• Title/Summary/Keyword: 오염화학물질

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Effects of weir on the change of water quality (하천수계의 보가 수질에 미치는 영향 분석)

  • Cho, Yong-Chul;Ahn, Hong-Kyu;Woo, Hyo-Seop;Oh, Jong-Min
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.1033-1037
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    • 2007
  • 하천의 수위를 유지하거나 농업용수를 취수할 목적으로 현재 국내에 약 18,000개 정도의 크고 작은 보가설치되어 있다. 이러한 보 중에는 극히 일부에 어도와 같은 생태통로가 인위적으로 설치되어 있지만 전체적으로는 매우 미미한 수준이다. 더욱이 도시 인구 집중황 따른 도심부의 확대로 인한 농경지의 도시화, 경작 방식의 변화에 의한 논농사 위주에서 비닐하우스 단지로의 변화와 같은 토지이용의 변화, 대형 저수지의 축조/양수장 설치 등에 따른 취수 시설물의 통합, 시설의 노후화 등으로 매년 50-150개 정도의보가 폐기되고 있다. 그러나 이렇게 폐기되는 보는 하천에 그대로 방치되어 하천생태통로의 단절, 수질악화, 수변 서식처악화 등의 문제를 지속적으로 야기시키고 있다. 연구지역은 경기도 고양시 곡릉천 곡릉2보로 선정하여 보 철거전 과 보 철거 후의 모니터링을 통한 수질분석을 시행하였다. 곡릉2보는 과거 취수용 보로 이용되었으나 주변지역 토지이용 변화로 용도를 상실한 보이다. 보 철거 전에는 보로 인한 보 상류 지역에 퇴적물이 쌓이면서 정체구역이 생기고 부유물질이 많아지면서 수질 악화를 초래하는 것으로 나타났다. 그러나 보 철거 후에는 화학적으로 상류 하류지점에서 SS 및 BOD의 농도가 감소하여 전체적으로 수질향상에 기여한 것으로 나타났다. 보 철거에 따른 수질분석에 대한 연구는 아직 진행 단계에 머물러 있으며, 그 주변에 대한 상세한 이론은 아직 미미하다. 따라서 현재 국내외 보의 현황 및 보 철거 기술을 조사하고, 우리나라의 조건이 다른 보를 선정하여 하천의 보가 수질에 미치는 영향을 정량적으로 분석함으로써, 향후 우리나라의 보 관리방안의 방향을 제시하는데 도움이 되고자 한다.를 제시하고 있다. 미국의 경우는 이러한 가이드라인을 실제로 현장에 적용하고 있으며 조성효과가 정성적으로 검증되었고 정량적인 관계 도출을 위한 연구가 지속적으로 진행되고 있다. 국내의 경우 수질개선 및 생태서식처 조성, 하천환경을 개선하기 위한 관련 정책이 꾸준히 제시되고 있다. 한 예로 정부에서는 수변구역을 지정 고시하여 상수원으로 유입되는 비점오염물질을 저감하고 생태서식처를 조성함으로써 양질의 상수원과 건전한 생태계를 확보하기 위한 제도를 시행 중이다. 수변 구역의 범위는 한강수변구역의 경우 약 $500{\sim}1,000m$로 설정되어 있으나 아직까지는 관리적 성격이 강하며, 향후에는 구체적인 조성방안이 요구된다. 본 연구에서는 한강 수변구역 내에 미국의 가이드라인에서 제시하는 수변완충지대의 물리적 조건과 국내 지역 토착식생을 적용하여 시험완충지대를 조성하였고, 실험조건 하에서 그 효과를 정량적으로 분석 검증한 결과와 외국사례를 분석하여 국내여건에 맞는 수변완충지대 조성 가이드라인(안)을 제시하였다.EX>$\ulcorner$세종실록$\lrcorner$(世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와의 비교를 해보면 상 중 하품의 통합 9개소가 삭제되어 있고, $\ulcorner$동국여지승람$\lrcorner$(東國與地勝覽) 에서는 자기소와 도기소의 위치가 완전히 삭제되어 있다. 이러한 현상은 첫째, 15세기 중엽 경제적 태평과 함께 백자의 수요 생산이 증가하자 군신의 변별(辨別)과 사치를 이유로 강력하게 규제하여 백자의 확대와 발전에 걸

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Biochemical and Cytological Changes of Pseudomonas sp. DJ-12 Cells in Response to Catechol Treatment (Catechol 처리에 의한 Pseudomonas sp. DJ-12의 생화학 및 세포학적 변화)

