• Title/Summary/Keyword: 염화물이온

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Evaluation of Durability Characteristics of High Performance Shotcrete Using Fly Ash (폐석탄회를 이용한 고성능 숏크리트의 내구특성 평가)

  • Park, Cheol-Woo;Lee, Hyeon-Gi;Kang, Tae-Sung
    • Journal of the Korea Concrete Institute
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    • v.22 no.3
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    • pp.305-311
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    • 2010
  • The industrial by-product market has increased at a geometric rate worldwide with the rapid economic growth. At present time, conventional disposal methods of industrial by-products in Korea including landfill, incineration and storage already have reached their limits. In this study, the industrial by-products such as fly ash and silicafume were used as mineral admixtures, which are commonly added to concrete mix to inhance the economic efficiency, long-term strength and durability of concrete, to determine the optimized mix proportion of high performance shotcrete. Through the series of tests (compressive strength test, accelerated chloride ion penetration test, measurement of chloride diffusion coefficient). The results of the study showed that the proposed mix proportions satisfied the requirements of domestic as well as international guidelines for shotcrete, with a higher durability than the existing shotcrete.

Evaluation of Steel Corrosion and Flexural Strength Coated with Cementitious Repair Material (시멘트계 보수재료로 코팅된 강재의 부식 및 휨강성 평가)

  • Yoon, Yong-Sik;Kim, Tae-Sang;Kim, Ho-Ryong;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.243-249
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    • 2016
  • The present work is for an evaluation of resistance to corrosion in steel coated with cementitious repair material, so that 3 cases of steel plate(Normal, Welding, Welding & coating case) are subjected to ICM(Impressed Current Method) for acceleration of corrosion for 7days. Tested and estimated corrosion ratio through Faraday's Law are compared, and the related flexural strength are evaluated. In Normal and Welding cases, similar level of corrosion ratio(70%) is evaluated, however only 17% level of corrosion ratio is evaluated in the Welding & coating case, which indicates that cementitious repair material is effective to anti-corrosion due to a block of chloride penetration. The flexural test results are consistent with those in accelerated corrosion test, which shows a significant flexural strength in Welding & coating case by 3.4times greater than the others. The cementitious material repair coating is evaluated to be effective to anti-corrosion in welding of steel plate.

A Study on the Development of Polymer-Modified Mortars Using Styrene-Butyl Acrylate Latexes (St/BA의 모노머 비에 따른 폴리머 시멘트 모르타르 개발에 관한 연구)

  • Hyung, Won-Gil;Mun, Kyung-Ju;Song, Hun
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.785-791
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    • 2006
  • The purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars based on styrene and butyl acrylate latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. This paper deals with the effects of monomer ratio on the typical properties of the polymer-modified mortars with styrene and butyl acrylate latexes. The polymer-modified mortars using the styrene and butyl acrylate latexes polymerized with various monomer ratios are prepared with different polymer-cement ratios, and tested for the particle size of polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer-modified mortars using styrene and butyl acrylate latexes with the mix proportions of synthesis having monomer ratios of 50:50 to 60:40 for the appropriate mix proportions can be recommended for practical applications. Their basic properties are greatly affected by the polymer-cement ratio rather than the monomer ratio, and are improved over un-modified mortar.

Performance Evaluation of a Connection Joint using a High-Ductility Concrete (고인성 콘크리트를 사용한 연결조인트의 성능평가)

  • Kim, Byeong-Ki;Kim, Jae Hwan;Yang, Il-Seung;Lee, Sang-Soo
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.185-192
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    • 2015
  • Expansion joint is the essential element of the bridge in many cases. When the bridge faces chloride of preventing freezing on the surface of the bridge, the expansion joints is damaged significantly, thus this reduces service life and increases maintenance cost of the bridge. As a solution of this problem, new technology using high ductile materials for the joint without expansion joint was developed and in this research, crack control performance, preventing leaking after the cracking, and chloride resistance were experimentally evaluated. As a result of the experiment, with PCM and FRC materials, the connecting joint suffered poor crack dispersion and severe damage by the chloride penetration while with high-ductile material, the connecting joint dispersed the tensile deformation to microcracks stably up to 7.5mm. Furthermore, under the sever conditions, the leaking was prevented and penetration of chloride ions was prevented after the crack occurred.

