• Title/Summary/Keyword: 염소확산계수

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Strength and Resistance to Chloride Penetration in Concrete Containing GGBFS with Ages (GGBFS를 혼입한 콘크리트의 재령에 따른 강도 및 염소이온 침투 저항성)

  • Park, Jae-Sung;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.307-314
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    • 2017
  • Concrete is a durable and cost-benefit construction material, however performance degradation occurs due to steel corrosion exposed to chloride attack. Penetration of chloride ion usually decreases due to hydrates formation and reduction of pores, and the reduced chloride behavior is considered through decreasing diffusion coefficient with time. In the work, HPC (High Performance Concrete) samples are prepared with 3 levels of W/B (water to binder) ratios of 0.37, 0.42, and 0.27 and 3 levels of replacement ratios of 0%, 30% and 50%. Several tests containing chloride diffusion coefficient, passed charge, and compressive strength are performed considering age effect of 28 days and 180 days. Chloride diffusion is more reduced in OPC concrete with lower W/B ratio and GGBFS concrete with 50% replacement ratio shows significant reduction of chloride diffusion in higher W/B ratio. At the age of 28 days, GGBFS concrete with 50% replacement ratio shows more rapid reduction of chloride diffusion than strength development, which reveals that abundant GGBFS replacement has effective resistance to chloride penetration even in the early-aged condition.

Evaluation of Testing Method for Quality Control of Chloride Diffusivity in Concrete under chloride attack environment (콘크리트 구조물의 염해 내구성능 검토를 위한 현장 품질관리 시험법 검토)

  • Kim, Hong-Sam;Cheong, Hai-Moon;Ahn, Tae-Song;Kim, Cheol-Ho;Geon, Byung-Sub
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.973-976
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    • 2008
  • Recently, it is increasingly reported that the deterioration of concrete structure under marine environments is due to diffusion and penetration of chloride ions. It is very important to estimate the diffusion coefficient of chloride ion in concrete. Estimation methods of chloride diffusivity by concentration difference is time-consuming. Therefore, chloride diffusivity of concrete is mainly conducted by electrically accelerated method, which is accelerating the movement of chloride ion by potential difference. However, there has not been any proper method for field quality control to closely determine the diffusion coefficient of chloride ion through accelerated tests using potential difference. In this paper, the various test methods for determination of chloride diffusion coefficient in concrete were investigated through comparison accelerated tests. From the results of estimated diffusion coefficient of chloride ion, relationship between the ponding test and acceleration test was examined.

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Estimation of Distributed Groundwater Recharge in Mihocheon Watershed (미호천 유역의 분포형 지하수 함양량 산정)

  • Chung, Il-Moon;Kim, Nam-Won;Lee, Jeong-Woo;Won, Yoo-Seung
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.698-701
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    • 2007
  • 지하수 개발가능량 산정을 위한 함양량의 평가는 수문계의 물리적인 형태나 함수층의 수리성 분석 및 수직인 지질분포를 파악하여 어떤 조건하에서 물이 유입 유출되는가를 파악한 후에만 가능하다. 또한 지하수계의 물리적인 형태를 이해함으로써 조사지역의 지표수계나 지하수계의 양계를 통해서 흐르는 물의 양을 결정짓는 물수지 분석이 수행되어야 한다. 이에 따라 강수량, 증발산량, 지하수 유출량, 지표유출량 그리고 하천유출량 등을 수문학적으로 고려해야만 한다. 본 연구는 지표수-지하수 결합모형을 도입하여 분포형 지하수 함양량의 시공간적인 변동성을 파악하는 데 그 목적이 있다. 이를 위해 지표수-지하수 결합모형인 SWAT-K모형을 미호천 유역에 적용하였으며, 지표수의 총유출량과 지하수위의 공간분포자료를 이용하여 검정과 검증을 수행하였다. 전체유역에 대한 연평균 함양량은 수문총량의 약 19%인 것으로 나타났다. 1999년${\sim}$2004년까지의 소유역별 연간 함양량 결과를 월별로 나타냈으며, HRU(Hydrologic Response Unit)별 함양량의 공간분포를 통해 월별, 계절별 특성을 살펴볼 수 있었다. 소유역 모두 강수가 집중하는 7-9월에 걸쳐 많은 함양이 이루어지며 $1{\sim}3$월에는 상대적으로 함양이 적은 것을 볼 수 있다. 월함양량의 경우 최대 약200mm범위내에서 유역의 토지이용 및 토양특성, 경사등에 따라 매우 비균질하게 분포하는 것을 확인할 수 있었다. 이와같은 함양량의 시공간적 불균일성으로 인해 지하수 관리방안은 소유역별 함양특성을 반영해야 할 것으로 판단된다.의 종분산지수가 일반적인 자연대수층에 비해 9.1배 정도 높다는 것을 의미한다. 이는 시험대수층의 투수성이 매우 높아 염소이온의 용질이송이 매우 빠르게 발생되었기 때문이다. 본 연구에서 추정된 종분산지수를 Gelhar et al.(1992)의 연구 결과와 비교 분석한 결과에서도 시험규모에 비해 매우 높은 수리분산이 발생된 것으로 나타났다. 그리고 염소이온의 확산면적을 추정하기 위해, 수렴흐름 추적자시험에 의한 종분산지수와 시험대수층의 평균선형유속을 이용하여 종분산계수를 구하였다. 현장에서 수행된 양수시험에 의한 평균선형유속 22.44 m/day와 평균 종분산지수 0.4155 m를 적용하여 산정된 종분산계수는 $9.32\;m^2/day$이었다. 따라서, 시험부지 내 충적층에서 일정한 양수율$(2,500\;m^3/day)$로 지하수를 개발할 시에 양수정 주변지역으로 유입되는 염소이온의 확산면적은 1일 $9.32\;m^2$ 정도일 것으로 나타났다.적인 $OH{\cdot}$ 의 생성은 ascorbate가 조직손상에 관여할 가능성을 시사하였다.었다. 정확한 예측치를 얻기 위하여 불균질 조직이 조사야에 포함되는 경우 보정이 요구되며, 골반의 경우 골 조직의 보정이 중요한 요인임을 알 수 있었다. 이를 위하여 불균질 조직에 대한 정확한 정보가 요구되며, 이는 CT 영상을 이용하는 것이 크게 도움이 되리라 생각된다.전시 슬러지층과 상등액의 온도차를 측정하여 대사열량의 발생량을 측정하고 슬러지의 활성을 측정할 수 있는 방법을 개발하였다.enin과 Rhaponticin

