• Title/Summary/Keyword: 오염수 측정

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A Study on the Amount and Major Compositions of Excreta from Broilers (육계의 분뇨 배설량 및 분뇨 성분 조사 결과)

  • HwangBo, J.;Hong, E.C.;Chung, I.B.;Kang, K.H.;Park, H.D.;Suh, O.S.;Chung, W.T.;Jang, S.K.
    • Korean Journal of Poultry Science
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    • v.36 no.2
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    • pp.157-163
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    • 2009
  • This work was conducted to investigate the amount and major compositions of excreta from broilers. One hundred fifty 1-d-old male and female Ross broilers were used in this work and ten broilers were selected to measure excreta. Average amount of excreta per broiler was 85.4 g, and average moisture content was 76.9%. N, $P_2O_5$ and $K_2O$ in excreta were 1.19, 0.29 and 0.49%, respectively. pH, $BOD_5$, $COD_{mn}$, and SS were 7.80, 42,134 mg/L, 52,668 mg/L, and 106,669 mg/L, respectively. Pb in poultry excreta was 0.803 mg/kg and highly lowed compared with the standard contents (150 mg/kg). Cd was not founded in excreta. Hg was founded in excreta as 0.002 mg/kg, but it was low compared with the standard level (2 mg/kg).

Characterization of Behavior of Colloidal Zero-Valent Iron and Magnetite in Aqueous Environment (나노크기의 교질상 영가철 및 자철석에 대한 수용상의 거동특성)

  • Lee, Woo Chun;Kim, Soon-Oh;Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.2
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    • pp.95-108
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    • 2015
  • Nano-sized iron colloids are formed as acid mine drainage is exposed to surface environments and is introduced into surrounding water bodies. These iron nanomaterials invoke aesthetic contamination as well as adverse effects on aqueous ecosystems. In order to control them, the characteristics of their behaviour should be understood first, but the cumulative research outputs up to now are much less than the expected. Using zero-valent iron (ZVI) and magnetite, this study aims to investigate the behaviour of iron nanomaterials according to the change in the composition and pH of background electrolyte and the concentration of natural organic matter (NOM). The size and surface zeta potential of iron nanomaterials were measured using dynamic light scattering. Characteristic behaviour, such as aggregation and dispersion was compared each other based on the DLVO (Derjaguin, Landau, Verwey, and Overbeek) theory. Whereas iron nanomaterials showed a strong tendency of aggregation at the pH near point of zero charge (PZC) due to electrostatic attraction between particles, their dispersions became dominant at the pH which was higher or lower than PZC. In addition, the behaviour of iron nanomaterials was likely to be more significantly influenced by cations than anions in the electrolyte solutions. Particularly, it was observed that divalent cation influenced more effectively than monovalent cation in electrostatic attraction and repulsion between particles. It was also confirmed that the NOM enhanced the dispersion nanomaterials with increasing the negative charge of nanomaterials by coating on their surface. Under identical conditions, ZVI aggregated more easily than magnetite, and which would be attributed to the lower stability and larger reactivity of ZVI.

Evaluation of Groundwater Quality in Northern Bangladesh for Irrigation, Drinking and Industrial Uses (북부 방글라데시에서 관개, 음용 및 공업용수로 사용되는 지하수의 수질)