Physical Properties and Durability of Polymer Modified Mortar Using Styrene and Butyl Acrylate Latexes (St/BA 폴리머 시멘트 모르타르의 물리적 특성 및 내구성)

  • Hyung, Won-Gil
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.342-346
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    • 2009
  • The effects of the monomer ratios on the typical properties of polymer modified mortars that contain styrene and butyl acrylate latexes was investigated. Basic data was also obtained that is necessary for the development of appropriate latexes for cement modifiers. Polymer modified mortars that contain styrene and butyl acrylate latexes polymerized with various monomer ratios were prepared for different polymer-cement ratios. They were then tested to obtain the particle size of the polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer modified mortars that have styrene and butyl acrylate latexes (with the mix proportions of synthesis having monomer ratios of between 40:60 to 60:40 for the appropriate mix proportions) could be recommended for practical applications. The basic properties of the polymer modified mortars were more affected by the polymer-cement ratio than by the monomer ratio, and were improved over unmodified mortar.

Strength and Durability of Polymer Modified Mortar according to Monomer Ratio of Methyl Methacrylate and Butyl Acrylate (MMA/BA의 단량체 비에 따른 폴리머 시멘트 모르타르의 강도 및 내구성)

  • Mun, Kyung-Ju;Hyung, Won-Gil
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.603-609
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    • 2008
  • The purpose of this study is to clarify the effect of the monomer ratio on properties of the polymer-modified mortars using methyl methacrylate-butyl acrylate (MMA/BA) latexes, and to obtain basic data necessary to develop appropriate latexes for cement modifiers. From the test results, the total pore volume of polymer-modified mortars using MMA/BA latexes is linearly reduced with an increase in the bound MMA content and increased in the polymer-cement ratio. In general, the superior flexural and compressive strength of polymer-modified mortars using MMA/BA latexes is obtained at a bound MMA content of 70 or 80 percent and a polymer-cement ratio of 15%. And, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the bound MMA content.

Development of Eco-friendly Cement using Reverse Osmosis Brine Water and Metakaolin (역삼투압 농축수와 메타카올린을 사용한 친환경 시멘트의 개발)

  • Kim, Taewan;Han, Ki-Bong;Kim, Do-Hyung;Seo, Ki-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.216-222
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    • 2021
  • This is an experiment to complement new ways of using concentrated water discharged from the seawater desalination plant. In this study, metakaolin, which has excellent chloride ion immobilization effect, was used as the main binder, and 10% and 20% of calcium oxide were substituted with the activator. In addition, tap-water(TW) and reverse osmosis brine water(RW) were used as mixed water. As a result of the experiment, the mixture using RW showed higher compressive strength than TW. It also showed low water absorption and high density. In the mixture using RW as mixed water, a hydration reaction substance called Friedel's salt could be observed. Considering the corrosion problem of steel, RW is considered to be applicable to products such as non-reinforced concrete, brick, and curb stone. Through this study, it is thought that it is meaningful to propose a new application method other than the ocean release of RW.

Field Applicability Evaluation of SB Latex-Modified Concrete for Concrete Bridge Deck Overlay (콘크리트 교면 덧씌우기를 위한 SB 라텍스개질 콘크리트의 현장적용성 평가)

  • Yun, Kyong-Ku;Lee, Joo-Hyung;Hong, Chang-Woo;Kim, Ki-Hyun;Kim, Tae-Kyong
    • International Journal of Highway Engineering
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    • v.3 no.4 s.10
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    • pp.93-103
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    • 2001
  • This study focused on the field applicability evaluation of SB latex-modified concrete (LMC) for concrete bridge deck overlay using mobile mixer. The main experimental factors were water-cement ratio(31, 33, 35 37%), latex contents(0, 5, 10, 15, 20%), and fine aggregate ratio(55, 56, 57, 58%) in order to evaluate the workability, mechanical properties, and durability property of LMC. The slump loss, air content, compressive and flexible strength tests were used to evaluate LMC workability and strength properties. Also, the rapid chloride permeability test was used to evaluate the relative permeability of LMC. As a results, the LMC with enough workability and good quality was produced when it was mixed in field using mobile mixer, satisfying the target compressive strength and flexural strength. The required water-cement ratio of LMC for same workability when mixing with mobile mixer was less than that when mixing in laboratory. Increasing the amount of latex produced concrete with increased flexural strength by mobile mixer. The required cement-water ratios for same initial $19{\pm}3cm$ slump were 37% and 33% at laboratory and mobile mixer, respectively. The mobile mixer was accurately calibrated satisfying the required specification.

