• Title/Summary/Keyword: 염소 이온 침투

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Compressive Strength and Chloride Permeability of High Strength Concrete according to the Variety of Mineral Admixtures (광물질혼화재 종류별 고강도콘크리트의 압축강도 및 촉진 염소이온침투 특성)

  • Moon Han-Young;Kim Byoung-Kwon
    • Journal of the Korea Concrete Institute
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    • v.16 no.3 s.81
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    • pp.407-414
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    • 2004
  • The purpose of this study is to evaluate the ability to resist chloride ions penetration of the concrete structure under marine environment in south-east asia especially. In this study, high strength concrete(HSC) with various combination of ordinary portland cement(OPC), blast-furnace slag(SG) and silica fume(SF) are cured 23 and $35^{\circ}C$ considering the site weather, and are cured in water for 3, 7 or 56 days respectively. And to investigate the fundamental properties and the resistance of chloride penetration of various HSC, setting time, slump flow, compressive strength, void and ASTM C 1202 test were conducted. Test results show that the compressive strength of HSC is similar regardless of SG replacement ratio and total charge passed of chloride is the smallest at 40% replacement of SG. The compressive strength of G4FS HSC is, besides, outstandingly high at early age compare with other HSC, but the compressive strength of G4F HSC, which is vary according to curing temperature and condition, most high at the age after 7 days. Total passed charge of HSC get larger in the order G4FS

Experimental Study for Evaluation of Chloride Ion Diffusion Characteristics of Concrete Mix for Nuclear Power Plant Water Distribution Structures (원전 취배수 구조물 콘크리트 배합의 염소이온 확산특성 평가를 위한 실험적 연구)

  • Lee, Ho-Jae;Seo, Eun-A
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.112-118
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    • 2022
  • In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

Parametric Analysis for the Simultaneous Carbonation and Chloride Ion Penetration in Reinforced Concrete Sections (중성화와 염화물 침투가 동시에 발생하는 철근콘크리트 단면의 매개변수 분석)

  • Zhu, Xingji;Kim, Soye;Kwak, Dong-Woo;Bae, Kyung-Tae;Zi, Goangseup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.66-74
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    • 2016
  • The objective of this study is the investigation of the influence of carbonation on the penetration of chloride ions in reinforced concrete sections for different mix proportions and environmental conditions. A comprehensive numerical model based on the change of the pore structure and the chemical equilibrium was used for this combined action of carbonation and chloride ingress. The empirical formulae of some parameters in this model are estimated according to numerous experimental data. And, a set of data analysis is carried out to simplify the estimation of model variables to reduce the computational cost. A coupled simulation of the transports of carbon dioxide, chloride ions, heat and moisture is carried out. Then, the parametric analysis is given and the numerical results show that the effect of carbonation of the free chloride ingress is significant and depends on the binder types and concrete mix proportion.

Time Dependent Evaluation of Corrosion Free Life of Concrete Tunnel Structures Based on the Reliability Theory (해저 콘크리트 구조물의 신뢰성 이론에 의한 시간 의존적 내구수명 평가)

  • Pack, Seung Woo;Jung, Min Sun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.3
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    • pp.142-154
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    • 2011
  • This study predicted the probability of corrosion initiation of reinforced concrete tunnel boxes structures using the Monte Carlo Simulation. For the inner wall and outer wall in the tunnel boxes, exposed to airborne chloride ion and seawater directly respectively, statistical values of parameters like diffusion coefficient D, surface chloride content $C_s$, cover depth c, and the chloride threshold level $C_{lim}$ were examined from experiment or literature review. Their average values accounted for $3.77{\times}10^{-12}m^2/s$, 3.0% by weight of cement, 94.7mm and 45.5mm for outer wall and inner wall, respectively, and 0.69% by weight of cement for D, $C_s$, c, and $C_{lim}$, respectively. With these parametric values, the distribution of chloride contents at rebar with time and the probability of corrosion initiation of the tunnel boxes, inner wall and outer wall, was examined by considering time dependency of chloride transport. From the examination, the histogram of chloride contents at rebar is closer to a gamma distribution, and the mean value increases with time, while the coefficient of variance decreases with time. It was found that the probability of corrosion initiation and the time to corrosion were dependent on the time dependency of chloride transport. Time independent model predicted time to corrosion initiation of inner wall and outer wall as 8 and 12 years, respectively, while 178 and 283 years of time to corrosion was calculated by time dependent model for inner wall and outer wall, respectively. For time independent model, the probability of corrosion at 100 years of exposure for inner wall and outer wall was ranged 59.5 and 95.5%, respectively, while time dependent model indicated 2.9 and 0.2% of the probability corrosion, respectively. Finally, impact of $C_{lim}$, including values specified in current codes, on the probability of corrosion initiation and corrosion free life is discussed.