  • Islam, Jahidul Mohammad;Laiju, Nahida;Nasirullah, Tarek;Miah, Nuruddin Mohammad;Owen, Jeffrey S.;Kim, Bom-Chul
    • Journal of Environmental Impact Assessment
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    • v.19 no.3
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    • pp.281-296
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    • 2010
  • 방그라데시 북부에 위치한 풀바리 우파질라 지역의 지하수에서 pH, EC, 주요 양이온 ($Ca^{2+}$, $Mg^{2+}$, $Na^+$, $K^+$, $Zn^{2+}$, $Cu^{2+}$, $Mn^{2+}$, $Fe^{3+}$, and $As^{3+}$), 주요 음이온 (${CO_3}^{2-}$, $HCO_3{^-}$, $NO_3{^-}$, ${SO_4}^{2-}$ and $Cl^-$) 그리고 total dissolved solids (TDS) 등의 용존물질 함량을 측정하였다. 또한 sodium adsorption ratio (SAR), soluble sodium percentage (SSP), residual sodium carbonate (RSC), 경도 등의 지표도 계산하였다. 전체적으로 지하수의 pH는 약알칼리성 (6.24 - 8.10)을 띄었으며, 주요 양이온은 $Ca^{2+}$, $Mg^{2+}$ and $Na^+$ 이었고, 주요 음이온은 $HCO_3{^-}$ and $Cl^-$ 으로서 전형적인 담수의 이온조성을 보였다. $Cu^{2+}$, $Mn^{2+}$ and $Fe^{3+}$ 의 최대 농도는 각각 1.71, 0.606, 0.125 mg/L 이었다. 방글라데시의 여러 지역에서는 비소에 의한 지하수의 오염이 흔히 나 타나고 있으나 이지역에서 비소의 최대농도가 0.41 mg/L로서 기준치인 0.05 mg/L 보다 낮은 오 염도를 보였다. TDS와 SAR, SSP 등으로 볼 때 이 지역의 지하수는 대부분 양호한 수질을 가지는 담수인 것으로 평가된다. $As^{3+}$, $Zn^{2+}$, $Mn^{2+}$, $Fe^{3+}$, ${SO_4}^{2-}$, $NO_3{^-}$ and $Cl^-$ 등의 농도는 음용수로 적합한 수준이었으나 일부 항목은 특정 산업용도로는 부적합한 농도를 보였다. 현재로서는 이지역 의 지하수는 대부분 음용이 가능하고 일부 산업용에 대해서만 부적합성을 보였다. 그러나 앞으로 지 하수의 이용과 산업활동이 증가하면 방글라데시의 많은 다른 지역의 지하수에서 발생한 사례와 같 이 용존물질의 농도가 증가하여 물의 용도에 제한을 받게 될 우려가 있다.

Increase of Electrokinetic Soil Remediation Efficiency using Ethanoic Buffer (초산완충액에 의한 동전기적 토양복원 효과 증진 연구)

  • Kim, Gye-Nam;Oh, Won-Zin
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2007-2016
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    • 2000
  • After kaolin clay was compulsorily contaminated with $Sr^{2+}$ ion. the remediation characteristics by electrokinetic method were analyzed. In the first experiment. NaCl solution was used as an electrolyte to raise the electric field strength. After remediation for 0.8 days. the pH of the cathode side of the soil column was elevated from 4.0 to 11.7. and thereby precipitation $Sr(OH)_2$, started to be formed in the side. Therefore. efficiency of soil remediation was reduced significantly and the 32% of total $Sr^{2+}$ ion in the column was decontaminated in 6.7 days. In the second experiment. ethanoic buffer was injected in the soil column and $CH_3COOH$ was continuously inputted in cathode reservoir to restrain the pH elevation. The pH of the cathode side of the soil column was only ascended from 4.0 to 6.0 in 3.8 days and $Sr(OH)_2$ was not formed. The 21% of total $Sr^{2+}$ in the soil column was decontaminated in 0.6 days. and the 33% of total $Sr^{2+}$ in 0.9 days. and the 84% of total $Sr^{2+}$ in 1.6 days. and the 92% of total $Sr^{2+}$ in 2.5 days. and the 97% of total $Sr^{2+}$ in 3.8 days. Meanwhile. the residual concentrations in the column calculated by the developed model were similar to those by experiment.

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A Sensitivity Analysis of Cell Size on a Distributed Non-Point Source Pollution Model (분산형 비점오염원 모델에서 단위유역 크기의 민감도 분석)

  • Bae, In-Hee;Park, Jung-Eun;Park, Seok-Soon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.952-957
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    • 2005
  • A sensitivity analysis study was performed to examine the effects of cell size on a distributed non-point source pollution model. The model, AnnAGNPS, whiff is a modified version of USDA's AGNPS, was applied to Eung stream watershed, a tributary of Cheongmi stream located in the South Branch of Han River System. The model components and results, such as channel length, slope, land use, and delivery ratio, were analyzed according to the various cell sizes from 10 to 200 ha. As cell sire increases, channel length decreases due to short-circuiting of meandering creek. The decreased channel length has more significant effects on the model results than any other geomorphological change. When the effects of land use and soil distribution are excluded, sediment delivery loads increase due to shorter time to reach the outlet of the watershed in larger tell size. When those effects are included, however, sediment delivery loads decrease in larger fell size because the variety of land use types can not be inputted. The predominant land use in the applied watershed is forest with very low soil erosion such that the predicted sediment delivery might be much lower than real system. The cell size of 30 ha was determined to produce the most appropriate resolution. Surface runoff and non-point source loads of TN, TP and BOD were predicted and the results agree well with the field measurements. From this study, it was shown that the model results would be very dependent on variations of topography, land use, and soil distribution, as a function of cell size, and the optimum cell size is very important for successful application of distributed non-point source pollution model.