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Ettringite/Thaumasite Formation, Stability and Their Effect on Deterioration of Concrete (에트린자이트/사우마사이트의 형성 및 안정도와 콘크리트 성능저하에 미치는 영향)

  • 이효민;황진연
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.1
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    • pp.75-90
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    • 2003
  • Ettringite and thaumasite were observed in some concrete. The morphology and occurrence of these minerals were closely examined by performing SEM/EDAX analyses. We also experimentally induced the concrete deterioration using $Na_2SO_4$ solution with application of various environmental conditions. The stability of these minerals and deterioration characteristics under applied experimental conditions were determined. Abundant ettringite formed by“through solution reaction”occurred in many open spaces, and some microscopic ettringite formed by "tophochemical replacement" of calcium aluminate also occurred in cement paste. Severe cracking of cement paste causing premature deterioration was often associated with ettringite location. Under specific condition, ettringite was transformed to thaumasite, tricthloroaluminate, or decomposed. Thaumasite occurred with association of ettrinsite in concrete containing carbonate aggregate being subject to dedolomitization or in some concrete being subject to carbonation. Thaumasite appears to be formed under the similar condition to the general ettringite forming condition, but it formed solid solution with ettringite by substituting pre-existing ettringite. Ettringite can also be transformed to trichloroaluminate in the presence of abundant chlorides, but trichloroaluminate changed back to ettringite in late sulfate attack. It is considered that the substitution reaction direction solely depend on the concentration of chloride and sulfate ion.

Trend of Sn and Sn Alloy plating (주석과 주석합금도금)

  • Kim, Yu-Sang;Seol, Pil-Su
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.175-175
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    • 2016
  • Sn도금액은 강산에서는 $Sn^{2+}$, 강알칼리에서는 $Sn^{4+}$석출이 안정하다. 중성영역은 도금액에 $Sn^{2+}$침전을 방지하기 위하여 착화제가 필요하다. 기록에 남아 있는 가장 오래된 Sn도금은 1856년 Gore가 4가의 주석산염을 사용한 알칼리성용액이다. 그 후 50~60년 사이에 2가의 염화주석($SnCl_2$)과 KOH에 Cyan 등의 착화제를 첨가한 도금액이 발표되었다. 최초의 실용적인 알칼리주석용액은 1931년 Oplinger의 4가 주석산 염으로서, $CH_3COONa$를 완충제로 사용하였고, $Sn^{2+}$을 산화시키기 위하여 과산화물이나 과 붕산염을 첨가하였다. 알칼리성 Sn용액은 Natrium용액과 Kalium용액이 있지만, Kalium염이 용해성이 좋고, Sn농도를 높여 전류밀도를 높일 수 있다. 알칼리성용액은 도금속도가 산성용액의 1/2로 되고, 음극효율도 80~90% 정도 낮아, 두꺼운 피막이나 생산성을 중시하는 부품에는 적합하지 않다. 초기의 산성용액은 Sn의 정련목적으로 사용되었고, Pb정련에 사용된 Fluor규산용액에 Gelatine을 첨가하였다. Mathers는 Cresol산을 첨가하여 미량의 Cresol포화용액을 사용하여 고속으로 두껍게 석출시킬 수 있었다. 독일의 Schloetter도 다양한 방향족 술폰산으로써 반 광택피막을 실현하였다. 산성Sn도금액은 첨가제에 어떠한 유기화합물을 사용하는가는 도금장치나 석출상태로써 결정할 수 있다. Hothersall과 Bradshaw는 Cresol술폰산을 첨가하여 도금액 안정성 향상을 발견했다. Cresol술폰산은 $Sn^{2+}$의 안정제이며, Gelatine은 분산제기능을 한다. 붕 불화용액은 Sn농도를 높일 수 있고, $2{\sim}12A/dm^2$의 고 전류밀도의 도금이 가능하다. 1937년 Schloetter가 개발하여 미국의 제철회사에서 사용되었다. Sn-Ni도금은 Ni도금보다도 뛰어난 내식성이 있기 때문에 자전거, 자동차부품에 사용되고 있다. 실용도금액은 1951년 Parkinson이 발표한 HBF/HCL용액이다. $SnCl_2$산성용액에서 표준전위는 -0.136V인데 비하여, Ni이온의 표준전위는 -0.25V이다. HF용액에서는 불화물이온이 $Sn^{2+}$의 석출전위를 (-)방향으로 이동시켜서 합금석출이 가능하다. Sn-Co도금은 Cr도금의 색조에 가깝고, 장식목적으로 사용된다. Cr도금 대체용으로 사용된다. 내마모성이나 내식성은 Cr도금보다도 떨어지기 때문에 장식목적에 한정된다. 1953년 Parkinson은 Sn-Ni도금연구에서 동일한 용액조성으로부터 Co 30%를 석출시켰다. Sn-Zn도금은 방식도금으로서 자동차부품에 많이 사용되고 있다. Sn과 Zn의 표준전위는 서로 멀리 떨어져 있기 때문에 산성용액에서는 공석될 수 없다. 1980년대에 들면서, 방식Cd(Cadmium)도금의 독성 때문에 Sn-Zn도금을 재인식 하게 되었다. 1957년 Vaid 등이 No Cyan도금액을 발표했다. 그 후 러시아의 연구자가 안정한 도금액을 연구하였고, Srivastava와 Muckergee가 1976년에 종합하였다.

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