• Title/Summary/Keyword: 열 수축률

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Evaluation of Physico-mechanical Properties and Durability of Larix kaempferi Wood Heat-treated by Superheated Steam (과열증기 열처리 낙엽송재의 물리·역학적 성능 및 내후성능 평가)

  • Park, Yonggun;Park, Jun-Ho;Yang, Sang-Yun;Chung, Hyunwoo;Kim, Hyunbin;Han, Yeonjung;Chang, Yoon-Seong;Kim, Kyoungjung;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.776-784
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    • 2016
  • In this study, green Larix kaempferi lumber was heat-treated by using superheated steam (SHS) at a pilot scale and then various physico-mechanical properties of the heat-treated wood were evaluated and compared with the properties of conventional hot air (HA) heat-treated wood. Decay resistance of brown rot fungi and compressive strength parallel to the grain of the SHS heat-treated wood without occurrence of drying check from green lumber were increased. On the other hand, density, equilibrium moisture content, shrinkage, and bending strength of the SHS heat-treated wood were lower than those of the conventional HA heat-treated wood. Because heat transfer and thermal hydrolysis of SHS heat treatment was accelerated by a large amount of water, the effect of SHS heat treatment on the physico-mechanical properties was higher than that of HA heat treatment at the similar conditions of temperature and time. From the results of this study, because green lumber can be heat-treated without occurrence of cracks or checks by using SHS and similar heat treatment effect on the physico-mechanical properties of wood can be produced despite a low temperature or short time of heat treatment, it is expected that heat time and energy consumption could be reduced by using SHS.

A Study on Ash Fusibility Temperature of Domestic Thermal Coal Implementing Thermo-Mechanical Analysis (TMA를 이용한 국내 발전용 탄의 용융점 변화에 대한 연구)

  • Lee, Soon-Ho;Lim, Ho;Kim, Sang Do;Jeon, Chung-Hwan
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.233-239
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    • 2014
  • The slagging which generated from ash deposition on furnace wall and tube in boiler reduces the heat transfer efficiency and damages to safety of boiler. The slag flow behavior in boiler is affected by melting temperature which is related to ash compositions. In this study, the behavior of slag is researched by using ash fusibility test, called TMA (Thermo-Mechanical Analysis). The technique measures the percentage shrinkage as the function of temperature, T25%, T50%, T75%, T90%. These temperatures indicate different stages of melting. Then, the effect of ash chemical compositions measured from XRF (X-ray Fluorescence Spectrometer) to ash fusion temperatures is discussed. Among the chemical compositions, refractory and fluxing influence on ash fusibility is described. High levels of refractory component and limited amount of fluxing components ($Fe_2O_3$, $K_2O$, CaO) increase overall melting temperatures. High $SiO_2/Al_2O_3$ ratio decrease high melting temperatures (T75%, T90%). Meanwhile, the presence of reasonable levels of fluxing components reduces overall melting temperature. A presence of fluxing component such as $K_2O$ and CaO is found to decrease the T25% values significantly. From this research, it is possible to make a reasonable explanation and prediction of ash fusion characteristic from analysis of TMA results and ash chemical compositions.

A Study on Characteristics of Polymer Organic Hard Mask Synthesis (고분자 유기하드마스크 합성에 따른 특성에 관한 연구)

  • Woo-Sik Lee
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.16 no.5
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    • pp.217-222
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    • 2023
  • The purpose of this paper was to synthesize a polymer organic hard mask that simplifies the manufacturing process, reduces process time significantly, and thereby lowers manufacturing costs. The results of measuring residual metals through vapor refining showed that 9-Naphthalen-1-ylcarbazole(9-NC) measured 101.75ppb in the 4th zone, 2-Naphthol (2-NA) measured 306.98ppb in the 5th zone, and 9-Fluorenone(9-F) measured between 129.05ppb across the 4th and 5th zones. After passing through a filtration system, the synthesized organic hard mask measured residual metals in the range of 9 to 7ppb. Additionally, the thermal analysis indicated a decrease of 2.78%, a molecular weight of 942, carbon content of 89.74%, and a yield of 72.4%. The etching rate was measured at an average of 18.22Å/s, and the coating thickness deviation was averaged at 1.19. For particle sizes below 0.2㎛ in the organic hard mask, no particles were observed. By varying the coating speed at 1,000, 1,500, and 1,800rpm and measuring the resulting coating thickness, the shrinkage rate ranged from 17.9% to 20.8%. The coating results demonstrated excellent adhesion to SiON, and it was evident that the organic hard mask was uniformly applied.

