• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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• pp.401-403
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• 1995

The degradation phenomena according to electrical stress in epoxy composites were studied. The formation of electrets were observed by appling high voltages, 22.9[kW/cm], during 5[hr] to five kinds of specimens for a given mixing rate, and then TSC(thermally stimulated current) values were measured at the temperature range of $-160\sim200[^{\circ}C]$.

• E2M - 전기 전자와 첨단 소재
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• 제1권3호
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• pp.261-268
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• 1988

본 논문에서는 두께 50[.mu.m]의 미연신 .alpha.형 폴리비닐덴 후로라이드 필름을 시료로 선정, .+-.4~.+-.6[kV]사이의 코로나대전 전압을 인가하여 얻은 코로나 일렉트렛트로 부터 온도 범위 -100[.deg.C]-100[.deg.C] 사이에서 열자격전류를 측정한 결과, 저온으로 부터 .delta., ..gamma., .betha. 및 .alpha.인 4개의 TSC 피크를 얻었다. 이들 피크의 기원을 정성적으로 고찰한 결과, .delta., .gamma.피크는 비정질 영역에서 카보닐기, 주쇄 및 극성기들에 의한 쌍극자의 탈분극으로 또 70[.deg.C]부근에서 관측된 .betha.피크는 비정질 영역 또는 비정질과 결정질의 경계면에서 전극으로 부터 공간전하의 탈트랩으로 그리고 180[.deg.C]근방에서 관측된 .alpha.피크는 결정영역에 깊이 트랩된 캐이어들의 탈트랩으로 각각 피크가 나타나는 것으로 사료된다. .delta., .gamma., .betha.및 .alpha.인 4개의 TSC 피크에 대하여 초기 상승법으로 얻은 활성화 에너지는 각각 0.54[eV], 0.24[eV], 0.99[eV] 및 1.26[eV]를 얻었다.

• 한국진공학회지
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• 제8권3A호
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• pp.187-193
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• 1999

In this study, PVDF thin films which show the excellent piezoelectricity and pyroelectricity, are prepared by PVD (physical vapor deposition) method, and thir electrical conduction phenomena for analyses of the electrical conduction mechanism and TSC (Thermally Stimulated Current) for identification of the behavior of conductive carriers are investigated. As a result of FT-IR(Fourier Transform Infrared Spectroscopy) spectra, the crystalline phase transforms $\alpha$ type into $\beta$ type with increasing electric field. From XRD (X-Ray diffraction) analyses patterns, the degree of crystallinity increases from 49.8% to 67%, as the substrate temperature increases from $30^{\circ}C$ to $80^{\circ}C$. As a result of electrical conduction phenomena, the electrical conduction mechanism of PVDF thin films is identified as ionic conduction mechanism. From TSC analyses, there are three peaks as P1, P2, P3 with increasing temperature, and with increasing substrate temperature, the peak temperature of TSC increases and the peak intensity of TSC decreases.

• E2M - 전기 전자와 첨단 소재
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• 제4권4호
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• pp.322-329
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• 1991

폴리테트라후로루에틸렌의 유전특성을 규명하기 위해 두께 100[.mu.m]를 시료로 선택하여 온도범위 30-150[.deg.C], 주파수범위 30~3*$10^{5}$[Hz]에서 유전특성과 열자격 전류를 측정하였다. 유전정접은 유리전이온도 부근에서 긴 체인의 마이크로 브라운 운동에 의한 손실로 이때 활성화 에너지는 15.18[kcal/mole]를 얻었으며 열자격전류방법에서 얻은 .betha. 피크의 활성화에너지와 거의 일치함을 확인하였다. 또한 열자격전류방법으로 게산된 유전정접의 크기도 유전특성의 초저주파에서 나타나는 값과 잘 일치됨을 확인하였다.다.

• E2M - 전기 전자와 첨단 소재
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• 제3권2호
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• pp.99-104
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• 1990

두께 30[.mu.m]의 코로나 대전된 포리비닐후로라이드 박막에 전압 -3~-6[kV]를 인가한 후, 온도범위 -100~200[.deg.C]에서 열자격 전류를 측정하였다. 결과로 .betha., .alpha. 그리고 .delta. 피크가 온도 -40, 40 그리고 90[.deg.C] 부근에서 각각 나타났다. 이들 피크의 기원으로 첫째 .betha. 피크는 카보닐기의 기여로 둘째로 .alpha. 피크는 주쇄와 비정질 영역의 측쇄에 트랩된 캐리어의 탈트랩의 기여로 나타났고 끝으로 .delta. 피크는 비정질 영역 또는 비정질과 결정질 영역 사이의 경계에 트랩된 캐리어의 탈트랩에 기여로 사료된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 제2회 학술대회 논문집 일렉트렛트 및 응용기술전문연구회
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• pp.50-55
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• 2000

In this paper, Thermally Stimulated Current(TSC) spectrum has been measured in oriented polypropylene of thickness of $40{\mu}m$ which was irradiated by Ultraviolet Ray. As a result of the investigation, four peaks have been observed-two peaks ($A_1$, $A_2$) were appeared in low temperature region($-20{\sim}20^{\circ}C$) and other two peaks ($B_1$, $B_2$) in high temperature region($80{\sim}120^{\circ}C$). Among four peaks $A_1$ and $A_2$ have bee observed in detail. These peaks are shown to be created due to the polarization of diploes from the experimental results which were measured as a function forming voltage, forming time, collecting voltage and heating rate. As the increase of irradiated-time by Ultraviolet ray, the number of dipoles was increased.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1993년도 하계학술대회 논문집 B
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• pp.1162-1164
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• 1993

