• Title/Summary/Keyword: 오염원소

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방사성 피부오염의 제염법에 관한 연구 (I)

  • 전제근;지평국;안병길;박종묵
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05d
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    • pp.113-117
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    • 1996
  • 원자력시설 및 동위원소 이용기관에서의 인체오염사고에 대비하여, 피부제염기준을 조사하였으며, 피부제염제의 개발을 위하여 실험용 쥐를 대상으로 Co-60 및 Cs-137에 대해 비눗물, EDTA 및 KAERI-CON의 제염효과를 비교하였으며, 가장 효율적인 제염방법을 제시하였다. 각 제염제의 제염실험결과 Co-60 보다 Cs-137에 대한 제염이 더 잘 이루어졌으며, 제염횟수의 증가에 따라 방사능잔류율도 급격히 낮아졌다. KAERI-CON은 Co-60의 경우 38-55%, Cs-137의 경우에는 44-50%까지 제염효율을 보임으로서 타 제염제보다 효과적임을 확인하였다.

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삼중수소 제거공정 모델링 및 정밀 모사

  • 금충기;정홍석;이한수;송명재;손순환
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.859-864
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    • 1995
  • 중수형발전로의 가동에 따라 중수는 삼중수소로 오염된다 오염된 중수의 정화에 적합한 공정으로 평가되는 기액촉매교환과 초저온증류공정으로 이루어진 촉매복합공정에 대하여 탑내의 유속비 및 이론단수의 변화에 따른 촉매탑과 증류탑에서의 삼중수소 제거율 및 농축률 그리고 탑내의 수소동위원소의 농도분포변화를 Newton-Raphson 방법을 사용하여 전산모사를 수행하여 구하였다. 이러한 해석은 본격적 최적화 설계의 기초입력자료로 활용될 것이다.

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A Comparative Assessment of INAA and ICP-MS for the Analysis of Airborne Trace Elements (대기입자 중 미량원소의 중성자방사화분석과 유도결합프라즈마분광법의 비교평가)

  • 이현석;임종명;장미숙;이진홍;문종화;정용삼
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.239-240
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    • 2002
  • 유해 대기오염물질에 대한 수용 모델링을 위해 대규모의 분진시료에 대한 분석이 필수적이나 현재로서는 미미한 실정이다. 대규모의 분진시료를 대상으로 미량금속을 분석하기 위해 기존 국내 연구에서 사용된 XRF, ICP-AES, PLXE 분석법 대신 검출 한계가 매우 낮고 재현성이 뛰어난 중성자 방사화 분석법(INAA)과 플라스마 분광법(ICP-MS)을 이용하여 대기오염분야에의 적용성을 평가하는 것은 매우 유용한 연구일 것으로 판단된다. (중략)

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보은제일탄광 수계에 분포하는 수질과 토양의 오염도 평가

  • 김기중;이찬희;이현구
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.223-225
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    • 2003
  • 충북 보은군 회남면 조곡리와 분저리 일대에는 옥천누층군의 변성퇴적암에 속하는 문주리층, 창리층, 황강리층 및 국사봉층이 분포한다. 특히 국사봉층에는 모암의 주향연장을 따라 3~6매의 저품위 탄층이 단속적으로 배태되어 있어, 이를 대상으로 개발되었던 한도탄광, 부국탄광, 삼성제일탄광 및 보은제일탄광이 있다. 각각의 탄광주변에는 탄층을 따라 노두의 여러 곳에 갱도와 지표 채굴적이 산재한다. 노두에서 관찰되는 탄층은 수직 20 m 내외에서 10~300 cm의 폭을 보이나 대부분 100 cm 미만이다. (중략)

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First GC-IRMS in Korea and Its Application Fields (국내 최초로 도입된 GC-IRMS와 응용분야 소개)

  • Shin, Woo-Jin;Lee, Kwang-Sik;Ko, Kyung-Seok
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.699-703
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    • 2007
  • Compound-specific isotope analysis (CSIA) by isotope ratio mass spectrometer (IRMS) interfaced with gas chromatography (GC) is a state of the art analytical technique for stable isotopes in earth sciences, environmental sciences and forensics. Since early 1990s, GC-IRMS has been widely used to investigate the authenticity of food in forensic science and to trace the sources of organic contaminants in environmental science. In Korea, a GC-IRMS was firstly installed at the Korea Basic Science Institute (KBSI) in early 2005. In this study, we introduce the GC-IRMS of the KBSI shortly to stimulate various isotope-related researches of Korea, and report preliminary CSIA results for BTEX of different manufacturers.

