• Title/Summary/Keyword: 염소 이온 확산계수

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A Study on the Quality Deviation of High-Strength Concrete from Multiple Ready Mixed Concrete Companies (다수 레미콘사에서 납품된 콘크리트 품질 편차에 관한 연구)

  • Park, Dong-Cheon;Seok, Won-Kyun;Jeon, Hyun-Soo;Kim, Young-Sun
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.577-583
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    • 2022
  • On large-scale sites, concrete is often delivered from a number of ready-mixed concrete companies, but even if the same concrete mixture table is used, it is thought that there will be a difference in quality due to differences in materials and manufacturing equipment. Due to a lack of previous research in this area, this study measured the properties of fresh concrete, compressive strength, and chlorine ion diffusion coefficient using the concrete supplied by 12 ready-mixed companies in Busan. The fresh concrete properties met the criteria. The compressive strength increased by 137% for 30MPa, 131% for 45MPa, and 117% for 80MPa by specified compressive strength. For the chlorine ion diffusion coefficient, the average value for each specified compressive strength could be derived without significant variation. The higher the compressive strength, the greater the deviation , and the lower the compressive strength, the greater the deviation in the chlorine ion diffusion coefficient.

An Experimental Study on the Resistance of Nylon Fiber Reinforced Concrete to Chloride Ion Penetration (나일론섬유보강 콘크리트의 염소이온 침투 저항성에 대한 실험적 연구)

  • Jeon, Joong-Kyu;Moon, Jae-Heum;You, Jin-O
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.557-560
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    • 2008
  • Fiber reinforcement has been being widely used in concrete to enhance the mechanical properties and to reduce the micro-cracking caused by plastic and drying shrinkage. While researches has been focused on the benefits of fiber reinforcement, the properties of fiber reinforced concrete are strongly dependent on the type, shape and the amount of fibers in concrete. In this study, the resistance of nylon fiber reinforced concrete against the chloride ion penetration was experimentally observed by NT Build 492. The test results showed that the addition of nylon fiber has little effect on the change of the resistivity of concrete to the chloride ion penetration.

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Rapid Chloride Penetration Test for Concrete Based on the Electrochemical Method (전기 영동법에 기초한 콘크리트의 급속 염소이온 확산 특성 평가)

  • Oh, Sang-Gyun;Park, Dong-Cheon
    • Journal of Navigation and Port Research
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    • v.34 no.10
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    • pp.787-792
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    • 2010
  • It is necessary to predict the penetration of chloride ions for designing RC construction in marine environments. However, it takes a long time to obtain chloride migration coefficients. Therefore, the rapid chloride penetration test (RCPT) is generally used to shorten the test time. But there is a difference between chloride migration coefficients determined by rapid chloride penetration tests and those based on exposure in marine environments. In this study, we evaluated the effect on the chloride ion migration coefficient caused by a change in voltage and NaCl concentration. We also compared the relationship between the chloride ion migration coefficient by RCPT and that by exposure in marine environments. As a result of the experiments, we found that there is only a small change in the experimental factors based on changes in voltage and NaCl concentration and since they are so small, we can conclude that they are in the range of experimental error and test results from chloride ion migration coefficients by RCPT and exposure were very different from each other. In the exposure experiments, when the water-cement ratio was increased, the smaller fine air gaps in concrete affected the chloride ion migration coefficient.

Comparison of Test Methods for Evaluation of Chloride Diffusion Coefficient in Concrete (콘크리트의 염소이온 확산계수 평가를 위한 시험방법 비교)

  • Lee, Chan-Young;Kim, Hong-Sam;Kim, Jin-Cheol;Cheong, Hai-Moon;Ahn, Tae-Song
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.581-584
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    • 2008
  • Generally, durability of concrete structures under marine environment is grossly declined by detrimental ions such as chlorides, which penetrate concrete and was diffused to corrode reinforcing rod. Therefore, chloride diffusion properties in concrete are important for durability evaluation and design of concrete structure. For estimation of chloride diffusion coefficient in concrete, both evaluation methods are used for steady state and non-steady state derived from Fick's 1st and 2nd law, respectively. However, as it is very difficult to evaluate diffusion coefficient for non-steady state like service environment where concrete is actually exposed, indirect evaluation method by laboratory accelerated test is generally used. In this study, comparison of chloride diffusion behavior was investigated for fixed mix proportion and age of concrete using four accelerated test methods based on domestic and foreign standards. From test results, only relative comparison between concrete mixtures was possible using ASTM C 1202 test, and diffusion coefficient for steady state was estimated as low as 1/10 of that for non-steady state. In addition, diffusion coefficient estimated by immersion test was similar to result by NT build 492 test.

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Properties of Latex Modified Concrete by Binder Content and Effect on Chloride Ion Diffusion (라텍스 개질 콘크리트(LMC)의 결합재량에 따른 배합 및 염화물 이온 확산 특성)

  • Park, Sung-Gi;Won, Jong-Pil;Park, Chan-Gi;Lee, Sang-Woo;Sung, Sang-Kyoung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.949-952
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    • 2008
  • The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. But it is added in LMC manufacture, which is a high price compares with different material and there is a weak point where the construction expense is very high. So, this study are decided mix proportion from the scope where the security strong point of LMC is possible and reduced the material expense by control the latex contents. and these mix proportions are estimated the chloride ion diffusion. The results of study appear that it can reduced the latex content until the $5{\sim}10$% of cements, and these mixtures are very low chloride ion diffusion.

