• Title/Summary/Keyword: 염해용액

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Long-Term Effect of Chemical Environments on FRP Reinforcing Bar for Concrete Reinforcement (화학적 환경에 노출된 콘크리트 보강용 FRP 보강근의 장기 효과)

  • Park, Chan-Gi;Won, Jong-Pil;Yoo, Jung-Kil
    • Journal of the Korea Concrete Institute
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    • v.15 no.6
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    • pp.811-819
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    • 2003
  • The corrosion of steel reinforcing bar(re-bar) has been the major cause of the reinforced concrete deterioration. FRP(Fiber-reinforced polymer) reinforcing bar has emerged as one of the most promising and affordable solutions to the corrosion problems of steel reinforcement in structural concrete. However, FRP re-bar is pone to deteriorate due to other degradation mechanisms than those for steel. The high alkalinity of concrete, for instance, is a possible degradation source. Other potentially FRP re-bar aggressive environments are sea water, acid solution and fresh water/moisture. In this study long-term durability performance of FRP re-bar were evaluated. The mechanical and durability properties of two type of CFRP-, GFRP re-bar and one type of AFRP re-bar were investigated; the FRP re-bars were subjected to alkaline solution acid solution, salt solution and deionized water. The mechanical and durability properties were investigated by performing tensile, compressive and short beam tests. Experimental results confirmed the desirable resistance of FRP re-bar to aggressive chemical environment.

Physiological Response of Barley to Water Stress and Salt Stress at Seedling Stage (보리 유묘기의 한해와 염해반응)

  • 최원열;박종환
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.6
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    • pp.693-698
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    • 1997
  • Drought resistance and salt resistance of seedlings were compared with the polyethylene glycol(P.E.G) and NaCl solutions of the same osmotic potential($\Psi_\pi$=-10 bar). Plant height, seedling dry weight, chlorophyll content and leaf water potential decreased while the free proline content increased more in the P.E.G. than in the NaCl solution. Free amino acids increased 2.6 times in the P.E.G. solution and 3.6 times in the NaCl solution more than in the untreated(Hoagland's solution). Free proline occupied 66% and 61% of the content of total amino acids under water stress and salt stress, respectively. Besides free proline, phenylalanine in the P.E.G. solution and phenylalanine, alanine and asparagine in the NaCl solution increased distinctly. In short, it was shown that water and salt stress responses in seedling stage were relatively similar.

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Differentiation of Barley Response to Drought and Salt Stress in Antioxidant Enzyme Activity and Free Amino Acid Content (염해 및 한발에 대한 보리의 생화학적 반응 - 항산화효소 활성 및 아미노산 함량의 변화)

  • Kim, Dea-Wook;Heo, Hwa-Young;Suh, Sae-Jung;Lee, Yeong-Ho;Kim, Si-Ju
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.spc1
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    • pp.133-138
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    • 2006
  • To differentiate barley responses to drought and salt stress, barley seedlings at the second leaf stage were treated with 218 mM NaCl and 29.5% PEG6000 iso-osmotic to 218 mM NaCl for 6 days. Shoot fresh weight and leaf relative water content of barley seedlings were more reduced by drought compared to salt stress. Hydrogen peroxide content increased under both stress conditions, but its accumulation was more severe at 6 days after salt stress. The activity of ascorbate peroxidase, glutathione reductase (GR) and catalase (CAT) was enhanced until 4 days after salt stress. On the other hand, the activity of GR and CAT increased gradually until 6 days after drought. Among the amino acids measured in this study, the accumulation of glycine, arginine and GABA (${\gamma}-aminobutyric$ acid) was lower under salt stress than drought. However, considerably larger amount of proline was accumulated by salt stress. It is concluded that the antioxidant enzymes activity and amino acid content of barley seed-lings were differently regulated in response to the isoosmotic condition of salt and drought stress.