The Thermally Stimulated Current(TSC) spectroscopy has been applied to study the influence of the structual cahange and interface on the electrical properties of epoxy composites. Three DGEBA-MeTHPA matrix model samples mixed different ratios and silica($SiO_2$) filled sample and silaln treating-filled sample has been studied. Above room temperature, the relaxation mode $\alpha$ peak associated with Tg has been located at $110^{\circ}C$. Below glass transition temperature(Tg), three relaxation modes are observed in all samples: a $\beta$ mode situated at $10^{\circ}C$, a $\gamma$ mode located at $-40^{\circ}C$ and a $\delta$ mode appeared in $-120^{\circ}C$. The analysis of its fine structure indicates that constitution of elementary processes is characterized by the activation energy and relaxation time. Also the dielectric relaxation properties have been investigated to compare the the change of the molecular structure and motion to the relaxation properties and conduction mechanism in TSC spectra.

• E2M - 전기 전자와 첨단 소재
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• 제10권2호
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• pp.97-104
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• 1997

In this paper, in order to investigate the behavior of charged particles on (Sr.Ca)TiO$_{3}$ ceramics with paraelectric properties, the characteristics of electrical conduction and thermally stimulated current was measured respectively. As a result, the conduction mechanism is divided into three regions having different mechanism as the current increased. The region I below 200[V/Cm] shows the ohmic conduction. The region B between 200[V/cm] and 2000[V/cm] can be explained by the Poole-Frenkel emission theory, and the region III above 2000[V/cm] is dominated by the tunneling effect. The three peaks of TSC were obtained at the temperature of -20[.deg. C], 20[.deg. C] and 80[.deg. C], respectively. The origins of these peaks are that the .alpha. peak observed at -20[.deg. C] looks like to be ascribed to the ionization excitation from donor level in the grain, and the .alpha.' peak observed at 20 [.deg. C] appears to show up by hopping conduction of the trapped carrier of border between the oxidation layer and the grain, and the .betha. peak observed at 80[.deg. C] seems to be resulted from hopping conduction of existing carrier in the trap site of the border between the oxidation and second phase.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 제2회 학술대회 논문집 일렉트렛트 및 응용기술전문연구회
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• pp.11-14
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• 2000

This paper describes a thennally stimulated displacement current(TSDC) of polyamic acid alkylamine salts(PAAS) Langmuir-Blodgett(LB) films, which is a precursor of polyimide(PI). The TSDC measurements of PAAS LB film were performed from room temperature to about $250^{\circ}C$ and the temperature was increased at a rate of $0.2^{\circ}C/s$. This show that this is TSDC peaks at about $70^{\circ}C$ in the arachidic acid LB films, and at about $70^{\circ}C$ and $160^{\circ}C$ in the PAAS LB films. Results of this measurements indicate that one small peak at $70^{\circ}C$ is resulted from a softening of the alkyl group and the large peak at $160^{\circ}C$ is possibly due to dipole moment of C-O group in the PAAS molecule. We have calculated the vertical component of dipole moment of the P AAS LB film out of the TSDC curves. It shows that the dipole moment of PAAS LB film is about -40mD at $70^{\circ}C$ and about 200mD at $160^{\circ}C$ in the first measurement of TSDC. In the second measurement of TSDC of PAAS LB film after cooling down to room temperature, the TSDC peaks are almost disappeared.

• 한국전기전자재료학회논문지
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• 제11권8호
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• pp.581-586
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• 1998

This paper describes athermally stimulated displacement current (TSDC) of arachidic acid(AA) and polyamic acid alkylamine salts(PAAS) Langmuir-Blodgett(LB) films, which is a precursor of polyimide(PI). The TSDC measurements of AA LB film were performed from temperature to about 11$0^{\circ}C$ at a rate of 0.2$^{\circ}C$/ｓ inside a vacuum chamber for a reference. And the TSDC measurements PAAS LB film were performed from room temperature to about 25$0^{\circ}C$ and temperature was increased at the same rate as that of AA LB film. They show that there are TSDC peaks at about 7$0^{\circ}C$ in the arachidic acid LB films, and at about 7$0^{\circ}C$ and 16$0^{\circ}C$ in the PAAs LB films. Results of these measurements indicate the one small peak at 7$0^{\circ}C$ is resulted from a softening of the alkyl group and the large peak at 16$0^{\circ}C$ is possibly due to dipole of C-O group in the PASS molecule. We have calculated the vertical component of the AA and PAAs L film out of the TSDC curves. It shows that the dipole moment of the AA LB film is about 70-mD at 7$0^{\circ}C$. And the dipole moment of PAAS LB film is about 040mD at 7$0^{\circ}C$ and about 200mD at 16$0^{\circ}C$ in the first measurement of TSDC. In the second measurement of TSDC of PASS LB film after cooling down to room temperature, the TSDC peaks are almost disappeared.