Chloride Diffusion Coefficient from NT BUILD 443 (NT BUILD 443에 의한 염소이온 확산계수 고찰)

  • Kim, Ki-Hyun;Cha, Soo-Won;Jang, Sung-Yup
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.295-296
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    • 2009
  • It is often the case with the durability design to use diffusion coefficient obtained from experimental test. From the analytic solution considering the starting time of exposure, it is confirmed that the diffusion coefficient from NT BUILD 443 underestimates real reference value.

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Analysis of Chloride ion Penetration of Marine Concrete Structure - Part II. Application of Analysis Program- (해양 콘크리트 구조물의 염소이온 침투해석 - 개발된 프로그램의 적용 중심으로-)

  • 한상훈
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 2002.08a
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    • pp.280-286
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    • 2002
  • 염소이온 확산해석을 실제 구조물에 대해서 수행하기 위해서는 여러 변수들에 대한 값들이 필요하다. 이러한 변수들에 대한 값들은 적용 배합에 대한 실험을 통해 직접 측정할 수도 있지만 설계 단계에서 염해에 의한 내구성을 평가를 위해 실험을 수행하기가 실용적인 관점에서 매우 어렵다. (중략)

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A Method on the Rapid Assessment of Resistance to Chloride Ion Penetration for Mortar and Concrete with Mineral Admixtures (혼화재를 사용한 모르타르 및 콘크리트의 염소이온 침투 저항성 평가)

  • Park Jung-Jun;Kim Sung-Wook;Koh Kyung-Taek;Lee Jong-Suk;Lee Jang-Hwa
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.485-492
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    • 2004
  • In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

Evaluation of Chloride Extraction under Electrochemical Chloride Extraction (전기화학적 염화물 추출법에 따른 염소이온 제거 성능 평가)

  • Jiseok, Kim;Ki-Yong, Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.553-557
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    • 2022
  • The present study evaluate the chloride extracion under electrochemical chloride extraction method. Chloride was penetrated into the concrete from external reservoir using a 4M NaCl solution, and an electrochemical chloride extraction method was applied after the curing period of 1 year. The current density was constantly kept 1000 mA/m2 for coulostatic application with the variation in potential difference. The duration of the ECE treatment was 2, 4, 8 weeks, respectively. The residual chloride concentration at all depths decreased, and the chloride concentration decreased as the application period increased. After the application period of 8 weeks, 62.9 to 77.6 % of chloride extracted in the total chloride profile, and 77.7 to 99.5 % of chloride extracted in the free chloride profile. In particular, the concentration of free chloride at a depth of 7 mm or more from the concrete surface was 0.01 % or less by cement. In addition, it was confirmed that the bound chloride could be extracted by the electrochemical chloride extraction.

Chloride Ion Penetration Resistance of Mortars including Expanded Vermiculite Immobilizing Bacteria (박테리아 흡착 팽창질석을 혼입한 모르타르의 염소이온 침투 저항성)

  • Jung, Seung-Bae;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.151-152
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    • 2017
  • This tests examined the effectiveness of bacteria slime on the chloride ion penetration resistance of cement mortar. Test results exhibited that the chloride ion penetration depth of mortars including 5% expanded vermiculite immobilizing bacteria was 17% smaller than that of the control mortar without expanded vermiculite.

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An Experimental Study on the Compressive Strength and Chloride ion penetration resistance of Cement Mortar mixing Anion Exchange Resin (음이온교환수지 혼입 시멘트 모르타르의 압축강도 및 염소이온 침투 저항성에 관한 실험적 연구)

  • Jung, Do-Hyun;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.23-24
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    • 2018
  • Reinforced concrete is a building material that is generally used in modern society. Also, reinforced concrete structures in high salinity environments have low durability due to corrosion of reinforcing bars due to infiltrated chlorine ions. Anion exchange resins have an ability to immobilize chlorine ions in the resin while releasing their anions. As a material, it has already been shown that it is possible to fix the chloride ion inside the cementitious material through the cement mortar experiment. The purpose of this study is to confirm the compressive strength of cement mortar using powdered anion exchange resin after powdering an anion exchange resin. In order to confirm the chloride ion fixation ability of the powder anion exchange resin, chlorine ion penetration resistance test was carried out.

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