Effects of Fly Ash on Chloride Binding Capacity in Cement Pastes (시멘트 페이스트 내의 염화물 고정화에 미치는 플라이 애쉬의 영향)

  • 소승영;소양섭
    • Magazine of the Korea Concrete Institute
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    • v.7 no.6
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    • pp.209-215
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    • 1995
  • Corrosion of steel reinforcment is the most significant factor of deterioration in reinforced concrete structures. Chloride ion is considered one of the most common culprits in the corrosion of steel in concrete. It breaks down the passive film and allows the steel to corrode actively at a high rate. The main objective of this study is to determine the critical chloride ion concentrations in the pore solutions and chloride binding effect of cement pastes made with and without fly ash. Cement pastes with water-binder ratio of 0.5, allowed to hydrate in sealed containers for 28 days and to express pore solution. The expressed pore fluids were analyzed for chloride and hydroxyl ion concentrations. Evaporable water on paralled specimens was determined a.s the loss of weight per 100g of unhydreded cement when the specimens were heated to constant weight at 105'C. It was found that the replaced cement with fly ash has negligible influnce on the chloride binding and chloride binding capacity and rises the $Cl^-$ /$OH^-$ ratio in pore solution.

Physiological Response of Barley to Salt Stress at Reproductive Stage (보리 생식생장기의 염(NaCl)처리가 수량 및 몇 가지 생리적 반응에 미치는 영향)

  • Choi, Won-Yul;Park, Jong-Hwan;Kwon, Yong-Woong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.6
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    • pp.687-692
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    • 1997
  • The barley grown in pot-soil was treated with the NaCl solution of -20 bar in osmotic potential for 10 days, varying the time of treatment: from 20th day before heading; from 10th day before heading and the time of heading. The greatest injury was observed in the case of salt stress at heading or at 10th day before heading: Culm length decreased by 87% : the number of spikes per plant by 82% ; the number of grain per spike by 92% : 1, 000-grain weight by 94% ; yield per pot by 75%. The results also greatly varied depending upon the cultivars and the time of salt stress. Salt stress at the time of heading or at 10th day before heading remarkably decreased yield and yield components. And in terms of grain yield the salt resistance was high in the order of Baegdong, Albori, Hyangmaeg, Olbori and Durubori.

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Service Life Assessment and Restrain Methods of Carbonation Attack on PC Outer Wall of LNG Storage Tanks (탄산염해에 대한 LNG 저장탱크 PC 외부벽체의 수명평가 및 억제방안)

  • Lee, Seung-Rim;Song, Il-Hyun;Kim, Han Sang
    • Journal of the Korean Institute of Gas
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    • v.18 no.2
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    • pp.73-80
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    • 2014
  • The objective of this paper is to assess the service life and retrain methods of specimens, which were subjected to carbonation attack, obtained from mix proportion of Sam-cheok LNG storage tank under construction. As the results, accelerated-carbonation penetration depths of 7, 28, 56 ages indicated 4.45, 9.19, 13.37mm, and even considering for cover depths of steel of LNG storage tank under real operation, it was enough. In addition, with carbonation velocity coefficient calculated by carbonation penetration depths, the service life to design cover depth(70, 80, 90, 100mm) of PC outer tank of LNG storage tank was 779, 1017, 1287, 1589 years and 466, 609, 771, 951 years, respectively, considering the $CO_2$ concentration in air which account for the 0.03% and 0.05%. Also, the restrain methods to carbonation attack were feasible through controlling the factors affecting the changes of hydration products such as $Ca(OH)_2$, ion composition in pore solution and matter mobility of organization structures within hardened concrete.

Investigation of Mechanical Behavior and Hydrates of Concrete Exposed to Chloride Ion Penetration (염해를 받은 콘크리트의 역학적 거동 및 수화 생성물 조사)

  • Yunsuk Kang;Gwihwan Lim;Byoungsun Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.381-390
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    • 2023
  • In this study, the mechanical performance of concrete exposed to chloride ion penetration was investigated. And a compressive stress-strain model was presented. CaCl2 solution was added when mixing concrete to simulate long-term chloride ion penetration, and the concentration of chlorine ions was set to 0, 1, 2, and 4 % based on the weight of the binder. To investigate the compressive stress-strain curve after the peak stress of concrete, the compressive strength was measured by displacement control. When the chlorine ion concentration was 1 %, peak stress increased, but when the chlorine ion concentration was 2 % or more, peak stress decreased. In the case of peak strain, no trend according to chloride ion concentration was observed at 7 days. At 28 days, peak strain decreased as the chloride ion concentration increased. A compressive stress-strain curve model based on the Popovics model was presented using changes in peak stress and peak strain at 28 days. Microstructure analyses were performed to investigate the cause of the decrease in mechanical performance as the concentration of chlorine ions increased. It was confirmed that as the concentration of chlorine ion increased, Friedel's salt increased and portlandite decreased.