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The Chloride Diffusion Properties of Concrete with Mineral Admixtures (혼화재를 사용한 콘크리트의 염소이온 확산 특성)

  • Park, Jung-Jun;Koh, Kyoung-Taek;Kim, Do-Gyeum;Kim, Sung-Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.2
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    • pp.239-246
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    • 2004
  • To improve the durability of concrete structure, we usually consider the reduction of water-cement ratio, the increase of concrete cover depth and the use of mineral admixtures. The use of admixtures make concrete more durable and tighten against water in recent papers so it is needed to study more about the relationship between the admixtures and the chloride ion diffusion. Therefore we analyzed the correlation between chloride ion diffusion and physical properties such as compressive strength, void ratio, air permeability of the concrete, and tried to use them as fundamental data for analyzing chloride ion diffusion mechanism of the concrete mixed with mineral admixtures.

Chloride Penetration Properties of Portland Cement Mortar Substituted with Anion Exchange Resin Powder (음이온교환수지 분말이 치환된 포틀랜드 시멘트 모르타르의 염소이온 침투 특성)

  • Lee, Yun-Su;Lim, Seung-Min;Park, Jang-Hyun;Jung, Do-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.1-9
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    • 2020
  • Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.

Time Dependent Evaluation of Corrosion Free Life of Concrete Tunnel Structures Based on the Reliability Theory (해저 콘크리트 구조물의 신뢰성 이론에 의한 시간 의존적 내구수명 평가)

  • Pack, Seung Woo;Jung, Min Sun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.3
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    • pp.142-154
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    • 2011
  • This study predicted the probability of corrosion initiation of reinforced concrete tunnel boxes structures using the Monte Carlo Simulation. For the inner wall and outer wall in the tunnel boxes, exposed to airborne chloride ion and seawater directly respectively, statistical values of parameters like diffusion coefficient D, surface chloride content $C_s$, cover depth c, and the chloride threshold level $C_{lim}$ were examined from experiment or literature review. Their average values accounted for $3.77{\times}10^{-12}m^2/s$, 3.0% by weight of cement, 94.7mm and 45.5mm for outer wall and inner wall, respectively, and 0.69% by weight of cement for D, $C_s$, c, and $C_{lim}$, respectively. With these parametric values, the distribution of chloride contents at rebar with time and the probability of corrosion initiation of the tunnel boxes, inner wall and outer wall, was examined by considering time dependency of chloride transport. From the examination, the histogram of chloride contents at rebar is closer to a gamma distribution, and the mean value increases with time, while the coefficient of variance decreases with time. It was found that the probability of corrosion initiation and the time to corrosion were dependent on the time dependency of chloride transport. Time independent model predicted time to corrosion initiation of inner wall and outer wall as 8 and 12 years, respectively, while 178 and 283 years of time to corrosion was calculated by time dependent model for inner wall and outer wall, respectively. For time independent model, the probability of corrosion at 100 years of exposure for inner wall and outer wall was ranged 59.5 and 95.5%, respectively, while time dependent model indicated 2.9 and 0.2% of the probability corrosion, respectively. Finally, impact of $C_{lim}$, including values specified in current codes, on the probability of corrosion initiation and corrosion free life is discussed.

Development of Chloride Penetration Analysis Program Considering Environmental Conditions (환경조건을 고려한 염소이온 침투해석 프로그램 개발)

  • Kim, Ki Hyun;Jang, Seung Yup;Cha, Soo Won;Chang, Sung Pil
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5A
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    • pp.709-718
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    • 2008
  • Developed is a chloride penetration analysis program in which changes of environmental conditions such as temperature, humidity and external chloride concentration, and the diffusion, convection and binding of chlorides are considered. In order to consider the changes of environmental conditions, analyses for temperature and moisture distribution are implemented simultaneously, and variation of diffusion coefficients due to temperature, humidity and age is also considered. By comparing the calculated total chloride contents with some experimental data, it has been confirmed that the proposed analysis program can trace measured chloride distribution well. Also, through some example analyses, the mechanism of accumulation of chlorides at near surface and acceleration of corrosion of steel reinforcement in case that the moisture distribution changes according to repeated drying and wetting cycles have been verified.

Chloride Ingress through Cracks in Concrete: from Experiment to Modeling Strategy (균열을 통한 콘크리트의 염소이온 침투: 실험에서 해석기법까지)

  • Yoon, In-Seok;Sung, Jae-Duck
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.467-468
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    • 2010
  • Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. The majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. Author of this study examined the effect of cracks on chloride penetration by short term experiment. However, it is necessary to accomplish the effect by long term experiment to get reliable goal. In this study, the long term and short term experiments were carried out. This can be useful for establishing new species model of chloride penetration through cracks in concrete.

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