Estimating the Global Inflow and Stock of Plastic Marine Debris Using Material Flow Analysis: a Preliminary Approach (물질흐름분석을 활용한 전세계 플라스틱 해양쓰레기의 유입량과 현존량 추정: 예비적 접근)

  • Jang, Yong Chang;Lee, Jongmyoung;Hong, Sunwook;Choi, Hyun Woo;Shim, Won Joon;Hong, Su Yeon
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.18 no.4
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    • pp.263-273
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    • 2015
  • We estimated the global inflow and stock of plastic marine debris. In South Korea, we estimated that the annual inflow of plastic marine debris (72,956 tons) was about 1.4% of annual plastics consumption (5.2 million tons) in 2012. By applying this 1.4% ratio to global plastics production from 1950 to 2013, we estimated that 4.2 million tons of plastic debris entered the ocean in 2013 and that there is a stock of 86 million tons of plastic marine debris as of the end of 2013, assuming zero outflow. In addition, with a logistic model, if 4% of petroleum is turned into plastics, the final stock of plastic marine debris shall be 199 million tons at the end. As the inflow and the stock are different units of measurement, better indicators to assess the effectiveness of inflow-reducing policies are needed. And, as the pollution from plastic marine debris is almost irreversible, countermeasures to prevent it should be valued more, and stronger preventive measures should be taken under the precautionary principle. As this is a preliminary study based on limited information, further research is needed to clarify the tendency of inflow and stock of plastic marine debris.

A Study on the Possibility of Using of Spent RHDS Catalyst as a SCR Catalyst wash-coated on the metal corrugated substrate (폐 RHDS 촉매재생 후 메탈 코로게이트 지지체상에서 워시코팅에 의한 NOx 저감 SCR 촉매에 관한 연구)

  • Na, Woo-jin;Cha, Eunji;Kang, Dae-hwan;Go, Young-ju;Cho, Ye-ji;Choi, Eun-young;Park, Hea-Kyung
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.4
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    • pp.723-732
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    • 2020
  • The spent RHDS (Residue HydroDeSulfurization) catalyst is deactivated mainly by deposition of various contaminants such as coke, sulfur and vanadium on the surface of catalyst. To eliminate those contaminants, the following remanufacturing process was conducted. The first, heavy oil on the surface of the spent RHDS catalyst was removed by kerosene and dehydrated. The second, the high temperature incineration was carried out to eliminate coke and sulfur components deposited on the surface of spent RHDS catalyst. The third, the excessive quantity of Vanadium deposited on the surface of catalyst was removed by leaching process as follows: ultrasonic agitation was carried out at 50℃, for 10 seconds with 0.5% and 1% oxalic acid solution. The purpose of this process is to find out regenerated RHDS catalyst can be used as SCR catalyst for NOx reduction by controlling the vanadium residual content of the regenerated RHDS catalyst through leaching process. The composition of regenerated RHDS catalyst was analyzed by XRF and the NOx reduction efficiency was also measured by continuous catalytic fixed bed reactor. As the result, regenerated catalyst, with 0.5% oxalic acid, ultrasonic agitation in 10 seconds, showed the most stable NOx reduction efficiency. Also, in comparison with commercial SCR catalyst, the NOx reduction performance of regenerated catalyst was similar to that of commercial SCR catalyst at the temperature 375℃ and higher whereas was lower than commercial SCR catalyst at the temperature range between 200~250℃. Therefore, it was confirmed that the regenerated catalyst as powder form wash coated on the surface of metal corrugated substrate can be used for commercial SCR catalyst.