Physiological Response of Winter Barley to Salt Stress at Seedling Stage (보리 유묘기의 염처리가 생리적 반응에 미치는 영향)

  • Choi, Won-Yul;Kwon, Yong-Woong;Park, Jong-Hwan
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.5
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    • pp.534-538
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    • 1997
  • Some physiological characteristics and cultivar differences of winter barley to salt stress were studied during seedling stage. Salt stress was caused by adding NaCl solution to the pot culture soil. Measurements of the responses to salt stress and of the responses after relief from stress were done in terms of leaf water potential, chlorophyll and free proline contents, seedling height and seedling dry weight, and survival rate of leaves. Under salt stress ($\Psi_{\pi}$ =-20bar) seedling height and seedling weight were decreased by 2~22% and by 25~39% respectively, showing some differences among cultivars. Chlorophyll contents was decreased by 33~49%, and free proline content was remarkably increased from control 0.2~0.3mg to salt stress 9.6~14.7mg. The leaf water potential of seedling grown under salt stress with NaCl solution($\Psi_{\pi}$ =-10 or -20bar) was decreased from control -3.3bar to salt stress -9.0bar or -16.2bar respectively but there were no large differences among cultivars with time after relief from salt stress. Leaf survival rate was high in order of Baegdong, Milyang12, Olbori, Durubori and Hyangmaeg, and decrease rate of seedling dry weight was low in the order of Baegdong, Olbori, Hyangmaeg, Milyang12, Durubori. The increase in free proline contents was high in the order of Milyang12, Hyangmaeg, Baegdong, Durubori and Olbori.

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Estimation of Concrete Cover Failure Time Considering the Corrosion Rate in Reinforced Concrete Structures (철근 부식속도 예측식을 이용한 철근 피복 파괴 시간 추정)

  • Jang, Bong-Seok
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.233-238
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    • 2006
  • In lifetime estimation, the FEM analysis method is proposed for predicting corrosion failure time of concrete structures exposed to sea-water. This study shows that the corrosion rate of rebar in artificial pore solution can be transferred to the corrosion rate of rebar in concrete using the relationship between pore volume and concrete volume by Jennings' model. And this study considered the pitting corrosion effects of reinforcement bar on corrosion failure analysis, rebar size to cover depth and nonlinear crack analysis. These analysis results have good accordance with the experimental results of Williamson's work. This methodology can be applied to lifetime prediction procedure of reinforced concrete structures and also gives more reasonable results of concrete cover failure time estimation of reinforced concrete structures exposed to sea-water.

Effect of Desalinization on Early Seedling Growth of Winter Barley in New Tideland (신간탁지 토양의 제염이 보리의 초기생육에 미치는 영향)

  • 이강수;최선영;최원열
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.1
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    • pp.112-118
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    • 1997
  • This study was conducted to obtain basic information on the desalinization in newly reclaimed tideland. A desalinization experiment with leaching method was carried out using the soil samples collected in Haenam tideland, and the early growth response of winter barley to salt stress during the desalinization was investigated by measuring emergence rate, plant height, leaf area and fresh weight. The soil in Haenam tideland was saline-sodic with 59mS / cm of electrical conductivity and pH 8.0, and the soil texture was silty loam with 16% clay and 75% silt. Depth of water for desalinization(DWD) to decrease the electrical conductivity below 4mS /cm was 140mm in 5cm depth soil and 240mm in 20cm depth soil. The value of pH of soil and leaching water increased from 8.0 to 8.3 until the electrical conductivity decreased to about 6mS / cm during the desalinization. .The emergence rate of winter barley was over 75% in the DWD above 80mm and showed no significant difference with the DWD. The DWD for the normal growth of winter barley seedling was above 120mm at 1 and 2 weeks after sowing(WAS), and above 160mm at 3 and 4 WAS. The leaf area and fresh weight showed no response for salt stress with the DWD above 12mm at 2 WAS, and above 16mm at 3 WAS. It was estimated that the electrical conductivity of soil saturation extract for the normal growth of winter barley during early seedling growth stage in new reclaimed tideland would be below 9mS / cm in 20cm depth soil.

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