• Proceedings of the Korea Crystallographic Association Conference
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• 2003.05a
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• pp.21-21
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• 2003

Pb(Zn/sub 1/3/Nb/sub 2/3/)O₃(PZN)은 전형적인 완화형 강유전체로서 급격하게 상전이를 일으키는 것이 아니라 온도에 따라 완만하게 변화하는 물질이다. 완화형 강유전체의 경우, 저온에서는 ㎛ 이상의 거시분역이 존재하고 일반적인 강유전체와 유사한 특성을 가지지만, 온도가 증가하면서 거시분역이 불안정해 지고 크기가 자가져서 수 nm 크기의 미소 극성 영역으로 나뉘는데, 이때 결정구조, 유전율, 유전 손실등의 온도와 주파수에 따른 변화를 관찰하여 강유전 상전이 현상의 특징을 살펴보고자 하였다. 이를 위해 본 연구에서는 융제법에 의해 PZN-xPT 단결정을 성장시킨 후 온도에 따른 결정구조를 변화를 측정하고, 이러한 결정구조의 변화가 강유전 특성에 미치는 영향에 대해 알아보았다. 순수한 PZN은 전형적인 완화형 강유전체의 상전이거동을 나타내었으며, PT의 함량이 증가하면서 점차 일반적인 강유전체로 전이하는 것이 관찰되었다. 그러나 PZN-0.12PT의 경우도 완전한 일반적 강유전체는 아니었으며 완화형거동을 일부 나타내었다. 모든 조성에서 온도가 감소하면서 국부적인 응력의 증가가 관찰되었으며, 응력의 인가 정도는 H 함량에 따라 증가하였다. 이상의 변화는 순수한 PEW에서 나타나는 미소분역들이 온도의 감소와 H 양의 증가에 따라 정전기적 상호작용을 일으키면서 강유전분역으로 성장하기 때문이었으며, Vogel-fulture식에 따른 유전율 최대온도와 측정주파수간의 관계는 분역들간의 상호작용을 됫받침해주었다.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.20 no.4
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• pp.477-483
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• 2007

In this study, the numerical fire analysis for temperature distribution and spalling behavior of underground concrete box structures that contained lifelines, such as power cables and communication cables. The temperature field of inner space was assumed based on the fire curve with the thermal gradient obtained from CFD analysis. It was assumed that the spalling behaviors of concrete are occurred when the concrete temperature reached the threshold, as dehydration degree. In this case, the elements correspond to spalling parts were removed and the analysis model were updated. Three fire scenarios were analyzed and the results were showed adequate spalling behavior. The bearing capacities of the box structures would be estimated in the companion paper.

• International Journal of Highway Engineering
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• v.6 no.2 s.20
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• pp.47-59
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• 2004

The temperature variation of concrete pavement at early-age significantly affects the initiation and propagation of its early-age cracks. This implies that the measurement and analysis of early age temperature trend are necessary to examine the causes of early age cracks in the concrete pavement. In this study, it is investigated how the early age temperature trend in concrete pavement affects the random crack initiation and behaviors of saw-cut joints using the actual construction site which is located at the KHC test road. During 72 hours after placing the concrete pavement, the ambient air temperature and temperatures at the top, middle, and bottom in concrete pavement were measured and the random crack initiation in concrete slabs and early age behaviors in the joints were surveyed. The investigation results indicate that the first random crack was initiated at one of the slabs placed in the early morning which have higher temperature changes during early 72 hours. The movement of slab was influenced by the early-age crack in the joint. It suggested that the different occurrence time of the cracks in the joint had an influence on the behavior of the cracks. Besides, the slab constructed In the morning had higher possibility of crack initiation than that in the afternoon. The rarely occurred cracks had bigger gap than other cracks.

• Journal of the Korean Geotechnical Society
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• v.33 no.11
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• pp.45-57
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• 2017

Temperature change affects consolidation behavior of soft clays. The increase of temperature in soft clays induces the increase of pore water pressure. The dissipation of the excess pore water pressure decreases volume and void ratio. Also, the consolidation rate is accelerated by high temperature which induces the decrease of viscosity of pore fluid. The effects of temperature on the consolidation behavior such as consolidation settlement, consolidation time, and pore water pressure were investigated in this study. A numerical analysis of hydro-mechanical (HM) and thermo-hydro-mechanical (THM) behavior was performed. The combination of heat injection and sand drain for consolidating the soft ground, with varying temperature (40 and $60^{\circ}C$) and sand drain diameter (40, 60, and 80 mm), was considered. The results show that the temperature inside soil specimen increases with the increase of the temperature of heating source and the diameter of sand drain. Moreover, the heat injection increases the excess pore water pressure and, accordingly, induces additional settlement in overconsolidated (OC) state and reduces the consolidation time in normally consolidated (NC) state.