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A Study on Corrosion Resistance of the Reinforement in Concrete Using Blast-Furnace Slag Powder (고로슬래그미분말을 사용한 콘크리트의 염화물이온에 의한 철근부식 저항성 연구)

  • Kim Eun-Kyun;Kim Jin-Keun;Lee Dong-Hyuk;Kim Young-Ung;Kim Yong-Chul
    • Journal of the Korea Concrete Institute
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    • v.16 no.1 s.79
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    • pp.1-9
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    • 2004
  • This paper represents the permeability of chloride ions and the corrosion performance in the concrete blended with granulate blast furnace slag exposed to chloride environment. An ordinary cement (type I ) and sulfate resisting cement(type V) were used for the experiment. The two cements were combined with $0\%$, $25 \%$, $40\%$, and $55\%$ of the granulated blast furnace slag. The accelerated permeability tests of chloride ions were performed in accordance with ASTM C1202, and the accelerated corrosion tests of steel were carried out by using the method of immersion/drying cycles. After water curing 28 days, 56 days and 91 days, these tests were conducted until 30 cycles. In every cycle, test specimens were wetted in $3\%$ NaCl solution for three days and dried again in $60^{\circ}C$ air for four days. As an experimental results, the diffusion coefficient of chloride ions of the ordinary cement Concrete Combined granulated blast furnace slag was much lower than that of non granulated blast furnace slag concrete. Moreover, the diffusion coefficient of chloride ions of sulfate resisting cement concrete was higher than that of ordinary cement concrete. On the basis of the results of accelerated corrosion tests, corrosion resistance of the concrete mixed with granulated blast furnace slag shows good to corrosion resistance, however, the concrete with sulfate resisting cement shows bad to corrosion resistance.

The Property Evaluation of the Marine Concrete Structure Constructed in the Period of Japanese Occupancy (YoungDo Bridge) (일제시대 건설된 해양 콘크리트구조물의 물성 평가(영도대교))

  • Park, Dong-Cheon;Ahn, Jae-Cheol
    • Journal of Navigation and Port Research
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    • v.37 no.2
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    • pp.165-171
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    • 2013
  • YoungDo bridge is the first suspension bridge in Busan which experienced several times repair and reinforcement after completion in 1934. The bridge is under demolition for extension and restoration work since 2011. The purpose of this research is to establish data base about modern concrete. The mix design of the concrete is like that cement : fine aggregate : coarse aggregate = 1 : 2 : 4 or 1 : 3 : 6 by the parts. The compressive strength is in the ranges from 50 to 55 MPa and the elastic modulus is in the ranges from 25 to 35 GPa. From the fact that the deviation is less than 10 %, considerably high quality control was conducted in those days. The carbonation depth is 5.92 cm at the bridge post and 14.3 cm at the machine room. That is why ocean environment keeps the high humidity. The diffusion coefficient of chloride ion through the pores in concrete is 1.052e-12 $m^2/s$ from the regression analysis using the experiment data. The water cement ration is estimated at approximately 35 % in case if the concrete using ordinary Portland cement.

