• Title/Summary/Keyword: 염결정

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Physical Property and Optimal Operating Condition in the Salting-out Dye Crystallization System (염료·염석결정화계에서 물성과 최적조업조건)

  • Pyun, Yu Ri;Han, Hyun Kak;Jung, Hyong Ki
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.157-162
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    • 2009
  • In this paper, the density, viscosity and solubility are measured to know the physical properties of dye. By changing the concentration of dye solution, the density change of the dye solution was very small and the viscosity of the dye solution was increased. Also, by changing the temperature of dye solution, the density change of the dye solution was increased but the viscosity of the dye solution was decreased. Solubility of dye conducts under the changing the salt and concentration of dye. In 20 wt% of dye and 15 wt% KCl, the amount of dye crystal is maximal. Also, batch salting-out experiments were performed with various conditions to know the optimal operating conditions of dye crystal. Under the various experiments, optimal operating condition was found based on amount of dye; added 15 wt% KCl, $25^{\circ}C$ temperature, 100 RPM, added at once.

이달의 과학자 - 경상대 지질학과 조현구교수

  • Korean Federation of Science and Technology Societies
    • The Science & Technology
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    • v.29 no.8 s.327
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    • pp.80-81
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    • 1996
  • 칼륨, 알루미늄을 함유하는 황산염 광물인 명반석을 가열하고 다시 냉각시킬 때 나타나는 변화를 연구하여 다른 광물질과 달리 가역반응을 일으키는 특성을 규명한 경상대 조현구박사. 경남 통영시가 고향인 조교사는 과학기술정책 결정 때는 많은 사람들의 의견을 수렴할 수 있는 제도적 장치가 마련되어야 한다고 강조한다.

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Influence of radio frequency bias on hydrogenated nanocrystalline silicon thin film (RF 바이어스가 수소화된 나노결정실리콘 박막에 미치는 영향)

  • Kim, In-Gyo;Lee, Hyeong-Cheol;Yeom, Geun-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.98-98
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    • 2009
  • Hydrogenated nano-, microcrystalline silicon 박막(nc-, ${\mu}c-Si:H$)은 박막 트랜지스터 및 실리콘 박막형 태양전지등에 널리 쓰이고 있다. 이러한 결정화 실리콘 박막을 내장형 안테나를 사용하여 고밀도 플라즈마를 발생시킬 수 있는 장치를 통하여 증착 후 열처리 공정이 없는 방법을 사용하여 박막을 제작하였다. 특히, 증착시 기판에 바이어스를 함께 인가하므로 증착된 박막의 결정화에 미치는 영향에 관한 연구를 하였다. 기판에 인가된 바이어스가 60W일 때 가장 높은 결정화율을 보이는 것을 알 수 있었다.

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Effect of the Calcium Ions on Crystal Structures Control of Calcium Carbonate Films with Large Area (대면적 탄산칼슘 막의 결정구조 제어에 미치는 칼슘 이온의 영향)

  • Lee, Seung-Hyo;Kim, Hye-Min;Lee, Seul-Gi;Mun, Gyeong-Man;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.146-147
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    • 2013
  • 본 연구에서는 탄산칼슘을 대면적의 막으로 형성하고, 그 결정구조를 제어하기 위해 제작된 합성용액 중 염(NaCl)의 첨가에 의한 Ca이온의 농도변화가 탄산칼슘 결정구조 변화에 미치는 영향을 알아보고자 하였다. 제작된 탄산칼슘 막은 SEM, EDS 및 XRD를 통해서 분석되었으며, 시간 별 탄산칼슘 막의 제작 및 분석을 통해서 결정구조 변화의 메커니즘을 규명하고자 하였다.

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Performance Evaluation to Develop an Engineering Scale Cathode Processor by Multiphase Numerical Analysis (다상유동 전산모사를 통한 공학 규모의 cathode processor의 성능평가)

  • Yoo, Bung Uk;Park, Sung Bin;Kwon, Sang Woon;Kim, Jeong Guck;Lee, Han Soo;Kim, In Tae;Lee, Jong Hyeon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.1
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    • pp.7-17
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    • 2014
  • Molten salt electrorefining process achieves uranium deposits at cathode using an electrochemical processing of spent nuclear fuel. In order to recover pure uranium from cathode deposit containing about 30wt% salt, the adhered salt should be removed by cathode process (CP). The CP has been regarded as one of the bottle-neck of the pyroprocess as the large amount of uranium is treated in this step and the operation parameters are crucial to determine the final purity of the product. Currently, related research activities are mainly based on experiments consequently it is hard to observe processing variables such as temperature, pressure and salt gas behavior during the operation of the cathode process. Hence, in this study operation procedure of cathode process is numerically described by using appropriate mathematical model. The key parameters of this research are the amount of evaporation at the distillation part, diffusion coefficient of gas phase salt in cathode processor and phase change rate at condensation part. Each of these conditions were composed by Hertz-Langmuir equation, Chapman-Enskog theory, and interphase mass flow application in ANSYS-CFX. And physical properties of salt were taken from the data base in HSC Chemistry. In this study, calculation results on the salt gas behavior and optimal operating condition are discussed. The numerical analysis results could be used to closely understand the physical phenomenon during CP and for further scale up to commercial level.