Pollution Characteristics of Hazardous Elements for Roadside Dust in Gwangju City, Korea (광주광역시 도로변 분진에 대한 유해원소의 오염특성)

  • Lee, Jang-Jon;Park, Young-Seog;Kim, Jong-Kyun;Han, Min-Su
    • Economic and Environmental Geology
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    • v.40 no.3 s.184
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    • pp.263-275
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    • 2007
  • The purpose of this study was to show the pollution characteristics of hazardous elements from roadside dust in the Gwangju city. We collected 47 samples from November to December in 2004 and separated four groups such as residential area, industrialized area, downtown area and heavy traffic area fer characteristics comparison on hazardous elements. Roadside dust mostly consisted of quartz, albite, microcline, muscovite in XRD analysis. Content of hazardous elements varied: As $3.4{\sim}11.9 ppm$, Cd $0.2{\sim}28.2 ppm$, Co $32{\sim}526 ppm$, Cr $25{\sim}526 ppm$, Cu $11{\sim}375 ppm$, Ni $14{\sim}247 ppm$, Pb $13{\sim}413 ppm$ and Zn $101{\sim}972 ppm$. Average contents of hazardous elements of Zn>Cu>Pb>Cr>Co>Ni>Cd. Content of hazardous elements was low in residential area, whereas that of heavy metal was much the same in both in heavy traffic area. Content of hazardous elements such as Cd, Co, Cr, Cu, Ni, Pb, Zn was found to be particularly high in industrialized area. According to these results it was possible to presume that industrialized area was affected by industry activity such as machinery, petrochemical, automobile and electronics industry. The SEM analysis, detected Pb, Cr, Ni, and Fe particles in samples of industrialized area contaminated by industry activity. The correlation coefficient table resulted from the samples of roadside dust showed that there was same direction increase of content between elements. In other words, when the content of Cd increase, Cr and Ni increase, as Cr increase, Cu and Ni increase, as Cu increase Ni increase and Pb increase Zn increase. Based on these results it was possible to predict and interpret similar contamination patterns in this study.

Heavy Metal Contamination around the Abandoned Au-Ag and Base Metal Mine Sites in Korea (국내 전형적 금은 및 비(base)금속 폐광산지역의 중금속 오염특성)

  • Chon Hyo-Taek;Ahn Joo Sung;Jung Myung Chae
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.101-111
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    • 2005
  • The objectives of this study we to assess the extent and degree of environmental contamination and to draw general conclusions on the fate of toxic elements derived from mining activities in Korea. 인t abandoned mines with four base-metal mines and four Au-Ag mines were selected and the results of environmental surveys in those areas were discussed. In the base-metal mining areas, the Sambo Pb-Zn-barite, the Shinyemi Pb-Zn-Fe, the Geodo Cu-Fe and the Shiheung Cu-Pb-Zn mine, significant levels of Cd, Cu, Pb and Zn were found in mine dump soils developed over mine waste materials, tailings and slag. Furthermore, agricultural soils, stream sediments and stream water near the mines were severely contaminated by the metals mainly due to the continuing dispersion downstream and downslope from the sites, which was controlled by the feature of geography, prevailing wind directions and the distance from the mine. In e Au-Ag mining areas, the Kubong, the Samkwang, the Keumwang and the Kilkok mines, elevated levels of As, Cd, Cu, Pb and Zn were found in tailings and mine dump soils. These levels may have caused increased concentrations of those elements in stream sediments and waters due to direct dis-charge downstream from tailings and mine dumps. In the Au-Ag mines, As would be the most characteristic contaminant in the nearby environment. Arsenic and heavy metals were found to be mainly associated with sulfide gangue minerals, and mobility of these metals would be enhanced by the effect of oxidation. According to sequential extraction of metals in soils, most heavy metals were identified as non-residual chemical forms, and those are very susceptible to the change of ambient conditions of a nearby environment. As application of pollution index (PI), giving data on multi-element contamination in soils, over 1.0 value of the PI was found in soils sampled at and around the mining areas.