Comparision of Test Methods for Estimating Chloride Ion Diffusion Coefficient in Concrete (콘크리트중의 염소이온 확산계수 추정 실험법의 비교)

  • 문한영;김홍삼;문재흠;한아름
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.787-790
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    • 1999
  • To estimate durability of reinforced concrete structures located in or nearby seawater, many different kinds of accelerated tests for evaluation of chloride ion permeation in concrete were proposed. At present the only standardized test is the ASTM C 1202(RCP test). This test method is used to estimate the concrete's resistivity of the chloride penetration in concrete by using the total charges passed and sometimes used to calculate the chloride diffusion coefficients. However, this test may lead to an erroneous chloride diffusion coefficient. So this test method was compared with the modified Dhir's test and the traditional concentration diffusion test. Experimental results showed that the diffusion coefficients determined the RCP test and the PD Index gave wrongous values, but the diffusion coefficient acquired by considering a migration term was nearly the same to the CD Test.

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Prediction of the Durability Life for RC Structures through the Analyzing Chloride Diffusion Coefficient of the Establish Data (기존 자료를 통한 염소이온 확산계수 분석 및 철근콘크리트 구조물의 염해 수명예측)

  • Lee, Woo-Jin;Lee, Sung-Bok;Lee, Han-Seung;Ryu, Jae-Jun;Yun, Byung-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.846-849
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    • 2004
  • It is important to decide the precise chloride diffusion coefficient in order to predict the durability plan of concrete structure chloride and prediction of remaining lifetime. However, the inland references are limited to the rapid test in laboratory. The purpose of this study is to examine and analyze the established data, which are restricted by chloride diffusion coefficient, and to examine the prediction of the concrete structure durability by an FEM interpretation and the chloride diffusion coefficient as a variable.

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A Study on the Chloride Ion Diffusion Coefficient of Concrete by Submergence in Salt Water (침적시험에 의한 콘크리트의 염소이온 확산계수 평가)

  • 김동석;양승규;정연식;유재상;이종열;본간건일
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.297-300
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    • 2003
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon. In this study, It is evaluated the diffusion coefficient of chloride ion in non-steady state by Fick's second law. Submergence method in salt water carried out in this experiment. Two types of cement which is different in mineral composition were used. In addition, the effect of mineral admixtures of blast-furnace slag and meta-kaolin was studied. In conclusion, the diffusion coefficient of chloride ion is much affected according to cement type and mineral admixtures, also, it is proved that meta-kaolin as well as blast-furnace slag is effective in preventing penetration of chloride ion.

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Application of Colorimetric Method for Evaluation of Apparent Chloride Diffusion Coefficient of Concrete (콘크리트 중 겉보기 염소이온 확산계수 추정을 위한 비색법의 적용)

  • 문한영;김홍삼;최두선;오세민
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.541-544
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    • 2003
  • Chloride diffusivity is one of the important properties of concrete affecting the durability of a structure. The diffusivity for porous materials is determined conventionally by immersion in a solution. However, this method is complicate and time-consuming, often requiring months or years to obtain results. Thus, the application of colorimetric method to estimate the apparent diffusivity of chloride ion was verified in this study. The result reveals that the apparent diffusivity of chloride ion can be predicted to use colorimetric method. Additionally the colorimetric method is capable to predict the profile of chloride ion.

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Estimation of Probability Valuable for Diffusion Coefficient of Chloride Ion (염소이온 확산계수의 확률변수 평가)

  • Bae Su Ho;Lee Kwang Myong;Kim Jee Sang;Jung Sang Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.515-518
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    • 2005
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures exposed to chloride environments. In particular, the development of new procedures for probability-based durability analysis and design has been proved to be very valuable. To carry out the procedures described above, the statistical properties of design valuables such as diffusion coefficient of chloride ion, surface chloride concentration, and chloride threshold value etc. should be known. For this purpose, this paper presents the statistical properties of the diffusion coefficient of chloride ion such as mean value and standard deviation with water-cement(w/c) ratio and curing conditions, respectively. It was observed from the test that the standard deviation for the diffusion coefficient of chloride ion was found to be small with decrease in the w/c ratio irrespective of curing conditions and that of standard curing was found to be smaller than that of field curing.

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