• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2001.11a
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• pp.67-72
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• 2001

오랜 동안의 경험으로부터 조건설정이 표준화되어 있는 석유화학공업과는 달리 정밀화학공업에 있어서는 대상이 되는 공정의 반응조건 등을 제조자 스스로 결정해야 하는 경우가 많다. 또한, 취급하는 화학물질의 열분해 또는 반응위험성에 대한 위험성평가는 물론 물질안전자료(MSDS)도 확보되지 않은 상태에서 취급되는 경우가 많아 폭발ㆍ화재로 인한 중대재해의 잠재적 위험성이 매우 높은 상태이다.(중략)

• Journal of Korean Society of Environmental Engineers
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• v.27 no.2
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• pp.130-137
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• 2005

This research programme include investigation of the adsorption behavior of heavy metals and VOCs by Pyrolysis char for using landfill cover material. The volatile potions in the sludge gasified during the pyrolysis period and gave birth to porosity throughout the matrix. The result of the ad/desorption experiment of nitrogen to find out the formation of some pore by the gasification of the volatile matter, we can certify that the pyrolysis char($14.56\;m^2/g$) has increased twice more than the organic wasted sludge($6.68\;m^2/g$) in specific surface area. The pyrolysis char has the adsorption characteristic of medium type of Type II and V in BDDT classification, and showed a little micro pore. In the adsorption experiment of ethylbenzene and toluene, as a result of applying the Freundlich adsorption isotherms, the pyrolysis char was higher in the adsorptivity of ethylbenzene and toluene than the granite and the organic wasted sludge. The results of the heavy metal adsorption test for the char indicated that it had some ability of adsorption. It is suggest that pyrolysis char has some advantages for utilizing as landfill covers because the pyrolysis char can adsorb/absorb hazardous substances from the landfill sites and inhibit the ground water and soil contamination.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.223-228
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• 2012

The low-temperature pyrolysis of ABS, polyethylene (PE) and an ABS-polyethylene (ABS-PE) mixture was conducted in a batch reactor at $450^{\circ}C$. The conversion and the product yield were measured as a function of the reaction time with a variation of the mixture composition. The oil products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of the Ministry of Knowledge Economy. The pyrolysis conversion increases with an increase in the content of PE. The yield of the pyrolytic products was ranked as heavy oil>gas>gasoline>gas oil>kerosene as the content of PE in the mixture increases.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.112.2-112.2
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• 2011

미곡종합처리장에서 발생되는 농업부산물인 왕겨는 대부분 퇴비의 재료로 활용되고 있으며, 수익성이 없는 것으로 알려져 있다. 근래에 화석자원의 고갈이 진행되면서, 왕겨, 볏짚을 포함한 농업부산물은 화석연료와 달리 재생이 가능하고 지속 가능한 자원으로 각광을 받고 있다. 바이오매스를 이용하는 신재생에너지 기술로는 생물학적, 열화학적, 물리적 변환 기술 등이 있다. 그중 열화학적 변환 기술은 반응시간이 짧고, 단위부피당 처리량이 높으며 공정상의 폐기물이 적은 장점을 지니고 있어 왕겨의 에너지 활용에 효율적인 기술로 알려져 있다. 왕겨의 열분해 가스화는 CO, $H_2$, $CO_2$, 및 $CH_4$ 가스가 주성분인 합성가스로 전환되는 것을 말하며, 생산된 합성가스는 가스엔진의 발전 연료로 사용될 수 있다. 본 연구에서는 농업부산물인 왕겨를 이용한 열분해 가스화기에서 발생된 합성가스를 정제한 후, 20kW급 가스엔진을 적용하여 합성가스 에너지 활용특성에 관하여 고찰하였다. 그 결과 왕겨의 열분해/가스화반응에 의해 발생된 합성가스를 가스엔진으로 안정적으로 공급하였으며,16kw의 전력이 생산되는 것으로 나타났다.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.478-482
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• 2016

In this study, a bubbling fluidized bed pyrolyzer (0.076 m I.D. and 0.8 m high) was employed to investigate the fast pyrolysis characteristics of larch sawdust which is abundant in Korea. The effects of operation conditions, such as bed temperature ($350-550^{\circ}C$), fluidization velocity ratio ($U_o/U_{mf} $: 2.0-6.0) and feeding rate (2.2-7.0 g/min) on product yields and their chemical components were studied. The number of chemical compounds in the bio-oil decreased with the increasing bed temperature because of secondary pyrolysis. The effects of the Uo/Umf ratio and feeding rate on bio-oil compositions were relatively lower than those of the bed temperature.

