^{\circ}C$ to $4^{\circ}C$, and the heat island potential was also higher around $4^{\circ}C$ to $5^{\circ}C$. However, the heat island phenomenon was alleviated in urban areas with high rate of change that also show high green area ratio. Therefore, we demonstrated that dense urban area increases the possibility of inducing heat island, but it can mitigate the heat island through green areas.

Temperature Compensation and Characteristics of Fiber Bragg Grating Filters (광섬유격자필터의 온도보상 및 온도보상특성 측정)

  • Yoon, Hyung-Do;Lee, Han-Young;Ku, Ja-Hyon;Chang, Jin-Hyeon;Park, Jong-Hoon;Lee, Kyung-Shik
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.11
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    • pp.82-87
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    • 1999
  • To temperature-compensate the Bragg wavelength of fiber grating filters two materials with different thermal expansion coefficients were depolyed for packaging. After temperature-compensation packaging the maximum difference of the Bragg wavelength in the temperature range of $-10^{\circ}C$ to $70^{\circ}C$ was 0.03nm, which is only about one thirtiety of the Bragg wavelength shift of the temperature-uncompensated fiber grating filter.

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A Numerical Analysis on Transient Fuel temperatures in a Military Aircraft under Non-operating Ground Static Condition (지상 정적 상태에서의 항공기내 연료온도변화에 대한 수치해석)

  • 김영준;김창녕
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.11-16
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    • 2003
  • A numerical study was performed on the transient fuel temperatures of a military aircraft stationed under non-operating static condition. Numerical calculation was peformed by an explicit method using modified Dufort-Frankel scheme. It was assumed that the non-operating aircraft is subjected to repeated daily cycles of air temperature with the solar radiation and wind speed corresponding to the 1 % hot day ambient condition. And, the aircraft was assumed to be in turbulent flow. The convective heat transfer coefficient for turbulent flow on the flat plate suggested by Eckert was employed to calculate heat transfer between the aircraft surface and the ambience. The energy conservation equation on fuel was used as governing equation for this analysis. As a result of this analysis, the wing tank temperature showed the highest temperature and the largest rate of temperature changes among fuel tanks. The results of this analysis could be used as initial foe] temperatures for analysis of the transient fuel temperatures in various flight missions. Also, this analysis method could be used to analysis and design of an aircraft thermal energy management system.