• Membrane Journal
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• v.34 no.3
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• pp.182-191
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• 2024

This review addresses the pressing need for effective wastewater treatment methodologies by exploring advanced thin-film nanocomposite (TFN) nanofiltration membranes aimed at efficient dye removal from industrial effluents. Utilizing insights from recent research, the review focuses on the fabrication of TFN membranes incorporating innovative materials such as nanocarbons, silica nanospheres, metal-organic frameworks (MOFs), and MoS₂. The primary goals are to enhance dye removal efficiency, improve antifouling properties, and maintain high selectivity for dye/salt separation. By leveraging the distinct advantages of these nanomaterials-including large surface areas, mechanical robustness, and specific pollutant interaction capabilities-this review aims to overcome the limitations of current nanofiltration technologies and provide sustainable solutions for water treatment challenges.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2005.05a
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• pp.219-222
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• 2005

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2135-2139
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• 2000

The coagulation of anionic colloidal particles by the cyanoguanidine(CG)-formaldehyde resin has been reported to be caused by an electrostatic interaction of the diaminomethylene urea (DU) cation with an anionic surface charge of particles. In this research, 100~500 nm sized cationic cyanoguanidine-formaldehyde resin was synthesized to coagulate anionic dye wastewater, and the results showed that the less pH of aqueous cyanoguanidine-formaldehyde resin solution was, the higher Zeta potential of that was. In case of coagulating 0.4 g/L reactive dye by cyanoguanidine-formaldehyde resin at pH 3, 5, 7, 9, and 11, COD removal and the percent decolorization of synthetic dye wastewater at pH 3 are higher than those of other pH conditions. The COD removal and the percent decolorization of synthetic dye wastewater were 74% and 90% at 400 ppm, pH 3.

• Proceedings of the Membrane Society of Korea Conference
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• 1992.10a
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• pp.76-76
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• 1992

본 연구의 목적은 국내 섬유산업에서 문제시되는 염색폐수처리에 막분리공정의 적용가능성과 문제점을 실험실규모와 pilot 규모의 실험을 통하여 규명하는 것이다. 염색폐수는 섬유의 가공공정에 따라 염료, 분산제, 정염제, 반응제 등 다양한 유기물질과 무기염을 함유하며 온도가 10-90$\circ$C로 높은 것이 특징이다. 본 연구에서는 2종류의 Nanofiltration: NF40, XU45; 두종류의 복합막; BW30, SW30HR; 2종류의 Cellulose Acetate 비대칭막의 평막 Sample을 사용하여 합성염색폐수의 배제율과 압력변화에 따른 투과수에 미치는 영향을 조사하였다. 실제 혼합염색폐수의 처리는 2개의 2.5"$\times$ 40" Nanofiltration 모듈을 장착한 Pilot 장치를 염색단지 종합처리장에 설치하여 3개월에 걸쳐 시행하였다. 현재까지 얻어진 실험결과에 의하면 전처리공정의 효율롸를 통해 부유물질에 의한 Fouling을 최소화하고 폐수의 성분분석과 사용된 막의 표면분석을 통한 체계적인 조사가 필요하다. 염색폐수처리에 막분리공정이 기존처리방법과 비교하여 경제성을 가지려면 효율적인 막세척방법을 개발하여 투과율의 감소를 최소화시켜야 한다.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.544-550
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• 2013

This work investigated the environmental application of an underwater dielectric barrier discharge plasma reactor consisting of a porous hydrophobic ceramic tube to the decolorization of an azo dyeing wastewater. The reactive species generated by the plasma are mostly short-lived, which also need to be transferred to the wastewater right after the formation. Moreover, the gas-liquid interfacial area should be as large as possible to increase the decolorization rate. The arrangement of the present wastewater treatment system capable of immediately dispersing the plasmatic gas as tiny bubbles makes it possible to effectively decolorize the dyeing wastewater alongside consuming less amount of electrical energy. The effect of discharge power, gas flow rate, dissolved anion and initial dye concentration on the decolorization was examined with dry air for the creation of plasma and amaranth as an azo dye. At a gas flow rate of $1.5Lmin^{-1}$, the good contact between the plasmatic gas and the wastewater was achieved, resulting in rapid decolorization. For an initial dye concentration of $40.2{\mu}molL^{-1}$ (volume : 0.8 L; discharge power : 3.37 W), it took about 25 min to attain a decolorization efficiency of above 99%. Besides, the decolorization rate increased with decreasing the initial dye concentration or increasing the discharge power. The presence of chlorine anion appeared to slightly enhance the decolorization rate, whereas the effect of dissolved nitrate anion was negligible.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2004.11a
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• pp.214-217
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• 2004

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2004.11a
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• pp.113-115
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• 2004

• Textile Coloration and Finishing
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• v.4 no.2
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• pp.84-88
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• 1992

셀룰로오스 펄프에 폴리비닐알코올의 블랜드, 가교, 및 카복시메칠화한 아니온성 셀룰로오스계 고분자 흡착제에 대한 모델 카치온 염료, C.I. Basic Red 18의 흡착 및 탈색 성능을 수용액계(pH 4.2)에서 검토하였다. 아니온성 셀룰로오스 고분자 흡착제의 카치온 모델 염료의 흡착등온성은 저농도 영역에서 Sigmoidal 형을 나타내었고 Donnan 흡착 모델 기구로 해석하였다. 하전기 도입에 따라 염료의 흡착능은 증가하였으며 이 흡착능력은 Sodium이온의 첨가에 의하여 저하하였다. 또 아니온 셀룰로오스계 흡착제에 의한 모델 염료의 배수 탈색율은 크게 증가하였으며 입상활성탄보다 우수한 탈색능력을 나타내었다.

• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.346-349
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• 1998

1.0 dtex이하의 섬도를 갖는 극세사 섬유는 수분율이 높아 촉감이 부드러우며 드레이프성이 우수하고 실크같은 광택효과를 갖고 있다. 그러나 극세사는 저온에서도 염착이 일어나며 넓은 표면적으로 인하여 염착속도가 빨라 불균염이 일어나기 쉽다. 또한 섬유의 직경이 작아 표면적이 넓기 때문에, 동일한 색상을 얻기 위해서는 다른 섬유로 된 직물에 비해 과량의 염료가 필요하게 되고 이로 인하여 낮은 견뢰도를 나타내며 오염물질이 고농도인 염색폐수를 방출하게 된다.(중략)

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.606-612
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• 2022

The purpose of this study is to convert hydrophobic dyestuff to hydrophilic dyestuff by reacting cationic collector with anionic dyestuff and reaction anionic collector with cationic dyestuff. The removal of colors from aqueous solutions and/or dispersions has been studied by dispersed-air flotation in a batch column. In this studies used generated micro bubble by ceramic gas diffuser having micro pore size for air flotation process. In this study, a ceramic gas diffuser with micro pore size was used to generate micro bubbles for the air flotation process. Two colours were used for the experiments: Basic Yellow 1 (cationic dyestuff) and Direct Orange 10 (anionic dyestuff). All two were effectively removed by flotation within 8 mins. Sodium dodecyl sulfate, sodium oleate (an anionic collector), and amines (a cationic collector) were found to be effective as collectors in the removal of color, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.