• Proceedings of the KAIS Fall Conference
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• 2007.11a
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• pp.344-346
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• 2007

본 논문은 유동층반응기에서 메탄의 열분해에 의한 수소 생산과 탄소 생성에 대한 연구를 수행하였다. 환경에 대한 영향을 최소화한 상태에서 메탄의 전환반응을 메탄 분해촉매활성에 영향을 미치는 인자에 대하여 연구하였다. 측정된 압력요동특성치의 해석을 통하여 유동층 열분해촉매의 유동화현상을 측정하였으며, 유동화특성에 따른 메탄열분해능을 측정하였다. 메탄의 분해는 생성되는 수소를 이용하였다. 유동층의 이동성, $U-U_{mf}$, 마모, 비산유출 유동화가스의 효율밀도에 따른 영향을 연구하였다.

• Journal of agriculture & life science
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• v.52 no.6
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• pp.73-79
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• 2018

In this study, a torrefaction unit with a capacity of 50 kg/hr was developed and experimented to produce of solid fuel by reuse of the food and agricultural wastes. Dried food wastes and agricultural wastes were used for the experiments and the heated-air torrefaction characteristics were investigated by the raw materials, torrefaction air temperature, and torrefaction time. For the dried agricultural wastes, measured torrefaction capacity and lower heating values were 55.35 kg/hr and 3,333 kcal/kg, respectively. As the lower heating values of the treated samples were greater, by around 7.8%, than those of the non-treated samples, torrefaction process was a very effective method to increase the heating value of the agricultural waste. In case of the dried food waste, torrefaction capacity and lower heating value was measured 88.27 kg/hr and 4,016 kcal/kg, respectively. As the lower heating value of treated ones showed around 9.0% higher than that of non treated ones, torrefaction process is very effective method to increase the heating value of the agricultural waste also. It will be assumed that the heating value shows more higher as increase the air temperature and decrease the moisture content of torrified matter.

• Proceedings of the KAIS Fall Conference
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• 2009.12a
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• pp.663-666
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• 2009

본 논문에서는 폭발법에 의해 합성된 나노다이아몬드의 열분해 및 연소특성에 대해 조사하였다. 나노 다이아몬드의 열분해 및 연소는 열중량 분석장치를 이용하여 측정하였으며, 소성된 나노다이아몬드의 표면 및 결합구조는 XRD, FT-IR, SEM-EDAX를 이용하여 측정하였다. 열분해 조건에서 나노다이아몬드는 $105{\sim}210^{\circ}C$와 $400^{\circ}C$ 부근에서 2중 피크가 나타난다. 또한 연소분위기하에서는 $420^{\circ}C$와 $490^{\circ}C$에서 2중 피크가 나타난다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.2
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• pp.487-492
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• 2008

In this paper, Thermocatalytic decomposition of methane in a fluidized bed reactor (FBR) was studied. The technical approach is based on a single-step decomposition of methane over carbon catalyst in air/water vapor free environment. The factors affecting methane decompostion catalyst activity in methane decomposition reactions were examined. The fluidization phenomena in a gas-fluidized bed of catalyst was determined by the analysis of pressure fluctuation properties, and the results were confirmed with characteristics of methane decomposition. The effect of parameters on the H2 yield was examined for methane decompostion. The decompstion rate was affected by the fluidization quality such as mobility, U-Umf, carbon attrition, elutriation and effectiveness density of fluidization gas.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.1955-1968
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• 2000

Thermal gravimetric change characteristics and gas phase product - CO, NO, $NO_2$, VOCs - generated in the process of pyrolysis and oxidation. were investigated with variation of process parameters including furnace reactor temperature both in pyrolytic and oxidative conditions. For the thermal gravimetric change characteristics. paper and wood were mainly decomposed at lower temperatures and they had similar thermal gravimetric change trend due to their similar compositions; plastics were mainly decomposed at higher temperatures; in the case of textile. natural compounds were decomposed at lower temperatures and synthetic compounds at relatively higher temperatures; food was decomposed in the wide range of temperatures possibly due to their different kinds of components. For the analysis results of gas phase product. the concentrations of NO, $NO_2$ were detected at higher level at the oxidative conditions than at the pyrolytic conditions except that of CO, which is due to complete combustion with sufficient oxygen at the oxidative condition; food gave off CO, NO, $NO_2$ more than the other wastes. VOCs were emitted more at the pyrolytic conditions than at the oxidative conditions.