  • 고연자;임재윤;김치경;이기성
    • Korean Journal of Microbiology
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    • v.35 no.2
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    • pp.139-145
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    • 1999
  • Aromatic hydrocarbons which are not easily degraded by microorganisms can be accumulated in the conlaminated environment for a long lime, producing toxic effects on wild lives and humans. However, the sublethal concentrations of the chemicals induce the synthesis of stress-shock proteins in the cells and increase the adaptability of the organisms to the environmental stresses. In this study, therefore, the cells of Psezido~nonus sp. DJ- 12 treated with catechol at various concentrations were inveshgated for their survival, biodegtadability of catechol, production of stress-shock proteins, and cytological changes. The organisms were capable of degrading catechol at the range of 0.5 to 1.0 mM concentration wilhin 6 hours incubation, but they were killed by $10^2$-10$^3$ celllinl at 3 mM or higel- concentration without any catechol degradation. These cells treated with catechol begm lo produce DnaK and GroEL at 1 mM and 0.5 mM. respectively. Pseudumonas sp. DJ-12 treated with 10 mM catechol for I hour exhihiled some punctuated pores on the cell wall and contortion of the rod shape. The cells treated with he sublethal concentration of catechol showed the increased tolerance for suvival when exposed to the lethal concentration, and such tolerant effects were functioned crossly among benzoate, 4-chlorobenzoate, 'and catechol.

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Investigation of Microbiological and Physiochemical Quality for Irrigation Water used in Napa Cabbage Cultivation (배추 재배에 이용되는 농업용수의 미생물 오염도 조사 및 이화학성분 분석)

  • Yun, Bohyun;Kim, Min Kyung;Ryu, Jin Hee;Kim, Won-Il;Park, Byeong-Yong;Kim, Hyun-Ju;Lee, Seung-Don;Kim, Se-Ri
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.396-403
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    • 2017
  • The purpose of this study was to investigate water quality for irrigation water used in Napa cabbage cultivation. The water samples were analyzed for physiochemical and microbiological quality for a total of 111 samples including surface water (n = 75) and groundwater (n = 36) collected from five different regions where Napa cabbage is massively grown. As a conclusion, the levels of fecal indicators for surface water were higher than those for groundwater. The numbers of coliform from surface water and groundwater were 1.96-4.96 and 0-3.98 log MPN/100 mL, respectively. Enterococci were detected in 95% (72/75) of surface water samples and 22% (8/36) of groundwater samples. Besides, 97% (73/75) of surface water samples were observed being contaminated with Escherichia coli, and 22% (8/36) of groundwater sample was positive for E. coli. In the case of surface water, E. coli and coliform correlate to T-P, and enterococci showed relevance to the suspended solid (SS) and biochemical oxygen demand (BOD). In groundwater, fecal indicator bacteria showed relevance to the SS and chemical oxygen demand (COD). These results could be provided as fundamental date for establishing microbial standard of water used in leafy vegetables cultivation.

Analysis of Surface Contaminants and Deterioration Degree on the Seated Stone Statue of Buddhist Master Seungga at Seunggasa Temple in Seoul, Korea (승가사 석조승가대사좌상의 손상도 및 표면오염물 분석)

  • Kim, Sung Han;Lee, Chan Hee;Naruto, Araki
    • Economic and Environmental Geology
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    • v.50 no.6
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    • pp.497-508
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    • 2017
  • This study was carried out to document and diagnose the conditions of the seated stone statue of Buddhist Master Seungga in Seunggasa temple immediately after its conservation treatment, which was found to be long covered in surface of white materials. The stone Halo was researched along with the Statue, and basic data was secured through precisely examination and nondestructive diagnosis. The result from the surface deterioration evaluation shows that both the Statue and Halo had a little bit of physical deterioration, although their level of chemical deterioration was proportionally higher due to discoloration. The physical property diagnosis using ultrasonic measurements on the Statue and Halo showed that the average ultrasonic velocity was found to be 3,570 m/s and 3,373 m/s, respectively, which corresponds to grade III, an indication of a favorable physical property. The surface covered materials were detected to be Ca, Ti, Pb, Fe, Al and Si, emanating from Hobun (Oster shell powder; $CaCO_3$) or lime ($CaO{\cdot}Ca(OH)_2$) and silicate minerals. Furthermore, Ti and Pb seems to be the component of the white coloring pigments, titanium white ($TiO_2$) and white lead ($2PbCO_2{\cdot}Pb(OH)_2$). Therefore, the seated stone statue of Buddhist Master Seungga is presumed to be painted with Hobun or lime and thereafter painted over with titanium white and white lead.