• Tunnel and Underground Space
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• v.31 no.4
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• pp.221-242
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• 2021

A numerical study of the performance assesment of coupled thermo-hydro-mechanical (THM) processes in improved Korean reference disposal system (KRS⁺) for high-level radioactive waste is conducted using TOUGH2-MP/FLAC3D simulator. Decay heat from high-level radioactive waste increases the temperature of the repository, and it decreases as decay heat is reduced. The maximum temperature of the repository is below a maximum temperature criterion of 100℃. Saturation of bentonite buffer adjacent to the canister is initially reduced due to pore water evaporation induced by temperature increase. Bentonite buffer is saturated 250 years after the disposal of high-level radioactive waste by inflow of groundwater from the surrounding rock mass. Initial saturation of rock mass decreases as groundwater in rock mass is moved to bentnonite buffer by suction, but rock mass is saturated after inflow of groundwater from the far-field area. Stress changes at rock mass are compared to the Mohr-Coulomb failure criterion and the spalling strength in order to investigate the potential rock failure by thermal stress and swelling pressure. Additional simulations are conducted with the reduced spacing of deposition holes. The maximum temperature of bentonite buffer exceeds 100℃ as deposition hole spacing is smaller than 5.5 m. However, temperature of about 56.1% volume of bentonite buffer is below 90℃. The methodology of numerical modeling used in this study can be applied to the performance assessment of coupled THM processes for high-level radioactive waste repositories with various input parameters and geological conditions such as site-specific stress models and geothermal gradients.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05a
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• pp.630-635
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• 1995

장차 우리나라에서 미래형 핵연료의 한 종류로서 사용될 가능성이 있는 경수로용 혼합핵연료가 기존의 $UO_2$ 핵연료와 노내거동에서 어떤 차이를 야기시키는가를 물리적 성질변화 및 반경방향 출력변화의 관점에서 예비적으로 분석하였다. 분석 결과 혼합핵연료는 $UO_2$ 핵연료에 비해 (1) 열전도도가 작아 핵연료 온도가 높았고 (2)증가된 핵연료 온도로 인해 핵분열기체 방출률도 증가하여 핵연료봉 내압의 관점에서는 불리하였으나 (9)증가된 핵연료 내압으로 인해 냉각수 압력과 핵연료봉 내압의 차이가 감소하여 피복관 변형도가 감소하므로써, PCI 판점에서는 $UO_2$ 핵연료에 비해 유리하였다.

• Polymer(Korea)
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• v.33 no.2
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• pp.183-188
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• 2009

Structural rearrangements of uni-axially deformed polyethylenes containing 1-octene comonomer and HDPE upon heating were investigated by time-resolved small and wide angle X-ray scattering techniques. During heating, structural changes including crystal transformation and lamellar rearrangement noted were very different depending on the comonomer contents. At low comonomer content below 2 wt%, inverse martensitic transformation of crystal lattice from monoclinic to orthorhombic cell and the rearrangement of broken lamellar units into more ordered and perfect lamellar stacks were noted with the temperature increase. At high contents above 9.5 wt%, however, polyethylene copolymers showed neither the crystal transformation nor lamellar rearrangement that can be attributed to low crystallinity and high content of branch units.

• Korean Journal of Materials Research
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• v.7 no.11
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• pp.929-933
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• 1997

에폭시 수지 DGEBA/MDA/GN계의 트링 열화에 미치는 전압과 온도의 영향에 대한 고찰을 통하여 고분자 절연재료의 절연파괴 거동을 연구하였다. 전압 인가시간에 따라 트리의 성장속도은 역S자의 형태로 나타났다. 인가전압과 온도가 증가함에 따라 트리의 성장속도는 증가하였으며 트리형상의 복잡함, 즉 국부적인 트링열화의 정도는 인가전압이 감소하거나 온도가 증가한 경우에 높게 나타났다. 절연파괴 강도는 유리 전이온도 이상에서 급격히 감소하였다.

• The Korean Journal of Rheology
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• v.8 no.2
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• pp.92-102
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• 1996

두 종류의 열방성 액정고분자와 세종류의 엔지니어링 고분자와의 블렌드들에 대해 유변학적/형구학적 연구를 한 결과 블렌드의 유동거동과 물성이현저히 다른 두 그룹으로 나 뉘어짐을 발견하였다. 즉 연속상의 조업온도가 분산상의 전이온도보다 높은 그룹A에 속하 는 블렌드의 전단점도/신장점도는 액정고분자를 첨가할수록 첨가할수록 감소하고 블렌드의 신장점도는 연속상의 그것처럼 신장변형률속도가 커질수록 증가하였다. 또한 분산상의 점도 가 연속상의 그것보다 작아서 분산상이 미세섬유구조의 형태로 존재하였다. 이와 대조적으 로 연속상의 조업온도가 액정고분자의 전이온도보다 낮은 그룹 B에 속하는 블렌드는 반대 의 거동을 보였고 분산상의 미세섬유구조가 존재하지 않았다. 그러나 연신변형이 주가 되는 방사공정을 거치면 그룹A와 B블렌드 공히 분산상이 비슷한 미세섬유구조의 형태로 존재하 고 기계적 성질도 크게 향상되는 결과를 보였다. 이는 블렌드내의 신장유동이 분산상의 섬 유구조형상에 결정적 역할을 하기 때문이라 판단된다.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.741-744
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• 2008

Quality control of early age concrete significantly influences the long term performance. Primary factors for early age concrete quality control should include the relative humidity and temperature variation, and these are more important as structures become massive and huge. Temperature raise due to cement hydration causes stress, which can develop to cracking with internal and/or external restraints. Exposure conditions including ambient temperature, humidity and wind also significantly affect the cracking behavior of early age concrete. Among many of studies on the early age concrete behavior, investigation on the variation of temperature and relative humidity internal of concrete is not common. That is in part because the difficulties in measuring the relative humidity and temperature inside the concrete. This study used a digital sensor with an appropriate logger to measure internal temperature and relative humidity. This direct measuring method is expected to provide more reliable and comprehensive data acquisition on the early age behavior of concrete.