A Study on the Hydration Characteristics and Fundamental Properties of Ternary Blended Cement Using Ferronickel Slag (페로니켈슬래그 및 고로슬래그 미분말을 결합재로 사용한 삼성분계 시멘트의 수화 특성 및 기초물성에 관한 연구)

  • Cho, Won-Jung;Kim, Han-Sol;Ann, Ki-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.39-48
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    • 2020
  • The present study investigates the chemical reaction and performance of ternary blended binders by mixing ferronickel slag. Cement was replaced using ground granulated blast furnace slag and ferronickel slag, combined up to 50% of the replacement rate. The blended cements were tested by setting times, length change, compressive strength at 1, 3, 7, 28 days. X-ray diffraction and scanning electron microscope were conducted for detecting hydration products while the MIP and microhydation heat were used for examining morphological characteristics. The results showed that by adding ferronickel slag, Pozzolanic reaction occurred, forming a dense pore structure and the effect of reducing hydration heat and dry shrinkage was also found. The compressive strength at 28 days was lower than that of 100% OPC control specimen (OSP0), but ternary blended cements showed no significant difference compared to binary blended (OSP50). If the optimal mix is derived later and used for the purpose, the potential for use as a cement binder is expected.

A Study on Characterization of Polyethylene Separators Irradiated at Various Electron Beam Current Conditions (다양한 전자선 전류 조건에서 조사된 폴리에틸렌 분리막의 특성 연구)

  • Im, Jong-Su;Sohn, Joon-Yong;Shin, Jun-Hwa;Lim, Youn-Mook;Choi, Jae-Hak;Kim, Jeong-Soo;Nho, Young-Chang
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.74-78
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    • 2010
  • In this paper, crosslinked polyethylene (PE) separators for lithium secondary batteries were prepared by an electron beam irradiation under various beam currents and dose rates. The crosslinking degree increased up to maximum 71% with an increasing absorption dose and with a decreasing beam current. The PE separators irradiated at lower beam currents showed better thermal shrinkage (51%) and mechanical properties than the original PE separator and PE separators irradiated at higher beam current. The ionic conductivity ($1.01{\times}10^{-3}\;S/cm$) and electrolyte uptake (275%) of the crosslinked PE separators were comparable to the original PE separator.

A Study on the Improvement of the Thermal Stability of a Commercial Polyethylene Separator for Lithium Secondary Battery by an Electron Beam Irradiation (전자선 조사에 의한 리튬 이차전지용 상용 폴리에틸렌 분리막의 내열성 향상에 관한 연구)

  • Sohn, Joon-Yong;Lim, Jong-Soo;Gwon, Sung-Jin;Shin, Jun-Hwa;Choi, Jae-Hak;Nho, Young-Chang
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.598-602
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    • 2008
  • In this study we prepared crosslinked separators with the improved thermal stability by irradiating a commercial polyethylene (PE) separator for lithium secondary battery with an electron beam, and the thermal and mechanical properties of the prepared separators were evaluated as a function of the absorption dose. The thermal shrinkage of electron beam irradiated separator was decreased with increasing absorption dose. As a result of the shutdown behavior using an AC impedance, it was observed that the irradiated separator had the better shutdown function than the unirradiated separator. The modulus of the irradiated separator was enhanced as the absorption dose was increased, while the tensile strength and the break elongation of the irradiated separator were decreased.

Strength Properties of Cement Mortar with Slurry-Typed Cellulous Fiber (슬러리형 셀룰로오즈 파이버를 혼입한 시멘트 모르타르의 강도 특성)

  • Ryu, Hwa-Sung;Shin, Sang-Heon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.210-215
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    • 2019
  • Concrete members with wide surface area are vulnerable to cracking due to material behavior such as hydration heat and drying shrinkage. Recently many researches have been performed on improvement of strength and cracking resistance through fiber reinforcement, which are mainly focused on enhancement of tensile strength against cracking due to material behavior. In this paper, CFs(Cellulous Fibers) are manufactured for slurry type, and the engineering properties in cement mortar incorporated with CFs are evaluated for flow-ability, compressive, and flexural strength. Through SEM analysis, a pull-off characteristics of CF in matrix are analyzed. With CF addition of $0.5kg/m^3{\sim}1.0kg/m^3$, flexural strength is much improved and enough toughness of pull-off is also observed unlike plastic fiber containing smooth surface.

THE EFFECTS OF DRYING AGENTS AND BONDING AGENTS ON THE SHEAR BOND STRENGTH OF SEALANTS TO ENAMEL (치면건조제와 접착제의 사용에 따른 치면열구전색재의 전단결합강도에 관한 연구)