Essential Oil Isolated from Iranian Yarrow as a Bio-rational Agent to the Management of Saw-toothed Grain Beetle, Oryzaephilus surinamensis (L.) (머리대장가는납작벌레의 합리적 방제 물질로 이란 서양가새풀 정유의 살충효과 평가)

  • Ebadollahi, Asgar
    • Korean journal of applied entomology
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    • v.56 no.4
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    • pp.395-402
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    • 2017
  • Overuse of synthetic pesticides caused negative side-effects such as environmental contamination, development of insect pests' resistance, and effects on non-target organisms. Plant origin substances without/or with low mammalian toxicity have been considered as promising alternatives to the synthetic pesticides. Fumigant toxicity of the essential oil of Iranian Yarrow, Achillea millefolium L., was investigated against a cosmopolitan stored-product insect pest: saw-toothed grain beetle (Oryzaephilus surinamensis L.). Chemical profile of this essential oil was studied by Gas Chromatography-Mass Spectrometry. Tested concentrations were significantly effective to the mortality of insect pest. A positive correlation between essential oil concentrations and pest mortality were realized. LC50 value (lethal concentration needed to 50% mortality) was achieved as $17.977(16.195{\pm}20.433){\mu}l/l$ air. The main components were 1,8-Cineole (13.17%), nerolidol (12.87%), ${\alpha}$-cubebene (12.35%), artemisia ketone (6.69%), ${\alpha}$-terpineol (5.27%), alloaromadendrene oxide (4.71%) and borneol (3.99%). Terpenic compounds including monoterpene hydrocarbons (8.19%), monoterpenoids (44.23%), sesquiterpene hydrocarbons (21.69%) and sesquiterpenoids (22.24%) were 96.35% of the total identified compounds. Results indicated that the terpene-rich A. millefolium essential oil may be considered as a safe bio-agent in the O. surinamensis management.

Electrochemical Treatment of Dyeing Wastewater using Insoluble Catalyst Electrode (불용성 촉매전극을 이용한 염색폐수의 전기화학적 처리)

  • Um, Myeong-Heon;Ha, Bum-Yong;Kang, Hak-Chul
    • Clean Technology
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    • v.9 no.3
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    • pp.133-144
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    • 2003
  • In this study, Insoluble catalyst electrode for oxide systems were manufactured, by using of them, carried out experiments on electrolytic treatment of dyeing wastewater containing persistent organic compounds, and then made a comparative study of the efficiency of treatment for environmental pollutants and whether each of them is valuable of not as an electrode for soluble electrode(Fe, Al) and insoluble electrode(SUS, R.C.E; Replaced Catalyst Electrode) which were used in the electrolytic system. Besides, it was investigated the conditions for electrolytic treatment to find the maximum efficiency of electrolytic treatment. As the result of this study, by using of insoluble catalyst electrode for oxide can solved the stability of electrode that is one of the greatest problems in order to put to practical use of electrolysis process in the treatment of the sewage and wastewater and the result runs as follows; 1. The durability of insoluble catalyst electrode(R.C.E) can be verified the most favorable when the molar ratio of $RuO_2-SnO_2-IrO_2-TiO_2$(4 compounds system) is 70/20/5/5. 2. The efficiency of treatment was obtained a more than 90% goodness for CODMn and also a good results for T-N removal in the experimental conditions of the distance of electrode 5 mm, time of electrolysis 60 minutes, permissible voltage 10V, processing capacity $0.5{\ell}$.

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Characteristics of Wastewater from the Pulp.Paper Industry and its Biological Treatment Technologies (펄프.제지산업(製紙産業) 폐수(廢水)의 특성(特性)과 생물학적(生物學的) 처리기술(處理技術))

  • Abn, Ji-Whan;Lim, Mi-Hee
    • Resources Recycling
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    • v.18 no.2
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    • pp.16-29
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    • 2009
  • This paper describes characteristics of pollutants in wastewater from the pulp and paper industry and biological technologies for the wastewater treatment. The wastewater from the pulp and paper industry contains high concentrations of biochemical oxygen demand (BOD) and chemical oxygen demand (COD) and shows high toxicity and strong black-brown color. In particular, organic chlorinated compounds such as dioxins and furans may be formed by the chlorination of lignin in wood chips. Thus the pulp and paper industry is recently trending toward total chlorine-free (TCF) bleaching processes. All biological technologies for pulp and paper wastewater treatment are based on the contact between wastewater and bacteria, which feed on organic materials in the wastewater, thus they reduce BOD concentration in it. Both aerobic and anaerobic treatments were found to be effective for the wastewater treatment. Furthermore, advanced technologies such as fungal application and combined biological-filtration process have been also introduced to the wastewater treatment field. These technologies would be useful for water recycling to reduce water consumption throughout pulp and paper making process.