Trace Elements and Source Assessment of Street Dust in Daegu, Korea (대구지역 도로먼지에 함유된 미량원소성분과 오염원 평가)

  • Song, Hee-Bong;Lee, Eun-Young;Do, Hwa-Seok;Jung, Cheol-Su;Shin, Dong-Chan;Lee, Myoung-Sook;Paek, Yoon-Kyoung;Jeon, Seong-Suk;Shin, Won-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.7
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    • pp.793-800
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    • 2007
  • A total of 48 samples of street dust were collected in Daegu area during April and May 2006, were sieved below 100 ${\mu}m$, and analysed by ICP for the analysis of 14 elements after an acid extraction. Results obtained from the source assessment of trace elements using enrichment factor showed that Ca, Fe, K, Mg, Mn, Na and V were influenced by natural sources such as soil and dust, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by urban anthropogenic sources such as fuel combustion and waste incineration. The measured values were remarkably higher in components from natural sources than in components from urban anthropogenic sources. The concentrations of trace elements in Daegu area were generally higher than in other foreign cities. Samples originated from industrial and commercial areas had higher concentrations of trace elements and pollution indices of heavy metals than those from residential and green areas. The correlation analysis among trace elements indicated that the correlations among components from urban anthropogenic sources were much significant, while those among components from natural sources were less correlated. In addition there were significant correlations between traffic density and components from urban anthropogenic sources.

Preliminary study on geochemical elements concentration changes in coral skeleton from Chuuk, Micronesia (마이크로네시아 축 경산호 골격의 지화학 원소 농도에 대한 예비연구)

  • Hyun, Sang-Min;Park, Heung-Sik;Kim, Su-Hyun;Kim, Han-Jun;Jang, Suk
    • The Korean Journal of Quaternary Research
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    • v.22 no.1
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    • pp.1-12
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    • 2008
  • We investigated metal concentrations and oceanic environment changes that have occurred over the past several years by studying the hard coral Porites lutea, which inhabits tropical and subtropical areas. Soft X-radiographs clearly showed distinctive annual bands within 71 mm coral sample, which reflect changes in the oceanic environment over this period. There were large fluctuations in the major and minor element concentrations. Considering the physicochemical partition coefficient, some elements accumulated in the aragonite matrix in a mechanical manner, while others were affected by environmental factors. The concentrations of some heavy metals varied over a wide range, implying local environmental effects. The variation of Sr/Ca and Mg/Ca in coral skeleton clearly showed large-scale fluctuation over the specific intervals, implying environmental changes during this period. The concentrations of heavy metals also show high fluctuations, and roughly accord with Mg/Ca variation. In addition, Cu and Zn seem to show cyclicity-like peaks, coincide with Mg/Ca variation over the specific intervals. Such variation might be related to local pollution and oceanographic changes. More detailed investigation is necessary, including the pretreatment of coral skeleton sediment.

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Trace Element Analysis and Source Assessment of Parking Lot Dust in Large Shopping Mall (대형유통업소주차장의 축적먼지 중 미량원소성분 분석과 오염원 평가)

  • Song, Hee-Bong;Ahn, Jeong-Eem;Jung, Yeoun-Wook;Yoon, Ho-Suk;Keum, Jong-Lok;Do, Hwa-Seok;Kim, Sun-Suk;Kim, Jong-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.168-176
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    • 2012
  • A total of 48 dust samples were collected from large shopping mall parking lots in Daegu metropolitan city in March 2011. Samples were sieved through a 100 ${\mu}m$ mesh and the concentration of 14 elements have been determined using by ICP after acid extraction. Results showed that Ca, Fe, K, Mg, Mn, Na and V were affected by natural sources while Cd, Cr, Cu, Ni, Pb and Zn were affected by anthropogenic sources. The measured values were remarkably higher in components from natural sources than in components from anthropogenic sources. Anthropogenic trace element concentrations of ground roof dust were higher than those of ground and underground indoor dust. A large percentage of trace elements came from natural sources rather than anthropogenic sources. The percentage composition of chemicals of ground roof dust were higher than those of ground and underground indoor dust. This study showed that investigated parking lots were rarely contaminated with hazardous heavy metals. The heavy metal pollution of ground roof were higher than those of ground and underground indoors. The correlation analysis among trace elements suggest that components in ground roof were more highly correlated than those in ground and underground indoor. Also anthropogenic trace element levels were well correlated with parking lot age and parking density.