  • Lim, Hyun-Hwa;Jang, Ki-Taek;Kim, Chong-Chul;Hahn, Se-Hyun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.30 no.2
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    • pp.196-203
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    • 2003
  • The application of sealants is a highly technique-sensitive procedure, requiring an extremely dry field prior to placement. Moisture contamination of the etched enamel surface before sealant placement is cited as the main reason for sealant failure. The purpose of this study was to evaluate the effects of different methods of sealant application on the shear bond strength of sealants to enamel. In groups 1, 2, 3, 4 Teethmate(unfilled sealant) was used, while Ultraseal XTplus(filled sealant) was used in groups 5, 6, 7, 8. Groups 1 and 5(control) were acid etched for 15 seconds using 35% phosphoric acid, washed and then dried. In groups 2, 6 drying agents were applied, and in groups 3, 7 bonding agents were applied and light cured. In groups 4 and 8 both drying agent and bonding agent were applied. Then sealant was cured to the specimen using molds 3mm in diameter and 2mm in height. Thermocycling was performed and shear bond strength was finally measured. The following results were obtained : 1. Groups using filled sealant(groups 5, 6, 7, 8) showed higher shear bond strengths compared to groups using unfilled sealant(groups 1, 2, 3, 4). 2. Among groups using unfilled sealant(groups 1, 2, 3, 4), groups 2, 3, 4 showed significantly higher shear bond strength compared to group 1(p<0.05). There were no significant differences among groups 2, 3 and 4. 3. There were no significant differences(p>0.05) among groups using filled sealant(groups 5, 6, 7, 8). 4. When modes of fracture were examined, cohesive failure was observed in groups 2, 3 and 4.

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Evaluation on Strain Properties of 60 MPa Class High Strength Concrete according to the Coarse Aggregate Type and Elevated Temperature Condition (60MPa급 고강도 콘크리트의 굵은골재 종류와 고온상태에 따른 변형특성 평가)

  • Yoon, Min-Ho;Choe, Gyeong-Cheol;Lee, Tae-Gyu;Kim, Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.26 no.3
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    • pp.247-254
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    • 2014
  • Strain properties of concrete member which acts as an important factor in the stability of the concrete structure in the event of fire, significantly affected the characteristics of the coarse aggregate, which accounts for most of the volume. For this reason, there are many studies on concrete using artificial lightweight aggregate which has smaller thermal expansion deformation than granite coarse aggregate. But the research is mostly limited on concrete using clay-based lightweight aggregate. Therefore, in this study, the high temperature compressive strength and elastic modulus, thermal strain and total strain, high temperature creep strain of concrete was evaluated. As a result, remaining rate of high-temperature strength of concrete using lightweight aggregate is higher than concrete with general aggregate and it is determined to be advantageous in terms of structural safety and ensuring high-temperature strength from the result of the total strain by loading and strain of thermal expansion. In addition, in the case of high-temperature creep, concrete shrinkage is increased by rising loading and temperature regardless of the type of aggregate, and concrete using lightweight aggregate shows bigger shrinkage than concrete with a granite-based aggregate. From this result, it is determined to require additional consideration on a high temperature creep strain in case of maintaining high temperature like as duration of a fire although concrete using light weight aggregate is an advantage in reducing the thermal expansion strain of the fire.

Recovery Trajectory in Tachycardia Induced Heart Failure Model (빈맥을 이용한 심부전 모델에서 회복궤도)

  • 오중환;박승일;원준호;김은기;이종국
    • Journal of Chest Surgery
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    • v.32 no.5
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    • pp.422-427
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    • 1999
  • Background: Tachycardia induced heart failure model would be the model of choice for the dilated cardiomyopathy. This more closely resembles the clinical syndrome and does not require major surgical trauma, myocardial ischemia and pharmacological or toxic depression of cardiac function. When heart failure is progressive, application of new surgical procedures to the faling heart is highly risky. It has been shown that recovery trajectory from heart failure is a new method in decreasing animal mortality. The purpose is to establish the control datas for recovery trajectory in the canine heart failure model. Material and Method: 21 mongrel dogs were studied at 4 stages(baseline, at the heart failure, 4 and 8 weeks after recovery). Heart failure was induced during 4 weeks of continuous rapid pacing using a pacemaker. Eight weeks of trajectory of recovery period was allowed. Indices of left ventricular function and dimension were measured every 2 weeks and the hemodynamics were measured by use of Swan-Ganz catheterization and thermodilution method every 4 weeks. Values were expressed as mean${\pm}$standard deviation. Result: 4(20%) dogs died due to heart failure. Left ventricular end-diastolic volume at the 4 stages were 40.8${\pm}$7.4, 82.1${\pm}$21.1, 59.9${\pm}$7.7 and 46.5${\pm}$6.5ml. Left ventricular end-systolic volume showed the same trend. Ejection fractions were 50.6${\pm}$4.1, 17.5${\pm}$5.8, 36.3${\pm}$7.3, and 41.5${\pm}$2.4%. Blood pressure and heart rate showed no significant changes. Pressures of central vein, right ventricle, pulmonary artery, and pulmonary capillary wedge showed significant increase during the heart failure period, normalizing at the end of recovery period. Stroke volumes were 21.5${\pm}$8.2, 12.3${\pm}$3.5, 17.9${\pm}$4.6, and 15.5${\pm}$3.4ml. Blood norepinephrine level was 133.3${\pm}$60.0pg/dL at the baseline and 479.4${\pm}$327.3pg/dL at the heart failure stage(p=0.008). Conclusion: Development of tachycardia induced heart failure model is of high priority due to ready availability and reasonable amenability to measurements. Recovery trajectory after cessation of tachycardia showed reduction of cardiac dilatation and heart function. Application of new surgical procedures during the recovery period could decrease animal mortality.

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