Organic Matter and Nutrient Budget of Constructed Tidal Flat in Gapo Area of the Masan Bay, Korea (마산만 가포지역 인공갯벌의 유기물 및 영양염 수지)

  • 안순모;백봉주
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.4
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    • pp.411-419
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    • 2003
  • Dredged material during Masan Bay cleaning in 1990-1994 was deposited in Gapo area. The site provides an ideal experimental condition to monitor environmental remediation and benthic ecosystem stabilization processes after the disturbance. Sea water samples were taken during one tidal cycle in one hour interval from Oct. 2001 to Apr. 2002 (4 times) to estimate the organic matter and nutrient fluxes in Gapo area. Hourly material fluxes were estimated from the water balance estimated from 3 dimensional topography of Gapo area and from material concentration. Net material fluxes were estimated from the difference between total influx and total outflux during one tidal cycle. Chemical oxygen demand showed net outflux in Nov. 2001, Dec. 2001 and Apr. 2002 (2.2∼3.9 g m$\^$-2/ h$\^$-1/) and showed net influx in Mar. 2002 (1.4 g m$\^$-2/ h$\^$-1/). Ammonium showed net outflux during the study (0.1∼118 mg m$\^$-2/ h$\^$-1/m-2h-I). According to this investigation, Gapo area was a source rather than a sink of organic matter. However, the variability of the material fluxes was high so that a long term study may be required.

Analysis of Fish Guild Compositions and Total Mercury Contents of Fish Tissues in Analysis in Mangyeong River. (만경강 중.상류의 어류 길드특성 및 어류 조직내 수은 함량 분석)

  • Park, Hyang-Mi;Lee, Eui-Haeng;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.172-182
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    • 2009
  • This study was to analyze characteristics based on tolerance and trophic guilds and to determine the level of total mercury in tissues of sentinel species, Zacco platypus at 3 sampling sites of the Mangyeong River in 2007. Total sampled fishes were 26 species and the most dominant species was Zacco temminckii (47%). Fish community analysis was resulted that eveness index and diversity index showed low value at S1. However, diversity index and richness index at other sites showed high. According to various guilds analysis, relative abundance of sensitive species was 70% and 42% at S1 and S2, respectively. While sensitive species were decreased (1%) and tolerant species were increased (60%) at S3. It was mainly carried to the impacts of wastewater treatment plants near the location. Relative abundance of insectivore species was decreased from up (S1) to midstream area (S3). In addition, chemical water quality, based on analyses of BOD, COD, TP, TN, EC, MPN and SS concentration showed similar trends. Qualitative Habitat Evaluation Index (QHEI) was averaged 164, judged as "good" habitat condition. Average concentrations of total [Hg] was 146.9 ${\mu}g$ $kg^{-1}$. In the muscles of total [Hg] was the highest, and then followed by kidney, vertebrae, liver, and gills. According to FDA standards (500 ${\mu}g$ $kg^{-1}$) of Korea, total [Hg] has not affected to the individual fish health.

The History and Development of the Marine Environment QA/QC (Quality Assurance/Quality Control) Management System (해양환경 정도관리제도 운영에 대한 고찰)

  • PARK, MI-OK;PARK, JUN-KUN;KIM, SEONG-GIL;KIM, SEONG-SOO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.3
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    • pp.185-200
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    • 2021
  • The Marine Environment QA/QC management system has been operated since 2010 to secure the reliability of data and improve the analysis capabilities of measurement and analysis institutions. From 2010 to 2020, the cumulative number of measurement and analysis institutions participated in the QA/QC management system was 266. And the number of certificates issued by the ministry of oceans and fisheries is 182. A total of 32 reference materials for proficiency testing and interlaboratory comparisons have been developed. They were first developed focusing on items (Nutrients, COD) commonly analyzed in marine environmental measuring network, marine pollution impact surveys, sea area utilization impact assessment, deepsea water surveys, and information network on fishing ground environments. In addition, it is time to expand the filed of the QA/QC management system, such as seawater temperature, salinity, PCBs and PAHs in sediments, which are mainly analyzed in most monitoring programs. On-site assessment has been conducted for 162 laboratories according to ISO/IEC 17025 to evaluate their conformity of the quality management system and deficiency. In terms of management and technology requirements, about 4.2% of organizations showed insufficient division of duties among employees 8.7% of them revealed the lack of employee training. By test item, about 6.3% of organizations showed the lack of standard substance management and the state of the cleaning glassware was pointed out in about 5.4% of them. The QA/QC management system should be continuously supplemented by identifying the causes of nonconformities and area for improvement.