A Study on the Development and Application of Perilla Oil Based Compound Wax Agent for Preserving Outdoor Metal Sculpture: A Case Study on Iron Sculptures (들기름 기반 야외 금속 조형물 보존용 혼합 Wax의 개발 및 적용성에 관한 연구: 철제 조형물 중심으로)

  • Oh, Seung-Jun;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.33 no.2
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    • pp.121-130
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    • 2017
  • The currently used wax agents for preserving outdoor metal structures, despite their advantages, have disadvantages such as low endurance and reliability. These wax agents are easily damaged by acid rain, dust, moisture in the air, yellow dust, and air pollutants, resulting in corrosion within a short period after the initial conservation treatment. In addition, aged wax can also exhibit changes in the color or gloss, and also give a sense of difference in the surface. Given these existing problems, it is necessary to develop improved materials for metal preservation. Therefore, this study analyzed the characteristics and applications of the existing wax coating agents in order to identify their disadvantages and to develop a better material for metal preservation. In this regard, this study developed a perilla oil based compound wax and conducted experiments to test its endurance. The new compound wax agent was exposed to outdoor and acid rain conditions: it showed four times and 1.5 times the endurance of the existing wax agents in outdoor and acid rain conditions, respectively. In addition, the new agent seems to be more durable and protective as evidenced by the chromaticity, polish maintenance, and contact angle results. Further, although it is 1.3-1.8 times thicker than the existing agents, the new agent shows a more even surface. Based on these findings, it can be concluded that the new compound wax agent based on perilla oil is a better alternative to the existing was coating agents.

Treatment of Wastewater Containing Cu(II)-EDTA Using Ferrate in Sequencing Batch Scale System (연속회분식 반응 장치에서 Ferrate를 이용한 Cu(II)-EDTA 함유 폐수 처리 연구)

  • Kim, Hyoung-Uk;Kim, Byeong-Kwon;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook;Kwan, Jung-An;Im, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.729-734
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    • 2008
  • The higher valence state of iron i.e., Fe(VI) was employed for the treatment of Cu(II)-EDTA in the aqueous/waste waters. The ferrate(VI) was prepared through wet oxidation of Fe(III) by sodium hypochlorite. The purity of prepared Fe(VI) was above 93%. The stability of Fe(VI) solution decreased as solution pH decreased through self decomposition. The reduction of Fe(VI) was obtained by using the UV-Visible measurements. The dissociation of Cu(II)-EDTA complex through oxidation of EDTA using Fe(VI) and subsequent treatment of organic matter and metal ions by Fe(III) reduced from Fe(VI) in bench-scale of continuous flow reactor were studied. The removal efficiencies of copper were 69% and 79% in pH control basin and reactor, respectively, at 120 minutes as retention time. In addition, Cu(II)-EDTA in the reactor was decomplexated more than 80% after 120 minutes as retention time. From this work, a continuous treatment process for the wastewater containing metal and EDTA by employing Fe(VI) as muluti-functional agent was developed.

Development of Base Concrete Block for Quiet Pavement System (저소음 포장용 기층 콘크리트 블록 개발)

  • Lee, Kwan-Ho;Park, Woo-Jin;Kim, Kwang-Yeom
    • Journal of the Korean Society of Hazard Mitigation
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    • v.10 no.1
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    • pp.35-42
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    • 2010
  • The rapid economic development induced the massive road constructions, becoming bigger and high-speed of the vehicles. However, it brings lots of social problems, such as air pollutions, traffic noise and vibration. Special concrete block for the base course of asphalt pavement is needed to decrease traffic noise such as tire's explosive and vehicles sound, applying Helmholtz Resonators theory to asphalt pavement. If it is applied to the area where it happens considerable noise such as a junction, the street of a housing complex and a residential street, it is one of considerable method to solve the social requirements of noise problem. This research examines couple of laboratory tests for the sound absorption effect of the concrete block and the base concrete block. There are specimens which is fixed hall-size, space, depth as the condition of this research, and these are analysed of noise decrease effect using different condition of the first noise of each vehicle. As a result of analysis data according to vehicle noise volume, measurement distance, a form and size of the hall using the base concrete block, the use of special concrete base showed a good alternative solution for decreasing traffic noise level, from 4 dB to 9 dB.